• Title/Summary/Keyword: high strength materials

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High Performance of Nano-sized LiFePO4 Positive Electrode Using Etched Al Current Collector

  • Lee, Gil-Won;Ryu, Ji-Heon;Oh, Seung-M.
    • Journal of the Korean Electrochemical Society
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    • v.13 no.3
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    • pp.157-162
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    • 2010
  • The electrodes comprising nano-sized $LiFePO_4$, carbon black and binder are prepared with two different Al current collectors. One is the generally used normal Al foil and the other is the chemically etched Al foil. Surface characteristics of each Al foil and electrochemical performance of the cathodes using each foil are investigated. The electrode from the etched Al foil exhibits better physical and electrochemical properties as compared to those of the normal Al foil because the etched Al foil has rough surface with sub-micron pores which improve the adhesion between the electrode materials and the substrate. The electrode on the etched Al foil has such a strong peel strength that the impedance is smaller than that of normal one. Indeed the $LiFePO_4$ electrode from the etched Al foil exhibits a better rate capability and remains intact even after storage for 1 week at the charged state at the elevated temperature $60^{\circ}C$.

Thermal conductivity and properties of sheath alloy for High-$T_c$ superconductor tape (고온초전도 선재용 피복합금의 열전도도 측정 및 특성평가)

  • 박형상;지봉기;김중석;임준형;오승진;오승진;주진호;나완수;유재무
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.8
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    • pp.711-717
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    • 2000
  • Effect of alloying element additions to Ag on thermal conductivity electrical conductivity and mechanical properties of sheath materials for BSCCO tapes has been characterized. The thermal conductivity at low temperature range(10~300K) of Ag alloys were evaluated by both direct and indirect measurement techniques and compared with each other. It was observed that thermal conductivity decreased with increasing the content of alloying elements such as Au, Pd and Mg. Thermal conductivity of pure Ag at 30 K was measured to be 994.0 W/m.K on the other hand the corresponding values of A $g_{0.9995}$/M $g_{0.0005}$, A $g_{0.974}$/A $u_{0.025}$/M $g_{0.001}$, A $g_{0.973}$/Au.0.025//M $g_{0.002}$, and A $g_{0.92}$/P $d_{0.06}$/M $g_{0.02}$ were 342.6, 62.1, 59.2, 28.9 W/m.K respectively indicating 3 to 30 times lower than that of pure Ag. In addition alloying element additions to Ag improved mechanical strength while reduced elongation probably due to the strengthening mechanisms by the presence of additive atoms.s.

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A Study on the Effect of Ti Ion Bombardment on the Interface in a Duplex Coating (Duplex coating에서 계면구조에 미치는 Ti 이온충격의 효과에 대한 연구)

  • Baek, Un-Seung;Gwon, Sik-Cheol;Lee, Jae-Yeong;Na, Jong-Ju;Lee, Sang-Ro;Lee, Gu-Hyeon;Lee, Geon-Hwan
    • 연구논문집
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    • s.28
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    • pp.219-227
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    • 1998
  • In order to investigate the interfacial structure between TiN and iron nitride, an AISI 4140 steel was nitrided to form a layer of thickness 15$\mum$ by DC ion nitriding, then the surface was bombarded with Ti ions and subsequently coated a TiN film of 5$\mum$ by arc ion plating method. The interfacial microstructure between TiN and iron nitride was characterized by optical microscope, SEM and XRD. So called black layer was observed in the duplex treatment. It was resulted from the decomposition of iron nitride during the bombardment. Its thickness was increased with increasing bombardment time at high bias voltage. But the thickness was greatly decreased when the iron nitride was bombarded with a nitrogen gas or at a reduced bias voltage. The adhesion strength of the top TiN coating was decreased with increasing thickness of the black layer. Furthermore, the reduced adhesion strength in this system was discussed in view of the interfacial structural relationship between TiN and iron nitride.

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Structural Characteristics of Pultruded Glass Fiber Reinforced Composite Strip (풀투루젼으로 제조한 유리섬유강화 복합소재를 스트립의 구조적 특성)

  • 이성우;신경재
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 1999.10a
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    • pp.11-18
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    • 1999
  • Recently advanced countries are now beginning to use ACM (Advanced Composites Material), which is mostly used in the industry of airplane, ship building and sports equipments, in the construction industry. Compared with existing construction materials, ACM possesses many advantages such as light-weight, high-strength, corrosion resistant property. Among other manufacturing process of ACM, pultrusion is one of the promising one of civil engineering application. In this paper, the structural characteristics of pultruded GFRP strip were studied. Major parameters to influence structural behavior of pultruded GFRP are considered to be fiber volume fraction, die temperature, pulling speed and fiber orientations. The effect of these parameters are studied by experimently and analytically. From this study, it is concluded that fiber volume fraction and fiber orientations influence more on the mechanical property of pultruded GFRP. In addition to above parametric study, off-axis tests were carried out and the results are compared with failure theories. It showed that they agree well each other. Since this study is carried out in limited scope, further research on the reinforcement in the transverse direction, experiment on the compressive strength and research on the durability should be conducted for wide application of pultruded GFRP sections.

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Cavitation Characteristics of Al-Mg and Al-Mg-Si Alloy for Ship in Sea Water (선체 재료용 Al-Mg 합금과 Al-Mg-Si 합금의 해수 내 캐비테이션 특성)

  • Kim, Seong-Jong;Kim, Kyu-Hwan;Lee, Seung-Jun
    • Corrosion Science and Technology
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    • v.10 no.4
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    • pp.136-142
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    • 2011
  • Al alloys have been used widely for commercial and military ships in most ocean countries since mid-1950s, and the value as light metal with high mechanical strength has been proven. As the safety and fuel efficiency of Al ships have improved, she can carry more freight, sail faster and travel longer distances. Furthermore, in the shipbuilding industry, Al alloys are applied as structural materials for ships to various areas including the deck of luxurious cruises, battleships and leisure ships. In addition, Al alloys are being spotlighted as environmental-friendly material as they can be recycled even after end of lifespan. However, Al alloys for ships must be carefully selected after considering corrosion resistance, endurance, strength, and weldability in sea water environment. Al alloys to satisfy these conditions are used widely include 5000 series Al-Mg alloy and 6000 series Al-Mg-Si alloy. Thus, this study selected and evaluated the cavitation characteristics of the 5000 series Al alloys that are used in hulls that directly contact seawater and the 6000 Al alloys that are used in the upper structures of ships. Results of cavitation test with time, weightloss and cavitation rate of 5456-H116 showed the smallest damage among 5052-O, 5456-H116 and 6061-T6.

Effect of Cold Rolling on Fatigue Crack Propagation of TiNi/A16061 Shape Memory Composite (TiNi/A16061 형상기억복합재료의 피로균열진전에 대한 냉간압연효과)

  • Lee Jin-Kyung;Park Young-Chul;Lee Kyu-Chang;Lee Sang-Pill;Cho Youn-Ho;Lee Joon-Hyun
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.29 no.10 s.241
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    • pp.1315-1320
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    • 2005
  • TiNi alloy fiber was used to recover the original shape of materials using its shape memory effect. The shape memory alloy plays an important role within the metal matrix composite. The shape memory alloy can control the crack propagation in metal matrix composite, and improve the tensile strength of the composite. In this study, TiNi/A16061 shape memory alloy(SMA) composite was fabricated by hot press method, and pressed by a roller for its strength improvement. The four kinds of specimens were fabricated with $0\%,\;3.2\%,\;5.2\%\;and\;7\%$ and volume fraction of TiNi alloy fiber, respectively. A fatigue test has performed to evaluate the crack initiation and propagation for the TiNi/A16061 SMA composite fabricated by かis method. In order to study the shape memory effect of the TiNi alloy fiber, the test has also done under both conditions of the room temperature and high temperature. The relationship between the crack growth rate and the stress intensity factor was clarified for the composite, and the cold rolling effect was also studied.

Characteristics of GMA Weld Zone on TiO2 Different Component Flux Cored Wire for S500 Grade Steel (TiO2 성분 플럭스충진와이어에 따른 S500강의 GMA 용접부 특성)

  • Yoo, Cheol;Ko, Young-Bong;Park, Kyeung-Chae
    • Journal of Surface Science and Engineering
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    • v.48 no.6
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    • pp.335-342
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    • 2015
  • Recently, the production of oil and gas at the arctic ocean and offshore has been growing. Accordingly, S500 steel with the high tensile strength and excellent toughness has been used and flux cored wire that can be welded to the S500 has been required. In this study, we carried out observation of microstructures, mechanical properties and CTOD (crack tip openning displacement) in the weld zone that GMA (gas metal arc) welded with different component of $TiO_2$ flux core wire (the main components, rutile or Ti-slag) for S500 steel. Weld zone produced with Ti-slag flux cored wire has formed a enough acicular ferrite and shown excellent impact toughness at $-40^{\circ}C$, tensile strength at room temperature and CTOD at $-20^{\circ}C$. As a result, the developed flux cored wire was suitable for S500 steel.

The Minimum Lap-spliced Length of the Reinforcement in the Steam Curing UHPC Bridge Deck Slab Joint (UHPC 바닥판 증기양생 현장이음부의 최소철근겹침이음길이)

  • Hwang, Hoon-Hee;Park, Sung-Yong
    • Composites Research
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    • v.26 no.2
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    • pp.135-140
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    • 2013
  • The static test was performed to verify the effect of the joint in the UHPC bridge deck slab and the minimum lap-spliced length was presented. A total of six test members was fabricated to estimate the static behavior of the steam curing UHPC bridge deck slab joint by the four points bending test method. The lap-spliced joint type was expected to be not only simple but also efficient in UHPC structure because of the high bond stress of UHPC. Test results show that the decrease of maximum flexural strength was about 30% and the minimum lap-spliced length which behaved similar to the continued reinforcement in strength and ductility was 150 mm.

Application of Copper Slag as Sand Substitute in SCP Pilot tests (SCP 현장시험시공을 통한 동슬래그의 모래대체재로서의 적용성 연구)

  • 천병식;정헌철;김경민
    • Proceedings of the Korean Geotechical Society Conference
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    • 2002.10a
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    • pp.613-620
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    • 2002
  • Sand Compaction Pile(SCP) is a soil improvement method that a sand charge is introduced into the pipe, and the pipe is withdrawn part away while the sand pile is compacted and its diameter is enlarged. The sand used in this method should be of good quality. In Korea, crushed stone and washed sea sand are used frequently in SCP. However, use of these materials is restricted because of environmental problem and deficiency of supply. In the copper smelting process, about 0.7 million tons of copper slag are produced in Korea. The range of particle size distribution of copper slag is from 0.15mm to 5mm, so it can be a substitute for sand, and the relatively high specific gravity compared with the sand, is its characteristic. Copper slag is hyaline and so stable environmentally that in foreign country, such as Japan, Germany etc., it is widely used in harbor, revetment and offshore structure construction works. Therefore, in this study, the several laboratory tests were peformed to evaluate the applicability of copper slag as a substitute for sand of SCP. From the mechanical property test, the characteristics of sand and copper slag were compared and analyzed, and from laboratory model test, the strength of composite ground was compared and analyzed by monitoring the stress and ground settlement of clay, SCP and copper slag compaction pile. Specially, this study focused on the application of copper slag as sand substitute in SCP pilot tests based on laboratory tests results.

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Effect of slag on stabilization of sewage sludge and organic soil

  • Kaya, Zulkuf
    • Geomechanics and Engineering
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    • v.10 no.5
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    • pp.689-707
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    • 2016
  • Soil stabilization is one of the useful method of ground improvement for soil with low bearing capacity and high settlement and unrequired swelling potential. Generally, the stabilization is carried out by adding some solid materials. The main objective of this research was to investigate the feasibility of stabilization of organic soils and sewage sludge to obtain low cost alternative embankment material by the addition of two different slags. Slags were used as a replacement for weak soil at ratios of 0%, 25%, 50%, 75% and 100%, where sewage sludge and organic soil were blended with slags separately. The maximum dry unit weights and the optimum water contents for all soil mixtures were determined. In order to investigate the influence of the slags on the strength of sewage sludge and organic soil, and to obtain the optimal mix design; compaction tests, the California bearing ratio (CBR) test, unconfined compressive strength (UCS) test, hydraulic conductivity test (HCT) and pH tests were carried out on slag-soil specimens. Unconfined compressive tests were performed on non-cured samples and those cured at 7 days. The test results obtained from untreated specimens were compared to tests results obtained from soil samples treated with slag. Laboratory tests results indicated that blending slags with organic soil or sewage sludge improved the engineering properties of organic or sewage sludge. Therefore, it is concluded that slag can be potentially used as a stabilizer to improve the properties of organic soils and sewage sludge.