• Title/Summary/Keyword: high temperature high pressure

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Changes in Carotenoid Pigments of Oleoresin Red Pepper during Cooking (고추 Oleoresin 의 가열조리중 Carotenoid 색소의 변화)

  • 최옥수;하봉석
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.23 no.2
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    • pp.225-231
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    • 1994
  • As the way of mass process of red pepper, extraction of oleoresin, which is labile during distribtuion and long-term storage, is alternative way to minimize markdown of red pepper quality. Changes of carotenoid pigments in modified oleoresin during cooking at high temperature were investigated. Dried red peperwas milled to 100 mesh of size particle and oily compounds were extracted by reduced pressure steam distillation. The rest part was reetracted and concentrated. The extracts were combined . The same volume of water and 4 % of polyglycerol condensed ricinoleate (PGDR) were added to the combined extract, and emulsified to make oleroesin. Capsanthin among dried red pepper, was the most abundant carotenoid (97.80mg%) followed by $\beta$ -cartoene, cryptoxanghin ,violaxanthin, crypotocapsin, and capsorubin. Oleoresin is acquiesce in the same order of raw red pepper. Transmittal of color components from raw red pepper to oleroresin was over 85% in cryptoxanthin, crytocapsin, and $\beta$ -carotene, over 70% in capsolutein and hydroxycapsolutein, and under 50% in antheraxanthin and mutatoxanthi Crytocapsin cryptoxanthin, an capsorubin in oleoresin red pepper were remained 72.1, 51.8 and 25.25, respectively, after cooking for 5hours at10$0^{\circ}C$. Color compounds were unsteady by cooking , About 90% of color compounds were destroyed by 3 hours cooking at 15$0^{\circ}C$. But, they were more thermostable under nitrogen circumstance than air one.

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Analysis of Coal Fly Ash (석탄회의 분석)

  • 이효진;김동원;이기강;김유택;홍성창;이시진
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.3 no.2
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    • pp.185-201
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    • 1993
  • The objectives of this study are to identify the physical, chemical and microstructural properties of coal fly ash and to increase the industrial use of coal fly ash. Experimental results show that 3 major constituents of coal fly ash are $SiO_2$, $Al_2O_3$ and coal fly ash includes the crystalline of Quartz and Mullite. Coal fly ash are classified into 7 groups based on the type of microstructure. Cenosphere is divided into floater and dry separated cenosphere which are consist mainly of $SiO_2$ and $Al_2O_3$. Cenosphere segregations are formed by adsorption and neck growth of the smaller sized cenosphere particles on the condition of the high temperature and air pressure.

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Characterization of Linear Microwave Plasma using the Fluid Simulation (유체 시뮬레이션을 이용한 선형 마이크로웨이브 플라즈마의 특성 분석)

  • Seo, Kwon-Sang;Han, Moon-Ki;Kim, Dong-Hyun;Lee, Ho-Jun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.64 no.4
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    • pp.567-572
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    • 2015
  • Discharge characteristics of linear microwave plasma were investigated by using fluid simulation of 2D axis-symmetry based on finite elements method. The microwave power was 2.45 GHz TEM mode and transmitted through linear antenna. Resistive power and pressure were considered simulation variables and argon was used for working gas. A decrease of electron density along the quartz tube was observed in low power condition but relatively uniform plasmas were generated in chamber by increasing the resistive power. The electron temperature was highly detected near the surface of quartz tube because the electron was heated only dielectric surface. The power transmission efficiency decreased and characteristics of surface plasma were observed in high electron density condition.

A Study on Wet Etch Behavior of Zinc Oxide Semiconductor in Acid Solutions

  • Seo, Bo-Hyun;Lee, Sang-Hyuk;Jeon, Jea-Hong;Choe, Hee-Hwan;Lee, Kang-Woong;Lee, Yong-Uk;Seo, Jong-Hyun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.926-929
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    • 2007
  • A significant progress has been made in the characterization of zinc oxide (ZnO) semiconductor as a new semiconductor layer instead of amorphous Si semiconductor used in thin film transistor due to its high electron mobility at low deposition temperature which is quite suitable for flexible display and OLED devices. The wet pattering of ZnO is another important issue with regard to mass production of ZnO thin film transistor device. However, the wet behavior of ZnO thin film in aqueous wet etching solutions conventionally used un TFT industry has not been reported yet, in this work, wet corrosion behavior of RF magnetron sputtered ZnO thin film in various wet solutions such as phosphoric and nitric acid solutions was studied using by electrochemical analysis. The effects of deposition parameters such as RF power and oxygen partial pressure on corrosion rate are also examined.

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Recovery of Mg-Ferrite Powder from Acid Leaching Mg Waste by Hydrothermal Method (산 침출 Mg폐액으로부터 수열법에 의한 Mg-Ferrite 분말회수)

  • 김영순;윤기석;안찬영;이종현;원창환
    • Resources Recycling
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    • v.6 no.4
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    • pp.31-37
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    • 1997
  • The Mg-ferrite powders were recovered from acid leaching Mg waste by hydrothermal method. Recovering conditions ofMg-Ferrite were investigated m this system and the powders prepared were characterized, using X-ray analysis, chemicalanalysis, SEM. TEM, and VSM. In this study, pH of solution and the kind of neutralizer wcre important factors on thecharacteristics of the product. The optimum condition of recovering MgPenite was the mole ratio of Fe" : Mg"=2'1, reactiontemperature : ZOWC, reaction time.lhr, at pH=lZ, and Oi partial pressure af 2000 psi. And the powders ~ccovered have amonodispersed and spherelike shapes with the narrow sue distribulion.ow sue distribulion.

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Numerical Study on Operating Parameters and Shapes of a Steam Reformer for Hydrogen Production from Methane (천연가스로부터 수소를 생산하기 위한 수증기 개질기의 작동조건과 형상에 대한 수치해석 연구)

  • Park, Joong-Uen;Lee, Shin-Ku;Lim, Sung-Kwang;Bae, Joong-Myeon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.33 no.1
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    • pp.60-68
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    • 2009
  • The steam reformer for hydrogen production from methane is studied by a numerical method. Langmuir- Hinshelwood model is incorporated for catalytic surface reactions, and the pseudo-homogeneous model is used to take into account local equilibrium phenomena between a catalyst and bulk gas. Dominant chemical reactions are Steam Reforming (SR) reaction, Water-Gas Shift (WGS) reaction, and Direct Steam Reforming (DSR) reaction. The numerical results are validated with experimental results at the same operating conditions. Using the validated code, parametric study has been numerically performed in view of the steam reformer performance. As increasing a wall temperature, the fuel conversion increases due to the high heat transfer rate. When Steam to Carbon Ratio (SCR) increases, the concentration of carbon monoxide decreases since WGS reaction becomes more active. When increasing Gas Hourly Space Velocity (GHSV), the fuel conversion decreases due to the heat transfer limitation and the low residence time. The reactor shape effects are also investigated. The length and radius of cylindrical reactors are changed at the same catalyst volume. The longer steam reformer is, the better steam reformer performs. However, system energy efficiency decreases due to the large pressure drop.

A Study on the Non-linear Surface Reaction Model for the GaAs Film Growth During MOCVD Process (MOCVD공정을 이용한 GaAs박막성장의 비선형 표면반응모델에 대한 연구)

  • Im, Ik-Tae
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.32 no.3
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    • pp.181-189
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    • 2008
  • GaAs film growth process from trimethylgallium(TMGa) and tertiary-butylarsine(TBAs) using a horizontal MOCVD reactor was numerically studied to explain the experimental result that the decreasing surface reaction rate as the increasing partial pressure of group III species. Using the non-linear model based on the Langmuir isotherm which considers the adsorption and desorption of molecules, film deposition over the entire reactor scale was predicted by computational fluid dynamics (CFD) with the aid of the parameters obtained from the selective area growth (SAG) technique. CFD Results using the non-linear surface reaction model with the parameters determined from the SAG experiments predicted too high film growth rate compared to the measured values at the downstream region where the temperature was decreased abruptly. The pairs of ($k_s^n$, K) from the numerical simulations was $(2.52{\times}10K^{-6}mol/m^2/s,\;1.6{\times}10^5m^3/mol)$, whereas the experimentally determined was $(3.58{\times}10^{-5}mol/m^2/s,\;6.9{\times}10^5m^3/mol)$.

Fabrication of Nano Master with Anti-reflective Surface Using Aluminum Anodizing Process (양극산화공정을 이용한 반사방지 성형용 나노 마스터 개발)

  • Shin, H.;Park, Y.;Seo, Y.;Kim, B.
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.18 no.6
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    • pp.697-701
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    • 2009
  • A simple method for the fabrication of porous nano-master for the anti-reflection effect on the transparent substrates is presented. In the conventional fabrication methods for antireflective surface, coating method using materials with low refractive index has usually been used. However, it is required to have a high cost and long processing time for mass production. In this paper, we developed a porous nano-master with anti-reflective surface for the molding stamper of the injection mold, hot embossing and UV imprinting by using the aluminum anodizing process. Through two-step anodizing and etching processes, a porous nano-master with anti-reflective surface was fabricated at the large area. Pattern size Pore diameter and inter-pore distance are about 130nm and 200nm, respectively. In order to replicate anti-reflective structure, hot embossing process was performed by varying the processing parameters such as temperature, pressure and embossing time etc. Finally, antireflective surface can be successfully obtained after etching process to remove selectively silicon layer of AAO master.

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Biochemical and NMR Characterization of MTH1880 Mutant Proteins for Folding-Unfolding Studies

  • Kim, Hee-Youn;Ryu, Soo-Young;Yun, Ji-Hye;Kim, Suhk-Mann;Chang, Ik-Soo;Lee, Weon-Tae
    • Bulletin of the Korean Chemical Society
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    • v.31 no.12
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    • pp.3521-3524
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    • 2010
  • MTH1880 is a hypothetical protein derived from Methanobacterium thermoautotrophicum, thermophilic methanogen. The solution structure determined by NMR spectroscopy showed that it has a novel $\alpha+\beta$-fold with a highly acidic ligand binding pocket. Since MTH1880 maintains its ultra-stable structural characteristics at both high temperature and pressure, it has been considered as an excellent model for studying protein folding. To initiate the structural and folding study of MTH1880 in proving its unusual stability, we performed the site directed mutagenesis and biochemical analysis of MTH1880 mutants. Data from circular dichroism and NMR spectroscopy suggest that the point mutations perturbed the structural stability of protein even though the secondary structure is retained. This study will provide the useful information in understanding the role of participating residues during folding-unfolding process and our result will be used in designing further folding experiments for hyper-thermopile proteins like MTH1880.

Analysis of Joints Using Metal Seals in Liquid Rocket Engine Turbopump (액체로켓엔진 터보펌프의 금속 실 체결부 해석)

  • Yoon, Suk-Hwan;Jeon, Seong Min;Kim, Jinhan
    • Journal of the Korean Society of Propulsion Engineers
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    • v.17 no.6
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    • pp.105-112
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    • 2013
  • Turbopump is typically an assembly of rotors and casings, and there are a number of joints between them. Every joint should be leak-proof, so there is always a seal to accomplish the goal. Among various seals, metal seals are advantageous in that they are robust at high pressure, and at wide range of temperature. In this study, flange joints using conical seal made of stainless steel, solid flat metal seal made of copper and metal C seal made of Inconel 718 were structurally designed and analyzed, considering both initial tightening and operating conditions.