• Title/Summary/Keyword: heavy metals concentration

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A Study on the Distributions of Heavy Metal Concentration in a Soil near Abandoned Mine (폐광산 주변 토양의 중금속 농도 분포에 관한 연구)

  • 양천회;고장석
    • Journal of the Korean Society of Safety
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    • v.13 no.4
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    • pp.186-191
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    • 1998
  • This study was investigated the distributions of heavy metal concentration in a soil near abandoned mine in Chung thong Nam Do. The abandoned mines were Gubong gold mine and Sinsung coal mine. The results were as follows : 1) The concentration of As and Pb in Gubong mine were 309.2mg/kg and 1163.5mg/kg, that is exceeded the countermeasure criteria. Cadmium concentration was 14.70mg/kg, that is exceeded anxiety criteria. But all items in Sinsung coal mine was detected below criteria. 2) The heavy metals contamination of riverbed soil by gold mine showed higher than coal mine. 3) The heavy metals contamination in the vicinal paddy and dry field soil area was higher than other mine. Arsenic concentration was 29.29mg/kg, that is exceeded the anxiety criteria as 10.22mg/kg.

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Heavy Metals in Ambient Air at Shinchon Area in Seoul (도시 대기중 중금속에 관한 연구 -서울시 신촌지역을 중심으로-)

  • Chung, Yong;Jang, Jae-Yeon;Chu, Ui-Jo
    • Journal of Korean Society for Atmospheric Environment
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    • v.3 no.2
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    • pp.18-26
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    • 1987
  • In order to investigate the character of air pollution by heavy metals and to elucidate the possible sources in Seoul city, this study was performed to measure the concentrations of heavy metals of total suspended particulate and air pollutants such as $SO_2, NO_2, CO, CH_4$, Non-methane hydrocarbon, ozone at the residential-traffic area (shinchon dong) in January and February, 1986. The results are as follows: 1. $SO_2$ and TSP concentration were 135ppb and 167 $\mug/m^3$ in average, respectively. 2. While concentrations of heavy metals such as Fe, Cu, Pb in the ambient air seems gradually decreasing annually, Ni compound has been shown the tendency of increasing. 3. Among heavy metals in TSP analysed, the iron was detected at the highest level, 0.905% and the cadimium was the lowest 0.004% in average, respectively. 4. V, Fe and Zn compounds in air were observed to be highly correlated with their correlation coefficients(r) higher than 0.7. Pb compound was highly correlated to the levels of Zn and Fe, however relatively less correlated to V compound. 5. Among concentrations of heavy metals in the particulates, V and Ni compounds were highly correlated with coefficient(r) of 0.8587; the cause might be imagined by the fact of releasing from combustion of fuel oil. Fe, Pb and Zn compounds were highly correlated $SO_2$ concentration. It might be explained that they were released by combustion of coal. 6. The level of $SO_2$ was highly correlated to most of heavy metals: especially correlation coefficient(r) to Pb compound was 0.9081. Pb compound was also highly correlated to NO, CO and TSP. TSP showed higher correlation to Pb and Cd compounds than to V and Ni compounds. It might be assumed that particulate was mainly produced by combusting coal from space heating and by exhausting gasoline and diesel oil from transportation rather than by burning fuel oil.

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Convergence Process for the Removal of Heavy Metals in the Abandoned Mine (휴폐광산의 중금속제어를 위한 융합공정 개발)

  • Dho, Hyonseung
    • Journal of the Korea Convergence Society
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    • v.7 no.1
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    • pp.155-160
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    • 2016
  • The convergence process utilized both leaching and ion exchange techniques has been investigated for the heavy metals removal in the abandoned mine of Chungyang Province, Korea. The contaminated soil samples by heavy metals from Samkwang mine were analysed by statistical analyses. The highly contaminated soils was initially separated by the flotation process. The selectivity indices were increased with increasing flotation reagents. The selectivity of separation was then improved by the use of both leaching and ion exchange processes in order to extract the heavy metals. The results of this study showed that the higher the sulfuric acid concentration, the leaching rate of heavy metals was increased. The lecheate then was removed by the ion exchange method. The anticipating results might imply that convergence process utilized both leaching and ion exchange techniques would somehow apply for the removal of heavy metals in the abandoned mine.

Ecological study on effects of heavy metal accumulation on pillbugs (토양 내 서식하는 공벌레의 중금속 축적에 따른 생태적 연구)

  • Lee, Sang-Don
    • Journal of Environmental Impact Assessment
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    • v.20 no.5
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    • pp.675-684
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    • 2011
  • In nature, the overall effect of heavy metals on the biota can be influenced by a number of environmental factors like soil characteristics and air pollution by elevated $CO_2$. Pillbugs (Isopoda, Armadillium vulgare) take up heavy metals with their food and store them mainly in the vesicles of hepatopancreas. They accumulate certain metals, occur in relatively large numbers, are easily collected and identified, and provide sufficient material for analysis. The species are decomposing litter well and soil impurities into N and P. Therefore, it has been suggested that total body concentration of metals in pillbugs could be positively correlated to the levels of environmental exposure and that pillbugs could be used as biological indicators of metal pollution and global change by $CO_2$. The aim of the study is to determine effects of heavy metal concentrations in soil and elevated $CO_2$ on pillbugs' body accumulation of heavy metal and growth rate. In this study, the concentrations of six metals (Fe, Mg Cu, Zn, Pb, Cd) have been determined. Pillbugs (N=287) were collected at five sites during Jul-Aug, 2006. Cu and Zn concentrations in the body were much higher than in the soils(1.39-41.70 times). This indicated that bioaccumulation of some of the heavy metals were increasing in the food-chain. The high bioconcentration of lead in Sangam may be partly associated with reclaimed land uses.

Risk assessment of heavy metals in soil based on the geographic information system-Kriging technique in Anka, Nigeria

  • Johnbull, Onisoya;Abbassi, Bassim;Zytner, Richard G.
    • Environmental Engineering Research
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    • v.24 no.1
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    • pp.150-158
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    • 2019
  • Soil contaminated with heavy metals from artisanal gold mining in Anka Local Government Area in Northwestern Nigeria was investigated to evaluate the human health risk as a result of heavy metals. Measured concentration of heavy metals and exposure parameters were used to estimate human carcinogenic and non-carcinogenic risk. GIS-based Kriging method was utilized to create a prediction maps of human health risks and probability maps of heavy metals concentrations exceeding their threshold limits. Hazard index calculation showed that 21 out of 23 locations are posing non-cancer risk for children. Adults and children are at high cancer risk in all locations as the total cancer risk exceeded $1{\times}10^{-6}$ (the lower limit CTR value). Kriging model showed that only a very small area in Anka has a hazard index of less than unity and cumulative target risk of less than $1{\times}10^{-4}$, indicating a significant carcinogenic and non-carcinogenic risks for children. The probability of heavy metals to exceed their threshold concentrations around the study area was also found to be high.

Evaluation of Heavy Metal Pollution in Soil on the Playgrounds for Children in I area (I시 어린이 놀이터의 토양 중 중금속 오염에 관한 연구)

  • 이충대;이윤진;조남영
    • Journal of Environmental Health Sciences
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    • v.27 no.3
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    • pp.57-62
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    • 2001
  • The study was conducted to measure the heavy metal pollution of soils at the playground for children and to investigate the characteristics of heavy metals distribution I city. The studied area was divided into two: the residential area and the industrial area. The samples of the sands and soils were collected from both areas. The results were obtained as follows. All average concentration of 6 different heavy metals was found to be lower than the standard of soil pollution. Zn, Pb and cu concentrations were higher than other species of heavy metals. The contents of heavy metals in the soil were higher than the sands. The average contents of Zn, Pb, Cu, As, Hg and Cd in soil were 38.36, 9.53, 7.31, 0.03, 0.18 and 0.09 mg/kg respectively. Comparing with the residential area, heavy metal concentrations of the industrial area were 4.60, 1.49, 2.60 and 4.29 times for Zn, Pb, Hg and Cd in soils, respectively.

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Effects of Heavy Metals on Clearance and Oxygen Consumption Rates of the Sea Squirt Halocynthia roretzi According to Various Body Sizes

  • Kang, Kyoung Ho;Hur, Jun Wook
    • Korean Journal of Environmental Biology
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    • v.30 no.4
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    • pp.349-354
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    • 2012
  • To evaluate the biological response of sea squirt Halocynthia roretzi with different body size to heavy metals and its suitability for ecotoxicity assays, the effects of Cr, Cu and Zn on its clearance and oxygen consumption rates were investigated. Clearance and oxygen consumption rates of H. roretzi with various body sizes were calculated at different metal concentrations. Both clearance and oxygen consumption rate were negatively correlated with body sizes. Clearance rate of H. roretzi decreased gradually with increasing concentration of heavy metal, the decreasing rate was in an order of Cr>Cu>Zn. The oxygen consumption rate first increased at low metal concentration (below $100{\mu}g\;L^{-1}$) and then decreased rapidly with increasing metal concentrations. The decreasing rate was in an order of Cu>Cr=Zn. There was a trend that the clearance rate and oxygen consumption rate decreased drastically under a concentration of $400{\mu}g\;L^{-1}$, and then decreased smoothly when the metal ion concentration increased continually. So the oxygen consumption and clearance rate at a concentration of $400{\mu}g\;L^{-1}$ Cu could be thought as a suitable biological tool for exotoxicology analysis.

Estimation of Source Contribution of Particulate Matter in Taegu Area using Factor Analysis (다변량 통계분석법을 이용한 대구지역 부유분진의 오염원 기여도 추정)

  • 최성우;송형도
    • Journal of Environmental Health Sciences
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    • v.26 no.4
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    • pp.1-8
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    • 2000
  • The objective of this study was to identify the sources and to estimate the source contributions to the atmospheric TSP(total suspended particulate matter) and PM-10(particulate matter with aerodynamic diameters less than 10$\mu\textrm{m}$) concentration in Taegu area. A total of 84 samples was collected during the January to December 1999. TSP and PM-10 were collected on filters by portable air sampler, and heavy metals in TSP and PM-배 were analyzed by ICO(Inductively Coupled Plasma Spectrometery) after preliminary treatment. The results were follow as : First, annual average of TSP and PM-10 concentration was 123 and 69$\mu\textrm{g}$/㎥ respectively. The concentration of TSP and PM-10 were highest in winter season compared to other seasons. Second, the concentration of Al, Fe, Mn were higher in TSP than in PM-10, indicating that these heavy metals are generally associate with natural contributions. Third, metal combinations showed that a high correlation among concentrations of heavy metals were follows: As Al, Fe and Mn in TSP ; Ni, Cr, Cd and Pb in PM-10. Finally, Statistical analysis was performed using Principal Components Analysis(PCA) in order to find possible sources of the pollutants. The factor analysis was permitted to identify four major sources(soil/road dust resuspension, waste incineration, furl combustion, vehicular emission) in each fraction. These source accounted for at least 83, 85% of variance of TSP and PM-10 concentration in Taegu area.

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Human Risk Assessment for Exposure to Heavy Metals within Finishing Materials of Playground Facilities for Children in Gwangju (광주지역 어린이 놀이시설 마감재의 중금속 노출에 의한 인체 위해성평가)

  • Sang-Hoon Yoon;So-Young Kim;Eun Cho;Tae-Hui Nam;Jin-Hwan Park;Hwa-Jin Kong;Ki-Won Lee;Gwang-Yeob Seo;Jeong-Hun Park;Kyoung-Woo Min
    • Journal of Environmental Health Sciences
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    • v.50 no.2
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    • pp.146-156
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    • 2024
  • Background: Children who use playground facilities are exposed to potential risks due to the high concentration of heavy metals contained in the finishing materials of facilities in children's playgrounds. Objectives: The purpose of this study was to investigate the concentration of heavy metals in the finishing materials of outdoor children's playgrounds where harmful heavy metals exist in Gwangju and to conduct human risk assessment for children and adults by age to find the risks and limitations. Methods: The bottom and top layers of double-painted paint were peeled off and collected together from the finishing materials of children's play facilities such as slides, swings, and seesaws in 147 children's parks in Gwangju. Heavy metals were analyzed using ICP-OES, etc., and human risk assessment was performed using the concentrations of heavy metals. Results: Based on 1.0E-04, which requires legal regulation, CTE was found to pose a carcinogenic risk for preschool children and no carcinogenic risk for the rest of the age groups. However, RME showed that both men and women of all ages had a carcinogenic risk. For reference, when the carcinogenic risk was based on 1.0E-06, CTE was found to pose a carcinogenic risk from infants to elementary school students, and RME was found to have a carcinogenic risk in all age groups. It was judged that there is a non-carcinogenic risk if the non-carcinogenic risk exceeds 1 based on the hazard index (HI) 1. In CTE, there was no non-carcinogenic risk, and RME for preschooler males (1.49E+00) and females (1.56E+00) were found to have non-carcinogenic risk. Conclusions: This study was meaningful in that it examines the differences in the current management of heavy metals concentration standards and potential carcinogenic and non-carcinogenic risks to the human body and discusses the relationship between heavy metals and human health effects.

Atmospheric Concentration of Polycyclic Aromatic Hydrocarbons and Heavy Metals in Suspended Particulate (大氣浮遊粉塵中 多環芳香族炭火水素 및 重金屬의 濃度)

  • 손동헌;권창호;정원태;허문영
    • Journal of Korean Society for Atmospheric Environment
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    • v.7 no.1
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    • pp.17-22
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    • 1991
  • Total suspended particulates (TSP) in the atmosphere was collected and size-fractionated by Andersen high volume air sampler for one year (Mar. 1987 $\sim$ Feb. 1988) in Seoul. The concentrations of several polycyclic aromatic hydrocarbons and heavy metals were determined to investigate the atmospheric concentrations, seasonal variations and its relationship with the size distribution of suspended particulate matter. The arithmetic mean concentration of total suspended particulates was 200.44 $\mug/m^3$. The concentrations of heavy metals were 2433.80 for Fe, 629.49 for Zn, 600.71 for Pb, 143.87 for Cu, and 107.21 $ng/m^3$ for Mn, respectively. The concentrations of PAHs were 3.83 for benzo(a) pyrene, 2.95 for benzo(k)fluoranthene, and 4.42 $ng/m^3$ for benzo(ghi)perylene, respectively. PAHs, Pb and Zn abounded in particles below 2.0 $\mu$m, while Fe and Mn aboounded in particles above 2.0 $\mu$m. TSP and its chemical compositions showed the seasonal variations. The concentrations of anthrophogenic pollutants like TSP, PAHs and heavy metals in the fine particles were highest in winter and lowest in summer. PAHs and Pb analyzed showed significant correlations between each other and between TSP concentration in fine particles, indicating that the particles in which they are contained have a similar behavior in the atmosphere.

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