• Title/Summary/Keyword: high strength materials

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Structure and Properties of Syndiotactic Polystyrene Fibers Prepared in High-speed Melt Spinning Process

  • Hada Yoshiaki;Shikuma Haruo;Ito Hiroshi;Kikutani Takeshi
    • Fibers and Polymers
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    • v.6 no.1
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    • pp.19-27
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    • 2005
  • High-speed melt spinning of syndiotactic polystyrene was carried out using high and low molecular weight poly­mers, HM s-PS and LM s-PS, at the throughput rates of 3 and 6 g/min. The effect of take-up velocity on the structure and properties of as-spun fibers was investigated. Wide angle X-ray diffraction (WAXD) patterns of the as-spun fibers revealed that the orientation-induced crystallization started to occur at the take-up velocities of 2-3 km/min. The crystal modification was a-form. Birefringence of as-spun fibers showed negative value, and the absolute value of birefringence increased with an increase in the take-up velocity. The cold crystallization temperature analyzed through the differential scanning calorimetry (OSC) decreased with an increase in the take-up velocity in the low speed region, whereas as the melting temperature increased after the on-set of orientation-induced crystallization. It was found that the fiber structure development proceeded from lower take-up velocities when the spinning conditions of higher molecular weight and lower throughput rate were adopted. The highest tensile modulus of 6.5 GPa was obtained for the fibers prepared at the spinning conditions of LM s-PS, 6 g/min and 5 km/min, whereas the highest tensile strength of 160 MPa was obtained for the HM s-PS fibers at the take-up velocity of 2 km/min. Elongation at break of as-spun fibers showed an abrupt increase, which was regarded as the brittle-duc­tile transition, in the low speed region, and subsequently decreased with an increase in the take-up velocity. There was a uni­versal relation between the thermal and mechanical properties of as-spun fibers and the birefringence of as-spun fibers when the fibers were still amorphous. The orientation-induced crystallization was found to start when the birefringence reached -0.02. After the starting of the orientation-induced crystallization, thermal and mechanical properties of as-spun fibers with similar level of birefringence varied significantly depending on the processing conditions.

The Study on Blast Effects of Stemming Materials by Trauzl Lead Block Test and High Speed 3D-DIC Systems (트라우즐 연주시험 및 고속 3차원 이미지영상상관 기법을 이용한 전색재 별 발파효과에 대한 연구)

  • Ko, Younghun;Seo, Seunghwan;Kim, Sik;Chung, Youngjun;Chung, Moonkyung
    • Journal of the Korean Geotechnical Society
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    • v.37 no.10
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    • pp.13-25
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    • 2021
  • The most widely used method for determining the blast effects of explosives is the Trauzl test. This test is used to measure the explosive power (strength) of a substance by determining volume increase, which is produced by the detonation of a tested explosive charge in the cavity of a lead block with defined quality and size. In this paper, Trauzl lead block test and High speed 3D-DIC (Digital Image Correlation) system were conducted to evaluate the stemming effect of the blast hole. The effects of stemming materials can be expressed as the expansion of the cavity in a standard lead block through explosion of the explosives. The blasting experiment was conducted with emulsion explosives. The stemming material in the blast hole of lead block, which was adopted in this study, were using sand and stone chips. Results of blasting experiment and numerical analysis showed that the expansion rates of lead block were most affected by stone chips followed by sand. Also, as result of dynamic strain measurement on the lead block surface of High speed 3D-DIC system, the displacement and surface strain on the block were the highest in the experiment case of stone chips stemming.

Effect of Porcelain/Polymer Interface on the Microstructure, Insulation Characteristics and Electrical Field Distribution of Hybrid Insulators (자기재/폴리머 계면이 하이브리드 애자의 미세구조, 절연특성과 전계분포에 미치는 영향)

  • Cho, Jun-Young;Kim, Woo-Seok;An, Ho-Sung;An, Hee-Sung;Kim, Tae-wan;Lim, Yun-Seog;Bae, Sung-Hwan;Park, Chan
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.9
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    • pp.558-565
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    • 2017
  • Hybrid insulators that have the advantages of both porcelain (high mechanical strength and chemical stability) as well as polymer (light weight and high resistance to pollution) insulators, can be used in place of individual porcelain and polymer insulators that are used for both mechanical support as well as electrical insulation of overhead power transmission lines. The most significant feature of hybrid insulators is the presence of porcelain/polymer interfaces where the porcelain and polymer are physically bonded. Individual porcelain and polymer insulators do not have such porcelain/polymer interfaces. Although the interface is expected to affect the mechanical/electrical properties of the hybrid insulator, systematic studies of the adhesion properties at the porcelain/polymer interface and the effect of the interface on the insulation characteristics and electric field distribution of the hybrid insulator have not been reported. In this study, we fabricated small hybrid insulator specimens with various types of interfaces and investigated the effect of the porcelain/polymer interface on the microstructure, insulating characteristics, and electric field distribution of the hybrid insulators. It was observed that the porcelain/polymer interface of the hybrid insulator does not have a significant effect on the insulating characteristics and electric field distribution, and the hybrid insulator can exhibit electrical insulating properties that are similar or superior to those of individual porcelain and polymer insulators.

Evaluation Method for Snap Cure Behavior of Non-conductive Paste for Flip Chip Bonding (플립칩 본딩용 비전도성 접착제의 속경화거동 평가기법)

  • Min, Kyung-Eun;Lee, Jun-Sik;Lee, So-Jeong;Yi, Sung;Kim, Jun-Ki
    • Journal of Welding and Joining
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    • v.33 no.5
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    • pp.41-46
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    • 2015
  • The snap cure NCP(non-conducive paste) adhesive material is essentially required for the high productivity flip chip bonding process. In this study, the accessibility of DEA(dielectric analysis) method for the evaluation of snap cure behavior was investigated with comparison to the isothermal DSC(differential scanning calorimetry) method. NCP adhesive was mainly formulated with epoxy resin and imidazole curing agent. Even though there were some noise in the dielectric loss factor curve measured by DEA, the cure start and completion points could be specified clearly through the data processing of cumulation and deviation method. Degree of cure by DEA method which was measured from the variation of the dielectric loss factor of adhesive material was corresponded to about 80% of the degree of cure by DSC method which was measured from the heat of curing reaction. Because the adhesive joint cured to the degree of 80% in the view point of chemical reaction reveals the sufficient mechanical strength, DEA method is expected to be used effectively in the estimation of the high speed curing behavior of snap cure type NCP adhesive material for flip chip bonding.

Diffraction Efficiency Analysis of Silver Halide Film for Color Holography Recording

  • Park, Sung Chul;Kim, Sang Il;Son, Kwang Chul;Kwon, Soon Chul;Lee, Seung Hyun
    • International Journal of Internet, Broadcasting and Communication
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    • v.7 no.2
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    • pp.16-27
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    • 2015
  • Holography technology which was developed by Dennis Gabor (1900~1979) in 1948 is a technology to record wave planes of actual 3D objects. It is known as the only technology which can express 3D information most perfectly close to human-friendly. Holography technology is widely used in advertisement, architecture and arts as well as science technology areas. Especially, digital holographic print which is an applied area is greatly used in military map, architecture map and cultural asset restoration by printing and reproducing 3D information. Holography is realized by recording and reproducing the amplitude and phase information on high resolution film using coherent light like laser. Recording materials for digital holographic printer are silver halide, photoresist and photopolymer. Because the materials have different diffraction efficiency according to film characteristics of each manufacturer, appropriate guide lines should be suggested through efficiency analysis of each film. This paper suggests appropriate guide lines through the diffraction efficiency measurement of silver halide which is a holographic printer recording medium. And the objective of this study is to suggest appropriate guide lines through diffraction efficiency analysis of Ultimate 08-C and PFG-03C which are commercially used. The experiment was prepared by self-diffraction efficiency system which measures the strength with the defector by penetrating RGB recording medium and concentrating diffracted beams through collimating lens. The experiment showed Geola's PFG-03C which is a silver halide for full color has price/performance advantage in optical hologram recording, but recording angles and reproduction angles are irregular for digital holographic printer recording. Ultimate's Ultimate08-C for full color shows its diffraction efficiency is relatively stable and high according to recording angles and laser wavelength.

Behavior of Rapidly Expansion Materials for Maintenance Railroad Bed Subjected to Cyclic Loading (반복하중을 받는 철도노반 보수용 급속 팽창재료의 거동)

  • Lee, Jundae;Shin, Eunchul
    • Journal of the Korean GEO-environmental Society
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    • v.10 no.2
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    • pp.45-50
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    • 2009
  • The differential settlement may be generated by the variation of stresses caused by the soft ground or ground water. The cracks are usually created when the structures are leaned or deformed due to the differential settlement. A grouting method has been mainly used till now to improve the bearing capacity of the ground when the foundation of the structure is deformed by differential settlements. However, when this method is used, it takes too long time to obtain the required strength and the period of the reinforcement effect is not long enough. The advantage of GPCON injection method is to have good mechanical properties and durability, and easy construction. In addition, the GPCON method rapidly fills up the void in soils by injecting some materials into underground and also obtain the increase of bearing and shearing forces due to the expansion. In this paper the restoration capability of the foundation settlement of railway and subway subjected to cyclic loading is analytically and experimentally evaluated using the high density rapidly expansion GPCON in order to investigate the types of deformations and vibrational characteristics.

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Digital Hologram Encryption Algorithm using Fresnel Diffraction (프레넬 회절을 이용한 디지털 홀로그램 암호화 알고리즘)

  • Lee, Yoon-Hyuk;Seo, Young-Ho;Kim, Dong-Wook
    • Journal of Broadcast Engineering
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    • v.20 no.6
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    • pp.807-817
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    • 2015
  • This paper is to propose an encryption method for only an allowed user to see the content for a digital hologram, that is a high value-added content. This paper uses a characteristic of Fresnel transform that the object region is concentrated to a relatively small part of the diffraction plane. By encrypting the concentrated part only the region to be encrypted and in turn the amount of data to be encrypted is reduced a lot, which results in an high efficiency with low encryption rate. As the methodology, a digital hologram is first Fresnel transformed for reconstruction and the result is secondly Fresnel transformed to concentrate the energy into the center of the diffraction plane to encrypt the concentrated region only. For the 2nd transform, energy concentration degree is determined by adjusting the diffraction distance and encryption strength is determined by adjusting the scaling factor. For this we analyze the optimal encryption area according to the diffraction distance and the scaling factor. When applying the proposed method with diffraction distance of 20m the object information was visually unrecognizable with the encryption ratio only 0.005% ~ 0.02%.

The Effect of Heat Treatment on the Microstructures and Mechanical Properties of Inconel 713C Alloy Vacuum Investment Castings (진공 정밀주조한 Inconel 713C 합금의 조직과 기계적 성질에 미치는 열처리의 영향)

  • Yoo, Byung-Ki;Choi, Hak-Kyu;Park, Heung-Il;Jeong, Hae-Yong
    • Journal of Korea Foundry Society
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    • v.40 no.2
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    • pp.16-24
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    • 2020
  • The effect of a heat treatment on the microstructure and mechanical properties of Inconel 713C alloy vacuum investment castings were investigated. The microstructure of the as-cast state was observed, showing well-developed dendrite structures and distributed carbide particles and solidified massive precipitates in the grain or grain boundary during solidification, in this case the γ′ phase and MC particles. During a heat treatment, the γ phase matrix was reinforced by solid solution elements, carbide particles from the film morphology precipitated along the grain boundary, and many micro-precipitates of second γ′ phases 0.2 ㎛~2 ㎛ in size were newly formed in the γ phase matrix according to SEM-EDS analysis results. The tensile strength at a high temperature (850℃) decreased slightly becoming comparable with the room-temperature result, while the hardness value of the specimen after the vacuum heat treatment increased by approximately 19%, becoming similar to that of the as-cast condition. However, the impact values at room temperature and low temperature (-196℃) were approximated; this alloy was mostly not affected by an impact at a low temperature. In the observations of the fracture surface morphologies of the specimens after the tensile tests, the fractures at room temperature were a mix of brittle and ductile fractures, and an intergranular fracture in the inter-dendrite structure and some dimples in the matrix were observed, whereas the fractures at high temperatures were ductile fractures, with many dimples arising due to precipitation. It was found that a reinforced matrix and precipitates of carbide and the γ′ phase due to the heat treatment had significant effects, contributing greatly to the excellent mechanical properties.

A Study on the Corrosion of Al-Alloy Propeller Used for a Coasting Vessel (연안 선박용 Al합금 프로펠러의 부식에 관한 연구)

  • LIM, Uh-Joh;PARK, Hee-Ok;YUN, Byoung-Du
    • Journal of Fisheries and Marine Sciences Education
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    • v.15 no.2
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    • pp.176-183
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    • 2003
  • Recently, with the tendency of lightening, high-strength and high-speed in the marine industries such as marine structures, ships and propellers, it is rapidly enlarged the use of the aluminium alloy. Therefore, there occurs much interest in the study on corrosion characteristics of aluminium alloy. This paper was studied on the corrosion characteristics of Al-Mg alloy propeller used for a coasting vessel. Under the various pH of marine environment, the corrosion test of Al-Mg alloy was carried out. And thus polarization resistance, corrosion potential, and current density behavior of Al-Mg alloy and galvanic corrosion behavior of Al-brass and Al-Mg alloy coupled Al 5086 and SS 400 for hull were investigated. The main results are as following: 1. The corrosion potential of Al-brass propeller is more nobel than materials for hull, but that of Al-Mg alloy propeller is low or similar to materials for hull. Therefore, the galvanic corrosion of hull due to Al-Mg propeller don't occur. 2. The polarization resistance of Al-Mg alloy in sea water of pH 4 is highest, and corrosion current density of Al-Mg propeller is the most controlled. 3. As pH value decreases, potential showed Evans polarization diagram approaches cathodic potential. The corrosion current density of Al-Mg alloy is controlled to anodic reaction rate, therefore, the corrosion reaction of Al-Mg alloy is anodic control.

The Effect of Degradation on the Fretting fatigue for 1Cr-0.5Mo Steel (1Cr-0.5Mo 강의 재질열화가 프레팅 피로거동에 미치는 영향)

  • Kwon, Jae-Do;Choi, Sung-Jong;Kim, Kyung-Soo;Bae, Yong-Tak
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.27 no.11
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    • pp.1979-1985
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    • 2003
  • Fretting is a kind of surface degradation mechanism observed in mechanical components and structures. The fretting damage decreases in 50-70% of the plain fatigue strength. This may be observed in the fossil power plant and the nuclear power plant used in special environments and various loading conditions. The thermal degradation of material is observed when the heat resisting steel is exposed for long period time at the high temperature. In the present study, the degraded 1Cr-0.5Mo steel used for long period time at high temperature (about 515$^{\circ}C$) and artificially reheat-treated materials are prepared. These materials are used for evaluating an effect of thermal aging on the fretting fatigue behavior. Through the experiment, it is found that the fretting fatigue endurance limit of the reheat-treated 1Cr-0.5Mo steel decreased about 46% from the non-fretting fatigue endurance limit, while the fretting fatigue endurance limit of the degraded 1Cr-0.5Mo steel decreased about 53% from the non-fretting fatigue endurance limit. The maximum value of fatigue endurance limit difference is observed as 57%(244 MPa) between the fretting fatigue of degraded material and non-fretting fatigue of reheat-treated material. These results can be a basic data to a structural integrity evaluation of heat resisting steel considered to thermal degradation effect.