• Title/Summary/Keyword: high temperature high pressure

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A Study on Sample Preparation for the Analysis of Trace Elements in Foods of Animal Origin by Ultra High Pressure Microwave Digestion (초고압초음파분해법을 이용한 축산물내 미량금속 잔류분석을 위한 시료전처리 방법)

  • Lee, Myoung-heon;Lee, Hee-su;Son, Seong-wan;Jung, Gab-soo;Park, Jong-myung;Kim, Sang-keun
    • Korean Journal of Veterinary Research
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    • v.43 no.3
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    • pp.393-398
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    • 2003
  • Simple and rapid sample preparation method for trace elements in foods of animal origin using ultra high pressure microwave digestion system (UHP/MDS) and inductively coupled plasma atomic emission spectrometer (ICP/AES) were developed. 1. For the digestion of sample using UHP-MDS, 20% nitric acid (v/v) was the most suitable solvent for the determination of trace elements in foods of animal origin. 2. The optimal digestion conditions for UHP-MDS were as follows: final temperature $180^{\circ}C$, final pressure 400 PSI, and magnetic power 900 W in the solid sample. For the liquid sample final temperature $170^{\circ}C$, final pressure 300 PSI and magnetic power 700 W were optimal conditions. 3. As result of interlaboratory test, the average recovery rate of the for solid sample were 88.3~99.1% for As, 82.4~93.3% for Cd, 89.2~101.2% for Hg and 86.5~93.8% for Pb, respectively. In liquid sample, it were 87.0~96.8% for As, 80.9~96.6% for Cd, 87.5~91.2% for Hg and 91.4~95.5% for Pb, respectively. 4. The average coefficient variation rate were 3.3~15.9% for solid sample and 2.9~10.8% for liquid sample.

Measurement and Modeling of Bubble Points for Binary Mixtures of Carbon Dioxide and N,N-Dimethylformamide (이산화탄소와 디메틸포름아마이드 혼합물의 기포점 측정 및 모델링)

  • Jung, Joon-Young;Lee, Byung-Chul
    • Clean Technology
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    • v.17 no.1
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    • pp.19-24
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    • 2011
  • The bubble point pressures of binary mixtures of carbon dioxide ($CO_2$) and N,N-dimethylformamide (DMF) were measured by using a high-pressure experimental apparatus equipped with a variable-volume view cell, at various $CO_2$ compositions in the range of temperatures above the critical temperature of $CO_2$ and below the critical temperature of DMF. The experimental bubble point pressure data were correlated with the Peng-Robinson equation of state (PR-EOS) to estimate the corresponding dew point compositions at equilibrium with the bubble point compositions. The experimentally measured bubble point pressures gave good agreement with those calculated by the PR-EOS. The variable-volume view cell equipment was verified to be an easy and quick way to measure the bubble point pressures of high-pressure compressible fluid mixtures.

Measurement of Bubble Points of Dimethyl Carbonate and Carbon Dioxide Mixtures (디메틸카보네이트와 이산화탄소 혼합물의 기포점 측정)

  • Ahn, Joon-Yong;Lee, Byung-Chul
    • Applied Chemistry for Engineering
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    • v.20 no.1
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    • pp.94-98
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    • 2009
  • The bubble point pressures of dimethyl carbonate and carbon dioxide mixtures were measured by using a high-pressure experimental apparatus equipped with a variable-volume view cell, at various $CO_2$ compositions in the range of temperatures above the critical temperature of $CO_2$ and below the critical temperature of dimethyl carbonate. The experimental bubble point pressure data were correlated with the Peng-Robinson equation of state (PR-EOS) to estimate the corresponding dew point compositions at equilibrium with the bubble point compositions. The experimentally measured bubble point pressures gave good agreement with those calculated by the PR-EOS. The variable-volume view cell equipment was verified to be an easy and quick way to measure the bubble point pressures of high-pressure compressible fluid mixtures.

Analysis of performance and combustion characteristics of D.O./butanol blended fuels in a diesel engine (디젤기관에서 경유/부탄올 혼합연료의 기관성능 및 연소특성 해석)

  • KIM, Sang-Am;WANG, Woo-Gyeong
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.55 no.4
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    • pp.411-418
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    • 2019
  • In this study, to investigate the effect of physical and chemical properties of butanol on the engine performance and combustion characteristics, the coefficient of variations of IMEP (indicated mean effective pressure) and fuel conversion efficiency were obtained by measuring the combustion pressure and the fuel consumption quantity according to the engine load and the mixing ratio of diesel oil and butanol. In addition, the combustion pressure was analyzed to obtain the pressure increasing rate and heat release rate, and then the combustion temperature was calculated using a single zone combustion model. The experimental and analysis results of butanol blending oil were compared with the those of diesel oil under the similar operation conditions to determine the performance of the engine and combustion characteristics. As a result, the combustion stabilities of D.O. and butanol blending oil were good in this experimental range, and the indicated fuel conversion efficiency of butanol blending oil was slightly higher at low load but that of D.O. was higher above medium load. The premixed combustion period of D.O. was almost constant regardless of the load. As the load was lower and the butanol blending ratio was higher, the premixed combustion period of butanol blending oil was longer and the premixed combustion period was almost constant at high load regardless of butanol blending ratio. The average heat release rate was higher with increasing loads; especially as butanol blending ratio was increased at high load, the average heat release rate of butanol blending oil was higher than that of D.O. In addition, the calculated maximum. combustion temperature of butanol blending oil was higher than that of D.O. at all loads.

High-pressure Compaction of Sawdust of Hyunsasi-poplar (Populus alba ${\times}$ P. glandulosa) for Densified Fuel (고밀화에 의한 현사시 톱밥의 고형연료화)

  • 한규성;여진기
    • Journal of Korea Foresty Energy
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    • v.22 no.2
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    • pp.54-59
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    • 2003
  • Recently, densified pellet fuel from wood biomass is widely used at North America and Europe as a regenerable and clean carbon neutral bioenergy. High-pressure compaction of sawdust of Hyunsasi-poplar (Populus alba ${\times}$ P. glandulosa) to form a densified fuel was studied. Calorific and elemental analysis were carried out to assess Hyunsasi-poplar clones as fuels. Hot-press process was adopted for compaction of sawdust and compaction was performed under temperature from 100 to 180$^{\circ}C$, at pressure of 250 to 1000 kgf/$\textrm{cm}^2$, and for 2.5 to 10 minutes. Densified fuels were evaluated by its oven-dry density and fines after 5-minute shaking test. The target density and fines of densified fuels were over 1.2 g/$\textrm{cm}^2$ and below 0.5%, respectively. When the press-temperature is over 160$^{\circ}C$, densified fuels with density eve. 1.2 g/$\textrm{cm}^2$ and with fines below 0.5% can be produced. And the pressure over 750 kgf/$\textrm{cm}^2$ was effective for this production. It was found that the optimum press condition for preparation of densified fuel was 180$^{\circ}C$ -1000 kgf/$\textrm{cm}^2$ minutes.

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Calculations of radical and ion densities in a $CF_4$ plasma using global model (글로벌 모델에 의한 $CF_4$플라즈마에서의 라디칼 및 이온 밀도 계산)

  • 이호준;태흥식;이정희;이용현;황기웅
    • Journal of the Korean Vacuum Society
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    • v.7 no.4
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    • pp.374-380
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    • 1998
  • Radical and ion densities in a $CF_4$plasma have been calculated as a function of input power density, gas pressure and feed gas flow rate using simple 0 dimensional global model. Fluorine atom is found to be the most abundant neutral particle. Highly fragmented species such as CF and $CF^+$ become dominant neutral and ionic radical at the high power condition. As the pressure increase, ion density increases but ionization rate decreases due to the decrease in electron temperature. The fractional dissociation of $CF_4$feed gas decreases with pressure after increasing at the low pressure range. Electron density and temperature are almost independent of flow rate within calculation conditions studied. The fractional dissociation of $CF_4$monotonically decreases with flow rate, which results in increase in $CF_3$and decrease in CF density. The calculation results show that the $SiO_2$etch selectivity improvement correlates to the increase in the relative density of fluorocarbon ion and neutral radicals which has high C/F ratio.

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A Numerical Study on Pressure Variation in a Shock Tube by Changing the Diameter Ratio of Low-Pressure (Driven) to High-Pressure (Driver) Part (충격파관 저압실/고압실 직경비에 따른 압력변동에 대한 수치해석)

  • Wang, YuanGang;Kim, Chul Jin;Sohn, Chae Hoon;Jeung, In-Seuck
    • Journal of the Korean Society of Combustion
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    • v.21 no.4
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    • pp.16-22
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    • 2016
  • Pressure and temperature variations in a shock tube have been studied numerically by changing the diameter ratio of a driven part to a driver part. There are five cases where the adopted diameter ratios are 40%, 50%, 60%, 80%, and 100% respectively. The diameter of the driver part remains unchanged meanwhile the shock tube driven part diameter increases from 40% to 100% of the driver part. In the 100% ratio case, the driver part and driven parts have the same diameter of 66.9 mm. As the diameter ratio decreases, the pressure in the shock tube and available test time are increased.

Pin-Boss Bearing Lubrication Analysis of a Diesel Engine Piston Receiving High Combustion Pressure (고 연소압을 받는 디젤엔진 피스톤의 핀-보스 베어링 윤활해석)

  • Chun, Sang-Myung;Ha, Dae-Hong
    • Tribology and Lubricants
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    • v.24 no.3
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    • pp.133-139
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    • 2008
  • In recently designed diesel engines, the running conditions for piston pin bearings have become very severe due to combustion pressure and temperature increase. In this paper, it will be investigated the tendency of piston pin rotating motion by calculating the friction coefficient at piston pin bearings, the oil film thickness and the frictional torques induced by hydrodynamic shear stress. Finally, the pressure distributions on the oil film of piston pin bearings will be found by two-dimensional lubrication analysis in order to help the optimum design of the bearings of piston pin. Specially, it is investigated the effects on the film pressure distribution due to the change in maximum combustion pressure.

Two-Dimensional Analysis of Pressure Distribute by Underwater Electric Discharge (수중방전에 의한 압력분포의 2차원 해석)

  • Kim, Y.S.
    • Journal of the Korean Society for Precision Engineering
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    • v.12 no.1
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    • pp.68-77
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    • 1995
  • The two-dimensional pressure distribution, which is the most important parameter in the casting cleaning installations(CCI), was analyzed using the K-FIX computer program for two-phase flow. Modelling was done using R-Z coordinates for the initial and boundary conditions which don't have periodic influx and efflux, and also there was the electric discharge due to high pressure and temperature. The marked particles were introduced to prodict the structure and the size of main and local moving surfaces. The initial and boundary conditions were modified due to the internal structure of CCI.From the results of numerical analysis, it was shown that the maximum pressure on casting was increased with the increase of a water level. The pressure on casting in the radial direction was higher than that in axial direction. Also, it was proved that by introducing the marked particles it was possible to predict the surface structure in case of two-phase flow.

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Environmental Characteristics on Larval Release of Rockworm Polychaete Marphysa sanguinea (바위털갯지렁이(Marphysa sanguinea) 유생 방출에 미치는 환경특성)

  • Kim, Kyeong-Hun;Vo, Thi Thu Em;Kim, Hong Jin;Kim, Chang-Hoon
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.49 no.4
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    • pp.486-492
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    • 2016
  • This study investigates the relationship between environmental factors, such as semilunar rhythm and atmospheric pressure, and the release of Marphysa sanguinea larvae. During artificial seed production in a temperature-regulated culture system, there was an increase in the number of released larvae at tide times between 3-4 and 9-11. Numbers of larvae released were significantly correlated with tidal rhythms. Atmospheric pressure also appeared to influence larval release, with increased numbers released when a period of high atmospheric pressure followed a period of low pressure.