• Journal of Hydrogen and New Energy
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• v.13 no.2
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• pp.119-126
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• 2002

The methanol partial oxidation using commercial $CuO/ZnO/Al_2O_3$ catalysts in a plug flow reactor was studied in the temperature range of $200{\sim}250^{\circ}C$ at atmospheric pressure, It was achieved the high activities by Cu-based catalysts and the selectivity of $CO_2$/$H_2$ was 100% when $O_2$ was fully convened. The reactivity changes and their hysteresis with increasing/decreasing temperatures were observed due to the chemical state differences between the oxidation and the reduction on the Cu surface, It was suggested as the two-step reaction: the complete oxidation and the following steam reforming for methanol, which was indicated by the distributions of final products vs. the residence time. In addition, the complete oxidation step was shown to be extremely fast and the total reaction rate can be controlled by the steam reforming reaction.

• Journal of Hydrogen and New Energy
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• v.19 no.4
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• pp.359-366
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• 2008

Hydrogen as a high-quality and clean energy carrier has attracted renewed and ever-increasing attention around the world in recent years, mainly due to developments in fuel cells and environmental pressures including climate change issues. In this processes for hydrogen production from fossil fuels, separation and purification is a critical technology. $(Ni_{60}-Nb_{40})_{95}-Pd_5$ alloy ingots were prepared by arc-melting the mixture of pure metals in an Ar atmosphere. Melt-spun ribbons were produced by the single-roller melt-spinning technique in an Ar atmosphere. Amorphous structure and thermal behavior were characterized by XRD and DSC. The permeability of the $(Ni_{60}-Nb_{40})_{95}-Pd_5$ amorphous alloy membrane was characterized by hydrogen permeation experiments in the temperature range 623 to 773 K and pressure of 2 bars. The maximum hydrogen permeability was $3.54{\times}10^{-9}[mol{\cdot}m^{-1}s^{-1}{\cdot}pa^{-1/2}]$ at 773 K for the $(Ni_{60}-Nb_{40})_{95}-Pd_5$ amorphous alloy.

• Culinary science and hospitality research
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• v.14 no.3
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• pp.16-30
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• 2008

Rapid change of surroundings has been influencing the work environment for cooks, making it more convenient; however, there are still many difficulties to improve. Especially, cooks are exposed to lots of occupational diseases due to tension and pressure as well as noise, high temperature and humidity in their work place. This study examines cooks' operational exhaustion caused by cooking operation and cooking circumstances. The analyzed result shows the job fatigue related to the general features of the cooks(such as charged cooking part, types of engaged business, class of position, cooking career, and working hours). For example, pains on the neck, back, arms and wrist are mostly affected by the charged cooking parts. Effects related to the types of engaged business, backaches usually occurred in Catering, pains in shoulder from serving at hotels and eye-tiredness from meal serving. As for working hours, most of backaches occurred from over 13-hour-work, and pains in shoulder and eye-tiredness under 8-hour-work. Pains in legs, tiredness, and the change of weight do not have any relations withthe general features of the cooks statistically(p>0.05).

• Journal of the Korean Ceramic Society
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• v.42 no.4
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• pp.219-223
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• 2005

A promising capacitor, which has conformable step coverage and good uniformity of thickness and composition, is needed to manufacture high-density non-volatile FeRAM capacitors with a stacked cell structure. In this study, ferroelectric $Bi_{3.61}Nd_{0.39}Ti_3O_{12}$ (BNdT) thin films were prepared on $Pt(111)/TiO_2/SiO_2/Si$ substrates by the liquid delivery system MOCVD method. In these experiments, $Bi(ph)_{3}$, $Nd(TMHD)\_{3}$ and $Ti(O^iPr)_{2}(TMHD)_{2}$ were used as the precursors and were dissolved in n-butyl acetate. The BNdT thin films were deposited at a substrate temperature and reactor pressure of approximately $600^{\circ}C$ and 4.8 Torr, respectively. The microstructure of the layered perovskite phase was observed by XRD and SEM. The remanent polarization value (2Pr) of the BNdT thin film was $31.67\;{\mu}C/cm^{2}$ at an applied voltage of 5 V.

• Ceramist
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• v.22 no.1
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• pp.56-69
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• 2019

Recent advances in low-power sensors and transmitters are driving the search for standalone power sources that utilize unused ambient energy. These energy harvesters can alleviate the issues related to the installation and maintenance of sensors. Particularly piezoelectric energy harvesters, with the ability to convert ambient mechanical energy into useful electricity, have received significant attention due to their high energy density, low cost and operational stability over wide temperature and pressure conditions. In order to maximize the generated electrical power, the natural frequency of the piezoelectric energy harvester should be matched with the dominant frequency of ambient vibrations. However, piezoelectric energy harvesters typically exhibit a narrow bandwidth, thus, it becomes difficult to operate near resonance under broadband ambient vibration conditions. Therefore, the resonating of energy harvesters is critical to generate maximum output power under ambient vibration conditions. For this, energy harvesters should have broadband natural frequency or actively tunable natural frequency with ambient vibrations. Here, we review the most plausible broadband energy harvesting techniques of the multi-resonance, nonlinearity, and self-resonance tuning. The operation mechanisms and recent representative studies of each technique are introduced and the advantages and disadvantages of each method are discussed. In addition, we look into the future research direction for the broadband energy harvester.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.18 no.11
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• pp.996-1000
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• 2005

Experimental results are presented for the degradation of 3 nm-thick gate oxide $(SiO_2)$ under both Negative-bias Temperature Instability (NBTI) and Hot-carrier-induced (HCI) stresses using P and NMOSFETS, The devices are annealed with hydrogen or deuterium gas at high-pressure $(1\~5\;atm.)$ to introduce higher concentration in the gate oxide. Both interface trap and oxide bulk trap are found to dominate the reliability of gate oxide during electrical stress. The degradation mechanism depends on the condition of electrical stress that could change the location of damage area in the gate oxide. It was found the trap generation in the gate oxide film is mainly related to the breakage of Si-H bonds in the interface or the bulk area. We suggest that deuterium bonds in $SiO_2$ film are effective in suppressing the generation of traps related to the energetic hot carriers.

• Proceedings of the KIEE Conference
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• 1997.07d
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• pp.1352-1354
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• 1997

Transparent conductive thin films have found many application in many active and passive electronic and opto-electronic devices as like flat Panel display electrode and window heat mirror, etc. Low resistivity and high transmittance of this films can be obtained by controlling deposition parameters, which are oxygen partial Pressure, substrate temperature and dopant concentration. In this study, We prepared non-stoichiometric and Sb-doped thin films of tin dioxide by reactive DC magnetron sputtering technology. The lowest resistivity of about $3.0{\times}10^{-3}\;{\Omega}cm$ and 80% transmittance in the visible light region have heed obtained at optimal deposition condition.

• Nuclear Engineering and Technology
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• v.31 no.1
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• pp.17-28
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• 1999

A thermal-hydraulic analysis is conducted on the loss-of-coolant-accident (LOCA) during shutdown operation of YGN Units 3/4. Based on the review of plant-specific characteristics of YGN Units 3/4 in design and operation, a set of analysis cases is determined, and predicted by the RELAP5/MOD3.2 code during LOCA in the hot-standby mode. The evaluated thermal-hydraulic phenomena are blowdown, break flow, inventory distribution, natural circulation, and core thermal response. The difference in thermal-hydraulic behavior of LOCA at shutolown condition from that of LOCA at full power is identified as depressurization rate, the delay in peak natural circulation timing and the loop seal clearing (LSC) timing. In addition, the effect of high pressure safety injection (HPSI) on plant response is also evaluated. The break spectrum analysis shows that the critical break size can be between 1% to 2% of cold leg area, and that the available operator action time for the Sl actuation and the margin in the peak clad temperature (PCT) could be reduced when considering uncertainties of the present RELAP5 calculation.

• Nuclear Engineering and Technology
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• v.48 no.5
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• pp.1096-1108
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• 2016

Metal fuel is being developed for the prototype generation-IV sodium-cooled fast reactor (PGSFR) to be built by 2028. U-Zr fuel is a driver for the initial core of the PGSFR, and U-transuranics (TRU)-Zr fuel will gradually replace U-Zr fuel through its qualification in the PGSFR. Based on the vast worldwide experiences of U-Zr fuel, work on U-Zr fuel is focused on fuel design, fabrication of fuel components, and fuel verification tests. U-TRU-Zr fuel uses TRU recovered through pyroelectrochemical processing of spent PWR (pressurized water reactor) fuels, which contains highly radioactive minor actinides and chemically active lanthanide or rare earth elements as carryover impurities. An advanced fuel slug casting system, which can prevent vaporization of volatile elements through a control of the atmospheric pressure of the casting chamber and also deal with chemically active lanthanide elements using protective coatings in the casting crucible, was developed. Fuel cladding of the ferritic-martensitic steel FC92, which has higher mechanical strength at a high temperature than conventional HT9 cladding, was developed and fabricated, and is being irradiated in the fast reactor.

• Journal of the Korean Chemical Society
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• v.30 no.1
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• pp.105-108
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• 1986

Ultrasound(50KHz) accelerated the reduction reaction of aromatic nitro group to aromatic amino group in high yield with mild condition using iron, hydrazine hydrate and activated carbon under room temperature and atmospheric pressure. The activated carbon has been used as a mixing material to highly active metals. However, aromatic nitro group does not reduce at all only with iron-hydrazine witliout adding activated carbon even under ultrasonic irradiation. We also discovered that the conversion yield from nitro group to amino group is directly proportional to the amount of activated carbon.