• Title/Summary/Keyword: high temperature high pressure

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A Study on the Microstructure and Properties of Y-BA-Cu-O/Ag composite High $T_{c}$ Superconductor prepared by Sinter-forging Process (Sinter forging으로 제조한 Y-BA-Cu-O/Ag 고온 초전도 복합체의 미세조직과 특성)

  • Park, Jong-Hyeon;Kim, Byeong-Cheol;Song, Jin-Tae
    • Korean Journal of Materials Research
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    • v.4 no.1
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    • pp.37-43
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    • 1994
  • Y-Ra-Cu-0 oxide superconductors were fabricated by the sinter-forging method to make the critical current density improve through controlling of microstructure and crystal texture. The grain alignment of oxide superconductor was formed by the sinter-forging process and it's c-axis orientation was parallel to the press direction.The orientation factor of texture increased with sinking temperature and pressure, and also grain alignment was improved by the addition of Ag. As for the sinterforged Y-Ba-Cu-O/Ag sample, the $T_c$(on-set) was not almost varied with the sinter-forging temperature, but $T_c\;^{zero}$ decreased more or less at high sinter-forging temperatures. In addition, it was observed that added-Ag was mainly distributed along the grain boundar~es in the (123) matrix, resulting in the densification of microstructure. From these results, i t was thought that the improvement of $J_c$ over 2000A/$\textrm{cm}^2$ was attributed to the texture, densification of microstructure, and (123) grain growth due to the Ag addition.

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Effect of Diluent Size on Aluminum Nitride Prepared by Using Self-Propagating High-Temperature Synthesis Process (희석제 입도가 고온자전연소법에 의한 질화알루미늄 합성에 미치는 영향)

  • Lee, Jae-Ryeong;Lee, Ik-Kyu;Shin, Hee-Young;Chung, Hun-Saeng
    • Journal of the Korean Ceramic Society
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    • v.42 no.1
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    • pp.69-75
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    • 2005
  • To investigate the morphological effect on synthesis of aluminum nitride by SHS Process, two type of Al Powder (granular and flacky shape) with the mean size of 34 $\mu$m and the diluent AIN powders of four different mean sizes.0.12, 9.7, 39.3, 50.5 $\mu$m, were used to prepare green compact. The packing density was fixed to $35 TD\%. The initial pressure of $N_{2}$ and diluent fraction was varied in the range of $1\~10 MPa,\;0.4\~0.7$, respectively. AlN with high purity of $98\% or over and large particle size of about several tens fm can be synthesized by SHS reaction as a consequence of adjusting particle size of AlN dilutent similarly to that of Al reactant. This may be caused by improvement of $N_{2}$ gas permeation to compact after passing the propagation wave. In the case of flaky-shape aluminum used as reactant, instead of granular Al-powder, unstable combustion would be occurred. As the result, irregular propagation of combustion wave and falling-off of maximum temperature would be observed during the reaction.

Hot Air Injection/Extraction Method for the Removal of Semi-Volatile Organic Contaminants from Soils (토양내 저휘발성 유류오염물 제거를 위한 고온공기 주입/추출기술 연구)

  • Gu Chung-Wan;Ko Seok-Oh
    • Journal of Soil and Groundwater Environment
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    • v.10 no.1
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    • pp.6-12
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    • 2005
  • Contamination of soils and groundwater by leakage of petroleum compounds from underground storage tanks (USTs) has become great environmental issues. Conventional methods such as soil vapor extraction (SVE) used for the remediation of unsaturated soils contaminated with volatile organic compounds might not be applied for the removal of semi-volatile organic compounds such as diesel fuels and PCBs, which have low volatility and high hydrophobicity. The objective of this study is to develop a hot air injection method to remove semi-volatile compounds. Additionally, operation parameters such as temperature, air flow rate, and water content are evaluated. Experimental results show that diesel ranged organics (DROs) are removed in the order of volatility of organic compounds. As expected, removal efficiency of organics is highly dependent on the temperature. It is considered that more than $90\%$ of organic contaminants whose carbon numbers range between 17 and 22 can be removed efficiently by the hot air injection-extraction method (modified SVE) over the $100^{\circ}C$. It is also found that increased air flow rate resulted in high removal rate of contaminants. However, air flow rate over 40 cc/min is not effective for the operation aspects, due to mass transfer limitation on the volatilization rate of the contaminants. The effect of the water content on the decane removal is minimal, but some components show large dependence on the removal efficiency with increasing water content.

A Study on Safety Estimation of Railroad Wheel (컨테이너 철도차륜의 안전성 평가에 관한 연구)

  • Lee, Dong-Woo;Kim, Jin-Nam;Cho, Seok-Swoo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.4
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    • pp.1178-1185
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    • 2010
  • Recently, high speed of container freight cars is causing fatigue damage of wheel. Sudden failure accidents cause a lot of physical and human damages. Therefore, damage analysis for wheel prevents failure accident of container freight car. Wheel receives mechanical and thermal loads at the same time while rolling stocks are run. The mechanical loads applied to wheel are classified by the horizontal load from contact of wheel and rail in curve line section and by the vertical force from rolling stocks weight. Also, braking and deceleration of rolling stocks cause repeated thermal load by wheel tread braking. Specially, braking of rolling stocks is frictional braking method that brake shoe is contacted in wheel tread by high breaking pressure. Frictional heat energy occurs on the contact surface between wheel tread and brake shoe. This braking converts kinetic energy of rolling stocks into heat energy by friction. This raises temperature rapidly and generates thermal loads in wheel and brake shoe. There mechanical and thermal loads generate crack and residual stress in wheel. Wetenkamp estimated temperature distribution of brake shoe experimentally. Donzella proposed fatigue life using thermal stress and residual stress. However, the load applied to wheel in aforementioned most researches considered thermal load and mechanical vertical load. Exact horizontal load is not considered as the load applied to wheel. Therefore, above-mentioned loading methods could not be applied to estimate actual stress applied to wheel. Therefore, this study proposed safety estimation on wheel of freight car using heat-structural coupled analysis on the basis of loading condition and stress intensity factor.

Properties of High Power Flip Chip LED Package with Bonding Materials (접합 소재에 따른 고출력 플립칩 LED 패키지 특성 연구)

  • Lee, Tae-Young;Kim, Mi-Song;Ko, Eun-Soo;Choi, Jong-Hyun;Jang, Myoung-Gi;Kim, Mok-Soon;Yoo, Sehoon
    • Journal of the Microelectronics and Packaging Society
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    • v.21 no.1
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    • pp.1-6
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    • 2014
  • Flip chip bonded LED packages possess lower thermal resistance than wire bonded LED packages because of short thermal path. In this study, thermal and bonding properties of flip chip bonded high brightness LED were evaluated for Au-Sn thermo-compression bonded LEDs and Sn-Ag-Cu reflow bonded LEDs. For the Au-Sn thermo-compression bonding, bonding pressure and bonding temperature were 50 N and 300oC, respectively. For the SAC solder reflow bonding, peak temperature was $255^{\circ}C$ for 30 sec. The shear strength of the Au-Sn thermo-compression joint was $3508.5gf/mm^2$ and that of the SAC reflow joint was 5798.5 gf/mm. After the shear test, the fracture occurred at the isolation layer in the LED chip for both Au-Sn and SAC joints. Thermal resistance of Au-Sn sample was lower than that of SAC bonded sample due to the void formation in the SAC solder.

Degradation Evaluation of Mechanical Properties for 12Cr Ferrite Heat Resisting Steel by Reversible Permeability (가역투자율에 의한 12Cr 페라이트 내열강의 역학적 물성의 열화평가)

  • Ryu, Kwon-Sang;Kim, Min-Gi;Nahm, Seung-Hoon;Kim, Chung-Seok
    • Journal of the Korean Society for Nondestructive Testing
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    • v.30 no.5
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    • pp.464-470
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    • 2010
  • The integrity of the industrial equipment in use under high temperature and high pressure must be assessed by regularly measuring the degraded mechanical properties during service time. In order to nondestructively monitor the degraded mechanical properties of industrial equipment, a measuring method of the reversible permeability(RP) using surface type probe is presented. The method for measuring the RP is based on that RP is the differential value of hysteresis loop. The RP is exactly the foundation hatmonics induced in a detecting coil measured by lock-in amplifier tuned to a frequency of the alternating perturbing magnetic field. The peak of RP is measured around the coercive force. Steel material used in this work was 12Cr ferritic heat resisting steel. The eleven kinds of samples aged during different times under same temperature ($700^{\circ}C$) were prepared. Peak interval of reversible permeability(PIRP), Vickers hardness, and tensile strength measured for the aged samples decreased abruptly for short aging time (below 500 h), but the change became small at a long aging time. Vickers hardness and tensile strength linearly decreased as RIRP decreased, so the degraded mechanical properties of 12Cr ferritic heat resisting steel could be nondestructively evaluated by measuring RIRP.

Unresolving Pneumonia (치료에 대한 반응이 없는 폐렴)

  • Bang, Do Seok;Jung, In Sung;Kang, Ki Man;Park, Bum Chul;Yoon, Young Gul;Kim, Jae Su;Park, Yol;Lee, Sung Hoon;Hong, Young Chul;Ko, Kyoung Tae;Park, Sang Min;Na, Dong Jib
    • Tuberculosis and Respiratory Diseases
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    • v.57 no.6
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    • pp.604-608
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    • 2004
  • A 47-year-old-man was admitted to the emergency department with dyspnea, right pleuritic pain, and high fevers for 3 days. He had a nonproductive cough that exacerbated the chest pain. A clinical examination revealed distressed and slightly tachypneic patient, with blood pressure of 110/90 mmHg, temperature of $39^{\circ}C$, pulse of 90 beats/min, respiratory rate of 24 breaths/min. A chest examination showed significantly diminished breath sounds in the right lung with dullness to percussion. Laboratory investigation demonstrated leukocytosis and a raised C-reactive protein. The results of arterial blood gas analysis revealed moderate hypoxemia. A radiograph and a CT scan of the chest showed extensive consolidation with multifocal low densities, and pleural effusion in the right lung. A diagnostic thoracentesis revealed straw-colored fluid, which was found to be a neutrophil-predominant exudate. At 7 days after admission, the clinical symptoms had not improved and the temperature was still $39^{\circ}C$ despite the aggressive therapy of community-acquired pneumonia. After comprehensive history taking, we realized then that he accidentally aspirated kerosene while siphoning from fuel tank to put into the boiler 3 days ago. Bronchoscopy with bronchial washings could be successful in establishing the diagnosis of hydrocarbon pneumonitis by demonstration of a high lipid-laden macrophage index. Thereafter, the symptoms and radiographic opacities gradually improved, and he was discharged several days later.

Influence of Land Use and Meteorological Factors for Evapotranspiration Estimation in the Coastal Urban Area (해안도시 지역에서 증발산량 산정에 토지이용도와 기상인자의 영향성)

  • Yang, Sung-Il;Kang, Dong-Hwan;Kwon, Byung-Hyuk;Kim, Byung-Woo
    • Journal of Environmental Science International
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    • v.19 no.3
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    • pp.295-304
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    • 2010
  • Actual evapotranspiration (AET) in the Suyeong-gu was estimated and correlations between AET and meteorological factors were analyzed. The study area was Suyeong-gu lay at the east longitude $129^{\circ}$ 05' 40" ~ 129$^{\circ}$ 08' 08" and north latitude $35^{\circ}$ 07' 59" ~ $35^{\circ}$ 11' 01". The Kumryun mountain, the Bae mountain, the Suyeong river and the Suyeong bay are located on west, north, northeaster and south side in the study area, respectively. AET was estimated using precipitation (P), potential evapotranspiration (PET) and plant-available water coefficient. Meteorological factors to estimate PET were air temperature, dewpoint temperature, atmospheric pressure, duration of sunshine and mean wind speed (MWS). PET and AET were estimated by a method of Allen et al. (1998) and Zhang et al. (2001), respectively. PET was the highest value (564.45 mm/yr) in 2002 year, while it was the lowest value (449.95 mm/yr) in 2003 year. AET was estimated highest value (554.14 mm/yr) in 2002 year and lowest value (427.91 mm/yr) in 2003 year. Variations of PET and AET were similar. The linear regression function of AET as PET using monthly data was AET=0.87$\times$PET+3.52 and coefficient of determination was high, 0.75. In order to analyze relationship between the evapotranspiration and meteorological factors, correlation analysis using monthly data were accomplished. Correlation coefficient of AET-PET was 0.96 high, but they of AET-P and PET-P were very low. Correlation coefficients of AET-MWS and PET-MWS were 0.67 and 0.73, respectively. Thus, correlation between evapotranspiration and MWS was the highest among meteorological factors in Suyong-gu. This means that meteorological factor to powerfully effect for the variation of evapotranspiration was MWS. The linear regression function of AET as MWS was AET=84.73$\times$MWS+223.05 and coefficient of determination was 0.54. The linear regression function of PET as MWS was PET=83.83$\times$MWS+203.62 and coefficient of determination was 0.45.

Characterization of Water-Filled Ag/AgCl Reference Electrode

  • Bahn Chi Bum;Oh Sihyoung;Hwang Il Soon;Chung Hahn Sup;Jegarl Sung
    • Journal of the Korean Electrochemical Society
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    • v.4 no.3
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    • pp.87-93
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    • 2001
  • Pressure-balanced external Ag/AgCl electrode has been extensively used for both Pressurized Water Reactor (PWR) and Boiling Water Reactor (PWR) environments. The use of KCI-based buffer solution often becomes the source of electrode potential drift due to slow leakage through its porous plug, typically made of zirconia. It is reported that results of our effort to improve the stability of electrode potential by using high purity water as the filling solution in which $Cl^-$ ion activity can be established and maintained at the solubility of AgCl even with the sustained leakage for a long period. Stability tests have been made in boron and lithium mixture solution at $288^{\circ}C$. The electrode potential remained stable within 10 mV over one week period. And after a thermal cycle between 288 to $240^{\circ}C$ the potential shift of Ag/AgCl electrodes did not exceed 15 mV By using the limiting equivalent ionic conductances and Agar's hydrodynamic theory, the thermal liquid junction potential (TLJP) of the electrode has been predicted. The calculated values for the water-fiued Ag/AgCl electrode potential, in which the chlorine concentration in the filling solution was derived from the measured data at ambient temperature, had a good agreement with the experimental values.

Comparison of Characteristics of Local Meteorological and Particulate Matter(TSP) on the Beopjusa Temple and Seonamsa Temple (법주사와 선암사의 국지 기상 및 미세먼지 특성 비교)

  • Kim, Myoung Nam;Lim, Bo A;Lee, Myeong Seong;Jeong, So Young
    • Journal of Conservation Science
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    • v.33 no.4
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    • pp.283-295
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    • 2017
  • It is crucial to measure meteorological elements in relation to the biodeterioration of building cultural heritages. The Beopjusa and Seonamsa temples located respectively in Chungbuk and Jeonnam provinces, Korea, exhibit biological damage to the building cultural heritages and cause noticeable climatic differences. To compare biodeterioration environments of the abovementioned temples, 10 meteorological elements were observed, and particulate matter (TSP) was collected at each location. Furthermore, a correlation analysis was conducted between meteorological elements, and between meteorological elements and TSP. The local meteorology at Beopjusa temple characteristically showcased high total horizontal radiation, UV radiation, evaporation, wind speed, and TSP concentration, whereas, that at Seonamsa temple showcased high temperature, humidity, dew point temperature, air pressure, precipitation and number of days with precipitation. An elemental analysis of TSP revealed the presence of sae-salts at Seonamsa temple, and compared to that of Beopjusa temple, the monthly frequencies of biogenic aerosol and Fe-containing particles were higher. The correlation analysis showed that wind speed and humidity were major meteorological factors at Beopjusa and Seonamsa temples, respectively. Subsequently, the characteristics of the local meteorology at Seonamsa temple are expected to affect the biological damage of the building cultural heritages, which is favorable for the growth of various organisms.