• Title/Summary/Keyword: high porosity

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Influence of Potassium on the Cement Clinker Formation : III. THe State and Formation Mechanism of Unstable Alkali (시멘트 클린커 생성과정에 미치는 Potassium의 영향 III. 불안정 알칼리의 상태 및 생성기구)

  • 서일영;최상홀
    • Journal of the Korean Ceramic Society
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    • v.22 no.3
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    • pp.60-66
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    • 1985
  • The formation mechanism of unstable alkali and its existing states in the clinker were studied. The relation of unstable alkali content vs. other water-soluble components porosity and the distributionof potassium were investigated. The results are as follows :1) Two states of unstable alkali seem to exist in clinker ie compounds of $K_2O-Al_2O_3$ system and free $K_2O$ 2) The content of water-soluble $Al_2O_3$ tends to increase with increase of unstable alkali content, 3) Most of alkalies in clinker are concentrated in liquid phase at high temperature. Therefore it is possible to make various $K_2O-Al_2O_3$ system compounds according to the content of $K_2O$ in the liquid phase of clinker. In this experiment we found out a $K_2O-Al_2O_3$ compound of high $Al_2O_3$ content (34%) and high $K_2O$ content (33%) in clinker with 1.09% unstable alkali. 4) The porosity of clinker tends to increase with increase of unstable alkali content. 5) The amount of trapped alkali vapor may increase in closed pore in the clinker with high alkali and low $SO_3$ condecent. Therefore free $K_2O$ is the condensed alkali on the wall of closed pore in the clinker.

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NH3 sensing properties of porous CuBr films prepared by spin-coating (스핀 코팅법으로 제작한 다공성 CuBr 필름의 암모니아 감응특성)

  • Kim, Sang-Kwon;Yu, Byeong-Hun;Yoon, Ji-Wook
    • Journal of Sensor Science and Technology
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    • v.30 no.6
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    • pp.451-455
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    • 2021
  • Porous copper bromide (CuBr) films are highly advantageous for detecting ammonia (NH3). The fabrication of porous CuBr films requires complex high-temperature processes or multistep processes. Herein, we report the uncomplicated preparation of porous CuBr films by a spin-coating method and the films' excellent NH3 sensing properties. The porous films were prepared by spin-coating 100, 150, and 200 mM CuBr solutions, and then dried in a vacuum oven for 2 h. All the films showed a high NH3 response; in particular, the film prepared using a 100 mM CuBr solution showed an extremely high response (resistance ratio = 852) to 5 ppm NH3. The film also showed fast response and recovery times, 272 s and 10 s respectively, even at room temperature. The outstanding NH3 sensing characteristics were explained in relation to the porosity and thickness of the prepared films. The high-performance NH3 sensors used in this study can be used for both indoor air quality and environmental monitoring applications.

Fabrication of a High Porous Polyethylene Membrane Using BET as a Novel Diluent (새로운 BET 희석제를 이용한 고다공성 폴리에틸렌 분리막 제조)

  • Cho, Inhyun;Lee, Soomi;Kim, Chang Keun
    • Polymer(Korea)
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    • v.38 no.4
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    • pp.530-534
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    • 2014
  • Polyethylene (PE) membranes having various porosities are used as microfilters and separators in lithium ion batteries. Membranes having a high porosity are required for use as separators in a large scale lithium ion secondary battery. In this study, BET was examined for use as a new nontoxic diluent for the fabrication of highly porous PE membranes by thermally induced phase separation process. It was confirmed that BET can be used as a new diluent for the fabrication of the PE membranes by exploring upper critical solution temperature type phase behavior of PE mixtures with BET. When the porosity of the membrane prepared from the PE/PO mixture was compared with that prepared from PE/BET mixture, the latter was about 1.8 times higher than the former.

Effects of Porosity and Water Content on Thermal Conductivity of Soils (토양의 공극률 및 함수비가 열전도도에 미치는 영향)

  • Cha, Jang-Hwan;An, Sun-Joon;Koo, Min-Ho;Kim, Hyoung-Chan;Song, Yoon-Ho;Suh, Myoung-Seok
    • Journal of Soil and Groundwater Environment
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    • v.13 no.3
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    • pp.27-36
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    • 2008
  • This paper presents a comprehensive laboratory study that examines the effects of porosity, water content, density and grain size distribution on the thermal conductivity of soils which were sampled from 16 synoptic stations of Korea. The experimental results clearly demonstrate that porosity and water content are important parameters which strongly affect the thermal conductivity of soils. Soils with lower porosities and higher water contents have higher thermal conductivities. On the contrary, increase of the matrix density slightly increases the thermal conductivity, and grain size distribution hardly affects the thermal conductivity. Dry soils with the same porosity tend to have more scattered values of thermal conductivity than wet soils. Based on the experimental results, a multiple linear regression model and a nonlinear regression model, having two regression variables of porosity and water content, were presented to predict thermal conductivity. Both models show a high accuracy of prediction with $R^2$ values of 0.74 and 0.82, respectively. Thus, it is expected that the suggested empirical models can be used for predicting thermal conductivity of soils by measuring porosity and water content.

Generation of Pseudo Porosity Logs from Seismic Data Using a Polynomial Neural Network Method (다항식 신경망 기법을 이용한 탄성파 탐사 자료로부터의 유사공극률 검층자료 생성)

  • Choi, Jae-Won;Byun, Joong-Moo;Seol, Soon-Jee
    • Journal of the Korean earth science society
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    • v.32 no.6
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    • pp.665-673
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    • 2011
  • In order to estimate the hydrocarbon reserves, the porosity of the reservoir must be determined. The porosity of the area without a well is generally calculated by extrapolating the porosity logs measured at wells. However, if not only well logs but also seismic data exist on the same site, the more accurate pseudo porosity log can be obtained through artificial neural network technique by extracting the relations between the seismic data and well logs at the site. In this study, we have developed a module which creates pseudo porosity logs by using the polynomial neural network method. In order to obtain more accurate pseudo porosity logs, we selected the seismic attributes which have high correlation values in the correlation analysis between the seismic attributes and the porosity logs. Through the training procedure between selected seismic attributes and well logs, our module produces the correlation weights which can be used to generate the pseudo porosity log in the well free area. To verify the reliability and the applicability of the developed module, we have applied the module to the field data acquired from F3 Block in the North Sea and compared the results to those from the probabilistic neural network method in a commercial program. We could confirm the reliability of our module because both results showed similar trend. Moreover, since the pseudo porosity logs from polynomial neural network method are closer to the true porosity logs at the wells than those from probabilistic method, we concluded that the polynomial neural network method is effective for the data sets with insufficient wells such as F3 Block in the North Sea.

Effect of Electrode Design on Electrochemical Performance of Highly Loaded LiCoO2 Positive Electrode in Lithium-ion Batteries (리튬이온 이차전지용 고로딩 LiCoO2 양극의 전극설계에 따른 전기화학적 성능연구)

  • Kim, Haebeen;Ryu, Ji Heon
    • Journal of the Korean Electrochemical Society
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    • v.23 no.2
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    • pp.47-55
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    • 2020
  • Highly loaded LiCoO2 positive electrodes are prepared to construct high-energy density lithium-ion batteries, their electrochemical performances are evaluated. For the standard electrode, a loading of about 2.2 mAh/㎠ is used, and for a high-loading electrode, an electrode is manufactured with a loading level of about 4.4 mAh/㎠. The content of carbon black as electronic conducting additive, and the porosity of the electrode are configured differently to compare the effects of electron conduction and ionic conduction in the highly loaded LiCoO2 electrode. It is expected that the electrochemical performance is improved as the amount of the carbon black increases, but the specific capacity of the LiCoO2 electrode containing 7.5 weight% carbon black is rather reduced. When the conductive material is excessively provided, an increase of electrode thickness by the low content of the LiCoO2 active material in the same loading level of the electrode is predicted as a cause of polarization growth. When the electrode porosity increases, the path of ionic transport can be extended, but the electron conduction within the electrode is disadvantageous because the contact between the active material and the carbon black particles decreases. As the electrode porosity is lowered through the sufficient calendaring of the electrode, the electrochemical performance is improved because of the better contact between particles in the electrode and the reduced electrode thickness. In the electrode design for the high-loading, it is very important to construct the path of electron conduction as well as the ion transfer and to reduce the electrode thickness.

Tribological Behavior of Multilayered WC-Ti1-xAlxN Coatings Deposited by Cathodic Arc Deposition Process on High Speed Steel

  • Kim, Jung Gu;Hwang, Woon Suk
    • Corrosion Science and Technology
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    • v.5 no.2
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    • pp.52-61
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    • 2006
  • Recently, much of the current development in surface modification engineering are focused on multilayered coatings. Multilayered coatings have the potential to improve the tribological properties. Four different multilayered coatings were deposited on AISI D2 steel. The prepared samples are designed as $WC-Ti_{0.6}Al_{0.4}N$, $WC-Ti_{0.53}Al_{0.47}N$, $WC-Ti_{0.5}Al_{0.5}N$ and $WC-Ti_{0.43}Al_{0.57}N$. The multilayered coatings were investigated with respect to coating surface and cross-sectional morphology, roughness, adhesion, hardness, porosity and tribological behavior. Especially, wear tests of four multilayered coatings were performed by using a ball-on-disc configuration with a linear sliding speed of 0.017 m/sec, 5.38 N load. The tests were carried out at room temperature in air by employing AISI 52100 steel ball ($H_R=66$) having a diameter of 10 mm. The surface morphology, and topography of the wear scars of samples and balls have been determined by using scanning electron spectroscopy (SEM). Results have showed an improved wear resistance of the $WC-Ti_{1-x}Al_xN$ coatings with increasing of Al concentration. $WC-Ti_{0.43}Al_{0.57}N$ coating with the lower surface roughness and porosity with good adhesion enhanced wear resistance.

Bending analysis of an imperfect advanced composite plates resting on the elastic foundations

  • Daouadji, Tahar Hassaine;Benferhat, Rabia;Adim, Belkacem
    • Coupled systems mechanics
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    • v.5 no.3
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    • pp.269-283
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    • 2016
  • A two new high-order shear deformation theory for bending analysis is presented for a simply supported, functionally graded plate with porosities resting on an elastic foundation. This porosities may possibly occur inside the functionally graded materials (FGMs) during their fabrication, while material properties varying to a simple power-law distribution along the thickness direction. Unlike other theories, there are only four unknown functions involved, as compared to five in other shear deformation theories. The theories presented are variationally consistent and strongly similar to the classical plate theory in many aspects. It does not require the shear correction factor, and gives rise to the transverse shear stress variation so that the transverse shear stresses vary parabolically across the thickness to satisfy free surface conditions for the shear stress. It is established that the volume fraction of porosity significantly affect the mechanical behavior of thick function ally graded plates. The validity of the two new theories is shown by comparing the present results with other higher-order theories. The influence of material parameter, the volume fraction of porosity and the thickness ratio on the behavior mechanical P-FGM plate are represented by numerical examples.

Nondestructive Evaluation of Advanced Ceramics by Means of Ultrasonic Velocity and a Micromechanics Model (초음파 속도와 미시역학 모델을 이용한 고급 세라믹스의 비파괴적 평가)

  • Jeong, Hyun-Jo
    • Journal of the Korean Society for Nondestructive Testing
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    • v.14 no.2
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    • pp.90-100
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    • 1994
  • Ultrasonic velocities are widely used in the investigation of material properties. In this paper, a micromechanics model and the ultrasonic velocity were used to develop a nondestructive method to determine the density variation due to porosity in structural SiC. The micromechanics model developed can consider the pore shape and orientation. The model also takes into account the interaction between pores so that it can be applied to the material with high porosity content. A contact pulse overlap method was used to measure the ultrasonic velocities of porous SiC samples, and there was a linear correlation between the velocity and density (or porosity). Using the model and the measured velocity, the bulk density can be easily calculated. The calculated density was in good agreement with that obtained by Archimedes' method.

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Effect of Yarns Cross-Sections and Structure Parameters of Its Knitted Fabrics to Moisture Transport of Perspiration Absorption and Fast Dry Fabrics (실 단면 형상과 니트 구조 인자가 흡한속건 소재의 수분이동 특성에 미치는 영향)

  • Kim, Hyun Ah
    • Fashion & Textile Research Journal
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    • v.20 no.4
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    • pp.457-463
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    • 2018
  • This study examined the water absorption and drying properties of the thirteen types of the knitted fabrics for sports wear. These physical properties were analysed with relation to the constituent fiber cross-sectional shape and structure parameters of the knitted fabrics by regression analysis. Absorption and drying properties of the knitted fabric specimens were increased with increasing the porosity of the constituent yarns, which was attributed to the capillary channels in the yarns. The water absorption and drying properties were increased and decreased with increasing tightness factor and stitch density of the knitted fabric. The absorption property of the knitted fabric for perspiration absorption and fast dry sport-wear clothing was mostly influenced mostly by fiber cross-sectional shape and its characteristics, whereas, drying property was dependent on the structural parameters of the knitted fabric such as tightness factor and stitch density. Therefore, superior perspiration absorption and fast drying knitted fabric could be obtained in the fabric structure with optimum tightness factor and stitch density, and constituent yarn structure with non-circular fiber crosssection and high porosity. GATS method and MMT method are used to measure sweating fast drying properties and it is necessary to carry out studies using these measurement methods in order to compare with the results of this study.