• 제목/요약/키워드: hexagonal

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육방정 페라이트의 결정과 Block 구조 (Crystal and Block Structures of Hexagonal Ferrites)

  • 신형섭
    • 한국세라믹학회지
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    • 제49권3호
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    • pp.205-215
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    • 2012
  • It has been studied the crystal and block structures of the hexagonal ferrites with M, W, Y and Z types prepared by various coprecipitation-oxidation method. The structures have been refined with a Rietveld analysis of the powder X-ray diffraction pattern with high precision ($R_{WP}$ <0.09, $R_I$ <0.03). The density difference between the S-blocks was proportioned to the cobalt contents in hexagonal ferrites, but that between the R or T-blocks was relatively small. Compared with the blocks and cation-oxygen polyhedra in BaM ($BaFe_{12}O_{19}$), those were bulky to the normal direction for the c-axis in $Co_2W$ ($BaCo_2Fe_{16}O_{27}$) and to the parallel direction for the c-axis in $Co_2Y$ ($Ba_2Co_2Fe_{12}O_{22}$) and $Co_2Z$ ($Ba_3Co_2Fe_{24}O_{41}$). The S-blocks of $Co_2W$, $Co_2Y$, and $Co_2Z$ were unstable and distorted. Because the T-block of $Co_2Z$ was unstable, the T-block was decomposed into the Ba-rich phase and $Co_2W$ at high temperatures above $1200^{\circ}C$. A standard powder X-ray diffraction pattern for $Co_2Z$ was proposed as well.

Effect of Cholesterol on the Phase Change of Lipid Membranes by Antimicrobial Peptides

  • Choi, Hyungkeun;Kim, Chul
    • Bulletin of the Korean Chemical Society
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    • 제35권5호
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    • pp.1317-1322
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    • 2014
  • Membrane disruption by an antimicrobial peptide (AMP) was investigated by measuring the $^2H$ solid-state nuclear magnetic resonance spectra of 1-palmitoyl-$d_{31}$-2-oleoyl-sn-glycero-3-phosphatidylcholine (POPC_$d_{31}$) in mixtures of POPC_$d_{31}$/cholesterol and either magainin 2 or aurein 3.3 deposited on thin cover-glass plates. The line shapes of the experimental $^2H$ solid-state nuclear magnetic resonance (SSNMR) spectra were best simulated by assuming the coexistence of a mosaic spread of bilayers containing pore structures and a fasttumbling isotropic phase or a hexagonal phase. Within a few days of incubation in a hydration chamber, an isotropic phase and a pore structure were induced by magainin 2, while in case of aurein 3.3 only an isotopic phase was induced in the presence of a bilayer phase. After an incubation period of over 100 days, alignment of the bilayers increased and the amount of the pore structure decreased in case of magainin 2. In contrast with magainin 2, aurein 3.3 induced a hexagonal phase at the peptide-to-lipid ratio of 1/20 and, interestingly, cholesterol was not found in the hexagonal phase induced by aurein 3.3. The experimental results indicate that magainin 2 is more effective in disrupting lipid bilayers containing cholesterol than aurein 3.3.

Thermal-Hydraulic Aspects of an Advanced Reactor Core with Triangular Lattice Fuel Assemblies

  • Hwang, Dae-Hyun;Yoo, Yeon-Jong;Kim, Young-Jin;Chang, Moon-Hee
    • 한국원자력학회:학술대회논문집
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    • 한국원자력학회 1996년도 춘계학술발표회논문집(2)
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    • pp.379-384
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    • 1996
  • Thermal-hydraulic performance has been analyzed for an advanced reactor core loaded with hexagonal fuel assemblies. Currently available CHF prediction models and data base for triangular lattice bundles have been thoroughly reviewed, and as a result the KfK-3 CHF correlation with limit CHFR of 1.235 has been determined to be most appropriate. The pressure drop model in COBRA-IV-I code has been modified for the analysis of triangular lattice rod bundles. In view of maximizing the thermal margin, the geometry of a hexagonal fuel assembly, such as rod diameter and rod pitch, has been optimized with a fixed fuel assembly cross sectional area The optimum value of the moderator-to-fuel volume ratio is estimated to lie between 0.65 to 1 with 9.5 mm rod diameter. The thermal margin of these hexagonal fuel assemblies in the AP600 core has been evaluated and compared with that of square lattice fuel assemblies such as VANTAGE-5H and KOFA. The analysis result shows that the performances of hexagonal fuel assemblies are more favorable than the square fuel assemblies in the aspect of steady-state overpower margin.

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수용액 합성법의 2단계 성장온도 변화를 통한 ZnO 결정의 선택적 용해 현상 (Selective Dissolution of ZnO Crystal by a Two-step Thermal Aging in Aqueous Solution)

  • 김정석;채기웅
    • 한국세라믹학회지
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    • 제48권4호
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    • pp.263-268
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    • 2011
  • ZnO hexagonal rods grown in aqueous solution can be changed into a tubular shape by two-step aging in the course of the growing process. In the first step, hexagonal ZnO rods is grown by aging at $90^{\circ}C$ under a highly supersaturated aqueous solution giving rise to a fast precipitation rate. Meanwhile, during the second step aging at $60^{\circ}C$ in the same aqueous solution, the hexagonal polar face (001) having higher surface energy than (010) side planes dissolves to minimize surface energy. Hence the flat (001) face changes to a craterlike face and the hexagonal rod length of ZnO decreases at an initial-stage of this step aging. The formation of the (101) wedge-type faces is ascribed to the resultant of competitive reactions between the dissolution of polar face minimizing the surface energy which is a dominant reaction at the initial stage and the precipitation reaction dissipating supersaturation. At a later stage of the second-step the reaction rates of these two processes in the aqueous solution become similar and the overall reaction is terminated.

Ba 육방정 페라이트의 소결 특성 및 마이크로파 특성 (Sintering and Microwave Properties of Ba Hexagonal Ferrite)

  • 김재식;류기원;배선기;이영희
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2009년도 제40회 하계학술대회
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    • pp.1293_1294
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    • 2009
  • The sintering and high frequency electro-magnetic properties of Ba-hexagonal ferrite were investigated. All samples of the Ba-hexagonal ferrite were prepared by the conventional mixed oxide method and sintered at $1150^{\circ}C$~$1400^{\circ}C$. From the X-ray diffraction patterns of sintered Ba-hexagonal ferrite, the $Ba_3Co_2Fe_{24}O_{41}$ phase was represented as main phase in the almost sintering conditions. The bulk densities with sintering temperature and decreased at $1400^{\circ}C$. The permittivity ($\varepsilon$') and loss tangent of permittivity ($\varepsilon$"/$\varepsilon$') of $Ba_3Co_2Fe_{24}O_{41}$ ceramics increased and decreased with sintering temperature, respectively. The permeability of $Ba_3Co_2Fe_{24}O_{41}$ ceramics decreased with sinteirng temperature. The loss tangent of permeability was not changed compared each other with sintering temperature. The bulk density of $Ba_3Co_2Fe_{24}O_{41}$ ceramics sintered at $1300^{\circ}C$ was 4.79 g/$cm^3$. The permittivity, loss tangent of permittivity and permeability, loss tangent of permeability were 19.896, 0.1718 and 14.218, 0.2046 at 210 MHz, respectively.

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용융염법으로 합성한 Ba-ferrite 입자의 특성 (Properties of ba-ferrite Particles Synthesized by Molten Salt Method)

  • 오영우
    • 한국전기전자재료학회논문지
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    • 제13권6호
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    • pp.545-550
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    • 2000
  • In order to synthesize Ba-ferrite particles by molten salt method KCl and NaCl were added to basic composition to 50% by weight. X was varied from 0.0 to 1.0 to control the magnetic properties in $BaFe_{12-2x}$/ $Co_{x}$ / $Ti_{x}$ / $O_{19}$ and 1 mol% of $SiO_2$was added to control the aspect ratio of hexagonal platelets. And the effects of reaction temperatures were examined by varying the temperature from 85$0^{\circ}C$ to 120$0^{\circ}C$ with 5$0^{\circ}C$ intervals. Eutectic composition of NaCl and KCl lowered the crystallizing temperature of Ba-ferrite in molten salts than using KCl and NaCl separatly. The morphology of resulting Ba-ferrite particles was clearly hexagonal-shaped plates. $H_{c}$ and $M_{r}$ were decreased when F $e^{3+}$ was substitued with $Co^{2+}$ and $Ti^{4+}$ from x=0 to x=1.0 in $BaFe_{12-2x}$/ $Co_{x}$ / $Ti_{x}$ / $O_{19}$ . Adding 1mol% $SiO_2$in molten salt method increased the size but shortened c-axis of the hexagonal ferrites and this result is an opposite phenomenon compared with the result in solid-statge reaction.n.ion.n.

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육각형 격자를 사용한 부드러운 경로생성 (Smooth Path Generation using Hexagonal Cell Representation)

  • 정동원
    • 한국항공우주학회지
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    • 제39권12호
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    • pp.1124-1132
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    • 2011
  • 본 논문에서는 2차원 공간에서 기동하는 고정익 무인항공기의 장애물 회피를 위한 부드러운 경로궤적을 생성하는 문제를 다룬다. 2차원 장애물맵의 이산화 모델링을 위해 육각형 격자를 채택하였고, 이는 사각형 격자에 비해 연결성이 높아 부드러운 경로궤적 생성이 가능하도록 하였다. 특히 본 논문에서 제안된 경로템플릿 기법은 일정거리 단위로 조합 가능한 대표경로들(경로템플릿)을 사용하여 무인항공기의 기준경로를 생성하는 방법이고, 온라인 경로궤적 생성에서 계산량을 줄여 메모리 및 연산리소스가 제한되는 소형 오토파일럿에서도 적용이 가능하다는 장점이 있다.

Pt/$MoO_3$ 촉매에서 $MoO_3$ 상변화가 수소 spillover에 미치는 효과 (Effect of Phase Change of $MoO_3$ on $H_2$ Spillover Kinetics over Pt/$MoO_3$)

  • 김진걸;김성수;유승준
    • 한국수소및신에너지학회논문집
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    • 제20권4호
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    • pp.331-336
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    • 2009
  • 수소가 Pt/$MoO_3$로 흡장되는 현상을 XRD, TEM, CO 화학흡착 분석방법을 사용하여 조사하였다. 소성과정은 Pt/$MoO_3$ 촉매의 Chlorine 함유량을 감소하며 박막을 형성하였다. 소성전과 비교하여 수소 흡장량은 소성 후에 증가하였다. Orthorhombic Pt/$MoO_3$은 Hexagonal Pt/$MoO_3$보다 항상 수소 흡장량이 증가하였다. 상대적으로 Hexagonal Pt/$MoO_3$에서 수소 흡장량이 감소하는 이유는 Hexagonal 결정격자 내에 존재하는 $NH_4^+$ 이온에 기인하는 것으로 판단된다. 결정격자 내부로의 수소 침투시 암모니움 이온이 수소내부 기공에 장애물 역할을 하므로, 수소 흡장량이 감소하는 것으로 판단된다.

십자와 육각패턴을 이용한 고속 블록 정합 동작 예측 기법 (A New Cross and Hexagonal Search Algorithm for Fast Block Matching Motion Estimation)

  • 박인영;남현우;위영철;김하진
    • 정보처리학회논문지B
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    • 제10B권7호
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    • pp.811-814
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    • 2003
  • 본 논문에서는 십자패턴과 육각패턴을 이용한 고속 블록 정합 동작 예측 기법을 제안한다. 블록 기반 탐색에서 전역 탐색방법이 가장 좋은 동작벡터를 찾지만, 탐색영역 내의 모든 전을 검색하기 때문에 많은 시간을 필요로 하게 된다. 본 방법은 대부분의 동영상에서 동작벡터가 블록의 중심 부근에 집중적으로 분포함을 착안하여 십자패턴으로 중앙을 우선 탐색한 다음 움직임이 큰 동작벡터를 육각패턴을 사용하여 찾는다. 실험결과, 본 방법은 기존의 탐색방법보다 화질과 탐색시간에서 대부분의 경우에 좋은 성능을 보임을 알 수 있다.

육각 슬롯 구조를 가진 UWB 안테나 설계 (Design of a UWB Antenna with Hexagonal Slot)

  • 안상철;김용희;정훈;정천석
    • 한국전자파학회논문지
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    • 제19권3호
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    • pp.336-342
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    • 2008
  • 본 논문에서는 UWB 통신 시스템에서 사용될 수 있는 CPW 급전을 이용한 새로운 육각 슬롯 구조를 가지는 UWB 안테나를 제안하였다. 제안된 안테나는 임피던스 대역폭을 넓히기 위해서 육각 패치(patch)를 가진다. 또한 IEEE 802.11a 대역과 상호 간섭 문제를 피하기 위해서 패치 위에 다각형 슬롯을 삽입하였다. 제안된 안테나는 유전율이 4.7이며, 두께가 1.6 mm인 FR-4 기판으로 제작하였으며, VSWR 특성과 그룹딜레이를 측정하였다. 제작된 안테나는 IEEE 802.11a 대역을 제외하고는 4 dBi의 이득 변화량을 나타내었다.