• Title/Summary/Keyword: high temperature high pressure

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Conversion of Methanol to Hydrocarbons over Heteropoly Acids(I) (헤테로폴리산 촉매에 의한 탄화수소로의 메탄올 전환반응(I))

  • Hong, Seong-Soo;Lee, Ho-In
    • Applied Chemistry for Engineering
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    • v.2 no.4
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    • pp.363-371
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    • 1991
  • The catalytic performance and availability of heteropoly compounds for the conversion of methanol to hydrocarbons have been studied. The effects of reaction conditions such as reaction temperature, methanol partial pressure and residence time and the effects of ion-exchange of the catalysts were examined for enhancing the yield of hydrocarbons and the selectivity of low olefins. Their acid strength depended on the kind of countercation, and the yield of hydrocarbons and the selectivity for propylene to propane were closely related to the electronegativity of the corresponding countercations. In contrast to the other heteropoly compounds, the ammonium salt showed a considerably high catalytic activity and a high selectivity for paraffins to low olefins.

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Effect of Heat Input on the Mechanical Properties of SA508 class 3 Steel Weldments with Submerged Arc Welding (SA508 class 3 서브머지드 아크용접부의 기계적 성질에 미치는 입열량의 영향)

  • Seo Yun-seok;Koh Jin-Hyun;Kim Nam-Hoon;Oh Se-Yong;Choo Kee-Nam
    • Journal of Welding and Joining
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    • v.22 no.5
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    • pp.38-45
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    • 2004
  • The present study is to investigate the effect of heat input on the microstructure, tensile properties and toughness of single-pass submerged arc bead-in-groove welds produced on SA508 class 3 steels. The heat input was varied in the range of 1.6, 3.2 and 5.0 kJ/mm. The toughness of weld metals was evaluated by using subsize Charpy V-notch specimens in the temperature range of -19$0^{\circ}C$ to 2$0^{\circ}C$. The weld microstructure and fractography were observed by optical and scanning electron microscopies, respectively. With increasing heat inputs, tensile strength and hardness of weld metals were decreased while elongation was increased. The poor notch toughness at 1.6 kJ/mm was attributed to the formation of ferrite with aligned second phase and banitic microstructure with high yield strength while that at 5.0 kJ/mm was due to the presence of grain boundary and polygonal ferrites. The microstructure of the intermediate energy input welds consisted of a high proportion of acicular ferrite with limited polygonal ferrites, which provide improved notch toughness.

Chemical Vapor Nucleation of Tungsten from $WF_6-SiH_4$ on Silicon Dioxide Surface (산화규소 표면위에서 $WF_6-SiH_4$ 화학증착에 의한 텅스텐 핵의 생성)

  • Choi, Kyeong-Keun;Yi, Chung;Rhee, Shi-Woo;Lee, Kun-Hong
    • Korean Journal of Materials Research
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    • v.2 no.1
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    • pp.19-26
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    • 1992
  • The rate of tungsten nuclei formation from $WF_6-SiH_4$ on silicon dioxide surface was measured. The nucleation rate became faster at high deposition temperature, low carrier gas flow rate and high deposition pressure. Also the rate became faster at the downstream of the oxide surface compared to the oxide surface near the inlet. Shape and cross-sectional view of the tungsten nuclei were observed with SEM and their chemical compositions were also determined.

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Analysis of the Maximum Electric Field for Changing Pressure using Breakdown Characteristic of $N_2+SF_6$, $N_2+CF_4$, $N_2$ Gases in a Cryogenic Environment (극저온 환경을 고려한 기압별 $N_2+SF_6$, $N_2+CF_4$, $N_2$가스의 절연파괴 전압 값을 이용한 최대전계 분석)

  • Oh, Seok-Ho;Lee, Sang-Hwa;Shin, Woo-Ju;Park, Tae-Gun;Seong, Jae-Kyu;Hwang, Jae-Sang;Lee, Bang-Wook
    • Proceedings of the KIEE Conference
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    • 2011.07a
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    • pp.1548-1549
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    • 2011
  • High voltage cryogenic insulation issues need to be addressed in order to promote the commercialization of high temperature superconducting (HTS) equipment. As a fundamental step in the development of the optimum bushings for HTS devices, the breakdown characteristics of liquid nitrogen mixed with liquefied insulating gases such as $N_2$, $SF_6$, and $CF_4$ have been investigated. In order to investigate the possibility of substituting $CF_4$ gas for $SF_6$ gas for the bushings of HTS electrical equipment, AC withstanding voltage tests have been performed. In this paper, finding the maximum electric field $E_{max}$ using utilization factor ${\eta}$. This result is applicable to developing the real scale HTS equipment of the design parameters.

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Liquid Cooling System Using Planar ECF Pump for Electronic Devices (평면형 ECF 펌프를 이용한 전자기기 액체냉각 시스템)

  • Seo, Woo-Suk;Ham, Young-Bog;Park, Jung-Ho;Yun, So-Nam;Yang, Soon-Young
    • Journal of the Korean Society for Precision Engineering
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    • v.24 no.12
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    • pp.95-103
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    • 2007
  • This paper presents a liquid cooling concept for heat rejection of high power electronic devices existing in notebook computers etc. The design, fabrication, and performance of the planar ECF pump and farced-liquid cooling system are summarized. The electro-conjugate fluid (ECF) is a kind of dielectric and functional fluids, which generates jet flows (ECF-jets) by applying static electric field through a pair of rod-like electrodes. The ECF-jet directly acts on the working fluid, so the proposed planar ECF pump needs no moving part, produces no vibration and noise. The planar ECF pump, consists of a pump housing and electrode substrate, achieves maximum flow rate and output pressure of $5.5\;cm^3/s$ and 7.2 kPa, respectively, at an applied voltage of 2.0 kV. The farced-liquid cooling system, constructed with the planar ECF pump, liquid-cooled heat sink and thermal test chip, removes input power up to 80 W keeping the chip surface temperature below $70\;^{\circ}C$. The experimental results demonstrate that the feasibility of forced-liquid cooling system using ECF is confirmed as an advanced cooling solution on the next-generation high power electronic devices.

Trend and Review of Corrosion Resistant Alloy (CRA) for Offshore Pipeline Engineering (내식합금 (CRA) 동향 및 해양 파이프라인 설계 적용에 대한 고찰)

  • Yu, Su-Young;Choi, Han-Suk;Lee, Seung-Keon;Kim, Do-Kyun
    • Journal of Ocean Engineering and Technology
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    • v.28 no.1
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    • pp.85-92
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    • 2014
  • Offshore fields are increasingly important for the development of offshore resources due to the growing energy needs. However, an offshore field for oil and gas production has difficult development conditions, e.g., high temperature, high pressure, sweet/sour compositions of fluids, etc. Corrosion is one of the biggest issues for offshore pipeline engineering. In this study, a Corrosion Resistant Alloy (CRA) pipe for corrosion prevention was investigated through its global demand and trends, and three types of CRA pipelines were introduced with detailed explanations. The usefulness of CRA was also evaluated in comparison to a carbon steel pipeline in terms of the structural strength, cost, and other factors. Offshore pipeline engineering, including mechanical design and verification of the results through an installation analysis based on numerical software, was performed for the carbon steel type and solid CRA type. The results obtained from this study will be useful data for CRA pipeline designers and researchers.

A Study on Lubricant additive of DME Common-rail Vehicle (DME 커먼레일 차량의 윤활향상제에 관한 연구)

  • Park, JungKwon;Kim, Hyunchul;Jeong, SooJin;Chon, MunSoo
    • Journal of Institute of Convergence Technology
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    • v.3 no.1
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    • pp.15-18
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    • 2013
  • The next generation alternative fuel of diesel, DME (Dimethyl Ether) discharges particulate matter hardly due to chemical structural as oxygen-fuel so it has the eco-friendly property. Despite these advantages, the DME has the technical difficulties to apply to the diesel engine because of a low calorific value, viscosity and compressibility effects. From this point of view, we performed experimental studies on improved reliability of DME common-rail vehicle and lubricity enhancement of DME fuel for empirical distribution of eco-friendly DME fuel. Also we analyzed solubility of lubrication enhancer according to a drop in temperature, try to secure reliability about core parts of DME vehicle by applying lubrication enhancer in the DME common-rail vehicle.

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Investigating of the Properties of ZnO Film Synthesized by Pulsed Laser Deposition (펄스레이저 증착법에 의해 성장된 ZnO 박막의 특성 관찰)

  • Choi, Jae-wan;Ji, Hyun-jin;Jung, Chang-Uk;Lee, Bo-Hwa;Kim, Gyu-Tae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.2
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    • pp.108-111
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    • 2011
  • The semiconducting material of ZnO in II-VI group was well known as its good application for photo electronics, chemical sensors and field effect transistors due to the remarkable optical properties with wide energy band gap and great ionic reactivities. Up to now the growth of a good quality of ZnO film has been issued for better performances. Even though there were many deposition methods for making ZnO films, pulse laser deposition methods have been preferred for high crystalline films. In this report, the ZnO film was also created by pulsed laser deposition technique which also showed high crystalinity. By controlling several factors when deposited, it was investigated that the optimal condition for ZnO film formation. Mainly, oxygen partial pressures and growth temperatures were changed when ZnO films were synthesized and followed the characterization by HRXRD and AFM.

Online Load Torque Ripple Compensator for Single Rolling Piston Compressor (싱글 로터리 컴프레셔의 온라인 부하 토크리플 보상기)

  • Gu, Bon-Gwan
    • The Transactions of the Korean Institute of Power Electronics
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    • v.19 no.5
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    • pp.457-462
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    • 2014
  • Given their low cost, single rolling piston compressors (SRPC) are utilized in low-power room air-conditioning systems. The SRPC cycle is composed of one compression and discharge process per mechanical rotation. The load torque is high during the compression process of the refrigerants and low during the discharge process of the refrigerants. This load torque variation induces a speed ripple and severe vibration, which cause fatigue failures in the pipes and compressor parts, particularly under low-speed conditions. To reduce the vibration, the compressor usually operates at a high-speed range, where the rotor and piston inertia reduce the vibration. At a low speed, a predefined feed-forward load torque compensator is used to minimize the speed ripple and vibration. However, given that the load torque varies with temperature, pressure, and speed, a predefined load torque table based on one operating condition is not appropriate. This study proposes an online load torque compensator for SRPC. The proposed method utilizes the speed ripple as a load torque ripple factor. The speed ripple is transformed into a frequency domain and compensates each frequency harmonic term in an independent feed-forward manner. Experimental results are presented to verify the proposed method.

Effect of Aging Time on Creep Property of Cast Haynes 282 Superalloy (초내열합금 Haynes 282 주조합금의 크리프강도에 미치는 시효처리의 영향)

  • Kim, Young-Ju;Ahn, Yong-Sik
    • Journal of Power System Engineering
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    • v.21 no.6
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    • pp.13-20
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    • 2017
  • Ni-base superalloy Haynes 282 was developed as a gas turbine material for use in the ultra-super-critical stage (USC) of next-generation coal-fired power plants. Temperatures in the USC stage exceed $700^{\circ}C$ during operation. In spite of its important role Haynes 282 in increasing the performance of high-pressure turbines, as a result of its high-temperature capability, there is little information on the microstructure, deformation mechanism, or mechanical properties of the cast condition of this alloy. The aim of present study is to examine the creep properties of cast alloy and compare with wrought alloy. The ${\gamma}^{\prime}-precipitates$ were coarsen with the increase of aging time ranging from 8 to 48 hrs. A creep test performed at $750^{\circ}C$ showed faster minimum creep rate and shorter rupture lifetime with the aging time. A creep test performed showed only a slight difference in the rupture life between cast and wrought products. Based on the creep test results, the deformation mechanism is discussed using fractographs.