• Title/Summary/Keyword: high temperature high pressure

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Development of $YSZ/La_0.85S_r0.15MnO_3$ Composite Electrodes for Solid Oxide Fuel Cells (고체산화물 연료전지용 $YSZ/La_0.85S_r0.15MnO_3$계 복합전극의 개발)

  • 윤성필;현상훈;김승구;남석우;홍성안
    • Journal of the Korean Ceramic Society
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    • v.36 no.9
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    • pp.982-990
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    • 1999
  • YSZ/LSM composite cathode was fabricated by dip-coating of YSZ sol on the internal pore surface of a LSM cathode followed by sintering at low temperature (800-100$0^{\circ}C$) The YSZ coating significantly increased the TPB(Triple Phase Boundary) where the gas the electrode and the electrolyte were in contact with each other. Sinter the formation of resistive materials such as La2Zr2O7 or SrZrO3 was prevented due to the low processing temperature and TPB was increased due to the YSZ film coating the electrode resistance (Rel) was reduced about 100 times compared to non-modified cathode. From the analysis of a.c impedance it was shown that microstructural change of the cathode caused by YSZ film coating affected the oxygen reduction reaction. In the case of non-modified cathode the RDS (rate determining step) was electrode reactions rather than mass transfer or the oxygen gas diffusion in the experimental conditions employed in this study ($600^{\circ}C$-100$0^{\circ}C$ and 0,01-1 atm of Po2) for the YSZ film coated cathode however the RDS involved the oxygen diffusion through micropores of YSZ film at high temperature of 950-100$0^{\circ}C$ and low oxygen partial pressure of 0.01-0.03 atm.

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Effects of A-Site Sr and B-Site Substitution on the Dielectric Properties of BaTiO3 Ceramics (A-site Sr 및 B-site Ca 첨가 BaTiO$_3$ 세라믹스의 유전특성)

  • 박재관;오태성;김윤호
    • Journal of the Korean Ceramic Society
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    • v.28 no.9
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    • pp.689-695
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    • 1991
  • Dielectric properties of Ba1-$\chi$Sr$\chi$Ti1-yCayO3-y ceramics, where Sr and Ca were doped to Ba-site and Ti-site within the range of 0 x 0.24 and 0 y 0.05, respectively, were investigated. The substitution of Ca for Ti, which maintained the high resistivity of these formulations after sintering in a reducing atmosphere, was confirmed. Ca addition decreased the tetragonality c/a, increased the unit cell volume, and lowered Curie temperature, which were attributed to the occupancy of Ca2+ ions on Ti-sites. The lowering of Curie temperature by Ca addition was affected by the substitution of Sr for Ba-site; within 2 mol% of Ca, Curie temperature was lowered at a rate of 2$0^{\circ}C$ and 16$^{\circ}C$ per mol% of Ca at x=0 and x=0.08, respectively. Whereas the resistivity of the formulations without Ca was reduced to 107 {{{{ OMEGA }}cm, when sintered at low oxygen partial pressure of 10-9 MPa, the resistivity value higher than 1011 {{{{ OMEGA }}cm was maintained for the formulations containing Ca more than 0.5 mol%. Dielectric loss factor, tan$\delta$, was about 1% for most formulations.

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Comparative Performance Analysis of Ammonia-Water Rankine Cycle and Kalina Cycle for Recovery of Low-Temperature Heat Source (저온 열원 발전을 위한 암모니아-물 랭킨 사이클과 칼리나 사이클의 성능특성의 비교 해석)

  • KIM, KYOUNGHOON;BAE, YOOGEUN;JUNG, YOUNGGUAN;KIM, SEWOONG
    • Journal of Hydrogen and New Energy
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    • v.29 no.2
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    • pp.148-154
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    • 2018
  • This paper presents a comparative analysis of thermodynamic performance of ammonia-water Rankine cycles with and without regeneration and Kalina cycle for recovery of low-temperature heat source. Special attention is paid to the effect of system parameters such as ammonia mass fraction and turbine inlet pressure on the characteristics of the system. Results show that maximum net power can be obtained in the regenerative Rankine cycle for high turbine inlet pressures. However, Kalina cycle shows better net power and thermal efficiency for low turbine inlet pressures, and the optimum ammonia mass fractions of Kalina cycle are lower than Rankine cycles.

A Study on Emission Characteristics of Ar Gas Using a Single Langmuir Probe Method in Radio-Frequency Inductively Coupled Plasma (13.56MHz ICP에서 단일 탐침법에 의한 Ar 가스의 발광특성 연구)

  • Jo, Ju-Ung;Choi, Yong-Sung;Kim, Yong-Kab;Park, Dae-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.11a
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    • pp.611-615
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    • 2004
  • In recent, there have been several developments in lamp technology that promise savings in electrical power consumption and improved quality of the lighting space. Above all, Electrodeless fluorescent lamp is the removal of internal electrodes and heating filaments that are a light-limiting factor of conventional fluorescent lamps. The electrodeless fluorescent lamp is intended as a high efficacy replacement for the incandescent reflector lamp in many applications. Therefore, the electrodeless fluorescent lamps is substantially higher than that of conventional fluorescent lamps and last up to 60,000 hours. In this paper, electron temperature and electron density were measured in a radio-frequency inductively coupled plasma using a Langmuir probe method for emission characteristics. Measurement was conducted in an argon discharge for pressure from 10 [mTorr] and input RF power 100 [W] to 150 [W]. As for the electron density, a electron temperature was more distinguished for a emission characteristic. The results of ideal may contribute to systematic understanding of a electrodeless fluorescent lamps of emission characteristics.

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Reliability Analysis for Deuterium Incorporated Gate Oxide Film through Negative-bias Temperature Instability and Hot-carrier Injection (Negative-bias Temperature Instability 및 Hot-carrier Injection을 통한 중수소 주입된 게이트 산화막의 신뢰성 분석)

  • Lee, Jae-Sung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.8
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    • pp.687-694
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    • 2008
  • This paper is focused on the improvement of MOS device reliability related to deuterium process. The injection of deuterium into the gate oxide film was achieved through two kind of method, high-pressure annealing and low-energy implantation at the back-end of line, for the purpose of the passivation of dangling bonds at $SiO_2/Si$ interface. Experimental results are presented for the degradation of 3-nm-thick gate oxide ($SiO_2$) under both negative-bias temperature instability (NBTI) and hot-carrier injection (HCI) stresses using P and NMOSFETs. Annealing process was rather difficult to control the concentration of deuterium. Because when the concentration of deuterium is redundant in gate oxide excess traps are generated and degrades the performance, we found annealing process did not show the improved characteristics in device reliability, compared to conventional process. However, deuterium ion implantation at the back-end process was effective method for the fabrication of the deuterated gate oxide. Device parameter variations under the electrical stresses depend on the deuterium concentration and are improved by low-energy deuterium implantation, compared to conventional process. Our result suggests the novel method to incorporate deuterium in the MOS structure for the reliability.

Characteristic Features Observed in the East-Asian Cold Anomalies in January 2011 (2011년 1월의 동아시아 한랭 아노말리 특성)

  • Choi, Wookap;Jung, Jiyeon;Jhun, Jong-Ghap
    • Atmosphere
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    • v.23 no.4
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    • pp.401-412
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    • 2013
  • East Asia experienced extremely cold weather in January 2011, while the previous December and the following February had normal winter temperature. In this study National Centers for Environmental Prediction/National Center for Atmospheric Research (NCEP/NCAR) reanalysis data are used to investigate the characteristic features observed in the meteorological fields such as temperature, sea-level pressure, geopotential height, and wind during this winter period. In January the planetary-wave pattern is dominated by stationary-wave form in the mid-to-high latitude region, while transient waves are significant in the previous month. To understand the planetary-wave features quantitatively, harmonic analyses have been done for the 500-hPa geopotential height field. In the climatological-mean geopotential heights the wave numbers 1, 2, and 3 are dominant during the whole winter. In January 2011 the waves of number 1, 2, and 3 are dominant and stationary as in the climatological-mean field. In December 2010 and February 2011, however, the waves of number 4, 5, and 6 play a major role and show a transient pattern. In addition to the distinctive features in each month the planetary-wave patterns dependent on the latitude are also discussed.

A Study on the Mitigation of Vapor Explosions with Tin-Water Sytem (주석-물 시스템의 증기폭발 완화에 대한 연구)

  • Shin Y.S.;Kim J.H.;Hong S.W.;Song J.H.;Kim H.D.
    • Proceedings of the KSME Conference
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    • 2002.08a
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    • pp.397-400
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    • 2002
  • Vapor explosion is one of the most important problems encountered in severe accident management of nuclear power plants. In spite of many efforts, a lot of questions still remain. So, KAERI launched a real experimental program called TROI using $UO_{2}$ and $ZrO_{2}$ to investigate the vapor explosion. Besides TROI tests, a small-scale experiment with molten-tin/water system was performed to quantify the characteristics of vapor explosion and to understand the phenomenology of vapor explosion. A vapor explosion was observed while the amount of air bubble and water temperature were systematically varied The mass and temperature of tin are $50\;g\;and\;150^{\circ}C$, respectively. Water temperature is set to $24^{\circ}C\;and\;50^{\circ}C$. The void fraction of air bubble ranges from $0\;to\;10\;{\%}$. The strength of vapor explosion was measured using dynamic pressure sensors attached in reactor tube wall. as a function of void fraction. In addition, a high speed video filming up to 1,000 flame/sec was taken in order to visually investigate the behavior of the vapor explosion .

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A Study on Thermal and Modal Characteristics for EGR System with Dimpled Rectangular Tube (딤플 사각 튜브형 배기 가스 재순환 시스템의 열 및 진동 특성에 관한 연구)

  • Seo, Young-Ho;Heo, Sung-Chan;Kwon, Young-Seok;Ku, Tae-Wan;Kim, Jeong;Kang, Beom-Soo
    • Journal of the Korean Society for Precision Engineering
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    • v.25 no.3
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    • pp.115-125
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    • 2008
  • Recently, Exhaust Gas Recirculation (EGR) system which re-flow a cooled exhaust gas from vehicles burning diesel as fuel to a combustion chamber of engine has been used to solve the serious air pollution. For the design and mass production of EGR system, it is essential to ensure structural integrity evaluation. The EGR system consisted of ten dimpled oval core rectangular tubes, two fix-plates, two coolant pipes, shell body and two flanges in this study. To confirm the safety of the designed system, finite element modeling about each component such as the dimpled oval core tube with the dimpled shape and others was carried out. The reliability of EGR system against exhaust gas flow with high temperature was investigated by flow and pressure analysis in the system. Also, thermal and strength analysis were verified the safety of EGR system against temperature change in the shell and tubes. Furthermore, modal analysis using ANSYS was also performed. From the results of FE analysis, there were confirmed that EGR system was safe against the flow of exhaust gas, temperature change in EGR system and vibration on operation condition, respectively.

A Study of the Behavior of Liquid Phase Spray Considering Critical Condition of the Fuel (연료의 임계조건을 고려한 디젤 액상분무거동에 관한 연구)

  • Park, Jong-Sang;Kim, Si-Pom;Chung, Sung-Sik;Ha, Jong-Yul;Yeom, Jeong-Kuk
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.31 no.5
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    • pp.467-472
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    • 2007
  • In this study the penetration distance of liquid phase fuel(i.e. liquid phsae length) was investigated in evaporative field. An exciplex fluorescence method was applied to the evaporative fuel spray to measure and investigate both the liquid and the vapor phase of the injected spray. For accurate investigation, images of the liquid and vapor phase regions were recorded using a 35mm still camera and CCD camera, respectively. Liquid fuel was injected from a single-hole nozzle (l/d=1.0mm/0.2mm) into a constant-volume chamber under high pressure and temperature in order to visualize the spray phenomena. Experimental results indicate that the liquid phase length decreased down to a certain constant value in accordance with increase in the ambient gas density and temperature. The constant value, about 40mm in this study the, is reached when the ambient density and temperature of the used fuel exceed critical condition.

A Study on the Riskiness of Dust Explosion of Feed-Stuff (가축사료의 분진폭발 위험성에 관한 연구)

  • 이창우;함영민;김정환;현성호
    • Fire Science and Engineering
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    • v.12 no.2
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    • pp.61-68
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    • 1998
  • According to the results for the thermodynamic stability of feed-stuff dust, there are little change of initiation temperature of heat generation and heating value for used particle size. But initiation temperature of heat generation decreased with high heating rate whereas decomposition heat increased with particle size. Using the supporting gas, O2, initiation temperature of heat generation decreased remarkably than using the inert gas, N2, and heating value increased as twenty times under the same condition. When the ignition energy is given from the outside, used fine particle which can float in the air easily reacted tremendously with oxygen. Average maximum explosion pressure was 6.88 Kgf/$\textrm{cm}^2$ for 80/100 mesh.

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