• Title/Summary/Keyword: high porosity

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Effect of Sintering Temperature on the Microstructure and Mechanical Properties of Solid Oxide Fuel Cell Anode Fabricated by Spark Plasma Sintering (플라즈마 소결법을 이용한 고체산화물 연료전지 음극 제조 시 소결온도에 따른 미세구조 및 물성평가)

  • Song, Byung Ju;Kim, Ka Ram;Kim, Hye Sung
    • Journal of Powder Materials
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    • v.20 no.6
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    • pp.425-431
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    • 2013
  • Microstructural and mechanical properties of Ni-YSZ fabricated using SPS processing have been investigated at various sintering temperatures. Our study shows samples to be applied as a SOFC anode have the proper porosity of 40% and high hardness when processed at $1100^{\circ}C$. These results are comparable to the values obtained at $100-200^{\circ}C$ higher sintering temperature reported by others. This result is important because when the fabrication processes are performed above $1100^{\circ}C$, the mechanical property starts to decrease drastically. This is caused by the fast grain coarsening at the higher temperature, which initiates a mismatch between thermal expansion coefficients of Ni and YSZ and induces cracks as well.

A Numerical Study on the Flow Characteristics in the Catalytic Muffler with Different Inlet and Outlet Configurations (입구 및 출구 형상 변화에 따른 촉매 삽입형 머플러 내부의 유동 해석)

  • An, Tae Hyun;Lee, Seung Yeop;Park, Yun Beom;Kim, Man Young
    • Transactions of the Korean Society of Automotive Engineers
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    • v.21 no.5
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    • pp.59-66
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    • 2013
  • Lack of the space in many diesel vehicles make it difficult to design and install the catalytic muffler to reduce emissions. For this reason, inlet part of the catalytic muffler is made of L-type which has lower flow uniformity than conventional I-type, and catalytic muffler has complex internal structure by various insertions, which affect the flow uniformity and pressure drop of the systems. In this work, the flow characteristics such as flow uniformity and pressure drop have been numerically investigated by changing such various geometries as inlet shape, porosity, and outlet shape inside the muffler with the three-dimensional turbulent incompressible flow solver. Total 4 different cases are considered in order to find optimal configurations of the catalytic muffler in view of high flow uniformity and low pressure drop. The results show that Case 2 which has no induction cone and outlet perforated pipe has higher uniformity index and lower pressure drop than others considered in this work.

Characteristics of Zr-base Passivation Layers of Tinplate (전기주석도금강판의 Zr계 화학처리 피막 특성)

  • Bae D.C.;Kim T.Y.;Cho K.
    • Journal of Surface Science and Engineering
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    • v.36 no.3
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    • pp.251-255
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    • 2003
  • With increasing environmental demands in surface treatment of steel sheets, the passivation layers containing hexavalent chromium $(Cr^{+6})$ are being replaced by non-chromium or trivalent chromium compounds. After review on the various types of inorganic compounds, the zirconates was chosen as the candidate for alternative to sodium dichromate in the aspect of its barrier properties with excellent adhesion to organics. The ammonium zirconium carbonate (AZC) and sodium hexafluorozirconate (SFZ) could be reach $70-80\%$ level of CDC (cathodic dichromate) treatment by their single applications. But high porosity in the AZC layer and poor electrical conductivity of SFZ solution limit the single application of zirconate. Mixed composition of zirconates to compensate their inferiorities or incorporation of organic compounds to seal the porosity seems to be inevitable to match up the target level of Cr-free passivation of tinplate.

Numerical Simulation of Internal-External Wave Field Interaction in Permeable Coastal Structures (투과성 해안구조물 내-외부 파동장의 수리특성에 관한 순치모의)

  • Cha, Jong-Ho;Yoon, Han-Sam;Ryu, Cheong-Ro;Kang, Yoon-Koo
    • Journal of Ocean Engineering and Technology
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    • v.22 no.3
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    • pp.18-23
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    • 2008
  • This study investigated interactions between the internal-external wave field of a permeable coastal structure consisting of rubble. The study examined the application criteria of an existing numerical model (CADMAS-SURF V.4.0) and proposed a modified method to provide reasonable results. In particular, the study focused on and emphasized the water surface profiles in front of a structure, wave run-up/run-down on a slope, and internal water level fluctuations due to the drag coefficient and porosity of a rubble mound structure. In conclusion, the result show that when the vertical fluctuations of the internal water levels in permeable coastal structures exhibited high-quality representation. Sane responses can be seen for wave run-up/run-down characteristics on its slopes.

A Basic Study for Improvement of Performance of Ice Thermal Storage in Ice Storage Tank (빙축열조 성능향상에 관한 연구)

  • Park, J.W.;Lee, W.S.
    • Solar Energy
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    • v.19 no.4
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    • pp.11-20
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    • 1999
  • The study on ice thermal storage system is to improve total system performance and increase the economical efficiency in actual air-conditioning facilities. To obtain the high charging and discharging efficiencies in ice thermal storage system, the improvement of thermal stratification is essential, therefore the process flow must be piston flow in the cylindrical type. In the influence of the inlet port type, the inflowing water in the distributor type diffuses through the whole storage tank more than in the slot type. In case of the flow process in the ice storage tank, the upward flow type in the charging process and the downward flow type in the discharging process make the stratification well, thereby the loss of energy wored be smaller. The influence of the inlet temperature difference and the change of the inlet flow rate is intensive when the temperature difference is larger, the flow rate is smaller in case of charging and the results are opposite in case of discharging with the reason that the good coduction condition. The total effeciency of the ice thermal storge system is 73% on condition that the porosity in the thermal storage tank is 0.55. This result shows that cylinderical ice storage tank has better storage capacity than rectangular type in case of the same porosity.

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Effect of LiCoO2 Cathode Density and Thickness on Electrochemical Performance of Lithium-Ion Batteries

  • Choi, Jaecheol;Son, Bongki;Ryou, Myung-Hyun;Kim, Sang Hern;Ko, Jang Myoun;Lee, Yong Min
    • Journal of Electrochemical Science and Technology
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    • v.4 no.1
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    • pp.27-33
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    • 2013
  • The consequences of electrode density and thickness for electrochemical performance of lithium-ion cells are investigated using 2032-type coin half cells. While the cathode composition is maintained by 90:5:5 (wt.%) with $LiCoO_2$ active material, Super-P electric conductor and polyvinylidene fluoride polymeric binder, its density and thickness are independently controlled to 20, 35, 50 um and 1.5, 2.0, 2.5, 3.0, 3.5 g $cm^{-3}$, respectively, which are based on commercial lithium-ion battery cathode system. As the cathode thickness is increased in all densities, the rate capability and cycle life of lithium-ion cells become significantly worse. On the other hand, even though the cathode density shows similar behavior, its effect is not as high as the thickness in our experimental range. This trend is also investigated by cross-sectional morphology, porosity and electric conductivity of cathodes with different densities and thicknesses. This work suggests that the electrode density and thickness should be chosen properly and mentioned in detail in any kinds of research works.

DETAILED EXAMINATION OF INVERSE-ANALYSIS PARAMETERS FOR PARTICLE TRAPPING IN SINGLE CHANNEL DIESEL PARTICULATE FILTER

  • Jung, S.C.;Park, J.S.;Yoon, W.S.
    • International Journal of Automotive Technology
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    • v.8 no.2
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    • pp.165-177
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    • 2007
  • Predictions of diesel particulate filtration are typically made by modeling of a particle collection, and providing particle trapping levels in terms of a pressure drop. In the present study, a series of single channel diesel particulate filter (DPF) experiments are conducted, the pressure traces are inversely analyzed and essential filtration parameters are deducted for model closure. A DPF filtration model is formulated with a non-linear description of soot cake regression. Dependence of soot cake porosity, packing density, permeability, and soot density in filter walls on convective-diffusive particle transportation is examined. Sensitivity analysis was conducted on model parameters, relevant to the mode of transition. Soot cake porosity and soot packing density show low degrees of dispersion with respect to the Peclet number and have asymptotes at 0.97 and $70\;kg/m^3$, respectively, at high Peclet number. Soot density in the filter wall, which is inversely proportional to filter wall Peclet number, controls the filtration mode transition but exerts no influence on termination pressure drop. The percolation constant greatly alters the extent of pressure drop, but is insensitive to volumetric flow rate or temperature of exhaust gas at fixed operation mode.

Effects of a Radiation Crosslinking on a Drawn Microporous HDPE Film with a Nucleating Agent

  • Park, Jong-Seok;Gwon, Sung-Jin;Lim, Youn-Mook;Nho, Young-Chang
    • Macromolecular Research
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    • v.17 no.8
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    • pp.580-584
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    • 2009
  • The effects of crystallinity and radiation crosslinking on the physical properties of a microporous high density polyethylene (HDPE) film with Millad3988 as a nucleating agent were investigated. The pores of the HDPE film were affected by the crystallinity. The crystallinity of the HDPE films increased with increasing Millad3988 amount up to 0.1 wt% but decreased with further addition. The mechanical characteristics of the HDPE containing Millad3988 films improved with increasing irradiation dose up to 50 kGy, but decreased at 75 kGy due to severe degradation. The thermal shrinkage behavior of the HDPE films decreased with increasing radiation dose up to 50 kGy. The porosity of the stretched HDPEIMillad3988 films after ${\gamma}$-ray radiation increased with increasing y-ray radiation dose up to 50 kGy. The pores of the irradiated films were formed more easily by a stretching due to the formation of a crosslinked structure.

Effects of Strain Rate and Water Saturation on the Tensile Strength of Rocks (변형률 속도 및 수분포화가 암석의 인장강도에 미치는 영향)

  • Jung, Woo-Jin
    • Tunnel and Underground Space
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    • v.20 no.2
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    • pp.119-124
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    • 2010
  • Hopkinson's effect tests were carried out for various strain rates on three different types of rock in both saturated and dry states in order to examine the effects of strain rate and water saturation on tensile strength. The tensile strength increased with the increase of the strain rate not only in dry state but also in saturated state. It was also especially recognizable that the dynamic tensile strength of rock in the dry state was proportional to approximately a one-third multiple of strain rate no matter what the type of rock. It was found that water saturation decreased tensile strength in the dry state of sandstone and tuff, both with high porosity, but no significant difference could be recognized between the dry and the saturated states of granite, which has a low porosity of 0.49%.

Assessment of compressibility behavior of organic soil improved by chemical grouting: An experimental and microstructural study

  • Ghareh, Soheil;Kazemian, Sina;Shahin, Mohamed
    • Geomechanics and Engineering
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    • v.21 no.4
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    • pp.337-348
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    • 2020
  • Tropical organic soils having more than 65% of organic matters are named "peat". This soil type is extremely soft, unconsolidated, and possesses low shear strength and stiffness. Different conventional and industrial binders (e.g., lime or Portland cement) are used widely for stabilisation of organic soils. However, due to many factors affecting the behaviour of these soils (e.g., high moisture content, fewer mineral particles, and acidic media), the efficiency of the conventional binders is low and/or cost-intensive. This research investigates the impact of different constituents of cement-sodium silicate grout system on the compressibility behaviour of organic soil, including settlement and void ratio. A microstructure analysis is also carried out on treated organic soil using Scanning Electron Micrographs (SEM), Energy Dispersive X-ray spectrometer (EDX), and X-ray Diffraction (XRD). The results indicate that the settlement and void ratio of treated organic soils decrease gradually with the increase of cement and kaolinite contents, as well as sodium silicate until an optimum value of 2.5% of the wet soil weight. The microstructure analysis also demonstrates that with the increase of cement, kaolinite and sodium silicate, the void ratio and porosity of treated soil particles decrease, leading to an increase in the soil density by the hydration, pozzolanic, and polymerisation processes. This research contributes an extra useful knowledge to the stabilisation of organic soils and upgrading such problematic soils closer to the non-problematic soils for geotechnical applications such as deep mixing.