• Journal of Soil and Groundwater Environment
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• v.21 no.6
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• pp.46-55
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• 2016

This experimental study was aimed to estimate interfacial tension of brine-$CO_2$ by using a pendant bubble method and image analysis. Measurements were performed for wide ranges of temperatures, pressures, and salinities covering reservoir conditions in Pohang basin, a possible candidate for $CO_2$ storage operation in Korea. The profiles of $CO_2$ bubbles in brine obtained from image analysis with the densities of brine and $CO_2$ from previous studies were applied to Laplace-Young equation for calculating interfacial twnsion in brine-$CO_2$ system. The experimental results reveals that the interfacial tension is significantly affected by reservoir conditions such as pressure, temperature and water salinity. For conditions of constant temperature and water salinity, the interfacial tension decreases as pressure increases for low pressures (P < $P_c$), and approaches to a constant value for high pressures. For conditions of constant pressure and water salinity, the interfacial tension increases as temperature increases for T < $T_c$, with an asymptotic trend towards a constant value for high temperatures. For conditions of constant pressure and temperature, the interfacial tension increases with increasing water salinity. The trends in changes of interfacial tension can be explained by the effects of the reservoir conditions on the density difference of brine and $CO_2$, and the solubility of $CO_2$ in brine. The information on interfacial tensions obtained from this research can be applied in predicting the migration and distribution of injecting and residual fluids in brine-$CO_2$-rock systems in deep geological environments during geological $CO_2$ sequestrations.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.38 no.8
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• pp.831-836
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• 2014

In this study, high temperature integrity evaluation on a pressure vessel of the expansion tank operating at elevated temperature of $510^{\circ}C$ in the sodium test facility of the SEFLA(Sodium Thermal-hydraulic Experiment Loop for Finned-tube Sodium-to-Air heat exchanger) to be constructed at KAERI has been performed. Evaluations of creep-fatigue damage based on a full 3D finite element analyses were conducted for the expansion tank according to the recent elevated temperature design codes of ASME Section III Subsection NH and French RCC-MRx. It was shown that the expansion tank maintains its integrity under the intended creep-fatigue loads. Quantitative code comparisons were conducted for the pressure vessel of austenitic stainless steel 316L.

• Journal of ILASS-Korea
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• v.24 no.4
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• pp.157-162
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• 2019

This numerical study was analyzed to predict the flammability limits of biodiesel and diesel fuels in the high temperature and pressure conditions. To achieve this, the biodiesel fuel was simulated with the chemical species of n-heptane (n-C₇H₁₆), methyl decanoate (C₁₁H₂₂O₂), and methyl-9-decenoate (C₁₁H₂₀O₂), and the diesel fuel was substituted the chemical species of n-heptane. The closed 0-D homogeneous reactor model which was employed the 1100 K of ambient temperature and 35 atm of ambient pressure was used for the simulation of constant volume combustion, and the equivalence ratio was changed from 0.3 to 2.5 conditions. In addition, a comparative analysis study was conducted with the results of HCCI engine simulation and flammability limits according to the changes of equivalence ratio. The results of combustion temperature, pressure, and ignition delay were increased when the equivalence ratio elevated from 0.3 to 1.3 conditions because the increase in fuel oxidation rate affects the chemical reaction of the overall combustion process. Furthermore, the CO and NO_X production under the rich combustion conditions are considered to have a trade off relationship since the OH radicals and O₂ chemical species are greatly affected the CO and NO_X production and oxidation processes.

• Bulletin of the Korean Chemical Society
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• v.31 no.11
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• pp.3252-3258
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• 2010

In this study, the effects of the various parameters of spinning and drawing processes on the properties of polyester full drawn yarn (FDY) prepared by steam processing during high-speed spinning were investigated using several techniques. The wet shrinkage ratio of the FDY was able to be manipulated by controlling the temperature and draw ratio. The FDY made using the steam high speed spinning technique exhibited identical properties (such as tenacity, elongation, and wet shrinkage ratio) to that of regular FDY, made using the spin-draw process. FDY prepared using the steam process during high-speed spinning showed excellent dyeability. The dye pick-up of the polyester yarn spun at high-speed spinning was found to be improved when dyed under an atmospheric pressure of $100^{\circ}C$. This result was the same as regular FDY dyed under a high pressure of $130^{\circ}C$.

• Transactions of the Korean Society of Pressure Vessels and Piping
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• v.7 no.3
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• pp.1-7
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• 2011

The analysis shows that the vibration is one of the main reasons of turbine failure. Especially, the problems caused by vibration occur right after retrofit of the turbine-generator and restarting the turbine. Through the case study of high vibration caused by after the turbine trip and restart, turbine vibration was identified to be influenced by startup condition. Turbine startup at high casing temperature right after unscheduled turbine trip cause radial expansion in rotor by contraction in axial direction, while casing continues to contract by steam flowing into casing. Consequently, gap between rotor and casing decrease until to metal contact to cause high vibration. Through the case study of high vibration of turbine-generator system after generator retrofit, it was identified that generator replacement could cause high vibration in turbine-generator system if the influence of generator replacement on entire system was not considered properly. To prevent startup delay caused by high vibration, it is important to keep the gaps at the design standard and start the turbine after thermal equilibrium.

• Proceedings of the Korean Vacuum Society Conference
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• 2010.02a
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• pp.213-213
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• 2010

Magnetic random access memory (MRAM), based on magnetic tunnel junction (MTJ) and CMOS, is one of the best semiconductor memories because it can provide nonvolatility, fast access time, unlimited read/write endurance, low operating voltage and high storage density. For the realization of high density MRAM, the etching of MTJ stack with good properties is one of a key process. Recently, there has been great interest in the MTJ stack using MgO as barrier layer for its huge room temperature MR ratio. The use of MgO barrier layer will undoubtedly accelerate the development of MTJ stack for MRAM. In this study, high-density plasma reactive ion etching of MgO films was investigated in an inductively coupled plasma of $Cl_2$/Ar gas mixes. The etch rate, etch selectivity and etch profile of this magnetic film were examined on vary gas concentration. As the $Cl_2$ gas concentration increased, the etch rate of MgO monotonously decreased and etch slop was slanted. The effective of etch parameters including coil rf power, dc-bais voltage, and gas pressure on the etch profile of MgO thin film was explored, At high coil rf power, high dc-bais voltage, low gas pressure, the etching of MgO displayed better etch profiles. Finally, the clean and vertical etch sidewall of MgO films was achieved using $Cl_2$/Ar plasma at the optimized etch conditions.

• Transactions of the Korean Society of Pressure Vessels and Piping
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• v.7 no.2
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• pp.34-41
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• 2011

Wrought nickel-base superalloys are being considered as the structural materials in very-high temperature gas-cooled reactors. To understand the effects of impurities, especially oxygen, in helium coolant on the mechanical properties of Alloy 617, creep tests were performed in high temperature flowing He environments with varying $O_2$ contents at 800, 900, and $1000^{\circ}C$. Also, creep life in static He was measured to simulate the pseudo-inert environment. Creep life was the longest in static He, while the shortest in flowing helium. In static He, impurities like $O_2$ and moisture were quickly consumed by oxidation in the early stage of creep test, which prevented further oxidation during creep test. Without oxidation, microstructural change detrimental to creep such as decarburization and internal oxidation were prevented, which resulted in longer creep life. On the other hand, in flowing He environment, surface oxides were not stable enough to act as diffusion barriers for oxidation. Therefore, extensive decarburization and internal oxidation under tensile load contributed to premature failure resulting in short creep life. Limited test in flowing He+200ppm $O_2$ resulted in even shorter creep life. The oxidation samples showed extensive spallation which resulted in severe decarburization and internal oxidation in those environments. Further test and analysis are underway to clarify the relationship between oxidation and creep resistance.

• Korean Journal of Metals and Materials
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• v.48 no.2
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• pp.122-132
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• 2010

Higher strength and fracture toughness of reactor pressure vessel steels can be obtained by changing the material specification from that of Mn-Mo-Ni low alloy steel (SA508 Gr.3) to Ni-Mo-Cr low alloy steel (SA508 Gr.4N). However, the operation temperature of the reactor pressure vessel is more than $300^{\circ}C$ and the reactor operates for over 40 years. Therefore, we need to have phase stability in the high temperature range in order to apply the SA508 Gr.4N low alloy steel for a reactor pressure vessel. It is very important to evaluate the temper embrittlement phenomena of SA508 Gr.4N for an RPV application. In this study, we have performed a Charpy impact test and tensile test of SA508 Gr.4N low alloy steel with changing impurity element contents such as Mn and P. And also, the mechanical properties of these low alloy steels after longterm heat treatment ($450^{\circ}C$, 2000hr) are evaluated. Further, evaluation of the temper embrittlement by fracture analysis was carried out. Temper embrittlement occurs in KL4-Ref and KL4-P, which show a decrease of the elongation and a shifting of the transition curve toward high temperature. The reason for the temper embrittlement is the grain boundary segregation of the impurity element P and the alloying element Ni. However, KL4-Ref shows temper embrittlement phenomena despite the same contents of P and Ni compared with SC-KL4. This result may be caused by the Mn contents. In addition, the behavior of embrittlement is not largely affected by the formation of $M_3P$ phosphide or the coarsening of Cr carbides.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.26 no.1
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• pp.1-11
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• 2002

Flow of fluid has been studied in various fields of fluid engineering. To hydraulic engineers, the unsteady flow such as pulsation and liquid hammering in pipes has been considered as a serious trouble. So we are supposed to approach the formalized mathematical model by using more exact momentum equation for fluid transmission lines. Most of recent studies fur pipe line have been studied without considerations of variation of viscosity and temperature, which are the main factors of pressure loss causing the friction of fluid inside pipe line. Frequency response experiments are carried out with use of a rotary sinusoidal flow generator to investigate wave equation take into account viscosity and temperature. But we observed that measured value of gains are reduced as temperature increased. And it was respectively observed that the measured value of gains are reduced and line width of gain is broadened out, when temperature was high in the same condition. As we confessed, pressure loss and phase delay are closely related with the length, diameter and temperature of pipe line. In addition, they are the most important factors, when we decide the momentum energy of working fluid.

• Journal of Hydrogen and New Energy
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• v.24 no.1
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• pp.70-75
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• 2013

It has fabricated membrane electrode assemblies (MEA) for proton exchange membrane fuel cell by hot-pressing method. The hot-pressing was used for the fabrication of MEA which is composed of commercial platinum electrode on carbon paper. The performance of MEA was studied with different fabrication conditions of temperature, pressure and torque. As the temperature increased, the performance of MEA was increased. and started to decrease l after arrived at the maximum performance of MEA. This is related with good contact between electrode and polymer electrolyte membrane at high temperature and microstructural change at much higher temperature. Similarly, as the pressure increased, the performance of the MEA increased up to highest values and start to decrease. According to the our results, the maximal performance of the MEA was at the temperature of $140^{\circ}C$ and the pressure of $1.5{\times}10^3$ kPa. The optimal torque to assemble the single stack was 3.2 N m.