• Korean Chemical Engineering Research
• /
• v.40 no.6
• /
• pp.709-714
• /
• 2002

To investigate the decomposition kinetics of poly(ethylene terephthalate) the high pressure molten-polymer injector has been devised. Using the experimental apparatus equipped with batch reactor and high pressure molten-polymer injector the decomposition of PET has been performed at constant pressure of 250 bar and 300, 320, $340^{\circ}C$, respectively. At each temperature conditions the conversions after initial 1 minute have shown very high values such as 76-90%. As the temperature increases the conversion reaches more than 98% at 10 minutes. Based on the second order reaction model the reaction rate constants have been obtained. We can calculate the conversions within 2% errors utilizing optimized rate constants. The activation energy for the decomposition of PET at subcritical conditions has shown to be 54.4 kJ/mol.

• Journal of the Korean Magnetics Society
• /
• v.26 no.6
• /
• pp.190-195
• /
• 2016

We report the effect of pressure varying from 0 to 1500 bar on the magnetic properties of magnetite nanoparticles synthesized from $Fe(OH)_2$ suspension using a high pressure homogenizer without any dispersing agent and oxidant. The observed X-ray diffraction (XRD) patterns showed that all the synthesized nanoparticles had the inverse spinel structure of magnetite. It was found from transmission electron microscopy (TEM) and XRD analysis that the average size of the synthesized magnetite particles could be controlled by the pressure of the high pressure homogenizer. The average particle size was found to range from 21 to 26 nm and decrease with increasing pressure. Magnetic hysteresis measurements performed at room temperature using a vibrating sample magnetometer (VSM) revealed the appearance of a superparamagnetic behavior in the magnetite nanoparticles synthesized at a pressure of 1500 bar.

• Journal of Surface Science and Engineering
• /
• v.34 no.5
• /
• pp.378-383
• /
• 2001

An out line of the material process with using the atmospheric pressure glow plasma is described as follows : (1) TiO powder coating with SiO$_2$ (2) Surface treatment of Fluorinated polymers and (3) Surface cleaning of electronic circuit board with using splay type.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.29 no.10 s.241
• /
• pp.1148-1155
• /
• 2005

In this study, the influence of changing combustor pressure on nitric oxide emission was investigated. Expansion of reaction region was more clear in the P$^{*}$ <1 conditions compared to the P$^{*}\geq1$ conditions, and it could be observed that flames are distinct in the P$^{*}\geq1$ conditions and that brightness is relative low and wide distribution is shown in the P$^{*}$ <1 conditions. In the respect of temperature distribution, narrow and high-temperature region was shown in the P$^{*}\geq1$ conditions. On the other hands, overall uniform temperature distributions were shown in the P$^{*}$ <1 conditions. Nitric oxide emission decreased with decreasing combustor pressure. This tendency was explained by the mean flame temperature distribution. Low NOx combustion is ascribed to wide-spread reaction region in the low combustor Pressure and oscillation were shown P$^{*}\leq0.97$, and strength and sizes of oscillation were more increased with lower pressure index. These results demonstrate that flame shape and nitric oxide emission can be controlled with changing combustor pressure.

• Bulletin of the Korean Chemical Society
• /
• v.6 no.2
• /
• pp.74-79
• /
• 1985

The stabilities of the charge transfer complexes of pentamethyl benzene with iodine in n-hexane have been investigated by UV-spectrophotometric measurements at 25, 40 and 60$^{\circ}C$ up to 1600 bars. The equilibrium constant of the complex formation was increased with pressure while being decreased with temperature raising. Changes of volume, enthalpy, free energy and entropy for the formation of the complexes were obtained from the equilibrium constants. The red-shift at higher pressure, the blue-shift at higher temperature, and the relation between pressure and oscillator strength have been discussed by means of thermodynamic functions. In comparison with the results in the previous studies, the absolute values of ${\Delta}$V at each temperature were increased with the number of methyl groups of polymethyl benzene. However, it can be seen that both ${\Delta}$H and ${\Delta}$S show extreme behaviors in durene near atmospheric pressure but they are negatively increased with the number of methyl groups near 1600 bar. This order of the thermodynamic parameters may be a measure of the relative basicities of polymethyl benzenes toward iodine under each pressure, and these phenomena are explained in terms of a positive inductive effect and a steric hindrance effect of the polymethyl benzene molecule.

• Journal of the Mineralogical Society of Korea
• /
• v.15 no.3
• /
• pp.161-169
• /
• 2002

high pressure and temperature conditions. However, those results are not consistent with one another, and phase boundary between ilmenite and perovskite phases determined only from the quenching method may be not so reliable at all. Therefore, in-situ high pressure-temperature (hP-T) X-ray diffraction measurements were performed up to 19 GPa and $700^{\circ}C$ in a large volume press apparatus using synchrotron radiation. Experimental results show that perovskite phase is stable at pressures above 16 GPa, and transforms back to $LiNbO_3$phase near 15 CPa at room temperature, and that the perovskite-ilmenite transition is back and forth near 15 CPa at $500^{\circ}C$. LiNbO$_3$phase transforms to ilmenite at 13 CPa and $300^{\circ}C$ and at 10.8 CPa and $400^{\circ}C$, respectively. These data indicate that $LiNbO_3$phase may have a stability region in the hP-T phase diagram and that the perovskite-ilmenite phase boundary would be quite different from that previously reported.

• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2007.11a
• /
• pp.23-26
• /
• 2007

A preliminary， study of low temperature condition was performed to simulate high altitude condition. The mixed air temperature were investigated at various condition by experiments using cryogenic air by heat exchanger and normal temperature air. An experimental setup was constructed to simulate low temperature condition with liquid nitrogen. To control mass flow rate, orifice and pressure regulators were used. The experimental results show that the mixed air temperature increases linearly with mass flow rate of normal temperature air. Therefore it can be help to simulate a low temperature condition of high altitude.

• Korean Journal of Materials Research
• /
• v.11 no.11
• /
• pp.936-940
• /
• 2001

Spray pyrolysis is a favorable technique to form complex mixed-metal oxide powders with high purity in high temperature region. Manganese oxide powders were prepared by spray pyrolysis from an aqueous solution of $Mn(NO_3)_2$. Powders were formed in the temperature range of 500~$700^{\circ}C$ under the constant pressure of 300torr. All the powders have hydrous forms. When the temperature was increased, the size and the surface area of the particles decreased. An electrochemical capacitors were made with manganese oxide electrodes and KOH electrolyte. With the temperature decreased, capacitors showed high capacitance. Capacitor which was prepared with powders formed in the temperature $500^{\circ}C$ demonstrated specific capacitances as high as 83F/g.

• Journal of the Korea Concrete Institute
• /
• v.11 no.5
• /
• pp.69-77
• /
• 1999

A spalling is defined as the damages of concrete exposed to high temperature during the fire by causing cracks and localized bursting of small pieces of concrete. It is reported that spalling is caused by the vapor pressure and polypropylene(PP) fiber has an important role in protecting from spalling. This paper is a study on the properties and spalling resistance of high-performance concrete with the kinds of aggregate and the contents of PP fiber. According to the experimental results, concrete contained no PP fiber take place in the form of the surface spalling and the failure of specimenns after fire test regardless of the kinds of aggregate. Concrete contained more than 0.05% of PP fiber with the aggregate of basalt does not take place the spalling, while the concrete using granite and limestone does the surface spalling. It is found that residual compressive strength after exposed at high temperature has 50~60% of its original strength. Although specimens after exposed at high temperature is cured at water for 28days, they do not recover their original strength.

• Korean Journal of Food Science and Technology
• /
• v.32 no.1
• /
• pp.111-116
• /
• 2000

Effects of ultra-high pressure treatment on viable cell count and quality characteristics of low salt fermented anchovy under different operating conditions such as pressure$(200{\sim}500\;MPa)$, temperature$(20{\sim}50^{\circ}C)$ and treatment time$(5{\sim}20\;min)$ were investigated. Viable cell count decreased gradually with the increase of pressure and suddenly at 400 MPa. It also decreased by seven folds at $50^{\circ}C$ and logarithmically with the increase of treatment time. Peroxide value increased with the increase of pressure, temperature and treatment time, and temperature played a major role. Thiobarbituric acid value was higher by two folds in samples treated than in the untreated regardless of any conditions investigated. Volatile basic nitrogen was almost the same in all samples except the one at $50^{\circ}C$. The sample treated at greater than $30^{\circ}C$ under high hydrostatic pressure indicated higher value in amino nitrogen. Treatment at $20^{\circ}C/300$ MPa/15 min showed greater reductions in viable cell counts, remaining better quality of low salt fermented anchovy.