• Title/Summary/Keyword: herbicidal

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Synthesis and herbicidal activities of 2-(5-Propargyloxyphenyl)-4,5,6,7-tetrahydro-2H-indazole and their related derivatives (새로운 2-(5-Propargyloxyphenyl)-4,5,6,7-tetrahydro-2H-indazole의 합성과 제초활성)

  • Jeon, Dong-Ju;Park, Kwaun-Yong;Kim, Young-Mi;Kim, Hyoung-Rae;Song, Jong-Hwan;Hwang, In-Taek;Ryu, Eung-K.
    • The Korean Journal of Pesticide Science
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    • v.5 no.4
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    • pp.68-71
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    • 2001
  • Of the cyclic imide type compounds, S-275 was known to exhibit a potent herbicidal effects. We have designed and synthesized the compounds having diverse subsutuents in place of the chlorine group of bicyclic 4,5,6,7-tetrahydroindazole part of S-275. Their herbicidal activities were studied under flooded paddy conditions. The results showed that the most compounds gave relatively weak herbicidal activities, whereas tile compound substituted with methylthio group showed potent herbicidal effects against paddy weeds at a rate of 0.015 kg/ha and improved tolerance on rice compared to S-275.

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Herbicidal Effect of 5-Aminolevulinic Acid, a Biodegradable Photodynamic Substance (생분해성 광활성 물질 5-aminolevulinic acid의 제초활성)

  • Chon, Sang-Uk;Kim, Young-Min
    • The Korean Journal of Pesticide Science
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    • v.11 no.1
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    • pp.38-45
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    • 2007
  • Laboratory and greenhouse experiments were conducted to determine the herbicidal effect of two types of ${\delta}$-aminolevulinic acid (ALA), microbiologically-produced ALA (Bio-ALA) and synthetically produced ALA (Synthetic-ALA), on plant growth and chlorophyll content of Chinese cabbage. ALA effect on early plant growth was greatly concentration dependant, showing significant inhibition at higher concentrations. Both pre- and post-emergence application of ALA exhibited significant degree of photodynamic phytotoxicity. Older plants with many leaves were more tolerant to ALA than younger plants, showing less injury. No significant difference in herbicidal activity of two types of ALA, Bio-ALA and Synthetic-ALA, on plant height and chlorophyll content of Chinese cabbage was observed. However, residual biological activity and physico-chemical properties of Synthetic-ALA were more stable than those of Bio-ALA. Our results suggest that ALA had herbicidal potential with both pre- and post-emergence application, and that the chemical may be a valuable mean of eco-friendly weed control based on natural microbial substance.

Isolation of Herbicidal Substances from Bulbs of Lycoris flavescens M.Y.Kim & S.T.Lee (붉노랑상사화 인경으로부터 살초활성 물질의 분리)

  • Lee, Dong-Gu;Kim, Kun-Woo
    • Korean Journal of Weed Science
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    • v.31 no.4
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    • pp.330-339
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    • 2011
  • This study was conducted to determine the herbicidal activity of herbicidal substances and identify them in bulbs of Lycoris flavescens. Methanol extract was purified by a series of chromatographic techniques including silica gel column chromatography, preparative TLC, and HPLC. The final HPLC gave two active fractions and two herbicidal substances were obtained. By GC/MS analysis, one was identified as galanthine (galanthan-1-ol) and the other was identified as montanine ($O^2$-methyl pancracine), an isoquinoline alkaloid. Montanine showed nearly 100% of growth inhibition on the shoot and root of barnyardgrass (Echinochloa crusgalli) seedlings at $20{\mu}g\;mL^{-1}$ as compared with the control. Meanwhile, methanol extract of L. flavescens bulbs showed only about 3.1% and 8.3% of growth inhibition on the shoot and root of rice cultivar, Hwayeongbyeo seedlings at $1,000{\mu}g\;mL^{-1}$ as compared with the control, respectively.

Increasing forage yield and effective weed control of corn-soybean mixed forage for livestock through using by different herbicides

  • Song, Yowook;Fiaz, Muhammad;Kim, Dong Woo;Kim, Jeongtae;Kwon, Chan Ho
    • Journal of Animal Science and Technology
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    • v.61 no.4
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    • pp.185-191
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    • 2019
  • The aim of this study was to evaluate different herbicides for optimum growth, yield and nutritive value of corn-soybean mixed forage under randomized complete block design. The experimental site was selected and divided equally into 3 blocks. Each block was further divided into 5 plots that each plot had 15 square meter space ($3{\times}5$). Five herbicidal treatments were randomly applied over 5 plots and herbicides were used under 5 herbicidal treatments, viz. 1) No herbicide (control); 2) Pendimethalin; 3) Linuron; 4) S-metolachlor and 5) Ethalfluralin. The collected data were analyzed using ANOVA through SAS 9.1.3 software. The results indicated that growth characteristics were not influenced (p > 0.05) by any herbicide. However, arithmetically corn stalk height was highest in the field of Pendimethalin treatment, whereas highest soybean height was found in the field of S-metolachlor. Arithmetically dry matter (DM) yield was increased with herbicidal treatments as compared to that of control treatment. Relatively highest DM yield (130%) was recorded in the treatment of Ethalfluralin followed by Pendimethalin (126%), S-metolachlor (126%) and Linuron (108%) as compared to that of control treatment. The weed emergence was significantly reduced in all herbicidal treatments as compared to that of control (p > 0.05), but the difference among herbicidal treatments was non-significant. It was concluded that weed emergence can be effectively controlled by use of any tested herbicide. However, optimum DM yield can be achieved through using herbicides; Ethalfluralin, Pendimethalin and S-metolachlor.

Synthesis and Herbicidal Activity of 2-(1-anilinobutylidene)-5,5-dimethyl-3-hydroxy-2-cyclohexen-1-ones (2-(1-Anilinobutylidene)-5,5-dimethyl-3-hydroxy-2-cyclohexen-1-ones의 합성과 제초활성)

  • Ha, Hyun-Joon
    • Applied Biological Chemistry
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    • v.37 no.6
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    • pp.522-525
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    • 1994
  • Fourteen 2-(1-anilinobutylidene)-5,5-dimethyl-3-hydroxy-2-cyclohexen-1-ones were prepared by condensation of 2-butanoyl-5,5-dimethyl-3-hydroxy-2-cyclohexen-1-one with various substituted anilines in good yield. These were tested for herbicidal activity against six different submerged paddy weed species. Most compounds showed significant activity against Echinochloa crus-galli and Sagittaria pygmaea with excellent tolerance to rice.

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Herbicidal Phytotoxicity in Relation to the Korean Soil Properties (한국(韓國) 경지토양특성(耕地土壤特性)에 관련(關聯)된 제초제(除草劑) 약해(藥害))

  • Ryang, Hwan-Seung;Chun, Jae-Chul
    • Korean Journal of Weed Science
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    • v.2 no.2
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    • pp.122-128
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    • 1982
  • This paper deals with herbicidal phytotoxicity which may occur because of unique properties of the Korean soils. Analysis of the Korean lowland and upland soils reveals that about 50% of the total area belongs to sandy loam and sandy gravel soils and most of both lowland and upland soils consists of kaolinite clay mineral. The chemical properties such as organic matter, pH, and cation exchange capacity show very low values by which there have been several instances of the herbicidal phytotoxicity occurred throughout the country. In addition, the paper emphasizes the need for selection and use of herbicides in the Korean soils.

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Effects of Pre-Emergence Herbieide for Control of Lawn Weeds (잡초 출아전 토양처리용 제초제의 처리가 잔디밭 잡초 방제 효과에 관한 연구)

  • 이명선
    • Asian Journal of Turfgrass Science
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    • v.2 no.1
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    • pp.65-69
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    • 1988
  • This experiment was conducted to study the effects of herbicides and their damages to lawn plant for the control of lawn weeds using pre-emergence granule herbicide at the two years old lawn field. The results obtained are summarized as follows. 1)Herbicidal damages to lawn grass were observed at the higher concentration than the recommended level in four herbicides used in this trial. The optimum dosages for the control of lawn weeds were 3-6g in Lasso, 3g in Machet, 8-24g in Simazine, and 4g in Trifluralin, respectively. 2)No herbicidal damages was observed in Simazine treatment, whereas Lasso and Machet treatment showed a little and severe herbicidal damages, respectively. The most severe damage was found in Trifluralin treatment, indicating that this herbicide is not suitable for the control of lawn weeds.

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Synthesis and Herbicidal Activity of Cyclohexane-1,3-diones : Rice Selective 5-(2-alkyl-2-methylindanyl) cyclohexane-1,3-dione herbicides under paddy submerged conditions (담수조건에서 벼에 선택적인 5-(2-alkyl-2-methylindanyl)cyclohexane-1,3-diones 유도체의 합성과 제초활성)

  • Kim, Kyoung-Mahn;Lee, Byung-Hoe;Ryu, Eung-Kul
    • The Korean Journal of Pesticide Science
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    • v.4 no.3
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    • pp.89-92
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    • 2000
  • A series of 5-(2-metllyl-2-alkylindallyl)cyclohexane-1,3-diones were synthesized and evaluated for herbicidal activities in a green house. Under submerged paddy conditions, those compounds showed high herbicidal activity against barnyardgrass with good tolerance on rice.

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Herbicidal Activity of Korean Native Plants (III) (살초활성물질 함유 국내 자생식물의 탐색 (III))

  • Kim, Song-Mun;Kim, Mi-Sung;Lee, Yu-Sun;Kim, Hee-Yeon;Choi, Hae-Jin;Heo, Su-Jeong;Kwon, Soon-Bae;Kim, Kyung-Hee;Han, Sang-Sub;Lim, Sang-Hyun
    • The Korean Journal of Pesticide Science
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    • v.9 no.2
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    • pp.173-180
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    • 2005
  • This study was conducted of Korean native plants to screen herbicidal activity which could be used for the development of new natural herbicides. Eighty-one plants were collected from Wan and Juju islands in Korea and their methanol extracts were obtained. Heibicidal activities of the methanol extracts were determined by seed bioassay using rapeseed (Brassica napus L.) seedlings. Among eighty-one species, eleven plants were highly herbicidal ($GR_{50}$ < 1,000 ${\mu}g\;g^{-1}$): Abies koreana WILS., Anthemis nobilis L., Callicarpa mollis SIEB. et ZUCC., Cirsium setidens, Euonymus maackii RUPR., Euphorbia jolkini BOISS., Kadsura japonica DUNAL, Paeonia aliflora Pall var. tricocarpa BUNGE, Philadelphus tenuifolius RUPR. et MAXIM., Sapium sebiferum, Vicia angustifolia var. segetilis K. KOCH. Fifty plants were shown moderate herbicidal activity (1,000 ${\mu}g\;g^{-1}$ < $GR_{50}$ < 2,000 ${\mu}g\;g^{-1}$), however, twenty plants were not shown any herbicidal activity.

Molecular Holographic QSAR Model on the Herbicidal Activities of New Novel 2-(4-(6-chloro-2-benzoxazolyloxy)phenoxy)-N-phenylpropionamide Derivatives and Prediction of Higher Activity Compounds (새로운 2-(4-(6-chloro-2-benzoxazolyloxy)phenoxy)-N-phenyl-propionamide 유도체들의 제초활성에 관한 HQSAR 모델과 높은 활성 화합물의 예측)

  • Sung, Nack-Do;Kim, Dae-Whang;Jung, Hoon-Sung
    • The Korean Journal of Pesticide Science
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    • v.9 no.4
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    • pp.279-286
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    • 2005
  • The herbicidal activities against pre-emergence barnyard grass (Echinochloa crus-galli) by a series of new 2-(4-(6-chloro-2-benzoxazolyloxy)phenoxy)-N-phenylpopionamide derivatives as substrate molecule were studied using molecular holographic (H) quantitative structure activity relationships (HQSAR) methodology. From the based on the findings, the higher herbicidal active compounds are predicted by the derived HQSAR model. The best HQSAR model (VI-1) was derived from fragment distinction combination of atoms/bonds in fragment size, $7{\sim}10$bin. The herbicidal activities from atomic contribution maps showed that the activity will be able to increased according to the R-substituents variation of the N-phenyl ring and change of 6-chloro-2-benzoxazolyloxy group. Based on the results, the statistical results of the best HQSAR model (VI-1) exhibited the best pedictability and fitness for the herbicidal activities based on the cross-validated value ($q^2=0.646$) and non cross-validated value ($r^2_{ncv.}=0.917$), respectively. From the graphical analyses of atomic contribution maps, it was revealed that the lowest herbicidal activitics depends upon the 4-(6-chloro-2-benzoxazolyloxy)phenoxy group ($pred.pI_{50}=-3.20$). Particularly, the R=4-fluoro, X=isobutoxy substituent (P2) of (X)-phenoxy-N-(R)-phenylpropionamide derivative is predicted as the highest active compound ($pred.pI_{50}=9.12$).