• Title/Summary/Keyword: high temperature high pressure

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Environmental Geochemistry of Atmospheric Mercury: Its Backgriound Concentrations and Exchange Across the Air-Surface Interface (대기수은의 환경지화학: 배경농도측정 및 대기-지표면간의 교환작용)

  • 김기현
    • Journal of Korean Society for Atmospheric Environment
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    • v.12 no.2
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    • pp.189-198
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    • 1996
  • Mercury (Hg) is ubiquitous throughout the earth's atmosphere. The uniqueness of its atmospheric geochemistry is well-known with the high environmental mobility and relatively long atmospheric residence time (c.a., 1 year) associated with its high chemical stability. Despite a growing recognition of the environmental significance of its global cycling, the prexisting Korean database for atmospheric Hg is extremely rare and confined to a number of concentration measurements conducted under relatively polluted urban atmospheric environments. To help activate the research on this suvject, an in-depth analysis on the current development in the measurements of atmospheric mercury and the associated fluxes has been made using the most using the most updated data ests reported worldwide. As a first step toward this purpose, the most reliable techniques commonly employed in the measurements of its concentration in the background atmosphere are introduced in combination with the flux measurement techniques over soil surface such as: dynamic enclosure (or field flux chamber) method and field micrometeorological method. Then the results derived using these measurement techniques are discussed and interpreted with an emphasis on its mobilization across the terrestrial biosphere and atmosphere interface. A unmber of factors including air/soil temperature, soil chemical composition, soil water content, and barometric pressure are found out to be influential to the rate and amount of such exchange processes. Although absolute magnitude of such exchange processes is insignificant relative to that of the major component like the oceanic environment, this exchange process is thought to be the the predominant natural pathway for both the mobilization and redistribution of atmospheric Hg on a local or regional scale.

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A Study for Measurements of In-Cylinder Residual Gas Fraction using Fast Response FID in an SI Engine (스파크점화기관에서 고속응답 FID를 이용한 실린더내 잔류가스량 측정에 관한 연구)

  • 송해박;조한승;이종화;이귀영
    • Transactions of the Korean Society of Automotive Engineers
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    • v.6 no.1
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    • pp.80-89
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    • 1998
  • The residual gas in an spark-ignition engine is one of important factors on emissions and performance such as combustion stability. With high residual gas fractions, flame speed and maximum combustion temperature are decreased and these are deeply related with combustion stability especially at idle and NOx emission at relatively high engine load. Therefore, there is a need to characterize the residual gas fraction as a function of the engine operating load. Therefore, there is a need to characterize the residual gas fraction as a function of the engine operating parameters. In the present study, the quantitative measurement technique of residual gas fraction was studied by using Fast Response Flame Ionization Detector(FRFID). The measuring technique and model for estimation of residual gas fraction were reported in this paper. By the assuming that the raw signal from FRFID saturates with the same slope for firing and misfiring cycle, in-cylinder hydrocarbon(HC) concentration can be estimated. Residual gas fraction can be obtained from the in-cylinder HC concentration measured at firing and motoring condition. The developed measurement and calibration procedure were applied to the limited engine operating and design condition such as intake manifold pressure and valve overlap. The results show relevant trends by comparing those from previous studies.

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Prediction of Insulation Capability for Ground Fault to Consider Asymmetry in SF6 Circuit Breaker

  • Oh, Yeon-Ho;Song, Ki-Dong;Kim, Hong-Kyu;Lee, Hae June;Hahn, Sung-Chin
    • Journal of Electrical Engineering and Technology
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    • v.10 no.5
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    • pp.2046-2051
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    • 2015
  • Currently, most high-voltage gas circuit breakers (CBs) include asymmetrical geometries in the shield, the tank, the hot-gas exhaust, and the connection parts for bushings. For this reason, a 3-dimensional (3-D) analysis of the insulation capability is necessary, rather than a 2-D analysis. However, a 3-D analysis has difficulties due to the computational time and complex modeling. This paper presents a 3-D analysis considering the asymmetry in high-voltage gas CBs and a technique to reduce the calculation time. In the proposed technique, the arc plasma requiring the most computational time is first calculated by a 2-D analysis. Then, the results such as pressure, temperature, and velocity are input as a source for the 3-D analysis. This technique is applied to a 145kV self-blast-type CB and the analysis result exhibits good agreement with the experimental result.

Thermal Performance Evaluations of Tungsten/Yttria as Nozzle Throat Insert Material for Long Duration Firing (장시간 연소 텅스텐/이트리아 노즐목 삽입재의 내열성능 평가)

  • Kang, Yoon-Goo;Park, Jong-Ho
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.38 no.2
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    • pp.200-205
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    • 2010
  • Heat-resistance of W/$Y_2O_3$ as throat insert material was evaluated to develop rocket motor keeping thrust uniformly under condition of high-temperature, high-pressure and long-burn time. Test was conducted with varying burn time, and test results were compared with CIT. Test showed that ablation rate was decreased according as burn time was increased, and that ablation rate of W/$Y_2O_3$ was about 55 % of CIT. Macro/micro structures of throat insert did not show a peculiar phenomenon by increased burn time. In addition, the vacuum heat treatment is effective for the prevention of crack in throat insert.

Simultaneous detection for synthetic antimicrobials in muscle by high performance liquid chromatography-mass selective detector (HPLC-MSD) (HPLC-MSD 를 이용한 식육 중 합성항균제의 동시분석)

  • Hong In-Suk;Choi Yoon-Hwa;Kwon Taek-Boo;Lee Jung-Hark
    • Korean Journal of Veterinary Service
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    • v.29 no.3
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    • pp.317-330
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    • 2006
  • This study was conducted to develop the analytical method about simultaneous determination for synthetic antimicrobials in muscle by high performance liquid chromatography - mass selective detector (HPLC- MSD). Solid phase extraction (SPE), matrix solid phase dispersion (MSPD) and liquid-liquid extraction (LLE) have been adapted as pretreatment procedures for HPLC- MSD. Among various solvent tested, methanol was chosen for extraction of synthetic antimicrobials in muscles. For the optimized response, the values of various MS parameters including fragment voltage, drying gas flow, nebulizer pressure, drying gas temperature were verified. The average recovery rates using MSPD and SPE for muscles of bovine and pork were 78.9-127.1% and 78.3-121.7%, respectively. This method was verified the satisfactory performance for fourteen synthetic antimicrobials excepting carbadox in muscle of pork as detection limit of $0.05{\mu}g/g$ on API/ES SIM mode.

Evaluation of Hydrogenation Properties on Ti-Cr-Nb Alloys Manufactured by Arc Melting (아크용해법에 의한 Ti-Cr-Nb합금의 제조와 수소와 특성 평가)

  • Lee, Young-Geun;Hong, Tae-Whan
    • Journal of Hydrogen and New Energy
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    • v.19 no.6
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    • pp.482-489
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    • 2008
  • Ti-Cr alloys consist of BCC solid solution, C36, C14 and C15 Laves phase at high temperature. Among others, the BCC solid solution phase was reported to have a high hydrogen storage capacity. However, activation, wide range of hysteresis at hydrogenation/dehydrogenation, and degradation of hydrogen capacity due to hydriding/dehydriding cycles must be improved for its application. In this study, to improve such problems, we added a Nb. For attaining target materials, Ti-10Cr-xNb(x=1, 3, 5wt.%) specimens were prepared by arc melting. The arc melting process was carried out under argon atmosphere. As-received specimens were characterized using XRD(X-ray diffraction), SEM(Scanning Electron Microscopy) with EDX(Energy Dispersive X-ray) and TG/DSC(Thermo Gravimetric Analysis/Differential Scanning Calorimetry). In order to examine hydrogenation behavior, the PCI(pressure-Composition-Isotherm) was performed at 293, 323, 373 and 423K.

Study on the Long Time Breakdown Voltage in the Macro Interface between Epoxy and Rubber (에폭시/고무 거시계면에서 장시간 절연파괴전압에 대한 연구)

  • 박우현;이기식
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.11
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    • pp.1003-1008
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    • 2002
  • In this paper, the estimation of lifetime with the various conditions of the interface between toughened epoxy and rubber which are consisting materials of underground power delivery system has been studied. After the measurement of the short time AC interfacial breakdown strength on macro interfaces at room temperature, the breakdown time at several voltages were measured under the constant voltages lower than the short time breakdown voltage. The long time breakdown voltage was calculated by using Inverse Power Law. Two types of interfaces was studied. One was the interface between toughened epoxy and EPDM(Ethylene Prorylene Diene Terpolymer). The other was the interface between toughened epoxy and silicon rubber. Interfacial pressure and roughness of interfaces was determined through the characteristic of short time AC interfacial breakdown strength. Oil condition was no oiled, low viscosity oiled and high viscosity oiled. High viscosity oiled interface between Toughened epoxy and silicon rubber had the best lifetime exponent, 20.69. and the breakdown voltage of this interface after 30 years was evaluated 19.27㎸.

On the Birefringence Distribution in Optical Disk Substrate Fabricated by Injection Compression Molding (광디스크 기판의 사출압축성형시 발생하는 복굴절에 관한 연구)

  • Kim, Jong-Seong;Kim, Hyeon;Gang, Sin-Il
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.23 no.11 s.170
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    • pp.2050-2057
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    • 1999
  • It is necessary to improve mechanical and optical properties in the optical disk substrates as the information storage devices with high storage density using short wavelength laser are being developed. Injection compression molding is regarded as the most suitable process to manufacture optical disk substrates with high dimensional accuracy, low residual stresses, and superb optical properties. In the present study, polycarbonate optical disk substrates were fabricated by injection compression molding and the birefringence, regarded as one of the most important optical properties for optical disk, is measured. The effects of various processing conditions upon the development of birefringence distribution were examined experimentally. It was found that the values of the birefringence distribution were very sensitive to the mold wall temperature history and the variance of the birefringence distribution in the radial direction was affected by the level of the packing and the compression pressure.

A Study on Improvement of WC Core Surface Roughness by Feedrate Control (Feedrate Control에 의한 초경코어 표면조도 향상에 관한 연구)

  • Kim, Hyun-Uk;Jeong, Sang-Hwa;Lee, Dong-Kil;Kim, Sang-Suk;Kim, Hye-Jeong;Kim, Jeong-Ho
    • Journal of the Korean Society for Precision Engineering
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    • v.26 no.1
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    • pp.57-62
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    • 2009
  • Recently, with the increasing lightness and miniaturization of high resolution camera phones, the demand for aspheric glass lens has increased because plastic and spherical lens are unable to satisfy the required performance. An aspheric glass lens is fabricated by the high temperature and pressure molding using a tungsten carbide molding core, so precision grinding technology for the molding core surface are required. This paper reports a development of feedrate control grinding method for aspherical molding core using parallel grinding method. A plane molding core was ground using conventional and feedrate control grinding method. The performance of the feedrate control method was evaluated by measurement of surface roughness. The result indicated that the average surface roughness was reduced to 1.5 nm, which is more efficient than the conventional grinding method.

Numerical Study on Heat Transfer Characteristic in Combustor Nozzle (추진기관 노즐의 열전달 특성에 관한 수치적 연구)

  • Namkoung, Hyuck-Joon;Han, Poong-Gyoo;Lee, Kyoung-Hoon;Kim, Young-Soo;Jeong, Hae-Seung
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2007.11a
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    • pp.275-281
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    • 2007
  • For a cooling performance research of the combustor operated in a extreme environment of a high temperature and high pressure, we accomplished a cooling performance analysis. Generally a heat transfer characteristic in cooling passage is known well experimentally and theoretically, however heat flux in the combustion chamber isn't. In this study, fluid flow combined with heat transfer analysis is accomplished about a combustor nozzle. We tried to analyze the cooling performance with a heat transfer characteristic of a gas and coolant side in the view point of quantity on the mass flow rate to be supplied to the cooling channel. And finally, evaluation on the thermal safety of nozzle wall material was accomplished.

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