• Title/Summary/Keyword: high temperature high pressure

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The temperature and density distribution of molecular gas in a galaxy undergoing strong ram pressure: a case study of NGC 4402

  • Lee, Bumhyun;Chung, Aeree
    • The Bulletin of The Korean Astronomical Society
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    • v.40 no.1
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    • pp.77.2-77.2
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    • 2015
  • Galaxies are known to evolve passively in the cluster environment. Indeed, much evidence for HI stripping has been found in cluster galaxies to date, which is likely to be connected to their low star formation rate. What is still puzzling however, is that the molecular gas, which is believed to be more directly related to star formation, shows no significant difference in its fraction between the cluster population and the field galaxies. Therefore, HI stripping alone does not seem to be enough to fully understand how galaxies become passive in galaxy clusters. Intriguingly, our recent high resolution CO study of a subsample of Virgo spirals which are undergoing strong ICM pressure has revealed a highly disturbed molecular gas morphology and kinematics. The morphological and kinematical peculiarities in their CO data have many properties in common with those of HI gas in the sample, indicating that strong ICM pressure in fact can have impacts on dense gas deep inside of a galaxy. This implies that it is the molecular gas conditions rather than the molecular gas stripping which is more responsible for quenching of star formation in cluster galaxies. In this study, using multi transitions of 12CO and 13CO, we investigate the density and temperature distributions of CO gas of a Virgo spiral galaxy, NGC 4402 to probe the physical and chemical properties of molecular gas and their relations to star formation activities.

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Improvement of Long-term Creep Life Prediction Method of Gr. 91 steel for VHTR Pressure Vessel (초고온가스로 압력용기용 Gr. 91 강의 장시간 크리프 수명 예측 방법 개선)

  • Park, Jae-Young;Kim, Woo-Gon;EKAPUTRA, I.M.W.;Kim, Seon-Jin;Kim, Min-Hwan
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.10 no.1
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    • pp.64-69
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    • 2014
  • Gr. 91 steel is used for the major structural components of Generation-IV reactor systems, such as a very high temperature reactor(VHTR) and sodium-cooled fast reactor(SFR). Since these structures are designed for up to 60 years at elevated temperatures, the prediction of long-term creep life is important for a design application of Gr. 91 steel. In this study, a number of creep rupture data were collected through world-wide literature surveys, and using these data, the long-term creep life was predicted in terms of three methods: the single-C method in Larson-Miller(L-M) parameter, multi-C constant method in the L-M parameter, and a modified method("sinh" equation) in the L-M parameter. The results of the creep-life prediction were compared using the standard deviation of error value, respectively. Modified method proposed by the "sinh" equation revealed better agreement in creep life prediction than the single-C L-M method.

Lipase-catalyzed Esterification of (S)-Naproxen Ethyl Ester in Supercritical Carbon Dioxide

  • Kwon, Cheong-Hoon;Lee, Jong-Ho;Kim, Seung-Wook;Kang, Jeong-Won
    • Journal of Microbiology and Biotechnology
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    • v.19 no.12
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    • pp.1596-1602
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    • 2009
  • A lipase-catalyzed esterification reaction of (S)-naproxen ethyl ester by CALB (Candida antarctica lipase B) enzyme was performed in supercritical carbon dioxide. Experiments were performed in a high-pressure cell for 10 h at a stirring rate of 150 rpm over a temperature range of 313.15 to 333.15 K and a pressure range of 50 to 175 bar. The productivity of (S)-naproxen ethyl ester was compared with the result in ambient condition. The total reaction time and conversion yields of the catalyzed reaction in supercritical carbon dioxide were compared with those at ambient temperature and pressure. The experimental results show that the conversion and reaction rate were significantly improved at critical condition. The maximum conversion yield was 9.9% (216 h) at ambient condition and 68.9% (3 h) in supercritical state. The effects of varying amounts of enzyme and water were also examined and the optimum condition was found (7 g of enzyme and 2% water content).

Large Eddy Simulation for the Analysis of Practical Combustion Field (실용 연소장 해석을 위한 대 와동 모사)

  • Hwang, Cheol-Hong;Lee, Chang-Eon
    • 한국연소학회:학술대회논문집
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    • 2005.10a
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    • pp.181-188
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    • 2005
  • Large eddy simulation(LES) methodology used to model the isothermal swirling flows in a dump combustor and the turbulent premixed flame in a model gas turbine combustor. The LES solver was implemented on parallel computer consisting 16 processors. In isothermal flow simulation, the results was compared with that of ${\kappa}-{\varepsilon}$ model as well as experimental data, in order to verify the capability of LES code. To model the turbulent premixed flame in a gas turbine, the G-equation flamelet model was used. The results showd that LES and RANS well predicted the mean velocity field of a non-swirling flow. However, in swirling flow, LES showed a better performance in predicting the mean axial and azimuthal velocities, and the central recirculation zone than those of RANS. In a model gas turbine combustor, the operation condition of high pressure and temperature induced the different phenomena, such as flame length and flow-field information, comparing with the condition of ambient pressure and temperature. Finally, it was identified that the flame and heat release oscillations are related to the vortex shedding generated by swirl flow and pressure wave propagation.

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Study on the Characteristics of Methanol Steam Reformer Using Latent Heat of Steam (수증기의 잠열을 이용한 메탄올 수증기 개질기의 특성 연구)

  • CHEON, UKRAE;AHN, KANGSUB;SHIN, HYUNKHIL
    • Journal of Hydrogen and New Energy
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    • v.29 no.1
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    • pp.19-24
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    • 2018
  • Fuel cells are used to generate electricity with a reformer. In particular, methanol has various advantages among the fuels for reformer. Methanol steam reformer devices can efficiently supply hydrogen to PEM fuel cell. This study investigated the optimal operation conditions of a methanol steam reforming process. For this purpose, aspen HYSYS was used for the optimization of reforming process. The optimal operating condition could be designed by setting independent variables such as temperature, pressure and steam to carbon ratio (SCR). The optimal temperature and steam to carbon ratio were $250-270^{\circ}C$ and 1.3-1.5, respectively. It is advantageous to operate at a pressure of 15-20 barg, considering the performance of the hydrogen purifier. In addition, a heat exchange network was designed to supply heat constantly to reformer through the latent heat of steam.

Effects of a Flow Guide on the Arcing History in a Thermal Puffer Plasma Chamber (유동 가이드가 열파퍼 플라즈마 챔버의 아크현상 이력에 미치는 영향)

  • Lee, Jong-Chul;Kim, Youn-Jea
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.31 no.10
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    • pp.832-839
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    • 2007
  • The geometry and dimensions of an expansion chamber are decisive factors in thermal puffer plasma chamber designs. Because they together dominate the temperature and speed at which the cooling gas from the chamber flows back through a flow channel to the arcing zone for the successful interruption of fault currents. In this study, we calculated the flow and mass transfer driven by arc plasma, and investigated the effects of a flow guide installed inside a thermal puffer plasma chamber. It is found that the existing cold gas of the chamber mixes with hot gases entrained from the arcing zone and is subjected to compression due to pressure build-up in the chamber. The pressure build-up with the flow guide is larger than that without due to a vortex which rotates clockwise around the chamber center. By the reverse pressure gradient, the mixing gas of the chamber flows back out for cooling down the residual plasma near current zero. In the case with the flow guide, the temperature just before current zero is lower than that without, and the Cu concentration with high electrical conductivity is also less than that without the flow guide.

The Effects of Temperature and Pressure on Synthesis of Zeolite 4A from Coal Fly Ash by Hydrothermal Reaction (석탄 비산회로부터 수열법에 의한 제올라이트 4A의 합성시 온도와 압력의 영향)

  • Yoon, Cheol;Yeon, Ik-Jun;Kim, Kwang-Yul
    • Journal of the Korean Applied Science and Technology
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    • v.16 no.3
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    • pp.217-221
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    • 1999
  • This study was carried out to synthesis the zeolite using the bituminous coal fly ash emitted from power plant that occurs several environmental problems. In spite of fly ash has contained high content of $SiO_2$ and $Al_2O_3$, it disposed mainly landfill. If the effective methods to recover the $SiO_2$ and $Al_2O_3$ were developed, the fly ash could be utilized valuable raw materials. In this study, fly ash was used as raw material to synthesize the zeolite by pressurized hydrothermal reaction. Also, experimental parameters included temperature($70{\sim}110^{\circ}C$, and pressure($140{\sim}200$ psi) of crystallization were investigated. The more crystallization pressure was increased, the more Zeolite 4A was synthesized at 70 and $90^{\circ}C$. Zeolite 4A of metastable phase tend to be transformed into sodalite of stable phase at $110^{\circ}C$.

Changes of Flavor Component in Tomato Fruits during Subatmospheric Pressure Storage (감압저장 중 토마토과실의 향기성분의 변화)

  • Sohn, Tae-Hwa;Cheon, Sung-Ho;Choi, Sang-Won;Moon, Kwang-Deok
    • Applied Biological Chemistry
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    • v.31 no.3
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    • pp.298-307
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    • 1988
  • The kinds of volatiles in tomato fruits during storage were increased with the period of climacteric rise. The increasing and decreasing rate of their contents were slower under subatmospheric pressure-low temperature (SAP-L) than under normal atmospheric pressure-normal temperature (NAP-N). High contents of 2-hexanone, n-pentanol, and ethanol were decreased at the early period of storage and then increased. The content of n-octanol and furfural were increased, while that of n-butanol, cyclohexanone, and phenylacetaldehyde was decreased during storage. On the other hand, the content of trans, trans-2,4-decadienol, benzyl alcohol, and 2-heptanone was not changed during storage.

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The Etching Characteristics of TMAH/AP for the Diaphragm Fabrication of Pressure Sensors (압력센서용 다이아프램 제작을 위한 TMAH/AP 식각특성)

  • 윤의중;김좌연
    • Journal of the Semiconductor & Display Technology
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    • v.2 no.4
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    • pp.19-22
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    • 2003
  • In this paper, Si anisotropic etching characteristics of tetramethylammonium hydroxide (TMAH)/ammonium persulfate (AP) solutions were investigated to realize the optimum structure of a diaphragm for the piezoresistive pressure sensor application. Due to its low toxicity and its high compatibility with the CMOS processing, TMAH was used as Si anisotropic etchants. The variations of Si etch rate on the etching temperature, TMAH concentration, and etching time were obtained. With increasing the etching temperature and decreasing TMAH concentrations, the Si etch rate is increased while a significant non-uniformity exists on the etched surface because of formation of hillocks on the <100> surface. With the addition of AP to TMAH solution, the Si etch rate is increased and an improvement in flatness on the etching front is observed. The Si etch rate is also maximized with increasing the number of addition of AP to TMAH solution per one hour. The Si square diaphragms of 20$\mu\textrm{m}$ thickness and 100-400 $\mu\textrm{m}$ one-side length were fabricated successfully by adding AP of (5/6)g to 800 ml TMAH solution every 10 minutes.

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Deposition of Super Hydrophobic a-C:F Films by Dielectric Barrier Discharge at Atmospheric Pressure

  • Kim, Duk-Jae;Kim, Yoon-Kee;Han, Jeon-Geon
    • Journal of Surface Science and Engineering
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    • v.44 no.2
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    • pp.50-54
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    • 2011
  • Hydrophobic a-C:F film was coated on polycarbonate film with $CF_4$, $C_2F_6$ and HFC ($C_2F_4H_2$) gas in helium discharge generated by 5~100 kHz AC power supply at atmospheric pressure and room temperature. The highest water contact angle of the a-C:F film formed with $He/C_2F_6$ mixed gas is $155^{\circ}$. X-ray photoelectron spectrum showed that there was 40% of C-$CF_3$ bond at the surface of the super hydrophobic film. The contact angle and deposition rate were decreased with increasing substrate temperature. The contact angle was generally increased with the surface roughness of the film. The contact angle was high when the surface microstructure of the film was fine and sharp at the similar roughness and chemical composition of the surface.