• Title/Summary/Keyword: high conductivity

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Ionic Conductivity of $Li_2O-B_2O_3-P_2O_5$ based Glasses ($Li_2O-B_2O_3-P_2O_5$계 유리의 이온전도성)

  • 박강석;강은태
    • Journal of the Korean Ceramic Society
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    • v.30 no.5
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    • pp.373-380
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    • 1993
  • Li2O-B2O3-P2O5 glasses with high lithium content were analysed by electrical characterization. The electrical conductivity increase with Li content and exhibits a maximum value of 1.2$\times$10-4S/cm near B2O3/P2O5=1 at 15$0^{\circ}C$. Glass transitiion temperature increased with conductivity. Concentration of charge carrier and distribution of relaxation time were independent of temperature. In this system the variation of conductivity with the composition was depend on mobility of lithium ion. Basically, it is attribute to primitive activation energy. Enhancement of conductivities was related to be formation of (B-O-P)-, di-, and metaborate group, which give additional available sites for Li+ diffusion.

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Water management for vapor-fed direct methanol fuel cells (수동급기 직접 메탄올 연료전지의 공기극 물 관리)

  • Chang, Ik-Whang;Ha, Seung-Bum;Cha, Suk-Won;Lee, Yoon-Ho
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.319-322
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    • 2009
  • This paper investigated environmental effects for passive, air-breathing, and vapor-feeding direct methanol fuel cells. In these experiments, experimental parameters are temperature($30^{\circ}C$, $40^{\circ}C$ and relative humidity(25%, 50%, 75%). From these experimental results, the water contents play a key role in terms of optimal ionic conductivity at the cathode catalyst layer. In case of pure methanol feeding, the performance is inversely proportional to the relative humidity. The water generation resulting from methanol crossover maintains ionic conductivity at the cathode. On the contrary, diluted methanol solution (50wt.%) lowers methanol crossover to the cathode. In order to increase ionic conductivity, the relatively high humidity is required to the cathode catalyst layer for the water generation. The relative humidity scales with the performance.

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An Empirical application of high-performance cement grout for ground heat exchanger (지중열교환기용 고성능 시멘트 그라우트 실증 적용)

  • Yang, Hee-Jung;Lee, Dong-Chul;Jeon, Joong-Kyu;Seo, Shin-Seok;Choi, Yong-Min
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.201.1-201.1
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    • 2011
  • Ground heat exchanger is the most important part which than 14% of the cost of construction and the performance of Ground heat exchanger is depended on it. Grout is inserted into the hole to the ground fixed and serves to enhance the thermal conductivity. So the research and development is needed. We were using cement grout. The result of the test thermal conductivity is 3.14 W/mK. It is much better than the existing grout is the thermal conductivity. The developed materials was examined by applying the grout in the field.

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Effect of Structural and Morphological Changes on the Conductivity of Stretched PANI-DBSA/HIPS Film

  • Lee, Jong-Hyeok;Kim, Eun-Ok
    • Bulletin of the Korean Chemical Society
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    • v.32 no.8
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    • pp.2661-2665
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    • 2011
  • We studied the effect of structural and morphological changes on the conductivity of a stretched conducting polymer film. To improve the poor processability of polyaniline, we used dodecylbenzenesulfonic acid as both a surfactant and a dopant during emulsion polymerization, followed by blending with high-impact polystyrene. UV-Vis/NIR spectra were obtained to observe conformational changes, and SEM and AFM were used to investigate morphological changes. FT-IR dichroism was applied to determine the microscopic orientation, and XRD patterns were obtained for quantitative crystallinity analysis. The electrical conductivity (${\sigma}_{\parallel}/{\sigma}_{\perp}$) was measured as a function of draw ratio. We found a clear correlation between morphological changes and (${\sigma}_{\parallel}/{\sigma}_{\perp}$), especially at the stretching limit. The conductivity of the films can be modified according to the desired application by controlling their structure and morphology.

Journal of the Environmental Sciences A Study on the Operating Conditions to Eliminate Feedpipe Backmixing for Fast Competitive Reactions

  • Jang, Jeong-Gook;Jo, Myung-Chan
    • Journal of Environmental Science International
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    • v.20 no.8
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    • pp.929-942
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    • 2011
  • A novel conductivity technique was developed to detect penetration depth of the vessel fluid into the feedpipe. For a given reactor geometry, critical agitator speeds were experimentally determined at the onset of feedpipe backmixing using Rushton 6 bladed disk turbine (6BD) and high efficiency axial flow type 3 bladed (HE-3) impellers. The ratio of the feedpipe velocity to the critical agitator speed ($v_f/v_t$) was constant for either laminar or turbulent feedpipe flow regimes. Compared to the results of fast competitive reaction, feedpipe backmixing had to penetrate at least one feedpipe diameter into the feedpipe to significantly influence the yield of the side product. However, higher $v_f/v_t$ than that for L/d = 0 (position at the feedpipe end) of the conductivity technique is recommended to completely eliminate feedpipe backmixing in conservative design criteria. The conductivity technique was successful in all feedpipe flow conditions of laminar, transitional and turbulent flow regimes.

Effect of a Magnetic Field on Electrical Conductivity of a Partially Ionized Plasma

  • Yun, Hong-Sik
    • Journal of The Korean Astronomical Society
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    • v.8 no.1
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    • pp.29-34
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    • 1975
  • Solar electrical conductivity has been calculated, making use of Yun and Wyller's formulation. The computed results arc presented in a tabulated form as functions of temperature and pressure for given magnetic field strengths. The results of the calculation show that the magnetic field does not play any important role in characterizing the electrical conductivity of the ionized gas when the gas pressure is relatively high (e.g., $P{\geq}10^4\;dynes/cm^2$). However, when the gas pressure is low (e.g., $P{\leq}10\;dynes/cm^2$), the magnetic field becomes very effective even if its field strength is quite small (e.g., $B{\leq}0.01$ gauss). It is also found that, except for lower temperature region (e.g., $T{\leq}10^{4^{\circ}}K$), there is a certain linear relationship in a log- log graph between the pressure and the critical magnetic field strength, which is defined as a field strength capable of reducing the non-magnetic component of the electrical conductivity by 20%.

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A Property of Porous Concrete applied by Recycled Cement and using Recycled Aggregates Made of EPS Waste (재생시멘트와 폐 EPS 재생골재를 사용한 포러스 콘크리트 물성)

  • Kim Sung-Su;Park Cha-Won;Ahn Jae-Cheol;Kang Byeung-Hee
    • Proceedings of the Korean Institute of Building Construction Conference
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    • v.y2004m10
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    • pp.59-63
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    • 2004
  • In recent days. it is necessary to find environment-friendly way of diposing industrial waste and reclying system. So this study will analyze the property of Porous concrete improved by concrete waste powder and recycled lightweight aggregate and then suggest the ways of reclying. The method deals with experimenting unit weight of capacity. thermal conductivity, compression and ultrasonic pluse velocity. Considering the relation between ultrasonic pluse velocity and unit weight & thermal conductivity through the graph. the result of relation between ultrasonic pluse velocity and unit weight & thermal conductivity on the graph expessed their high interaction shown as direct proportion on the graph. Recycled Porous concrete merits lightweight and adiabatic. Therefore. we will expect that the current using ALC and Recycled Porous concrete has be similar thermal conductivity.

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Conductivity measurements at low oxygen partial pressure of the stabilized $ZrO_{2}$ ceramics prepared by SHS

  • Soh, Dea-Wha;Korobova, Natalya
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.451-454
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    • 2001
  • The ionic conductivity of cubic solid solutions in the system $Y_{2}O_{3}-ZrO_{2}$ prepared by SHS was examined. Conductivity-temperature data obtained at $1000^{\circ}C$ in atmosphere of low oxygen partial pressure ($10^{-40}$ atm) for $Y_{2}O_{3}-ZrO_{2}$ cubic solid solutions indicated that these materials could be reduced, the degree of reduction being related to the measuring electric field. At low impressed fields no reduction was observed. Thus, these conductivity data give a transference number for the oxygen ion in $Y_{2}O_{3}-ZrO_{2}$ cubic solid solutions greater than 0.99.

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The Effect of Additive on the Electric conductivity of Insulating Oil (절연유의 전기전도에 미치는 첨가제의 영향)

  • 정광현;김영봉;김용운;임헌찬;이덕출
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.05a
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    • pp.158-161
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    • 1996
  • The static charges are generated by streaming electrification phenomena in insulating oil flowing by force for the purpose of cooling at the internal of Ultra-high power transformer. In this thesis, their elimination method was studied. In this paper the effect of Additive on the electric conductivity of Insulating oil is studied. The variation of electric conductivity disappear when Additive is molten in insulating oil BTA(Benzotriazole) appear more variation of electric conductivity than that of SP-S10(Sorbitan mono-stearate). But the variation is not enough to decrease streaming electrification of insulating oil($\sigma$>10$\^$-12/[S/cm]).

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Synthesis and Characterization of Cu Nanofluid Prepared by Pulsed Wire Evaporation Method (전기선 폭발법을 이용하여 제조된 구리 나노유체의 특성평가)

  • Kim, Chang-Kyu;Lee, Gyoung-Ja;Rhee, Chang-Kyu
    • Journal of Powder Materials
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    • v.17 no.4
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    • pp.270-275
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    • 2010
  • Ethylene glycol-based Cu nanofluids were prepared by pulsed wire evaporation (PWE) method. The structural properties of Cu nanoparticles were studied by X-ray diffraction (XRD) and high resolution transmission electron microscopy (HRTEM). The average diameter and Brunauer Emmett Teller (BET) surface area of Cu nanoparticles were about 100 nm and $7.46\;m^2/g$, respectively. The thermal conductivity and viscosity of copper nanofluid were measured as functions of Cu concentration and temperature. As the volume fraction of Cu nanoparticles increased, both the enhanced ratios of thermal conductivity and viscosity of Cu nanofluids increased. As the temperature increased, the enhanced ratio of thermal conductivity increased, but that ratio of viscosity decreased.