• Title/Summary/Keyword: high temperature high pressure

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The Effect of Molding Conditions on the Surface Gloss of HIPS Molding (HIPS 성형품에서 성형조건이 표면 광택에 미치는 영향)

  • Jeong, Y.D.;Lee, M.H.
    • Journal of Power System Engineering
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    • v.4 no.3
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    • pp.81-85
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    • 2000
  • The surface gloss of the injection molded part is one of the most significant point for evaluation the quality of products appearance. The effects of molding condition on the gloss of HIPS(High Impact Poly Styrene) molded part were investigated in this work. The measurements of gloss on the surface of molded part were carried out with different melt temperature, mold temperature, injection pressure and holding pressure. We observed the result of HIPS gloss compared with our's previous ABS study. The more melt and mold temperature increased, the brighter the gloss increase. Holding and injection pressure had little effect on the gloss. The gloss was effected in order of melt temperature, mold temperature, injection pressure, holding pressure.

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Simultaneous Synthesis and Sintering of Titanium Carbide by HPCS(High Pressure-Self Combustion Sintering) (고압연소 소결(HPCS)법에 의한 탄화티타늄(TiC)의 합성 및 소결)

  • 김지헌;최상욱;조원승;조동수;오장환
    • Journal of the Korean Ceramic Society
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    • v.34 no.5
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    • pp.473-482
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    • 1997
  • Titanium carbide(TiC) has a poor sinterability due to the strong covalent bond. Thus, it is generally fabricated by either hot pressing or pressureless-sintering at elevated temperature by the addition of sintering aids such as nickel(Ni), molybdenum(Mo) and cobalt(Co). However, these sintering methods have the following disadvantages; (1) the complicated process, (2) the high energy consumption, and (3) the possibility of leaving inevitable impurities in the product, etc. In order to reduce above disadvantages, we investigated the optimum conditions under which dense titanium carbide bodies could be synthesized and sintered simultaneously by high pressure self-combustion sintering(HPCS) method. This method makes good use of the explosive high energy from spontaneous exothermic reaction between titanium and carbon. The optimum conditions for the nearly full-densification were as follows; (1) The densification of sintered body becomes high by increasing the pressing pressure from 400kgf/$\textrm{cm}^2$ upto 1200 kgf/$\textrm{cm}^2$. (2) Instead of adding the coarse graphite or activated carbon, the fine particles of carbon black should be added as a carbon source. (3) The optimum molar ratio of carbon to titanium (C/Ti) was unity. In reality, titanium carbide body which were prepared under optimum conditions had relatively dense textures with the apparent porosity of 0.5% and the relative density of 98%.

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The Electromotive Force and Thermodynamic Properties of the Cell at High Pressure (고압하에서의 전지의 기전력과 열역학적 성질)

  • Jee Jong-Gi;Jung Jong-Jae;Hwang Jung-Ui
    • Journal of the Korean Chemical Society
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    • v.18 no.5
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    • pp.320-328
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    • 1974
  • It is unable to derive the standard emf ($E^{\circ}$) of the cell at high pressure from the conventional method. However, when the concept of the complete equilibrium constant($K{\circ})$) is available to the conventional Nernst equation, it is possible to get the standard emf of the cell at high pressure(complete Nernst equation). Moreover, the other thermodynamic properties, such as the net change of solvation number(k), the compressibility of solvent(${\beta}$), ionization constant(K), the standard free energy change(${\Delta}G^{\circ}$), the standard enthalpy change(${\Delta}H^{\circ}$) and the standard entropy change (${\Delta}S^{\circ}$) of the cell reaction at equilibrium state have been also obtained. In this experiment, the emf of the cell; 12.5 % Cd(Hg)│$CdSO_4(3.105{\times}10^{-3}M),\;Hg_2SO_4│Hg$ have bee measured at temperature from 20 to $35^{\circ}C$ and at pressures from 1 to 2500 atms. The emf of the cell increased with increasing pressure at constant temperature, and did with increasing temperature at constant pressure. The net change of solvation number(k) of the cell reaction was 41.96 at $25^{\circ}C$, and kept constant value with pressure, while, K and ${\Delta}S^{\circ}$ increased with pressure, but whereas ${\Delta}G^{\circ}$ and ${\Delta}H^{\circ}$ decreased. Since the standard emf of the cell at high pressure can be calculated from the complete Nernst equation, the theory of chemical equilibrium could be developed with at high pressure as well as at the atmosphere.

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Phase-Resolved CARS Temperature Measurement in a Lean Premixed Gas Turbine Combustor (II) -Effect of Equivalence Ratio on Phase-Resolved Gas Temperature- (CARS를 이용한 희박 예혼합 가스터빈 연소기내 온도 측정 (II)-당량비가 위상별 온도에 미치는 영향-)

  • Lee Jong Ho;Jeon Chung Hwan;Park Chul Woong;Hahn Jae Won;Chang Young June
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.10
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    • pp.1193-1201
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    • 2004
  • The effect of equivalence ratio and fuel/air mixing quality on the phase-resolved gas temperatures at different phases of the oscillating pressure cycle was experimentally investigated. An atmospheric pressure, optically accessible and laboratory-scale dump combustor operating on methane with heat release rate of 1.59kW was used. Temperature measurements were made using coherent anti-Stokes Raman spectroscopy (CARS) at several spatial locations fur typical unstable combustion conditions. Analysis was conducted using parameters such as phase-resolved averaged temperature, normalized standard deviation and temperature probability distribution functions (PDFs). Also the probability on the occurrence of high temperature (over 1900K) was investigated to get the information on the perturbation of equivalence ratio and NOx emission characteristics. It was shown that most of temperature histograms exhibit Gaussian profile which has short breadth of temperature fluctuation at equivalence ratio of 0.6, while beta profile was predominant for the cases of other equivalence ratios (${\Phi}$=0.55, 0.50). It was also shown that phase-resolved averaged temperature oscillated in phase with pressure cycle, while normalized standard deviations which represent temporal turbulent intensity of temperature showed nearly constant value around 0.1. The characteristics on the occurrence of high temperature also displayed periodic wave form which was very similar to the pressure signal. And the amplitude of this profile went larger as the fuel/air mixing quality became poorer. These also provided additional information on the perturbation of equivalence ratio at flame as well as NOx emission characteristics.

Numerical study on extinction and acoustic response of diluted hydrogen-air diffusion flames with detailed and reduced chemistry (상세 및 축소 반응 메커니즘을 이용한 희석된 수소-공기 확산화염의 소염과 음향파 응답 특성에 관한 수치해석)

  • Son, Chae-Hun;Jeong, Seok-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.21 no.11
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    • pp.1527-1537
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    • 1997
  • Extinction characteristics and acoustic response of hydrogen-air diffusion flames at various pressures are numerically studied by employing counterflow diffusion flame as a model flamelet in turbulent flames in combustion chambers. The numerical results show that extinction strain rate increases linearly with pressure and then decreases, and increases again at high pressures. Thus, flames are classified into three pressure regimes. Such nonmonotonic behavior is caused by the change in chemical kinetic behavior as pressure rises. The investigation of acoustic-pressure response in each regime, for better understanding of combustion instability, shows different characteristics depending on pressure. At low pressures, pressure-rise causes the increase in flame temperature and chain branching/recombination reaction rates, resulting in increased heat release. Therefore, amplification in pressure oscillation is predicted. Similar phenomena are predicted at high pressures. At moderate pressures, weak amplification is predicted since flame temperature and chain branching reaction rate decreases as pressure rises. This acoustic response can be predicted properly only with detailed chemistry or proper reduced chemistry.

Transient Response Analysis of a Control Valve for CO2 Refrigerant (CO2냉매용 제어밸브의 응답 특성)

  • Kim, Bo Hyun;Jang, Ji Seong
    • Journal of Drive and Control
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    • v.15 no.4
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    • pp.11-16
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    • 2018
  • Pilot operated control valve for $CO_2$ refrigerant is a valve that can perform various functions according to the user's intention by replacing pilot units, widely used for flow rate, pressure, and temperature control of refrigeration and air conditioning systems. In addition, $CO_2$ refrigerant, that requires high pressure and low critical temperature, can be installed and used in all positions of the refrigeration system, regardless of high or low pressure. In this paper, response characteristics are modeled and analyzed based on behavior of the main piston of the pilot-operated control valve. Although various factors influence operation of the main piston, this paper analyzes the effect of equilibrium pressure depending on valve installation position and application, and inlet and outlet orifice size of the load pressure feedback chamber to determine feedback characteristics of the main piston. As a result, it was possible to quantitatively analyze the effect of change in equilibrium and load pressure feedback chamber flow path size on the change in main piston dynamic and static characteristics.

A Welding Characteristics of Large Caliber-Thick Plate Pressure Vessel Low Alloy Steel (Mn-Mo) (대구경-후판 압력용기용 저 합금강(Mn-Mo)의 용접특성)

  • Ahn, Jong-Seok;Park, Jin-Keun;Yoon, Jae-Yeon
    • Journal of Welding and Joining
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    • v.30 no.6
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    • pp.10-14
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    • 2012
  • Recently the low alloy steel plate made with manganese-molybdenum is used widely in steam drum and separator of the new coal-fired power plant boiler. This material is suitable for the vapor storage of high pressure and high temperature. The high temperature creep strength of Mn-Mo alloy is higher than the carbon plate(SA516) that used in the subcritical pressure boiler. It reduces the thickness of the pressure vessel and makes the lightweight possible. Recently in the power plant boiler operation and production process, the damage has happened frequently in the heat affected zone and base material according to the hydrogen crack and delayed crack. This paper describes the research result about the damage case experienced in the boiler steam drum production process and present the optimum manufacture method for the similar damage prevention of recurrence.

An Experimental Study for the Effect of Ventilation Velocity on Performance of a High Pressure Water Mist Fire Suppression System (객차내 환기속도가 고압 미세물분무 화재제어 시스템 성능에 미치는 영향에 대한 실험적 연구)

  • Kim, Dong-Woon;Bae, Seung-Yong;Ryou, Hong-Sun
    • Journal of the Korean Society of Safety
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    • v.23 no.4
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    • pp.1-6
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    • 2008
  • This experiments are perfol1ned to investigate the effect of ventilation velocity on a high pressure water mist tire suppression in train. The experiment is conducted in half scale modeled train of a steel-welled enclosure (5.0m${\times}$2.4m${\times}$2.2m). The ventilation velocity is controlled by the ventilation duct through an inverter in the range of 0 to 3m/s. The coverage-radius and an injection angle of an high pressure water mist system are measured. The mist nozzle with 5-injection holes is operated with pressure 60bar. The heptane pool fires are used. The fire extinguishment times and the temperature are measured for the ventilation velocities. In conclusion, because the momentum of injected water mist is more dominant than that of ventilation air, the characteristics of water mist, the fire extinguishment times and the temperature are affected very little by ventilation velocity.

Characteristics of thin-film type pressure sensors for high pressure (고압용 박막형 압력센서의 특성)

  • 서정환;최성규;정찬익;류지구;남효덕;정귀상
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.737-740
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    • 2001
  • This paper describes the fabrication and characteristics of CrN thin-film type pessure sensors, which the sensing elements were deposited on SUS. 630 diaphragm by DC reactive magnetron sputtering in an argon-nitride atmosphere(Ar-(10%)N$_2$). The optimized condition of CrN thin-film sensing elements was thickness range of 3500${\AA}$ and annealing condition(300$^{\circ}C$, 3 hr) in Ar-10 %N$_2$deposition atmosphere. Under optimum conditions, the CrN thin-films for strain gauges is obtained a high resistivity, $\rho$=1147.65 ${\mu}$$\Omega$cm, a low temperature coefficient of resistance, TCR=-186 ppm/$^{\circ}C$ and a high temporal stability with a good longitudinal, 11.17. The output sensitivity of fabricated CrN thin-film type pressure sensors is 2.36 mV/V, 4∼20 mA and the maximum non-linearity is 0.4 %FS and hysteresis is less than 0.2 %FS.

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Analysis of Process Parameter dependency on the characteristics of high density fluoro carbon plasma using global model (글로벌 모델에 의한 저온 고밀도 플루오로카본 플라즈마 특성의 공정변수 의존성 해석)

  • Lee, Ho-Jun;Tae, Heung-Sik
    • Proceedings of the KIEE Conference
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    • 1999.11d
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    • pp.879-881
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    • 1999
  • Radical and ion densities in a CF4 plasma have been calculated as a function of input power density. 9as pressure and feed gas flow rate using simple 0 dimensional global model. Fluorine atom is found to be the most abundant neutral particle. Highly fragmented species such as CF and CF+ become dominant neutral and ionic radical at the high power condition. As the pressure increases. ion density increases but ionization rate decreases due to the decrease in electron temperature. The fractional dissociation of CF4 feed gas decreases with pressure after increasing at the low pressure range. Electron density and temperature are almost independent of flow rate within calculation conditions studied. The fractional dissociation of CF4 monotonically decreases with flow rate. which results in increase in CF3 and decrease in CF density. The calculation results show that the SiO2 etch selectivity improvement correlates to the increase in the relative density of fluorocarbon ion and neutral radicals which has high C/F ratio.

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