• Title/Summary/Keyword: high temperature high pressure

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Temperature-Pressure Estimation of Metasediments in Seosan Area (서산지역의 변성퇴적암류에 대한 온도-압력 추정)

  • Song, Yungoo;Moon, Hi-Soo;Lee, Han Yeang
    • Economic and Environmental Geology
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    • v.22 no.4
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    • pp.371-379
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    • 1989
  • Peak or near-peak metamorphic temperatures and pressures for Seosan area could be estimated from major element method. Temperatures calculated from garnet-biotite geothermoneter(Ferry and Spear, 1978; Ganguly and Saxena, 1984) are $620{\pm}40^{\circ}C$ and $520{\pm}20^{\circ}C$ for Seosan and Daesan Formation respectively. Presures derived from garnet-plagiciase-$Al_2Si_O_2$-quartz geobarometer(Newton and Haselton, 1981; Ganguly and Saxena, 1984)suggest 5-6kb for both of Seosan and Daesan Formation. These results suggest that under isobaric, Seosan Formation underwent relatively high temperature metamorphism compared with Daesan Formation. Chemical zonations of garnet for major elements such as Fe, Mg, and Mn in Seosan and Dasan Formation show different patterns each other probably caused by different thermal history.

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Activity and Selectivity in Low Temperature for Dibenzothiophene Hydrodesulfurization based Zeolite Support (제올라이트 담체상의 디벤조티오펜 수첨탈황반응에서 저온활성 및 선택성)

  • Kim, Moon-Chan
    • Applied Chemistry for Engineering
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    • v.9 no.1
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    • pp.101-106
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    • 1998
  • Two types of CoMo/zeolite as well as $NiMo/{\gamma}-Al_2O_3$ were prepared and their activities and selectivities of low-temperature dibenzothiophene(DBT) hydrodesulfurization(HDS) were studied in high pressure fixed bed reactor. The HDS activities of CoMo/zeolites were higher than that of $NiMo/{\gamma}-Al_2O_3$ at temperatures below $225^{\circ}C$ while they were lower than that of $NiMo/{\gamma}-Al_2O_3$ at temperatures higher than $275^{\circ}C$. The main products from $NiMo/{\gamma}-Al_2O_3$ were biphenyl and cyclohexylbenzene. The product distribution of CoMo/zeolite catalysts was different from that of $NiMo/{\gamma}-Al_2O_3$. It is speculated that DBT is converted to alkylcyclohexane over zeolite based catalysts through both alkylation and hydrogenation reactions. The crystal structure of molybdenum was $MoO_3$ in fresh zeolite support while mixtures of $MoO_3$ and $MoS_2$ were observed in the aged catalyst.

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Redrying Fire - Retardant - Treated Structural Plywood (구조용(構造用) 내화처리(耐火處理) 합판(合板)의 재건조(再乾燥)에 관(關)한 연구(硏究))

  • Lee, Phil-Woo;Schaffer, E.L.
    • Journal of the Korean Wood Science and Technology
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    • v.9 no.4
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    • pp.1-21
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    • 1981
  • Exterior grades of Douglas-fir and aspen plywood were impregnated with interior fire-retardant chemicals and redried under low-, intermediate-, and high-temperature drying conditions. Fire-retardant treatments included borax-boric acid, chromated zinc chloride, minalith, pyresote, and a commercial formulation. Drying processes included kiln and press-drying. Evaluated were drying rates and defects generated. The borax-boric acid and the commercial treatments redried at rates similar to water-treated controls. Other salt treatments were significantly slower drying and more defect prone. Chromated zinc chloride treatment was consistently the slowest drying and most defect prone. Press drying was three times faster at an equivalent temperature level. However, thickness shrinkage doubled because of 50 1b/in. platen pressure.

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A Change of Z-directional Structure in Multi-ply Sheet by Calendering (캘린더 처리에 의한 다층지의 두께방향 구조 특성 변화)

  • Youn, Hye-Jung;Lee, Hak-Lae;Chin, Seong-Min;Jung, Hyun-Do
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.37 no.3
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    • pp.23-32
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    • 2005
  • A change of z-directional structural and surface properties by calendering has a great influence on liquid penetration into a sheet. It could be also important for multi-ply sheet because it contacts liquid dunhg coating or converting process. Therefore, this study was aimed to evaluate of a change of z-directional structure in multi-ply sheet by calendering. To do this, multi-ply sheets were prepared with various raw materials and calendered at the different pressure and temperature conditions. In multi-ply sheet which consisted of one kind of pulp fiber, thickness reductions were higher in top and bottom plies than in middle plies. And in the case of soft nip calender treatment with high temperature, top layer which was in contact with heating roll showed the highest reduction of thickness. Hard nip calender treatment showed U-shaped density profile in z-direction, but compression profile by SNC treatment was dependent on calendering condition. To examine z-directional structure of multi-ply sheet which was composed of different raw material for each layer, CLSM (Confocal Laser Scanning Microscopy) analyses were carried out on cross direction of sheet. It turned out to be a useful tool for investigating z-directional analysis. As a result, variation of thickness reduction in z-direction is dependent on ply structure, compressibility of pulp fiber, and calendering condition.

Numerical Analysis of Combustion and Heat Transfer of Domestic Gas Boiler Equipped with 2-stage Heat Exchanger (수치해법을 이용한 2단 열교환기 장착 가정용 보일러 연소실의 연소 및 열전달 특성 해석)

  • Kang, Seung-Kyu;Choi, Kyoung-Suhk;Kwon, Jeong-Rack
    • Journal of the Korean Institute of Gas
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    • v.14 no.5
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    • pp.1-6
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    • 2010
  • In this work, a numerical investigation is performed for the combustion chamber of domestic gas boiler with 1-stage and 2-stage heat exchangers. The fluid flow and heat transfer performance is simulated with a structure change of heat exchanger. The numerical solution shows that the heat transfer of the 2-stage heat exchanger is about 24% higher than that of the 1-stage heat exchanger, while the pressure loss of the 2-stage heat exchanger increases. The temperature of combustion chamber with 2-stage heat exchanger is lower than that of 1-stage. This effect reduces thermal NOx with decrease of high temperature staying time of the combustion gas.

Assesment of pCO2 in the Yellow and East China Sea Using an Earth System Model (지구시스템모형을 이용한 황동중국해 이산화탄소분압 분포 특성 평가)

  • Park, Young-Gyu;Choi, Sang-Hwa;Kim, Cheol-Ho
    • Ocean and Polar Research
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    • v.33 no.4
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    • pp.447-455
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    • 2011
  • Using results from an earth system model, the distribution of partial pressure of $CO_2$ ($pCO_2$) in surface seawater over the East China Sea is investigated. In this area $pCO_2$ shows minimum along the edge of the continental break along the path of the Taiwan-Tsushima Current System. Apparently modelled chlorophyll is also great along the current but the maximum of the chlorophyll and the minimum of $pCO_2$ do not coincide suggesting that the primary production is not the main cause of the $pCO_2$ minimum. As we move toward the Yellow Sea from the Kuroshio area the temperature decreases so that the $pCO_2$ becomes smaller. If we move further toward the Yellow Sea beyond the Taiwan-Tsushima Current System, alkalinity starts to drop substantially to intensify $pCO_2$ while overcoming the effect of decreasing temperature and salinity. Thus $pCO_2$ minimum occurs along the Taiwan-Tsushima Current System. Of course, the primary production lower $pCO_2$ during spring when it is high but the effect is local. Near the Yangtze river mouth and northeastern corner of the Yellow Sea the fresh water input is large enough and dissolved inorganic carbon (DIC) becomes low enough so that $pCO_2$ becomes lower again.

Preparation of GdBCO Thin Film by Ex-situ Process using Nitrate Precursors (질산염 전구체 원료로 Ex-situ 공정에 의한 GdBCO 박막 제조)

  • Kim, Byeong-Joo;Lee, Chul-Sun;Lee, Jong-Beom;Lee, Jae-Hun;Moon, Seung-Hyun;Lee, Hee-Gyoun;Hong, Gye-Won
    • Progress in Superconductivity
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    • v.13 no.2
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    • pp.127-132
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    • 2011
  • Many research groups have been manufacturing coated conductor by various processes such as PLD, MOD, and MOCVD, but the methods with production cost suitable for wide and massive application of coated conductor did not develop yet. Spray pyrolysis method adopting ultrasonic atomization was tried as one of the possible option. GdBCO precursor films have been deposited on IBAD substrate by spray pyrolysis method at low temperature and converted to GdBCO by post heat treatment. Ultrasonic atomization was used to generate fine droplets from precursor solution of Gd, Ba, and Cu nitrate dissolved in water. Primary GdBCO films were deposited at $500^{\circ}C$ and oxygen partial pressure of 1 torr. After that, the films were converted at various temperatures and low oxygen partial pressures. C-Axis oriented films were obtained IBAD substrates at conversion temperature of around $870^{\circ}C$ and oxygen partial pressures of 500 mtorr ~ 1 torr in a vacuum. Thick c-axis epitaxial film with the thickness of 0.4 ~ 0.5 ${\mu}m$ was obtained on IBAD substrate. C-axis epitaxial GdBCO films were successfully prepared by ex-situ methods using nitrate precursors on IBAD metal substrate. Converted GdBCO films have very dense microstructures with good grain connectivity. EDS composition analysis of the film showed a number of Cu-rich phase in surface. The precursor solution having high copper concent with the composition of Gd : Ba : Cu = 1 : 2 : 4 showed the better grain connectivity and electrical conductivity.

Performance Evaluation of a $CO_2$ Heat Pump System for Fuel Cell Vehicles (연료전지 자동차용 이산화탄소 열펌프 시스템의 성능평가)

  • Kim, Sung-Chul;Park, Jong-Chul;Kim, Min-Soo;Won, Jong-Phil
    • Transactions of the Korean Society of Automotive Engineers
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    • v.16 no.1
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    • pp.37-44
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    • 2008
  • The global warming potential (GWP) of $CO_2$ refrigerant is 1/1300 times lower than that of R134a. Furthermore, the size and weight of the automotive heat pump system can decrease because $CO_2$ operates at high pressure with significantly higher discharge temperature and larger temperature change. The presented $CO_2$ heat pump system was designed for both cooling and heating in fuel cell vehicles. In this study, the performance characteristics of the heat pump system were analyzed for heating, and results for performance were provided for operating conditions when using recovered heat from the stack coolant. The performance of the heat pump system with heater core was compared with that of the conventional heating system with heater core and that of the heat pump system without heater core, and thus the heat pump system with heater core showed the best performance among the selected heating systems. On the other hand, the heating performance of two different types of coolant/air heat pump systems with heater core was compared each other at various coolant inlet temperatures. Furthermore, to use exhausted thermal energy through the radiator, experiments were carried out by changing the arrangement of a radiator and an outdoor evaporator, and quantified the heating effectiveness.

Thermo-responsive antifouling study of commercial PolyCera® membranes for POME treatment

  • Haan, Teow Yeit;Chean, Loh Wei;Mohammad, Abdul Wahab
    • Membrane and Water Treatment
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    • v.11 no.2
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    • pp.97-109
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    • 2020
  • Membrane fouling is the main drawback of membrane technology. Frequent membrane cleaning and membrane replacement are, therefore, required to reduce membrane fouling that causes permeate flux reduction, lower rejection, or higher operating pressure. Studies have proved that the alteration of membrane properties is the key controlling factor in lessening membrane fouling. Among stimuli-responsive membranes, thermo-responsive membrane is the most popular, with a drastic phase transition and swelling-shrinking behavior caused by the temperature change. In this study, the thermo-responsive ability of two commercial membranes, PolyCera® Titan membrane and PolyCera® Hydro membrane, at different temperatures was studied on the antifouling function of the membrane in palm oil mill effluent (POME) treatment. The evaluation of the membrane's thermo-responsive ability was done through three cycles of adsorption (fouling) and desorption (defouling) processes in a membrane filtration process. The experimental result depicted that PolyCera® Hydro membrane had a higher membrane permeability of 67.869 L/㎡.h.bar than PolyCera® Titan membrane at 46.011 L/㎡.h.bar. However, the high membrane permeability of PolyCera® Hydro membrane was compensated with low removal efficiency. PolyCera® Titan membrane with a smaller mean pore size had better rejection performance than PolyCera® Hydro membrane for all tested parameters. On the other hand, PolyCera® Titan membrane had a better hydrodynamic cleaning efficiency than PolyCera® Hydro membrane regardless of the hydrodynamic cleaning temperature. The best hydrodynamic cleaning performed by PolyCera® Titan membrane was at 35℃ with the flux recovery ratio (FRR) of 99.17 ± 1.43%. The excellent thermo-responsive properties of the PolyCera® Titan membrane could eventually reduce the frequency of membrane replacement and lessen the use of chemicals for membrane cleaning. This outstanding exploration helps to provide a solution to the chemical industry and membrane technology bottleneck, which is the membrane fouling, thus reducing the operating cost incurred by the membrane fouling.

Study of Hydrolysis of Al Powder and Compaction of Nano Alumina by Spark Plasma Sintering(SPS) (Al 분말의 수화 반응과 스파크 플라즈마 열처리법으로 제조된 알루미나 성형체 연구)

  • Uhm Y. R.;Lee M. K.;Rhee C. K.
    • Journal of Powder Materials
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    • v.12 no.6 s.53
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    • pp.422-427
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    • 2005
  • The $Al_2O_3$ with various phases were prepared by simple ex-situ hydrolysis and spark plasma sintering (SPS) process of Al powder. The nano bayerite $(\beta-Al(OH)_3)$ phase was derived by hydrolysis of commercial powder of Al with micrometer size, whereas the bohemite (AlO(OH)) phase was obtained by hydrolysis of nano Al powder synthesized by pulsed wire evaporation (PWE) method. Compaction as well as dehydration of both nano bayerite and bohemite was carried out simultaneously by SPS method, which is used to fabricate dense powder compacts with a rapid heating rate of $100^{\circ}C$ per min. under the pressure of 50MPa. After compaction treatment in the temperature ranges from $100^{\circ}C\;to\; 1100^{\circ}C$, the bayerite and bohemite phases change into various alumina phases depending on the compaction temperatures. The bayerite shows phase transition of $Al(OH)_3{\to}{\eta}-Al_2O_3{\to}{\theta}-Al_2O_3{\to}\alpha-Al_2O_3$ sequences. On the other hand, the bohemite experiences the phase transition from AlO(OH) to ${\gamma}-Al_2O_3\;at\;350^{\circ}C.$ It shows AlO(OH) ${\gamma}-Al_2O_3{\to}{\delta}-Al_2O_3{\to}{\alpha}-Al_2O_3$ sequences. The ${\gamma}-Al_2O_3$ compacted at $550^{\circ}C$ shows a high surface area $(138m^2/g)$.