• Title/Summary/Keyword: high temperature aging

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Trend and Further Research of Rice Quality Evaluation (쌀의 품질평가 현황과 금후 연구방향)

  • Son, Jong-Rok;Kim, Jae-Hyun;Lee, Jung-Il;Youn, Young-Hwan;Kim, Jae-Kyu;Hwang, Hung-Goo;Moon, Hun-Pal
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.47
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    • pp.33-54
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    • 2002
  • Rice quality is much dependent on the pre-and post harvest management. There are many parameters which influence rice or cooked rice qualitys such as cultivars, climate, soil, harvest time, drying, milling, storage, safety, nutritive value, taste, marketing, eating, cooking conditions, and each nations' food culture. Thus, vice evaluation might not be carried out by only some parameters. Physicochemical evaluation of rice deals with amy-lose content, gelatinizing property, and its relation with taste. The amylose content of good vice in Korea is defined at 17 to 20%. Other parameters considered are as follows; ratio of protein body-1 per total protein amount in relation to taste, and oleic/linoleic acid ratio in relation to storage safety. The rice higher Mg/K ratio is considered as high quality. The optimum value is over 1.5 to 1.6. It was reported that the contents of oligosaccharide, glutamic acid or its derivatives and its proportionalities have high corelation with the taste of rice. Major aromatic compounds in rice have been known as hexanal, acetone, pentanal, butanal, octanal, and heptanal. Recently, it was found that muco-polysaccharides are solubilized during cooking. Cooked rice surface is coated by the muco-polysaccharide. The muco-polysaccharide aye contributing to the consistency and collecting free amino acids and vitamins. Thus, these parameters might be regarded as important items for quality and taste evaluation of rice. Ingredients of rice related with the taste are not confined to the total rice grain. In the internal kernel, starch is main component but nitrogen and mineral compounds are localized at the external kernel. The ingredients related with taste are contained in 91 to 86% part of the outside kernel. For safety that is considered an important evaluation item of rice quality, each residual tolerance limit for agricultural chemicals must be adopted in our country. During drying, rice quality can decline by the reasons of high drying temperature, overdrying, and rapid drying. These result in cracked grain or decolored kernel. Intrinsic enzymes react partially during the rice storage. Because of these enzymes, starch, lipid, or protein can be slowly degraded, resulting in the decline of appearance quality, occurrence of aging aroma, and increased hardness of cooked rice. Milling conditions concerned with quality are paddy quality, milling method, and milling machines. To produce high quality rice, head rice must contain over three fourths of the normal rice kernels, and broken, damaged, colored, and immature kernels must be eliminated. In addition to milling equipment, color sorter and length grader must be installed for the production of such rice. Head rice was examined using the 45 brand rices circulating in Korea, Japan, America, Australia, and China. It was found that the head rice rate of brand rice in our country was approximately 57.4% and 80-86% in foreign countries. In order to develop a rice quality evaluation system, evaluation of technics must be further developed : more detailed measure of qualities, search for taste-related components, creation and grade classification of quality evaluation factors at each management stage of treatment after harvest, evaluation of rice as food material as well as for rice cooking, and method development for simple evaluation and establishment of equation for palatability. On policy concerns, the following must be conducted : development of price discrimination in conformity to rice cultivar and grade under the basis of quality evaluation method, fixation of head rice branding, and introduction of low temperature circulation.

Life-time Prediction of a FKM O-ring using Intermittent Compression Stress Relaxation (CSR) and Time-temperature Superposition (TTS) Principle (간헐 압축응력 완화와 시간-온도 중첩 원리를 이용한 FKM 오링의 수명 예측 연구)

  • Lee, Jin-Hyok;Bae, Jong-Woo;Kim, Jung-Su;Hwang, Tae-Jun;Park, Sung-Doo;Park, Sung-Han;Min, Yeo-Tae;Kim, Won-Ho;Jo, Nam-Ju
    • Elastomers and Composites
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    • v.45 no.4
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    • pp.263-271
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    • 2010
  • Intermittent CSR testing was used to investigate the degradation of an FKM O-ring, also the prediction of its life-time. An intermittent CSR jig was designed taking into consideration the O-ring's environment under use. The testing allowed observation of the effects of friction, heat loss, and stress relaxation by the Mullins effect. Degradation of O-rings by thermal aging was observed between 60 and $160^{\circ}C$. In the high temperature of range ($100-160^{\circ}C$) O-rings showed linear degradation behavior and satisfied the Arrhenius relationship. The activation energy was about 60.2 kJ/mol. From Arrhenius plots, predicted life-times were 43.3 years and 69.9 years for 50% and 40% failure conditions, respectively. Based on TTS (time-temperature superposition) principle, degradation was observed at $60^{\circ}C$, and could save testing time. Between 60 and $100^{\circ}C$ the activation energy decreased to 48.3 kJ/mol. WLF(William-Landel-Ferry) plot confirmed that O-rings show non-linear degradation behavior under $80^{\circ}C$. The life-time of O-rings predicted by TTS principle was 19.1 years and 25.2 years for each failure condition. The life-time predicted by TTS principle is more conservative than that from the Arrhenius relationship.

Quantitative Evaluation of Free CaO in Electric Arc Furnace Reduction Slag using the Ethylene Glycol Method (에틸렌 글리콜법을 이용한 전기로 환원슬래그의 Free CaO 정량 평가에 관한 연구)

  • Kwon, Seung-Jun;Lim, Hee-Seob;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.18 no.4
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    • pp.321-327
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    • 2018
  • Blast furnace slag has been actively used as a substitute for cement in the construction field with high value-added through resource recycling research. However, most of the slag cannot find a clear recycling purpose. This is because some slags contain unstable materials and are used for road-use asphalt and embankment, which are low value-added materials. Electric arc furnace reduction slag(ERS) has been reported to contain a large amount of unstable free CaO due to deoxidation and component adjustment. In this study, free CaO of ERS which is generated in Korean steelmakers is quantitatively evaluated by using ethylene glycol method. As a result of free CaO quantitative evaluation of ERS, it was confirmed that there is a big difference according to the location of each field. In addition, ERS generally existed in powder form as undifferentiated characteristics, but it was confirmed that free CaO content was different due to hydration product in aggregate form due to water treatment. In addition, free CaO is an amorphous material and its crystallization characteristics are different due to the influence of temperature when it is cooled. ERS requires a long-term aging period as it contains a lot of free CaO.

The Properties of Flow and Compressive Strength of Mortar According In Replacement Ratio of Rapidly-Chilled Steel Slag Pine Aggregate (급냉 제강 슬래그 잔골재 대체율에 따른 모르타르의 유동성 및 압축강도 특성)

  • Cho Sung-Hyun;Kim Jin-Man;Kim Moon-Han;Han Ki-Suk
    • Journal of the Korea Concrete Institute
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    • v.17 no.1 s.85
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    • pp.77-84
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    • 2005
  • The steel slag, a by-product which is produced by refining pig iron during the manufacture of steel, is mainly used as road materials after aging. It is necessary to age steel slag for long time in air because the reaction with water and free-CaO in steel slag could make the expansion of volume. This problem prevents steel slag from being used as aggregate for concrete. However, steel slag used in this study was controled by a air-jet method which rapidly cools substance melted at a high temperature. The rapidly-chilled method would prevent from generation of free-CaO in steel slag. This study dealt with the influence of the using rate of rapidly-chilled steel slag on flow, dosage of SP, W/C ratio, and strength of mortar by statistical experimental design. Also, the results of this experiment were approved by statistical analysis methods, such as analysis of variance and F-testing. As results of F-testing, this paper proved at $1\%$ level of significance that the more the using rate of rapidly-chilled steel slag increased, the more this affected the enhancement of flow, the decrease of dosage of SP and W/C ratio, and the development of compressive strength. Also, considering the fluidity and compressive strength of mortar, it is desirable to use $75\%$ of rapidly-chilled steel slag for river sand.

Neuroprotective Effect of Hwangryunhaedok-tang on the Brain Ischemia Induced by Four-Vessel Occlusion in Rats (황련해독탕(黃連解毒湯)의 4-VO로 유발한 흰쥐뇌허혈에 대한 신경보호효과)

  • 이민정;김영옥;이강진;유영법;김선여;김성수;김호철
    • The Journal of Korean Medicine
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    • v.23 no.4
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    • pp.161-168
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    • 2002
  • Objectives: Hwangryunhaedok-tang (Huang-lian-jie-du-tang, HRHDT, 黃連解毒湯) is a traditional Korean herbal medicine that is formulated with Coptidis Rhizoma, Phellodendri Cortex, Scutellariae Radix and Gardeniae Fructus. HRHDT is cold (寒) and bitter (苦) in nature and has general properties of clearing heat and detoxifying (淸熱解毒), strengthening the stomach and settling the liver (健胃平肝), and reducing inflammation, fever and swelling. This formula can prevent and treat artherosclerosis, hyperplasia of the endothelium, cerebral fluid circulation, cerebral vascular deterioration through aging, impairment of neurotransmitters, or disruption of the functioning of the cerebral cortex following infection or trauma. The purpose of the study reported here was to determine the neuroprotective effect of HRHDT on global ischemia induced by 4-vessel occlusion in Wistar rats. Methods: HRHDT extract was lyophilized after extraction with 85% methanol and 100% water. Rats were induced to 10 minutes of forebrain ischemia by 4-vessel occlusion (4-VO) and reperfused again. HRHDT was administered with a dose of 100 mg/kg, and 500 mg/kg of 85% methanol extracts and 100 mg/kg of 100% water extracts, respectively, at 0 min and 90 min after 4-VO. Rats were killed at 7 days after ischemia and the number of CA1 pyramidal neurons was counted in hippocampal sections stained with cresyl violet. Results: Body temperature of animals showed no significant difference between saline-treated groups and HRHDT extracts-treated groups until 5 hours of reperfusion. This result indicated that neuroprotective effects of HRHDT extracts were not due to hypothermic effects. The administration of HRHDT showed a significant neuroprotective effect on hippocampal CA1 neurons at 7 days after ischemia compared to the saline-treated group (P<0.001). HRHDT methanol extracts of 100 mg/kg, 500 mg/kg and HRHDT water extracts of 100 mg/kg showed 88.5%, 98.3% and 95.1 % neuroprotection, respectively. Conclusions: The results of this study demonstrate that administration of HRHDT is highly effective in reducing neuronal damage in response to transient global cerebral ischemia. HRHDT may involve many mechanisms that might account for its high degree of efficacy. A number of factors including free radicals, glutamate, calcium overload, NO, and various cytokines have been proposed to have an important role in causing neuronal death after short periods of global ischemia. Further studies are needed to know the neuroprotective mechanisms of HRHDT.

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Formation and Stability of Nanoemulsion Containing CoQ10 by Mechanical Emulsification (코엔자임 Q10을 함유하는 나노에멀젼의 제조)

  • Yoo, In-Sang
    • Applied Chemistry for Engineering
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    • v.23 no.5
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    • pp.467-473
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    • 2012
  • Coenzyme Q10 (CoQ10) is a natural lipid cofactor with antioxidant and anti-aging properties as cosmetic and food ingredients, involved in cellular energy metabolism. Here, nano-emulsions with CoQ10 were fabricated with lecithin, ethanol, oil, and sorbitan monostearate (Arlacel 60), as major components. Phase inversion emulsion method with ultrasonicator was utilized in producing CoQ10 solution, and stabilization effects from lecithin and ethanol and other diverse perturbation factors were evaluated over time. Physical properties of the emulsion were characterized such as its size, surface charges by zeta-potential, and the overall structures. Optimal concentrations of CoQ10 and Arlacel 60 were 0.8% and 3%, respectively, for producing the smallest sizes of nanoemersions in a 100 nm diameter with best morphology. No notable changes in the size were observed over 7 days from Ostwald ripening, when the concentration of Arlacel 60 was higher than 2%. Even after 270 days at room temperature, the size of nanoemulsions maintained as 115 nm in diameter, revealing only a 10% increase with high degrees of long termed stability and substantiality. In addition, changes in the surface potential occurred possible due to the flocculation effect on the nanoparticles.

The Stabilization of 20.0% Ascorbic Acid in Aqueous Cosmetic Formulation (아스코빅애씨드 고함량 안정화 수계 조성물 제조 방법)

  • Park, Jeong Mi;Eun, So Hee;Ko, Eun Ah;Han, Sang Keun;Kang, Hak Hee;Hyun, Seung Min
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.44 no.2
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    • pp.125-131
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    • 2018
  • Ascorbic acid (Vitamin C) has been widely used in skin care formulations. Due to its remarkable effects on anti-oxidation, collagen biosynthesis and whitening, ascorbic acid is considered as an effectible anti-aging active ingredient. But, the instability problems of ascorbic acid in cosmetic formulation such as oxidation, browning and changes in smell is the difficult issue to be overcome for the application of high concentration of ascorbic acid. We tried to stabilize the ascorbic acid in non-aqueous liquid formulation that contains polyol solvent at first. The non-aqueous system was effectible to reduce oxidation. But, ascorbic acid was crystallized in the non-aqueous formulation at the low temperature below $5^{\circ}C$. We tried to develop way to stabilize the ascorbic acid in aqueous solutions to solve the crystallizing problem. In this study, we search the optimal ratio of antioxidant combination, such as zinc sulfate, glutathione and curcuma longa (turmeric) root extract. Formulations were stored at - $16^{\circ}C$, $5^{\circ}C$, $25^{\circ}C$, $40^{\circ}C$, $50^{\circ}C$ and cycle($5-40^{\circ}C$) (in incubator) for a period of eight weeks to investigate their stability. In the stability analysis, the test parameters consisted of color, scent, phase separation and sedimentation. Ascorbic acid stability was checked by HPLC analysis.

Adaptive Digital Predistorter Using the NLMS Algorithm for the Nonlinear Compensation of the OFDM Communication System (OFDM통신시스템의 비선형 왜곡 보상을 위한 NLMS 알고리즘 방식의 디지털 적응 전치 왜곡기)

  • Kim Sang-Woo;Hieu Nguyen Thanh;Kang Byoung-Moo;Ryu Heung-Gyoon
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.16 no.4 s.95
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    • pp.389-396
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    • 2005
  • In this paper, we propose a pre-distortion method using the NLMS(Normalized Least Mean Square) algorithm to cope with hish PAPR(Peak to Average Power Ratio) problem in OFDM communication system. This proposed scheme estimates the distortion characteristics of HPA, and changes the characteristic against the distortion. Therefore, it can be shown that the adaptive characteristic of the NLMS pre-distorter is good to track the various nonlinear characteristic of HPA, even though HPA characteristic is changed by temperature variation or aging. From the performance analysis, SNR efficiency of NLMS pre-distorter is about $0.5\;\cal{dB}$ less than that of common numerical non-adaptive pre-distorter, when IBO(Input Back Off) is $0\;\cal{dB}$. However, the NLMS pre-distorter is better than the common numerical pre-distorter, because these two pre-distorters have similar performance in higher than $3\;\cal{dB}$ IBO, and the NLMS pre-distorter maintains the constant performance even though characteristic of HPA is changed.

Black Onions Manufactured via the Browning Reaction and Antioxidant Effects of Their Water Extracts (갈변반응을 이용한 흑양파의 제조 및 물 추출물의 항산화 효과)

  • Yang, Ya-Ru;Park, Yang-Kyun
    • Food Science and Preservation
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    • v.18 no.3
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    • pp.310-318
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    • 2011
  • The main objective of this study was to manufacture black onions using different methods, and to analyze the color and physiological and antioxidant activities of their water extracts. Black onions were produced via high-temperature aging (70, 80, and $90^{\circ}C$). At $90^{\circ}C$, onions with different weights (large, 90-L; medium, 90-M; and small, 90-S) and small onions with different appearances (whole, 90-S-W; cut, 90-S-C; and peeled, 90-S-P) were also produced. The colorimetry measurements showed that the extract from the 90-S-C black onion had the highest ${\Delta}E$ value among all the extracts from all the black onion groups. The extract from the 90-S-C black onion had a 3.3 times higher total phenol content than that from the $70^{\circ}C$ black onion extract (11.62 and 3.51 mg/g, respectively). The DPPH radical scavenging activities of the extracts from 90-S-W, 90-S-C, and 90-S-P were higher than those of the other black onion extracts, and the 90-S-C black onion extract had the highest level of 48.3% (at the concentration of 10 mg/ml). The 90-S-C black onion extract also had the highest level of antioxidant activities (ABTS radical scavenging activity, 0.84 mg AA eq/100 g, and nitrite scavenging ability, 49.8%). These results clearly demonstrated that 90-S-C was the best among the conditions used and that the water extract of the 90-S-C black onions had a significantly higher level of antioxidant activities than the extracts from the other black onions.

Effects of Weather Factors on the Work Loss Days of the Elderly Workers (기상요소가 장년근로자의 근로손실일수에 미치는 영향)

  • Choi, Jaewook;Kim, Taewan;Lee, Chansik
    • Korean Journal of Construction Engineering and Management
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    • v.20 no.1
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    • pp.41-51
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    • 2019
  • With the aging of the population and the slowdown of the job market, elderly workers make up a large portion of the construction workforce. Also, due to the nature of the construction industry, where outdoor work is frequent, the weather has a more sensitive impact on elderly workers than on younger ones. The study aims to analyze the degree of weather risks exposed to elderly workers in the construction industry using the measure of work loss days. To that end, construction accidents that affected 28,514 elderly workers in seven cities from 2012 to 2016 (a total of 12,789 days) were analyzed to calculate work loss days per different weather factors. The results show that the elderly workers were seriously affected when the temperature was between $-12^{\circ}C$ and $-10^{\circ}C$, humidity between 55% and 60%, precipitation between 128mm and 181mm, and wind speed between 5.5m/s and 6.5m/s, with the highest work loss days. The combined effects between the weather factors were also analyzed to identify the conditiosn that leaded to high work loss days of elderly workers. This study contributes to effective safety management and pleasant working environment between weather factors and shedding light on the relationship between weather factors and work loss days of elderly workers.