• Title/Summary/Keyword: high conductivity

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Modeling of Electrical Conductivity from $\sigma$tot vs. Po21/4 Plot in Wet Atmosphere for High-Temperature Proton-Conducting Oxides

  • Baek, Hyun-Deok
    • The Korean Journal of Ceramics
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    • v.4 no.2
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    • pp.136-140
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    • 1998
  • This work demonstrates a method for modeling of electrical conductivity in high-temperature proton-conducting oxides. Total conductivity was calculated assuming that it comprises partial conductivities contributed by protons, oxygen ions and electron holes. From the polt $\sigma_{tot}$ vs. $po_2\;{1/4}$ in wet atmosphere, thermodynamic and kinetic parameters were obtained representing transport properties such as concentration and mobility of the charge-carrying defects. The formulas for the calculation of partial conduction were derived based on the defect structure of HTPCs. Illustrative calculation were made for $SrCe_{0.95}Yb_{0.05}O_{2.975}$ system.

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The Effect of Contact Resistance and Electric Conductivity on PEMFC Performance (접촉저항 및 전기전도도가 연료전지 성능에 미치는 영향)

  • Kim, Ki-Jung;Yun, Yong-Sik;Jeon, Yu-Taek
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.133-136
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    • 2007
  • In this work, 3-dimensional, non-isothermal numerical simulation was performed to analyse the effects of contact resistance and electric conductivity of GDL on the fuel cell performance. For numerical simulation contact resistance of Carbon and Stainless steel was measured. The simulation results reveal that 10 times change of electric conductivity leads only 6.5% decrease of PEMFC performance. But stainless steel which has high contact resistance decrease fuel cell performance over 25% at a high current density region than carbon. This results show that suitable Surface treatment technology is needed for metal bipolar plate, especially stainless steel.

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A Study on the Characteristics of New Type of Composite Bipolar Plate for the PEM Fuel Cell (고분자전해질 연료전지용 새로운 타입의 복합재료 분리판의 특성연구)

  • Kim, Jong-Wan;Lee, Jin-Sun;Sun, Kyung-Bok;Lee, Joong-Hee
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.180-183
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    • 2009
  • Composite bipolar plates offer several advantages of low cost, light weight, and ease of manufacturing compared to traditional graphite plate. However, it is difficult to achieve both high electrical conductivity and high flexural strength. In this study, the hybrid carbons filled epoxy composite bipolar plates were fabricated to test electrical conductivity and flexural properties. Graphite powders were used as the main conducting filler and continuous carbon fiber fabrics were inserted to improve the mechanical properties of the composite. This hybrid composite showed improved in-plane electrical conductivity and flexural property. The moldability of the hybrid composite was also improved comparing to the continuous prepreg composite. This study suggested that the continuous carbon fiber inserted graphite/epoxy composites can be a potential candidate material to overcome the disadvantages of conventional graphite composite or continuous prepreg composite bipolar plates.

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The Effects of Thermo-mechanical Treatment on the Thixoforming Process of Cu-Ca Alloys for High Efficiency Electrical Motors (고효율 전동기용 Cu-Ca 합금의 반응고 성형공정에 미치는 가공열처리의 영향)

  • Lee, E.Y.;Kang, B.M.;Lee, S.Y.
    • Journal of the Korean Society for Heat Treatment
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    • v.16 no.5
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    • pp.267-274
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    • 2003
  • The effect of the thermo-mechanical treatment on the microstructural development and the electric conductivity of Cu-Ca alloys are studied for the thixoforming processed rotor of the induction motor The Cu-Ca alloys containing Ca less than 1.0wt% show the electrical conductivity higher than 80% IACS They also show broad melting range over $150^{\circ}C$ which is desirable for the thixoforming process The semi-solid microstructure of cast alloy changes from the dendrite structure to globular structure by prior deformation before reheating. The details of microstructural changes by the thermo-mechanical treatment are discussed.

Thermal Conduction in Transparent Carbon Nanotube Films

  • Zhu, Lijing;Kim, Duck-Jong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.201-201
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    • 2012
  • Using materials with high thermal conductivity is a matter of great concern in the field of thermal management. In this study, we present our experimental results on an important physical property of carbon nanotube (CNT) films, two-dimensional thermal conductivity obtained by using an optical method based on Raman spectroscopy. We prepared four kinds of CNT films to investigate the effect of CNT type on heat spreading performance of films. This first comparative study using the optical method shows that the arc-discharge single-walled carbon nanotubes yield the best heat spreading film. And we observed thermal conductivity values of CNT films with various transmittances and found that the Raman method works as long as the sample is a transparent film. This study provides useful information on characterization of thermal conduction in transparent CNT films and could be an important step toward high-performance carbon-based heat spreading films.

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Ultra High Conductivity Diamond Composites

  • Bollina, Ravi;Stoiber, Monika
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.922-923
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    • 2006
  • Thermal management is one of the critical aspects in the design of highly integrated microelectronic devices. The reliability of electronic components is limited not only to operating temperature but also by the thermal stresses caused during the operation. The need for higher power densities calls for use of advanced heat spreader materials. A copper diamond composite has been developed with high thermal conductivity $(\lambda)$ and tailorable coefficient of thermal expansion (CTE). Copper diamond composites are processed via gas pressure assisted infiltration with different copper alloys. Emphasis has been placed on the addition of trace elements in deisgning the copper alloys to facilitate a compromise between thermal conductivity and mechanical adhesion. The interfaces between the alloy and the diamond are related to the thermal properties of these copper composites.

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Microstructural Effects Influencing the Thermal Conductivity of High-Temeprature Insulation Firebricks (고온 단열벽돌의 열전도성에 미치는 미세구조의 영향)

  • 장복기;임재봉
    • Journal of the Korean Ceramic Society
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    • v.27 no.6
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    • pp.729-734
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    • 1990
  • The microstructural dependence of thermal conductivity of a high-alumina (ca. 70%) heat-insulating frebricks(ca. 75%porosity) was investigated under special consideration of the tailored-pore shape effects. Pores different shape could be incorporated into the insulators through pore formers : Styrofoam produces spherical pores while saw dust results in parallel plate pores. Concerning the pore-shape effectiveness of thermal insulation, the specimen with irregular plate pores showed much lower values of heat conductivity than those with spherical pores, the values being 0.31 to 0.38 at $600^{\circ}C$ and 0.35 to 0.47 at 100$0^{\circ}C$, respectively. On the contrary, however, other material properties such as strength and softening temeprature under load were turned out to be better in the case of the spherical pores.

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The Effect of Contact Resistance and Electric Conductivity on PEMFC Performance (접촉저항 및 전기전도도가 연료전지 성능에 미치는 영향)

  • Kim, Gi-Jeong;Yun, Yong-Sik;Jeon, Yu-Taek
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.05a
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    • pp.184-186
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    • 2012
  • In this work, 3-dimensional, non-isothermal numerical simulation was performed to analyse the effects of contact resistance and electric conductivity of GDL on the fuel cell performance. For numerical simulation contact resistance of Carbon and Stainless steel was measured. The simulation results reveal that 10 times change of electric conductivity leads only 6.5% decrease of PEMFC performance. But stainless steel which has high contact resistance decrease fuel cell performance over 25% at a high current density region than carbon. This results show that suitable Surface treatment technology is needed for metal bipolar plate, especially stainless steel.

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Prediction Model on Electrical Conductivity of High Density Metallic Plasma (고밀도 금속 플라즈마 전기전도도 예측모델)

  • Kyoungjin Kim
    • Journal of the Korean Society of Propulsion Engineers
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    • v.26 no.6
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    • pp.1-9
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    • 2022
  • This study introduces the calculation model of ionization composition and electrical conductivity for metallic plasma for practical application to modeling and simulation of modern electrical detonators. The present model includes the correction for non-ideality of dense plasma conditions which are expected in electrical explosion of bridge in detonators. The computational results for copper plasma show favorable agreement with experimental data for a wide range of plasma temperature and high density conditions and the model is proper for detonator modeling with good prediction accuracy.

Volume Resistivity, Specific Heat and Thermal Conductivity Measurement of Semiconducting Materials for 154[kV] (154[kV]용 반도전층 재료의 최적저항, 비열 및 열전도 측정)

  • Lee, Kvoung-Yong;Yang, Jong-Seok;Choi, Yong-Sung;Park, Dae-Hee
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.54 no.11
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    • pp.477-482
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    • 2005
  • We have investigated volume resistivity and thermal properties showed by changing the content of carbon black which is the component parts of semiconducting shield in underground power transmission cable. Specimens were made of sheet form with the nine of specimens for measurement. Volume resistivity of specimens was measured by volume resistivity meter after 10 minutes in the preheated oven of both 25$\pm$1[$^{\circ}C$] and 90$\pm$1[$^{\circ}C$]. And specific heat (Cp) and thermal conductivity were measured by Nano Flash Diffusivity and DSC (Differential Scanning Calorimetry). The measurement temperature ranges of specific heat using the BSC was from 20[$^{\circ}C$] to 60[$^{\circ}C$], and the heating rate was 1[$^{\circ}C$/min]. And the measurement temperatures of thermal conductivity using Nano Flash Diffusivity were both 25[$^{\circ}C$] and 55[$^{\circ}C$]. Volume resistivity was high according to an increment of the content of carbon black from these experimental results. And specific heat was decreased, while thermal conductivity was increased by an increment of the content of carbon black. And both specific heat and thermal conductivity were increased by heating rate because volume of materials was expanded according to rise in temperature.