• Title/Summary/Keyword: high temperature high pressure

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A Technique for Defect Detection of Condenser Tube in Support Plate Region using Guided Wave (유도초음파를 이용한 복수기 튜브지지판 영역에서의 결함검출기법)

  • Kim, Yong-Kwon;Park, Ik-Keun;Park, Sae-Jun;Ahn, Yeon-Shik;Gil, Doo-Song
    • Journal of Welding and Joining
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    • v.30 no.6
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    • pp.36-41
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    • 2012
  • General condensers consist of many tubes supported by tube sheets and support plates to prevent the deflection of the condenser tubes. When a fluid at high pressure and temperature runs over the tubes for the purpose of transferring heat from one medium to another, the tubes vibrate and their surface comes into contact with the support plates. This vibration causes damage to the tubes, such as cracks and wear. We propose an ultrasonic guided wave technique to detect the above problems in the support plate region. In the proposed method, the ultrasonic guided wave mode, L(0,1), is excited using an internal transducer probe from a single position at the end of the tube. In this paper, we present a preliminary experimental verification using a super stainless tube and show that the defects can be discriminated from the support signals in the support region.

Ionic Liquid Pretreatment of Lignocellulosic Biomass

  • Han, Song-Yi;Park, Chan-Woo;Kwon, Gu-Joong;Kim, Nam-Hun;Kim, Jin-Chul;Lee, Seung-Hwan
    • Journal of Forest and Environmental Science
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    • v.36 no.2
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    • pp.69-77
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    • 2020
  • Lignocellulosic biomass has recalcitrant characteristics against chemical and biological conversion due to its structural heterogeneity and complexity. The pretreatment process to overcome these recalcitrant properties is essential, especially for the biochemical conversion of lignocellulosic biomass. In recent years, pretreatment methods using ionic liquids (ILs) and deep eutectic solvents (DESs) as the green solvent has attracted great attention because of their advantages such as easy recovery, chemical stability, temperature stability, nonflammability, low vapor pressure, and wide liquids range. However, there are some limitations such as high viscosity, poor economical feasibility, etc. to be solved for practical use. This paper reviewed the research activities on the pretreatment effect of various ILs including DESs and their co-solvents with organic solvents on the enzymatic saccharification efficiency of lignocellulosic biomass and the nanocellulose preparation from the pretreated products.

Synthesis of ultrafine particles and thin films of $SnO_2$ by the spray-ICP technique (Spray-ICP technique에 의한 $SnO_2$미분말 합성 및 박막 제조)

  • 김정환;박종현;김영도;신건철
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.3
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    • pp.487-492
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    • 1998
  • Ultrafine particles of $SnO_2$ or $(Sn,Ti)O_2$ and thin films of $SnO_2$ were synthesized by introducing aqueous tin chloride solution into a high temperature argon inductively coupled plasma (ICP) generated under ambient pressure (the spray-ICP technique). As-deposited $SnO_2$ particles from each concentration of solution were all tetragonal $SnO_2$ crystallline phase and their mean size decreased in proportion to the increase of solution concentration. The mean size of $SnO_2$ particles was in the 10~40 nm range.

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Growth of GaAs Crystal by an Improved VGF Apparatus

  • Chul-Won Han;Kwang-Bo Shim;Young-Ju Park;Seung-Chul Park;Suk-Ki Min
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.1 no.1
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    • pp.17-25
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    • 1991
  • The construction details of VGF apparatus with a DM(direct monitoring) furnace for the growth of low defect crystal and characteristics of GaAs crystal grown by this apparatus are described. The average dislocation densities and EL2 concentration of as-grown undoped GaAs along the different solidified fractions exhibit $4{\times}10^{2}-7{\times}10^{3}cm^{-2}$ and $6{\times}10^{14}-4{\times}10^{15}cm^{-3}$, which are less than those observed for liquid encapsulated Czochralski(LEC) or high-pressure vertical gradient freeze(VGF) crystals. These remarkable reduction of the dislocation densities and EL2 concentrations were explained by the lower temperature gradient ($dT/dx-10^{\circ}/cm$) and slower rates of post - growth cooling ($20^{\circ}C/hr:1240-1000^{\circ}C,\;30^{\circ}C/hr:1000-700^{\circ}C$). Also, The Hall mobilities, carrier concentrations show uniform distribution throughtout 80% of the ingot length.

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The electrical and optical properties of transparent ZnO:Al films using HCl wet chemical etching (HCL 습식 에칭에 의한 ZnO:Al 투명전도막의 전기적, 광학적 특성)

  • Yoo, Jin-Su;Lee, Jeong-Chul;Kang, Ki-Hwan;Kim, Seok-Ki;Yoon, Kyung-Hoon;Song, Jin-Soo;Park, I-Jun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.05b
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    • pp.62-65
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    • 2002
  • Transparent conducting aluminum-doped Zinc oxide films (ZnO:Al) were prepared by rf magnetron sputtering on glass (Coming 1737) substrate as a variation of the deposition condition. After deposition, the smooth ZnO:Al films were etched in diluted HCl (0.5%) to examine the electrical and surface morphology properties as a variation of the time. The most important deposition condition of surface-textured ZnO films by chemical etching is the processing pressure and the substrate temperature. In low pressures (0.9mTorr) and high substrate temperatures $({\leq}300^{\circ}C)$, the surface morphology of films exhibits a more dense and compact film structure with effective light-trapping to apply the silicon thin film solar cells.

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Design and Exergy Analysis for a Combined Cycle of Liquid/Solid $CO_2$ Production and Gas Turbine using LNG Cold/Hot Energy

  • Lee, Geun-Sik
    • International Journal of Air-Conditioning and Refrigeration
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    • v.15 no.1
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    • pp.34-45
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    • 2007
  • In order to reduce the compression power and to use the overall energy contained in LNG effectively, a combined cycle is devised and simulated. The combined cycle is composed of two cycles; one is an open cycle of liquid/solid carbon dioxide production cycle utilizing LNG cold energy in $CO_2$ condenser and the other is a closed cycle gas turbine which supplies power to the $CO_2$ cycle, utilizes LNG cold energy for lowering the compressor inlet temperature, and uses the heating value of LNG at the burner. The power consumed for the $CO_2$ cycle is investigated in terms of a solid $CO_2$ production ratio. The present study shows that much reduction in both $CO_2$ compression power (only 35% of the power used in conventional dry ice production cycle) and $CO_2$ condenser pressure could be achieved by utilizing LNG cold energy and that high cycle efficiency (55.3% at maximum power condition) in the gas turbine could be accomplished with the adoption of compressor inlet cooling and regenerator. Exergy analysis shows that irreversibility in the combined cycle increases linearly as a solid $CO_2$ production ratio increases and most of the irreversibility occurs in the condenser and the heat exchanger for compressor inlet cooling. Hence, incoming LNG cold energy to the above components should be used more effectively.

Pancreas로부터 의약품 원료생산을 위한 초임계 추출

  • Gwon, Hyeok-Su;Jeon, Byeong-Su;Lee, Baek-Cheon;An, Byeong-Geun
    • 한국생물공학회:학술대회논문집
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    • 2000.04a
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    • pp.516-519
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    • 2000
  • Generally pancreas consist of lipid, water and protein, digestion enzyme complex (pro-tease, lipase, amylase). The sample used in this work was frozen dry and treated by a semi-batch flow type. In order to develop a supercritical fluid extraction process to rem-ove lipid from the pancreas, experiments were conducted at various operating conditions(pressure range $1500{\sim}2800psi$, temperature range $25{\sim}40^{cdot}C$, particle size$(0.25{\sim}1.0mm$, flow rate $20{\sim}80m{\ell}/min)$. Also cholesterol in the pancreas was removed. The highest extraction efficiency was 2500psi, $35^{\cdot}C$, 0.25mm of pancreas size. The enzyme activity of the pancreas produced from this work showed high value compared with imported pancreas.

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Synthesis of Boron-Nitride Film by Plasma Assisted Chemical Vapor Deposition Using $BCl3-NH3-Ar$ Mixed Gas ($BCl3-NH3-Ar$계의 플라즈마화학증착공정을 이용한 질화붕소막의 합성)

  • 박범수;백영준;은광용
    • Journal of the Korean Ceramic Society
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    • v.34 no.3
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    • pp.249-256
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    • 1997
  • The effect of process parameter of plasma assisted chemical vapor deposition (PACVD) on the variation of the ratio between cubic boron nitride (c-BN) and hexagonal boron nitride (h-BN) in the film was in-vestigated. The plasma was generated by electric power with the frequency between 100 and 500 KHz. BCl3 and NH3 were used as a boron and nitrogen source respectively and Ar and hydrogen were added as a car-rier gas. Films were composed of h-BN and c-BN and its ratio varied with the magnitude of process parameters, voltage of the electric power, substrate bias voltage, reaction pressure, gas composition, sub-strate temperature. TEM observation showed that h-BN phase was amorphous while crystalline c-BN par-ticle was imbedded in h-BN matrix in the case of c-BN and h-BN mixed film.

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Characterization of PTFE Electrode Made by Bar-Coating Method Using Alcohol-Based Catalyst Slurry (알코올계 촉매 슬러리를 활용한 바 코팅으로 제조된 PTFE 전극의 형성 및 특성 조사)

  • JUNG, HYEON SEUNG;KIM, DO-HYUNG;PAK, CHANHO
    • Journal of Hydrogen and New Energy
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    • v.31 no.3
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    • pp.276-283
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    • 2020
  • Alcohol-based solvents including ethanol (EtOH) and tert-butyl alcohol (TBA) are investigated instead of isopropanol (IPA), which is a common solvent for polytetrafluoroethylene (PTFE), as an alternative solvent for preparing the catalyst slurry with PTFE binder. As a result, the performance at 0.2 A/㎠ from the single cells from using catalyst slurries based on EtOH and TBA showed very similar value to that from the slurry using IPA, which implies the EtOH and TBA can be used as a solvent for the catalyst slurry. It is also confirmed by the very close values of the total resistance of the membrane electrode assemblies from the slurries using different solvents. In the energy dispersive spectrometry (EDS) image, the shape of crack and dispersion of PTFE are changed according to the vapor pressure of the solvent.

Mineralogical and Gechemical Studies of Titaniferous Iron Ores and Ultramafic to Mafic Rocks from the Boreundo Iron Ore Deposits, South Korea (볼음도 자철광상의 초염기성-염기성암과 티타늄자철광석의 광물 및 지구화학적 연구)

  • 김규한
    • Economic and Environmental Geology
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    • v.33 no.1
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    • pp.1-18
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    • 2000
  • Lens shaped and stratiform titanomagnetite orebodies in the Boreumdo iron mine are closely associated with amphibolite which intruded into Precambrian metasediments. Mineralogical and petrochemical analyses of amphilbolite and titanomagnetite ores were carried out in order to interpret the origin of amphilbolite and the genesis of titanomagnetite ore deposits. Amphibolites belong to orthoamphilbolite interms of Niggli value and mineralogy, and are characterized by the occurrence of relict olivine. The amphilbolites responsible for titanomagnetite mineralization have extremely high content of $TiO_2$, ranging from 2.12 to 4.59 wt.% with the average value of 3.43 wt.%. Amphibole minerals in amphibolites are consist mainly of calcic amphiboles such as hornblende, ferroan pargasitic hornblende and tremolite. Most plagioclases belong to andesine ($An_{30-50}$\ulcorner). The metamorphic temperature and geobarometric pressure which are calculated by the calcic amphibole-plagioclase geothermometer and calcic amphilbole geobarometer are estimated to be 537$^{\circ}C$~579$^{\circ}C$(avg. 555$^{\circ}C$) and 2.9~6.6 kbar (avg. 4.5 kbars), respectively. It shows a typical amphibolite facies. Based on the mineral chemistry and petrochemisty of amphibolites and iron ores which are composed mainly of titanomagnetite and ilmenite in the Boreumdo iron mine, the titaniferous oxide melts could be immiscibly separatd from the titaniferous ultrabasic magma. The genesis of the Boreumdo titanomagnetite ore deposits are analogous to the Soyeonpyeongdo and Yonchon iron ore deposits in terms of their mineralogy, mineral chemistry and geologic setting.

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