• Journal of Hydrogen and New Energy
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• v.29 no.4
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• pp.393-400
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• 2018

To confirm the operating range of two oxygen carriers for chemical looping combustion system, the effects of operating variables on solid circulation rate were measured and discussed using a two-interconnected circulating fluidized bed system at ambient temperature and pressure. Moreover, suitable operating ranges to avoid choking of the fast fluidized bed (air reactor) were confirmed for two oxygen carriers. A continuous long-term operation of steady-state solid circulation more than 24 hours was also demonstrated within the operating windows. Finally we could confirm that those two oxygen carriers are suitable for chemical looping combustion system with high solid circulation rate and smooth solid circulation.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.11a
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• pp.77-78
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• 2008

ZnO thin films were deposited on glass substrates by pulsed laser deposition (PLD) at various oxygen pressures. We observed structural, electrical and optical properties of ZnO films. Structural properties were analysed by XRD and FE-SEM. Electrical properties for applications of transparent thin film transistors (TTFTs) were measured by hall measurement using van der pauw methods at room temperature. In order to apply in transparent devices, we measured transmittance, and optical bandgap energy was calculated by Tauc's equation. The results showed that ZnO films deposited at 200mTorr oxygen pressure were applicable to channel layers of transparent TFTs. It had high hall mobilities ($52.92cm^2$/V-s) and suitable transmittance at visible wavelength region (above 80%).

• Particle and aerosol research
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• v.12 no.3
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• pp.57-63
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• 2016

The laser-induced breakdown spectroscopy (LIBS) has been used for rapid detection of elemental compositions of various materials in multi-media (solid, liquid, gas, and aerosols). In this study, the aerosol-LIBS has been developed for real-time monitoring of process-induced particles produced during the semiconductor manufacturing. The developed aerosol-LIBS mainly consists of laser, optics, spectrometer, and aerosol chamber. A new aerosol chamber was constructed for the aerosol-LIBS to be applied for various semiconductor manufacturing process, including exhaust tubes, and low pressure and high temperature chamber. The aerosol-LIBS was evaluated by using laboratory generated aerosols for detection of various elements. As a result, P, Fe, Mg, Cu, Co, Ni, Ca, Na, and K emission lines were successfully detected by the aerosol-LIBS. Further evaluation of the aerosol-LIBS is being conducted.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.26 no.9
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• pp.1736-1745
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• 2002

The objective of this study is to predict the roll wear in hot rod rolling process. In this study hot rod rolling process for round and oval passes has been investigated. In order to predict the roll wear, the wear model is reformulated as an incremental form and then wear depth of roll is calculated at each deformation step on contact area using the results of finite element analysis, such as relative sliding velocity and normal pressure at contact area. Archard's wear model was applied to predict the roll wear. To know the thermal softening of DCI (Ductile Cast Iron) roll according to operating conditions, high temperature micro hardness test is executed and a new wear model has been proposed by considering the thermal softening of DCI roll expressed in terms of the main tempering parameter curve. 3D wear program developed in this study might be used for adjusting the gap of rolls to set up a suitable rolling schedule for keeping dimensional tolerance of the product.

• Proceedings of the KSME Conference
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• 2001.11b
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• pp.682-687
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• 2001

This study represents effect of exhaust performance by according to active muffler valve spring. The experimental parameter were divided engine speed and torsion coil spring constant. The sound pressure level was generally low at engine speed 2000-2500rpm but That was showed the lowest at spring constant k=0.75. Flow speed of exhaust gas was showed the fast at spring constant k=0.75 but the low value was showed at k=0.97. It was contained a rather low concentration of carbon monoxide(CO) at engine speed 2000-2500rpm and k=0.81, low concentration of hydrocarbon(HC) at spring constant k=0.81 but that was high at spring constant k=0.97. A conclusion based on FFT analysis was generally low concentration value at k=0.79 and k=0.81. The temperature distributions into the muffler was shown similar conditions. Heat transfer was well spreaded at thermocouple No.8 because valve was opened.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.24 no.5 s.176
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• pp.1331-1342
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• 2000

In power generation systems a variety of structural components typically operate at high temperature and pressure. Therefore a life assessment methodology accounting for gradual creep fracture is increasingly needed for these components. The most critical defects in such structure are generally found in the form of semi-elliptical surface cracks in the welded tubular joints. Therefore the analysis of a semi-elliptical surface crack in a plate or a shell is an important problem in engineering fracture mechanics. On this background, via shell/line-spring finite element analyses of such surface cracks in the welded T and L joints under various loadings, we investigate J-integral along the crack front We first develop T and L joints auto mesh generation program providing ABAQUS input file composed of shell/line-spring finite elements. We then further develop a T and L joints life assessment program based on the experimental creep crack growth law and auto mesh generation program in a graphical user interface format Finally the remaining life of T and L joints for various analytical parameters are assessed using the developed life assessment program.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 1997.10a
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• pp.1036-1041
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• 1997

The objective of this study is to adjust the roll gap for the dimension accuracy of bar in hot bar rolling process considering roll wear. In this study hot bar rolling processes for round and oval passes have been investigated. In order to predict the roll wear, the wear model is reformulated as an incremental form and then wear depth of roll is calculated at each deformation step on contact area using the results of finite element analysis, such as relative sliding velocity and normal pressure at contact area. Archard's wear model was applied to predict the roll wear. To know the effects of thermal softening of DCI (Ductile Cast Iron) roll material according to operating conditions, high temperature micro hardness test is executed and a new wear model has been proposed by considering the thermal softening of DCI roll expressed in terms of the main tempering curve. The new technique developed in this study for adjusting roll gap can give more systematically and economically feasible means to improve the dimension accuracy of bar with full usefulness and generality.

• Fire Science and Engineering
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• v.12 no.4
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• pp.13-19
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• 1998

We investigated the weight loss according to temperature using Thermal Gravimetric Analysis(TGA) in order to find the thermal hazard of carbon black(Hi-Black 10, Hi-Black 50L) dusts, and the properties of dust explosion in variation of the surface functional groups and specific surface area of their dust with the same particle size. Using Hartman's dust explosion apparatus which estimate dust explosion by electric ignition after making dust disperse by compressed air, dust explosion experiments have been conducted by varying concentration and size of carbon black dust. The explosion pressure of both carbon black increased as the specific surface area increased. The results indicated that Hi-Block 50L of which specific surface area was larger three to four times than that of Hi-Black 10 was much easier of dust explosion.

• Journal of the Korean Chemical Society
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• v.59 no.6
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• pp.493-498
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• 2015

The reductive amination of cyclohexanone with ammonia over Cu-Cr-a/γ-Al₂O₃ was investigated. It was found that a proper solvent with high solubility of ammonia and 4Å molecular sieves for the elimination of generated water contributed to the formation of cyclohexylamine in the premixing process. In addition, the addition of ammonia in the fixedbed reactor could obviously improve the conversion of cyclohexanone to cyclohexylamine. Finally, reaction conditions including reaction temperature, hydrogen pressure and charging rate of the premix were optimized. Under the optimized conditions, cyclohexylamine was obtained in 83.06% yield.

• Corrosion Science and Technology
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• v.2 no.4
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• pp.178-182
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• 2003

Slow Strain Rate Tests (SSRT) were carried out to investigate the effect of environmental factors on the Stress Corrosion Cracking (SCC) susceptibility of 3.5NiCrMoV steels used in discs for Low-Pressure (LP) steam turbines in electric power generating plants. The influences of dissolved oxygen on the stress corrosion cracking of turbine steel were studied, For this purpose, specimens were strained at variously oxygenated conditions at $150^{\circ}C$ in pure water. When the specimen was strained with $1{\times}10^{-7}s^{-1}$ at $150^{\circ}C$ in pure water, increasing concentration of dissolved oxygen decreased the elongation and the UTS. The corrosion potential and the corrosion rare increased as the amounts of dissolved oxygen increased. The increase of the SCC susceptibility of the turbine steel in a highly dissolved oxygen environment is due to the non protectiveness of the oxide layer on the turbine steel surface and the increase of the corrosion current. These results clearly indicate that oxygen concentration increases Stress Corrosion Cracking susceptibility in turbine steel at $150^{\circ}C$.