• Title/Summary/Keyword: high temperature high pressure

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P-type Electrical Characteristics of the Amorphous La2NiO4+δ Thin Films

  • Hop, Dang-Hoang;Lee, Jung-A;Heo, Young-Woo;Kim, Jeong-Joo;Lee, Joon-Hyung
    • Journal of Surface Science and Engineering
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    • v.51 no.4
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    • pp.231-236
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    • 2018
  • We report p-type electrical characteristics of the amorphous $La_2NiO_{4+{\delta}}$ thin films which were sputtered on the glass substrates using an RF sputtering system. As-deposited thin films at room temperature and $300^{\circ}C$ were amorphous in nature. Post-annealing of the thin film samples over $400^{\circ}C$ resulted in the nano-crystallization of the $La_2NiO_{4+{\delta}}$. The electrical properties of the films were much dependent on the oxygen partial pressure, temperature of the post-annealing and sputtering ambient. The as-deposited samples at room temperature show a hole concentration of $7.82{\times}10^{13}cm^{-3}$, and it could be increased as high as $3.51{\times}10^{22}cm^{-3}$ when the films were post-annealed in an oxygen atmosphere at $500^{\circ}C$. Such p-type conductivity behavior of the $La_2NiO_{4+{\delta}}$ films suggests that the amorphous and nano-crystallized $La_2NiO_{4+{\delta}}$ films have potential for the application as p-type semiconductive or conductive materials at low temperatures where material diffusion is limited.

The Design of a Wind Speed & Direction Module and a DSP Sensor Interface System for the Meteorological System (기상계측시스템을 위한 풍향.풍속모듈 및 DSP 센서 인터페이스시스템 설계)

  • Song, Do-Ho;Joo, Jae-Hun;Ock, Gi-Tae;Kim, Sang-Gab;Choi, Jung-Keyng
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.11 no.8
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    • pp.1478-1485
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    • 2007
  • In this paper, a meteorological system including a wind speed & direction module and the DSP(Digital Signal Processor) sensor interface circuit board are proposed. This DSP system accepts and process the informations from a wind speed & direction module, the atmospheric pressure sensor, the ambient air temperature sensor and transfers it to the PC monitoring system. Especially, a wind speed & direction module and a DSP hardware are directly designed and applied. A wind speed & direction module have a construction that it have four film type RID(Resistive Temperature Detectors) resistive sensor adhered around the circular metal body heated constantly by heating coil for obtaining vector informations about wind. By this structure, the module is enabled precise measurement having a robustness about vibration, humidity, corrosion. A sensor signal processing circuit is using TMS320F2812 TI(Texas Instrument) Corporation high speed DSP. An economical meteorological system could be constructed through the data from wind speed & direction module and by the fast processing of DSP interface circuit board.

Study on Experimental and Theroretical performances for a Compact Metallic Heat Exchanger for Fuel Cell Systems (연료전지용 소형 금속 열교환기의 성능에 대한 실험 및 이론적 연구)

  • Yoon, Young-Hwan;Paeng, Jin-Gi
    • Journal of the Korean Solar Energy Society
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    • v.31 no.4
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    • pp.9-18
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    • 2011
  • This study assessed the performance of a compact heat exchanger with staggered tube banks for recuperation of high temperature exhaust thermal energy for SOFC fuel cell system. The compact heat exchanger in this study is two pass system which consists of $315{\times}202.5{\times}48.5mm^3$ and 132 tubes of $6.0mm{\Phi}$ for each heat exchanger. From experiments of the 2 pass heat exchanger system, air temperature was increased from $60{\sim}85^{\circ}C$ to $402{\sim}482^{\circ}C$ while gas temperature was decreased from $600^{\circ}C$ to $305{\sim}402^{\circ}C$ according to mass flow rates of 3.9~7.8 g/s. The experimental heat transfer rates of the heat exchanger were compared with CFD numerical solutions with the conventional ${\xi}-NTU$ method. From the comparisons, the following conclusions were obtained. For the heat exchanger system, the relative errors of heat transfer rate by CFD solution were from 7.1 to 27%, and those by ${\xi}-NTU$ method were from 0.6% to 21% compared with experimental data. From the comparisons, it can be said that both of CFD and ${\xi}-NTU$ method almost simulated to experimental data except specific conditions. Pressure drops through air tubes and gas passages were calculated with both of the CFD computation and head loss equations. The differences between them were from 14 to 22%.

Study on the mixing performance of mixing vane grids and mixing coefficient by CFD and subchannel analysis code in a 5×5 rod bundle

  • Bin Han ;Xiaoliang Zhu;Bao-Wen Yang;Aiguo Liu;Yanyan Xi ;Lei Liu ;Shenghui Liu;Junlin Huang
    • Nuclear Engineering and Technology
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    • v.55 no.10
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    • pp.3775-3786
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    • 2023
  • Mixing Vane Grid (MVG) is one of the most important structures in fuel assembly due to its high performance in mixing the coolant and ultimately increasing Critical Heat Flux (CHF), which avoids the temperature rising suddenly of fuel rods. To evaluate the mixing performance of the MVG, a Total Diffusion Coefficient (TDC) mixing coefficient is defined in the subchannel analysis code. Conventionally, the TDC of the spacer grid is obtained from the combination of experiments and subchannel analysis. However, the processing of obtaining and determine a reasonable TDC is much challenging, it is affected by boundary conditions and MVG geometries. In is difficult to perform all the large and costing rod bundle tests. In this paper, the CFD method was applied in TDC analysis. A typical 5 × 5 MVG was simulated and validated to estimate the mixing performance of the MVG. The subchannel code was used to calculate the TDC. Firstly, the CFD method was validated from the aspect of pressure drop and lateral temperature distribution in the subchannels. Then the effect of boundary conditions including the inlet temperature, inlet velocities, heat flux ratio between hot and cold rods and the arrangement of hot and cold rods on MVG mixing and TDC were studied. The geometric effects on mixing are also carried out in this paper. The effect of vane pattern on mixing was investigated to determine which one is the best to represent the grid's mixing performance.

Effects of Drying Methods on the Quality and Physiological Activities of Blueberry(Vaccinium ashei) (건조방법에 따른 블루베리의 품질 및 생리활성)

  • Park, Sung-Jin;Choi, Young-Bum;Ko, Jung-Rim;Rha, Young-Ah;Lee, Hyeon-Yong
    • Culinary science and hospitality research
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    • v.20 no.1
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    • pp.55-64
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    • 2014
  • This study was performed to determine the effects of drying methods on the quality and physiological activities of blueberry. Blueberries(Vaccinium ashei) were dried by hot-air ($60^{\circ}C$), cyclic low pressure ($50^{\circ}C$), and freeze drying methods. They contained high properties of carbohydrates(68.48~80.00%), crude protein(1.63~5.41%), crude fat(0.58~1.25%), and ash(0.71~1.11%) regardless of the drying methods. There were no differences in pH according to the drying methods. Browning index increased as the drying temperature increased. The L, a values of the freeze-dried sample were higher than those of the other dried samples, whereas the b value of the cyclic low pressure dried sample was higher than that of the other samples. The free sugar contents of the hot-air sample were higher than those of the other samples. Vitamin C content of the freeze dried sample was higher than that of either the hot-air or cyclic low pressure dried sample. The contents of total polyphenols and anthocyanins were higher in the freeze dried sample. The DPPH radical scavenging activity of freeze drying sample was higher than that of either the hot-air or cyclic low pressure dried sample. The result indicated that there were no differences in product quality depending on the freeze-drying and cyclic low pressure drying methods.

Separation Permeation Characteristics of N2-O2 Gas in Air at Cell Membrane Model of Skin which Irradiated by High Energy Electron (고에너지 전자선을 조사한 피부의 세포막모델에서 공기 중의 O2-N2 혼합기체의 분리투과 특성)

  • Ko, In-Ho;Yeo, Jin-Dong
    • Journal of the Korean Society of Radiology
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    • v.13 no.2
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    • pp.261-270
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    • 2019
  • The separation permeation characteristics of $N_2-O_2$ gas in air at cell membrane model of skin which irradiated by high energy electron(linac 6 MeV) were investigated. The cell membrane model of skin used in this experiment was a sulfonated polydimethyl siloxane(PDMS) non-porous membrane. The pressure range of $N_2$ and $O_2$ gas were appeared from $1kg_f/cm^2$ to $6kg_f/cm^2$. In this experiment(temperature $36.5^{\circ}C$), the permeation change of $N_2$ and $O_2$ gas in non-porous membrane by non-irradiation were found to be $1.19{\times}10^{-4}-2.43{\times}10^{-4}$, $1.72{\times}10^{-4}-2.6{\times}10^{-4}cm^3(STP)/cm^2{\cdot}sec{\cdot}cmHg$, respectively. That of $N_2$ and $O_2$ gas in non-porous membrane by irradiation were found to be $0.19{\times}10^{-4}-0.56{\times}10^{-4}$, $0.41{\times}10^{-4}-0.76{\times}10^{-4}cm^3(STP)/cm^2{\cdot}sec{\cdot}cmHg$, respectively. The irradiated membrane was significantly decreased about 4-10 times than membrane which was not irradiated. And ideal separation factor of $N_2$ and $O_2$ gas by non-irradiation was found to be from 1.32 to 0.42 and that of $N_2$ and $O_2$ gas by irradiation was found to be from 0.237 to 0.125. The irradiated membrane was significantly decreased about 4-5 times than membrane which was not irradiated. When the operation change(cut) and pressure ratio(Pr) by non-irradiation were about 0, One was increased to the oxygen enrichment and the other was decreased to the oxygen enrichment. The irradiated membrane was significantly decreased about 4-19 times than membrane which was not irradiated. As the pressure of $N_2$ and $O_2$ gas was increased, the selectivity was decreased. As separation permeation characteristics of $N_2-O_2$ gas in cell membrane model of skin were abnormal, cell damages were appeared at cell.

Effects of Gamichangbaek-san(Jiaweichangbai-san) on Anti-inflammatory, Analgesic, Anti-febrile Activities and Immune Responses in Carrageenan-induced Arthritic Animals (가미창백산(加味蒼栢散)이 Carrageenan유발 동물모델 관절염의 소염, 진통, 해열 및 면역에 미치는 영향)

  • Han, Young-Gyu;Park, Young-Hoi;Keum, Dong-Ho;Lee, Myeong-jong
    • Journal of Korean Medicine Rehabilitation
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    • v.15 no.1
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    • pp.127-141
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    • 2005
  • Objectives : This study was performed to investigate the effects of Gamichangbaek-san(Jiaweichangbai-san) on anti-inflammatory, analgesic, anti-febrile and immune response on the arthritis of carrageenan-induced animals. Methods and Materials : Rats were classified into control and sample groups which are 7 individuals each for the experiments about anti-inflammatory and anti-febrile. Each of the 7 mice were classified into normal, control, sample groups for the analgesic experiments. Gamichangbai-san(Jiaweichangbai-san) was administered to sample group and normal saline was administered to normal and control groups. Arthritis was induced by injection of 1% carrageenan $0.1m{\ell}$ and Gamichangbaek-san(Jiaweichangbai-san) was administered after 30 minutes. The change of edema in Carrageenan-induced Arthritic Rats' Paws was measured after 1 hour and 5 hours from the injection of carraqeenan with Plethysmometer(7150, UGO BASILE, ltaly) by Winter' method. WBC, Lymphocyte and ESR were measured by heart puncture and CD4+ T cell, CD8+ T cell and CD4+/CD8+ T cell ratio were measured from the spleen tissue. Writhing syndrom was measured with Tail flick unit(UGO BASILE, Italy) in the experiments conducted to check the analgesic activity. The temperature of the paws of carrageenan-induced arthritic rats was measured by Laser thermometer. Rectal temperature was measured by Yeast's method in anti-febrile experiments. Immune response was measured by CD4+, CD8+ T cell ratio and CD4+/CD8+ T cell ratio. Results : 1. It was recognized that Gamichangbaek-san(Jiaweichangbai-san) decreased the increase rate of Paw Edema effectively with statistical significance. 2. It was recognized that Gamichangbaek-san(Jiaweichangbai-san) decreased WBC, Lymphocyte and ESR with statistically high significance. 3. It was recognized that Gamichangbaek-san(Jiaweichangbai-san) did not show significant analgesic effect, but the Pressure pain threshold of the paws was increased with statistical significance. 4. It was recognized that Gamichangbaek-san(Jiaweichangbai-san) decreased rectal temperature effectively and had an anti-febrile effect about the febrile of a joint with statistical significance. 5. It was recognized that Gamichangbaek-san(Jiaweichangbai-san) increased CD4+ T cell ratio with statistically high significance and increased CD+8 T cell ratio with statistical non significance but increased CD4+/CD8+ T cell ratio effectively with statistical significance, too. Conclusions : According to the above results, it can be concluded Gamichangbaek-san(Jiaweichangbai-san) showed the treatment effects on the artificial arthritis resulted from carageenan in rats and it is suggested that more interest and study in the security for the clinical use were needed.

Steam Gasification of Coal and Petroleum Coke in a Thermobalance and a Fluidized Bed Reactor (열천칭과 유동층반응기에서 석탄과 Petroleum Coke의 수증기 가스화반응)

  • Ji, Keunho;Song, Byungho
    • Korean Chemical Engineering Research
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    • v.50 no.6
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    • pp.1015-1020
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    • 2012
  • Lignite of low rank coal and petroleum coke of high sulfur content can be high potential energy sources for coal gasification process because of their plentiful supply. The steam gasification of lignite, anthracite, and pet coke has been carried out in both an atmospheric thermobalance reactor and a lab-scale fludized bed reactor (0.02 m i.d. ${\times}$ 0.6 m height). The effects of gasification temperature ($600{\sim}900^{\circ}C$) and partial pressure of steam (0.15~0.95 atm) on the gasification rate and on the heating value of product gas have been investigated. The modified volumetric reaction model was applied to the experimental data to describe the behavior of carbon conversion, and to evaluate kinetic parameters of char gasification. The results shows that higher temperature bring more hydrogen in the product syngas, and thus increased gas heating value. The feed rate of steam is needed to be optimized because an excess steam input would lower the gasification temperature which results in a degradation of fuel quality. The rank of calorific value of the product gas was anthracite > lignite > pet coke. Their obtained calorific value at $900^{\circ}C$ with 95% steam feed were 10.0 > 6.9 > 5.7 $MJ/m^3$. This study indicates that lignite and pet coke has a potential in fuel gas production.

Explosion Properties and Thermal Stability of Reactive Organic Dust (반응성 유기물 분진의 폭발특성과 열안정성)

  • Han, Ou-Sup;Han, In-Soo;Choi, Yi-Rac;Lee, Keun-Won
    • Journal of the Korean Institute of Gas
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    • v.15 no.4
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    • pp.7-14
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    • 2011
  • Using 20 L spherical explosion vessel and differential scanning calorimeter (DSC), an experimental investigation was carried on explosion characteristics and thermal decomposition of some reactive organic dust. As the result, the minimum explosion concentration of Benzoyl peroxide (BPO), Phthalic anhydride (PA) and 1-Hydroxybenzotriazol (HBT) exist between 10 and 15 g/$m^3$, which indicates that their explosion sensitivity are high. The maximum Kst values of HBT, PA and 97 % BPO are 251, 146 and 80 [$bar{\cdot}m/s$], respectively and the explosion severity of HBT is the explosion class of St-2. The flame velocity was also calculated from the combustion time of dust and flame arrival time to estimate the flame propagation characteristics in a closed vessel. The decomposition temperature and heat of decomposition reaction for 97 % BPO and HBT are $107^{\circ}C$ (1025 J/g), $214^{\circ}C$ (1666 J/g), respectively and it was found that these low decomposition temperature and high released heat affect the explosion characteristics.

Study on Growth Optimization of InAs/GaSb Strained-Layer Superlattice Structures by High-Resolution XRD Analysis (고분해능 XRD 분석에 의한 InAs/GaSb 응력초격자 구조의 성장 최적화 연구)

  • Kim, J.O.;Shin, H.W.;Choe, J.W.;Lee, S.J.;Kim, C.S.;Noh, S.K.
    • Journal of the Korean Vacuum Society
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    • v.18 no.4
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    • pp.245-253
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    • 2009
  • For the growth optimization of InAs/GaSb (8/8-ML) strained-layer superlattice (SLS), the structure has been grown under various conditions and modes and characterized by the high-resolution x-ray diffraction (XRD) analysis. In this study, the strain modulation is induced by changing parameters and modes, such as the growth temperature, the ratio of V/III beam-equivalent-pressure (BEP), and the growth interruption (GI), and the strain variation is analyzed by measuring the angle separation of 0th-order satellite peak in XRD patterns. The XRD results reveal that the growth temperature and the V/III(Sb/Ga) ratio are major parameters to change the crystallineity and the strain modulation in SLS structures, respectively. We have observed that the SLS samples with compressive strain prepared in this study are show a transition to tensile strain with decreasing V/III(Sb/Ga) ratio, and the GI process is a sensitive factor giving rise to strain modulation. These results obtained in this study suggest that optimized growth temperature and V/III(Sb/Ga) ratio are $350^{\circ}C$ and 20, respectively, and the appropriate GI time is approximately 3 seconds just before InAs growth that the crystallineity is maximized and the strain relaxation is minimized.