• Title/Summary/Keyword: high temperature high pressure

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Effects of Biomass Additives on Yield of Coal Liquefaction (석탄액화시 바이오매스계 첨가제의 효과)

  • Kim, J.W.;Sim, K.S.;Lee, S.H.;Park, K.B.;Lalvani, S.B.
    • Solar Energy
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    • v.18 no.3
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    • pp.161-167
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    • 1998
  • The effects of some additives(black liquor, wood and lignin) on the conversion of coal and product were investigated in the lab-scale, high pressure reacting system around $375^{\circ}C$. The addition of lignin to coal during liquefaction significantly increased the depolymerization of coal and enhanced the quality of the liquid products. Coprocessing of wood and coal at $400^{\circ}C$ increased yield of liquid product about 8%, but higher temperature above $400^{\circ}C$ reduced liquid product due to increase of gas products. The addition of black liquor resulted in an enhancement in coal conversion yields, however, the observed increase is lower than that obtained in the presence of NaOH because lignin present in black liquor is not very effective due to the $OH^-$ presence.

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Micro-gap DBD Plasma and Its Applications

  • Zhang, Zhitao;Liu, Cheng;Bai, Mindi;Yang, Bo;Mao, Chengqi
    • Journal of the Speleological Society of Korea
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    • no.76
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    • pp.37-42
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    • 2006
  • The Dielectric Barrier Discharge (DBD) is a nonequilibrium gas discharge that is generated in the space between two electrodes, which are separated by an insulating dielectric layer. The dielectric layer can be put on either of the two electrodes or be inserted in the space between two electrodes. If an AC or pulse high voltage is applied to the electrodes that is operated at applied frequency from 50Hz to several MHz and applied voltages from a few to a few tens of kilovolts rms, the breakdown can occur in working gas, resulting in large numbers of micro-discharges across the gap, the gas discharge is the so called DBD. Compared with most other means for nonequilibrium discharges, the main advantage of the DBD is that active species for chemical reaction can be produced at low temperature and atmospheric pressure without the vacuum set up, it also presents many unique physical and chemical process including light, heat, sound and electricity. This has led to a number of important applications such as ozone synthesizing, UV lamp house, CO2 lasers, et al. In recent years, due to its potential applications in plasma chemistry, semiconductor etching, pollution control, nanometer material and large area flat plasma display panels, DBD has received intensive attention from many researchers and is becoming a hot topic in the field of non-thermal plasma.

Design and Exergy Analysis for a Combined Cycle using LNG Cold/Hot Energy (액화천연가스 냉온열을 이용한 복합사이클의 설계 및 엑서지 해석)

  • Lee Geun Sik
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.17 no.4
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    • pp.285-296
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    • 2005
  • In order to reduce the compression power and to use the overall energy contained in LNG effectively, a combined cycle is devised and simulated. The combined cycle is composed of two cycles; one is an open cycle of liquid/solid carbon dioxide production cycle utilizing LNG cold energy in $CO_2$ condenser and the other is a closed cycle gas turbine which supplies power to the $CO_2$ cycle, utilizes LNG cold energy for lowering the compressor inlet temperature, and uses the heating value of LNG at the burner. The power consumed for the $CO_2$ cycle is investigated in terms of a production ratio of solid $CO_2$. The present study shows that much reduction in both $CO_2$ compression power (only $35\%$ of power used in conventional dry ice production cycle) and $CO_2$ condenser pressure could be achieved by utilizing LNG cold energy and that high cycle efficiency ($55.3\%$ at maximum power condition) in the gas turbine could be accomplished with the adoption of compressor inlet cooling and regenerator. Exergy analysis shows that irreversibility in the combined cycle increases linearly as a production ratio of solid $CO_2$ increases and most of the irreversibility occurs in the condenser and the heat exchanger for compressor inlet cooling. Hence, incoming LNG cold energy to the above components should be used more effectively.

Enhancement of Pool Boiling Heat Transfer in Water Using Sintered Copper Microporous Coatings

  • Jun, Seongchul;Kim, Jinsub;Son, Donggun;Kim, Hwan Yeol;You, Seung M.
    • Nuclear Engineering and Technology
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    • v.48 no.4
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    • pp.932-940
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    • 2016
  • Pool boiling heat transfer of water saturated at atmospheric pressure was investigated experimentally on Cu surfaces with high-temperature, thermally-conductive, microporous coatings (HTCMC). The coatings were created by sintering Cu powders on Cu surfaces in a nitrogen gas environment. A parametric study of the effects of particle size and coating thickness was conducted using three average particle sizes (APSs) of $10{\mu}m$, $25{\mu}m$, and $67{\mu}m$ and various coating thicknesses. It was found that nucleate boiling heat transfer (NBHT) and critical heat flux (CHF) were enhanced significantly for sintered microporous coatings. This is believed to have resulted from the random porous structures that appear to include reentrant type cavities. The maximum NBHT coefficient was measured to be approximately $400kW/m^2k$ with APS $67{\mu}m$ and $296{\mu}m$ coating thicknesses. This value is approximately eight times higher than that of a plain Cu surface. The maximum CHF observed was $2.1MW/m^2$ at APS $67{\mu}m$ and $428{\mu}m$ coating thicknesses, which is approximately double the CHF of a plain Cu surface. The enhancement of NBHT and CHF appeared to increase as the particle size increased in the tested range. However, two larger particle sizes ($25{\mu}m$ and $67{\mu}m$) showed a similar level of enhancement.

Tensile and impact toughness properties of various regions of dissimilar joints of nuclear grade steels

  • Karthick, K.;Malarvizhi, S.;Balasubramanian, V.;Krishnan, S.A.;Sasikala, G.;Albert, Shaju K.
    • Nuclear Engineering and Technology
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    • v.50 no.1
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    • pp.116-125
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    • 2018
  • Modified 9Cr-1Mo ferritic steel is a preferred material for steam generators in nuclear power plants for their creep strength and good corrosion resistance. Austenitic stainless steels, such as type 316LN, are used in the high temperature segments such as reactor pressure vessels and primary piping systems. So, the dissimilar joints between these materials are inevitable. In this investigation, dissimilar joints were fabricated by the Shielded Metal Arc Welding (SMAW) process with Inconel 82/182 filler metals. The notch tensile properties and Charpy V-notch impact toughness properties of various regions of dissimilar metal weld joints (DMWJs) were evaluated as per the standards. The microhardness distribution across the DMWJs was recorded. Microstructural features of different regions were characterized by optical and scanning electron microscopy. Inhomogeneous notch tensile properties were observed across the DMWJs. Impact toughness values of various regions of the DMWJs were slightly higher than the prescribed value. Formation of a carbon-enriched hard zone at the interface between the ferritic steel and the buttering material enhanced the notch tensile properties of the heat-affected-zone (HAZ) of P91. The complex microstructure developed at the interfaces of the DMWJs was the reason for inhomogeneous mechanical properties.

Static and Dynamic Analysis of Reinforced Concrete Axisymmetric Shell on the Elastic Foundation -With Application to an Static Behavior Analysis of Axisymmetric Shell- (탄성지반상에 놓인 철근콘크리트 축대칭 쉘의 정적 및 동적 해석 (III) -비선형 정적거동을 중심으로-)

  • 조진구
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.39 no.3
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    • pp.72-82
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    • 1997
  • In all inelastic deformations time rate effects are always present to some degree. Whether or not their exclusion has a significant influence on the prediction of the material behaviour depends upon several factors. In the study of structural components under static loading conditions at normal temperature it is accepted that time rate effects are generally not important. However metals, especially under high temperatures, exhibit simultaneously the phenomena of creep and viscoplasticity. In this study, elastoplastic and elasto-viscoplastic models include nonlinear geometrical effects were developed and several numerical examples are also included to verify the computer programming work developed here in this work. Comparisons of the calculated results, for the elasto-viscoplastic analysis of an internally pressurised thick cylinder under plane strain condition, have shown that the model yields excellent results. The results obtained from the numerical examples for an elasto-viscoplastic analysis of the Nuclear Reinforced Concrete Containment Structure(NRCCS) subjected to an incrementally applied internal pressure were summarized as follows : 1. The steady state hoop stress distribution along the shell layer of dome and dome wall junction part of NRCCS were linearly behave and the stress in interior surfaces was larger than that in exterior. 2.However in the upper part of the wall of NRCCS the steady state hoop stress in creased linearly from its inner to outer surfaces, being the exact reverse to the previous case of dome/dome-wall junction part. 3.At the lower part of wall of NRCCS, the linear change of steady state hoop stress along its wall layer began to disturb above a certain level of load increase.

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Fabrication of poly(ethylene oxide)/clay nanocomposites using supercritical fluid process (초임계 공정을 이용한 폴리에틸렌옥사이드/클레이 나노복합체 제조)

  • Kim, Yong-Ryeol;Jeong, Hyeon-Taek
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.1
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    • pp.143-150
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    • 2014
  • Recently, supercritical fluid process has been widely used in material synthesis and processing due to their remarkable properties such as high diffusivity, low viscosity, and low surface tension. Supercritical carbon dioxide is the most attractive solvent owing to their characteristics including non-toxic, non-flammable, chemically inert, and also it has moderate critical temperature and critical pressure. In addition, supercritical carbon dioxide would dissolve many small organic molecules and most polymers. In this study, we have prepared the poly (ethylene oxide)/clay nanocomposites using supercritical fluid as a carbon dioxide. Commercialized Cloisites-15A and Cloisites-30B used in this study, which are modified with quaternary ammonium salts. The nanocomposites of polymer/clay were characterized by XRD, TGA and DSC. Poly (ethylene oxide)/clay nanocomposites by supercritical fluid show higher thermal stability than nanocomposites prepared by melt process. In addition, supercritical fluid process would be increased dispersibility of the nanoclay in the matrix.

Intercooler for Multi-stage Turbocharger Design and Analysis of the Hydrogen Reciprocating Engine for HALE UAV (고고도 장기체공 무인기용 수소 왕복 엔진의 다단터보차저용 인터쿨러 설계 및 해석)

  • Lee, Yang Ji;Rhee, Dong Ho;Kang, Young Seok;Lim, Byoeung Jun
    • The KSFM Journal of Fluid Machinery
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    • v.20 no.1
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    • pp.65-73
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    • 2017
  • Intercoolers for multi-stage turbocharger of the hydrogen reciprocating engine for HALE UAV are installed for reducing the charged air inlet temperature of the engine. The intercooler is air to air, cross flow, plate-fin type and the fin configuration is offset-strip fin which is referenced from the heat exchanger of the ERAST. Most of HALE UAV's cruising altitude is 60,000 ft and the density of air for this altitude is very low compared to sea level. Therefore the required heat transfer area for the HALE UAV is about three-times bigger than the sea level. Consequently, it is essential to design to meet the required efficiency of intercooler in the range of not excessively growing the weight of the heat exchanger. The quasi-one dimensional heat transfer design/analysis for satisfying the requirement of the engine are written in this paper. The numerical analyses for estimating the coolant flow rate of the engine bay and pressure loss in the header and core are also summarized.

Distance between source and substrate and growth mode control in GaN nanowires synthesis (Source와 기판 거리에 따른 GaN nanowires의 합성 mode 변화 제어)

  • Shin, T.I.;Lee, H.J.;Kang, S.M.;Yoon, D.H.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.18 no.1
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    • pp.10-14
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    • 2008
  • We synthesized GaN nanowires with high quality using the vapor phase epitaxy technique. The GaN nanowires were obtained at a temperature of $950^{\circ}C$. The Ar and $NH_3$ flow rates were 1000 sccm and 50 sccm, respectively. The shape of the GaN nanowires was confirmed through FESEM analysis. We were able to conclude that the GaN nanowires synthesized via vapor-solid (VLS) mechanism when the source was closed to the substrate. On the other side, the VS mechanism changed to vapor-liquid-solid (VLS) as the source and the substrate became more distant. Therefore, we can suggest that the large amount of Ga source from initial growth interrupt the role of catalyst on the substrate.

A study on growing of bulk AlN single crystals grown having a (011) growth face of by PVT method (PVT법을 이용한 (011)면으로 성장된 AlN 단결정 성장에 관한 연구)

  • Kang, Seung-Min
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.25 no.1
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    • pp.32-34
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    • 2015
  • AlN Single Crystal were grown by PVT (Physical vapor transport) method on bulk seed. It was performed by high-frequency induction-heating coil. AlN source powder was loaded at bottom side of the carbon crucible and the crystal seed was loaded at the upper side of the crucible. The temperature conditions of the growth was varied $2000{\sim}2100^{\circ}C$ and the surrounding pressure was $1{\times}10^{-1}{\sim}200$ Torr. And the hot-zone of the heating position was controlled elaborately according to growth. The 17 mm-diameter, 7 mm-thickness AlN single crystal is obtained for about 600 hours growing. It was recognized that the growth direction of as grown crystal was R[011] by the Laue X-Ray camera measurement.