• Title/Summary/Keyword: high porosity

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Airtightness performance evaluation of ultra-high performance concrete using polymer coating materials (그래핀을 활용한 폴리머 도막재료의 물리적 특성 평가)

  • Lee, Hyun Seung;Kim, Kang Min;Yoon, Seob;Seo, Tae Suk
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.11a
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    • pp.257-258
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    • 2023
  • In this study, it was conducted to improve the physical properties of VAE polymer matrix used as a coating material. A nanocomposite was manufactured using graphene as a reinforcing agent based on a VAE matrix. As a result, improvements in tensile strength, adhesion strength, and porosity were confirmed.

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Preparation and properties of porous (Ca,Mg)0.15Zr0.7O1.7 ceramics (다공성 (Ca,Mg)0.15Zr0.7O1.7 세라믹스의 제조 및 특성)

  • Kim, Bok-Hee;Kim, Sang-Hee;Choi, Eun-Sil
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.21 no.2
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    • pp.70-74
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    • 2011
  • [ $(Ca,Mg)_{0.15}Zr_{0.7}O_{1.7}$ ]ceramics was investigated for the application to SOFC ceramic supporter with high porosity and mechanical strength. $ZrO_2$ powder was prepared by combustion method with glycine using the solution of $ZrO(NO_3)_2{\cdot}2H_2O$ dissolved into deionized water and calcination at $800^{\circ}C$ Porous $(Ca,Mg)_{0.15}Zr_{0.7}O_{1.7}$ ceramics was prepared by sintering the mixture of prepared $ZrO_2$ powder, dolomite and carbon black at $1200{\sim}1400^{\circ}C$ for 1 h. The open porosity ofthe $(Ca,Mg)_{0.15}Zr_{0.7}O_{1.7}$ ceramics sintered at $1300^{\circ}C$ was over 30 % and increased linearly with the amount of carbon black. The crystal structure of $(Ca,Mg)_{0.15}Zr_{0.7}O_{1.7}$ ceramics consisted of single cubic phase. The open pore of this ceramics was connected continuously and distributed well on the whole. This ceramics sintered at $1300^{\circ}C$ showed the porosity from 32 to 55 % and mechanical strength from 90 MPa to 30 MPa with increasing the content of added carbon black.

Study on the Relationship between Aggregation Structure and Flow Rate Depending on Extrusion Temperature at Complex Mold of (Activated Carbon/Polymer Binder) ((활성탄/고분자바인더)복합성형체의 압출온도에 따르는 응집구조 및 유량 상관성에 관한 연구)

  • Lim, Yong Gyun;Kim, Young Jun;Park, Sang Jin;Hong, Sung-Kyu
    • Korean Chemical Engineering Research
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    • v.52 no.2
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    • pp.261-265
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    • 2014
  • As the need for miniaturization in water purification filter increases, the development of filter media for single filtration with multiple function was strongly required. In this study, the molded activated carbon composed of single unit was manufactured by extrusion-sintering process, and then the flow rate, density and porosity were investigated using the molded activated carbon manufactured at various extrusion temperature. We confirmed that it was possible to manufacture the single unit-molded activated carbon when the extrusion temperature was $140{\sim}230^{\circ}C$ more than $133^{\circ}C$ being of polymer binder melting point, and the optimal extrusion temperature for the molded activated carbon with maximum flow rate was $170^{\circ}C$ since the molded activated carbon had low density and high through porosity. Also we confirmed that the flow rate through the molded activated carbon was strongly dependent upon through pore porosity compared to total porosity for the molded activated carbon.

Soil Physical and Chemical Properties of Forest-Fired Area in Koseong, Kangwon (강원도 고성 산화지역의 토양 이화학성 변화)

  • Nam, Yi;Min, Ell-Sik;Jang, In-Soo
    • Korean Journal of Environment and Ecology
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    • v.14 no.1
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    • pp.38-45
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    • 2000
  • This research has been done to investigate influence of soil physical and chemical properties on forest environmental change by fired pine forest in Koseong, Kangwondo. The sample sites were divided by not-fired sites(NF), not-cutting site after fired(FNC), cutting and planting sites after fired(FCP) and cutting and not-planting sites after fired(FC). Soil texture of whole sites was sandy clay loam. Sand content of NF top soil were lower than those of sub soil and clay content were higher, while FNC, FCP and FC sand content of top soil were higher than those of sub soil. Total porosity didn't differ between the sites. Coarse porosity and permeability had the increasing order as NF> FNC> FCP> FC, but fine porosity and bulk density had the opposite trends. Because forest fire removed the vegetation and then soil erosion was accelerated, forest environmental changes by forest fire greatly degraded soil porosity and permeability which were indices for forest water retention, so that soil physical properties were deteriorated. Both top and sub soil pHs of NF and FNC were higher than those of FCP and FC. Organic matter content and total nitrogen content of top and sub soils were high in order as NF> FNC> FCP> FC. Cation exchange capacities and exchangeable cation(K+, Na+, $Ca^2$+, $Mg^2$+) content in top soils were higher than those in sub soils, and in order as NF> FNC> FCP> FC, to be compared by the sites. Those mean that forest fire result from the erosion of top soil layers.

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Weathering of Rock Specimens Exposed to Recurrent Freezing and Thawing Cycles (동결-융해 풍화에 의한 암석 물성 변화 양상과 추정에 관한 연구)

  • Ryu, Sung-Hoon;Song, Jae-Joon
    • Tunnel and Underground Space
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    • v.22 no.4
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    • pp.276-283
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    • 2012
  • Changes in rock properties due to freezing and thawing cycles ranging from $-20^{\circ}C$ to $10^{\circ}C$ were checked for the typical Korean rocks: granite (weathered), limestone, sandstone, tuff, shale and basalt. The porosity, seismic velocity, shore hardness and specific gravity were measured every 10 cycles for each type of rock up to 40 cycles. The specific gravity was rarely changed. Granite (w), shale and basalt decreased gradually in their shore hardness and seismic velocity values, these values for limestone, sandstone and tuff changed only a very little. The porosity increased in the granite (w), shale and basalt, whereas in the others it did not change. Due to the low tensile strength with high porosity, granite (w), shale and basalt were susceptible to the F-T cycles. A linear regression equation was calculated based on the experiment results according to properties and types of rock. The relationship between the freeze-thaw sensitivity (=initial porosity/initial tensile strength) and the coefficients of the regression equation was examined. With additional experimental data, the coefficients of the regression equation can be estimated using the F-T sensitivity. This makes it possible to predict the properties of rock as affected by freeze-thaw weathering by only measuring the initial properties without knowledge of the regression equation coefficients for each type of rock.

Preparation and Evaluation of Hybrid Porous Membrane for the Application of Alkaline Water Electrolysis (알칼리 수전해 적용을 위한 하이브리드 다공성 격리막 제조 및 특성평가)

  • Han, Seong Min;Im, Kwang Seop;Jeong, Ha Neul;Kim, Do Hyeong;Nam, Sang Yong
    • Membrane Journal
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    • v.31 no.6
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    • pp.443-455
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    • 2021
  • In this study, polyphenylene sulfide (PPS) was used as a support and a separator was manufactured using polysulfone and inorganic additives to manufacture a separator with low membrane resistance for application of an alkali water electrolysis system, and then the effect on the thickness and porosity of the support was analyzed. The PPS felt used as a support was compressed with variables of temperature (100℃, 150℃, 200℃) and pressure (1 ton, 2 tons, 3 tons, 5 tons) to adjust the thickness. A porous separator could be manufactured by preparing a slurry with polysulfone using BaTiO3 and ZrO2 which have high hydrophilicity and excellent alkali resistance as inorganic particles and casting the slurry on a compressed PPS felt. Changes in morphology of the separator according to compression conditions were confirmed through an electron scanning microscope (SEM). After that, the porosity was calculated, and the thickness and porosity tended to decrease as the compression conditions increased. Various characteristics were evaluated to confirm whether it could be used as a separator for water electrolysis. As a result of measuring the mechanical strength, it was confirmed that the tensile strength gradually increased as the compression conditions (temperature and pressure) increased. Finally, it was confirmed that the porous separator manufactured through the alkali resistance test has excellent alkali resistance, and through the IV test, it was confirmed that the membranes compressed at 100℃ and 150℃ had a lower voltage and improved performance than the existing uncompressed membrane.

Assessment of Frozen Soil Characterization Via Electrical Resistivity Survey (전기비저항 탐사를 활용한 동결 지반의 거동 평가)

  • Jang, Byeong-Su;Kim, Young-Seok;Kim, Se-Won;Choi, Hyun-Jun;Yoon, Hyung-Koo
    • Journal of the Korean Geotechnical Society
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    • v.39 no.12
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    • pp.115-125
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    • 2023
  • In this study, we evaluated the behavior of frozen soil using an electrical resistivity survey method-a nondestructive technique-and examined its characteristics through field experiments. Frozen soil was artificially prepared by injecting fluid to accelerate the freezing process, and naturally frozen soil was selected in a nearby area for comparison. A dynamic cone penetration test (DCPT) was performed to compare the reliability of the electrical resistivity survey, and time-domain reflectometry surveys were performed to assess the moisture content of the ground. Field experiments were conducted in February-when the atmosphere temperature was below freezing-and May-when the temperature was above freezing. This temperature-compensated method was used to determine reliability because the behavior of frozen soil depends on the underlying temperature. In the resistivity survey method, a section of high electrical resistivity was observed under freezing conditions due to the frozen water and converted into porosity. The converted porosity was compared with the porosity inferred from the DCPT, and the results showed that the measured electrical resistivity was valid.

Mix Design of High Performance Concrete Using Maximum Density Theory (최대 밀도 이론을 이용한 고성능콘크리트의 배합 설계)

  • Lee, Seung-Han;Jung, Yong-Wook
    • Journal of the Korea Concrete Institute
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    • v.19 no.3
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    • pp.377-383
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    • 2007
  • In recent years the field application of high performance concrete has been increased to improve the quality and reliability of concrete structures. The mix design of the high performance concrete includes the 2 set-off mixture theory of mortar and coarse aggregate and that of paste and aggregate. The 2 set-off mixture theory of mortar and coarse aggregate has a problem of having to determine its value through repeated experiments in applying the rheological characteristics of mortar. The 2 set-off mixture theory of paste and aggregate has never been applied to high performance concrete since it doesn't take into account the relationship between optimum fine aggregate ratio and unit volume of powder nor does it consider the critical aggregate volume ratio. As the mixture theory of these high performance concretes, unlike that of general concrete, focuses on flowability and charge-ability, it does not consider intensity features in mix design also, the unit quantity of the materials used is determined by trial and error method in the same way as general concrete. This study is designed to reduce the frequency of trial and error by accurately calculating the optimum fine aggregate ratio, which makes it possible to minimize the aperture of aggregate in use by introducing the maximum density theory to the mix design of high performance concrete. Also, it is intended to propose a simple and reasonable mix design for high performance concrete meeting the requirements for both intensity and flowability. The mix design proposed in this study may reduce trial and error and conveniently produce high performance concrete which has self-chargeability by using more than the minimum unit volume of powder and optimum fine aggregate with minimum porosity.

Effect Mo Addition on Corrosion Property and Sulfide Stress Cracking Susceptibility of High Strength Low Alloy Steels

  • Lee, Woo Yong;Koh, Seong Ung;Kim, Kyoo Young
    • Corrosion Science and Technology
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    • v.4 no.2
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    • pp.39-44
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    • 2005
  • The purpose of this work is to understand the effect of Mo addition on SSC susceptibility of high strength low alloy steels in terms of microstructure and corrosion property. Materials used in this study are high strength low alloy (HSLA) steels with carbon content of 0.04wt% and Mo content varying from 0.1 to 0.3wt%. The corrosion property of steels was evaluated by immersion test in NACE-TM01-77 solution A and by analyzing the growth behavior of surface corrosion products. SSC resistance of steels was evaluated using constant load test. Electrochemical test was performed to investigate initial corrosion rate. Addition of Mo increased corrosion rate of steels by enhancing the porosity of surface corrosion products. However, corrosion rate was not directly related to SSC susceptibility of steels.

Characteristics of Volcanic Ash Soils (화산회토(火山灰土)의 특성(特性)에 관(關)하여)

  • Shin, Yong Hwa;Kim, Hyong Ok
    • Korean Journal of Soil Science and Fertilizer
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    • v.8 no.3
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    • pp.113-119
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    • 1975
  • Volcanic Ash Soils are widely distributed in Jeju island, and constitute the important upland soils which are either presently being cultivated or are suitable for reclaiming. The characteristics of Volcanic Ash Soils according to data made available by previous studies in Jeju and the outside of the country are as following: The most conspicuous mineralogical property is the presence of amorphous mineral colloids. The colloids have large and highly reactive surface to which the common physical and chemical properties are related. Soils are low in bulk density and higher both in porosity and permeability. Accumulation of humus in the upper part of soil is found in great quantity. Cation exchange capacity is high mainly due to high humus content, but the absorbing intensity of ammonium and potassium is weaker than that of crystalline clays. The phosphate absorption coefficient is extremely high and deficiency of minor element may occur both crops and animals. Soils are densely populated with actinomycetes and anaerobic bacteria. Nitrification and activity of urease are distinctly stronger than that of non-Volcanic Ash Soils.

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