• Title/Summary/Keyword: heavy metal residues

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Effect of Heating Treatment on the Cooking Loss and Heavy Metal Residues of Porcine Variety Viscera (열처리에 의한 돈 내장근의 중량손실 및 미량 중금속 잔류에 미치는 영향)

  • 양철영
    • The Korean Journal of Food And Nutrition
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    • v.7 no.4
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    • pp.297-306
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    • 1994
  • This experiment was carried out to investigate the healing loss and the heavy metal residues such as copper, zinc, manganese, cadmium and lead In porcine visceras by inductively coupled argon plasma spectrometer(ICP), and to probe changes when porcine visceras were boiling In water treatment(BWT), heating in autoclave treatment (HAT) and heating In oil treatment (HOT) . The range of heating loss on porcine viscera were BWT(23.11∼34.53%) , HAT(18.48∼28.00%) and HOT(14.20∼25.22%)and the heart tissue were higher and liver were lower than those of the other tissues. The total value of heavy metal residues in large intestine, small intestine, heart, kidney, liver and stomach tissue were 11.298${\pm}$5.302 ppm, 27.825${\pm}$8. 177 ppm, 16.756${\pm}$6.334 ppm 21.107${\pm}$6.057 ppm, 25.369 ${\pm}$ 10.164 ppm and 12.611 ${\pm}$5.513 ppm, respectively. Heavy metal residues in porcine visceras tended to decrease according to heating methods and the variety viscera, and the change of total heavy metal residues on BWT, HAT and HOT were 4.16∼32.57%, 12.01∼28.09% and 9.60∼25.76%, respectively. The decrease of lead element of mean value were 21.76% and copper, zinc, manganese and cadmium element were 18.00∼ 18.16%. The change of heavy metal residues were not significant in the porcine visceras(P>0.05), and the these were significantly correlated among the three heating method(P < 0.05).

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Fiber Analysis and Environmental Assessment of Recycled Waste paper for Eco-friendly Corrugated Box Manufacture (친환경 골판지 상자 제조를 위한 재활용 폐지 섬유의 물리적·환경적 특성 평가)

  • Park, Jung-Yoon;Lee, Tai-Ju;Kim, Hyoung-Jin;Kim, Jin-Mu
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.4
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    • pp.65-74
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    • 2013
  • In the manufacture of corrugated box, the fibrous raw materials are mainly consisted of recycled papers, such as KOCC(Korean Old Corrugated Container), kraft sack, and AOCC(American Old Corrugated Container). Among these recycled waste paper, the proportion of KOCC is relatively higher than others in fibrous raw materials. Generally, KOCC shows some poor fiber properties and contains hazardous heavy metal sources. Therefore, it is to evaluate the property of recycled paper sources for eco-friendly corrugated box manufacture. In this study, the physical and mechanical properties of 3 kinds of recycled fibers and their mixed stocks were analyzed. The environmental assessment was also evaluated by analyzing the 4 representative heavy metal contents and evaporation residues in waste papers. As the results, KOCC showed the poorest fiber qualities and had the highest heavy metal contents and evaporation residues among the recycled fibers. Finally, the mechanical strength properties were increased by decreasing KOCC proportion of mixed stock conditions. In addition, the heavy metal contents and evaporation residues were also decreased by increasing recycled AOCC and kraft sack proportion.

CO2 sequestration and heavy metal stabilization by carbonation process in bottom ash samples from coal power plant

  • Ramakrishna., CH;Thriveni., T;Nam, Seong Young;kim, Chunsik;Ahn, Ji Whan
    • Journal of Energy Engineering
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    • v.26 no.4
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    • pp.74-83
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    • 2017
  • Coal-fired power plants supply roughly 50 percent of the nation's electricity but produce a disproportionate share of electric utility-related air pollution. Coal combustion technology can facilitate volume reduction of up to 90%, with the inorganic contaminants being captured in furnace bottom ash and fly ash residues. These disposal coal ash residues are however governed by the potential release of constituent contaminants into the environment. Accelerated carbonation process has been shown to have a potential for improving the chemical stability and leaching behavior of bottom ash residues. The aim of this work was to quantify the volume of $CO_2$ that could be sequestrated with a view to reducing greenhouse gas emissions and stabilize the contaminated heavy metals from bottom ash samples. In this study, we used PC boiler bottom ash, Kanvera reactor (KR) slag and calcined waste lime for measuring chemical analysis and heavy metals leaching tests were performed and also the formation of calcite resulting from accelerated carbonation process was investigated by thermo gravimetric and differential thermal analysis (TG/DTA).

Safety Profile Assessment and Identification of Volatile Compounds of Krill Eupausia superba Oil and Residues Using Different Extraction Methods

  • Haque, A.S.M. Tanbirul;Kim, Seon-Bong;Lee, Yang-Bong;Chun, Byung-Soo
    • Fisheries and Aquatic Sciences
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    • v.17 no.2
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    • pp.159-165
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    • 2014
  • In this study, Krill Eupausia superba oil was extracted using different solvents and supercritical carbon dioxide (SC-$CO_2$). During SC-$CO_2$ extraction, the pressure was set at 40 MPa and temperatures ranged from $40^{\circ}C$ to $55^{\circ}C$. We examined the differences in volatile compounds and safety profiles among extraction methods. Volatile compounds were determined using the thermal desorption system integrated with gas chromatography-mass spectrometry (GC-MS). Heavy metal content was analyzed by inductively coupled plasma mass spectrometry (ICP-MS). According to our results 10 volatile compounds were identified in krill sample. After SC-$CO_2$ extraction of oil, the concentrations of volatile compounds decreased, but increased after solvent extraction. In krill, heavy metal concentrations remained within the permissible limit. Moreover, Zn and Fe which have health benefits were detected at high concentrations. During a 90 days storage period at different temperatures, microbial activity was found to be lowest in SC-$CO_2$ extracted residues. Thus, the quality of krill oil and the residues obtained using SC-$CO_2$ extraction was higher and the oil was safer than those obtained using conventional solvent extraction. These results can be applied to the food industry to maintain high quality krill products.

Remediation of Heavy Metal-Contaminated Soil Within a Military Shooting Range through Physicochemical Treatment (물리화학적 처리를 이용한 군부대 사격장 내 중금속 오염 토양의 정화)

  • Lee, Sang-Woo;Lee, Woo-Chun;Lee, Sang-Hwan;Kim, Soon-Oh
    • Journal of Soil and Groundwater Environment
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    • v.26 no.5
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    • pp.9-19
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    • 2021
  • This study evaluated the feasibility of combined use of physical separation and soil washing to remediate heavy metals (Pb and Cu) contaminated soil in a military shooting range. The soils were classified into two types based on the level of heavy metal concentrations: a higher contaminated soil (HCS) with Pb and Cu concentrations of 6,243 mg/kg and 407 mg/kg, respectively, and a lower contaminated soil (LCS) with their concentrations of 1,658 mg/kg and 232 mg/kg. Pb level in both soils exceeded the regulatory limit (700 mg/kg), and its concentration generally increased with decreasing soil particle size. However, in some cases, Pb concentrations increased with increasing soil particle size, presumably due to the presence of residues of bullets in the soil matrix. As a pretreatment step, a shaking table was used for physical separation of soil to remove bullet residues while fractionating the contaminated soils into different sizes. The most effective separation and fractionation were achieved at vibration velocity of 296 rpm/min, the table slope of 7.0°, and the separating water flow rate of 23 L/min. The efficiency of ensuing soil washing process for LCS was maximized by using 0.5% HCl with the soil:washing solution mixing ratio of 1:3 for 1 hr treatment. On the contrary, HCS was most effectively remediated by using 1.0% HCl with the same soil:solution mixing ratio for 3 hr. This work demonstrated that the combined use of physical separation and soil washing could be a viable option to remediate soils highly contaminated with heavy metals.

Effect of Heavy Metal Contents in Upland Soil on the Uptake by Green onion and Lettuce and their growth (토양중(土壤中) 중금속함량(重金屬含量)이 파, 상치의 중금속흡수(重金屬吸收) 및 생육(生育)에 미치는 영향(影響))

  • Kim, Bok-Young
    • Korean Journal of Environmental Agriculture
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    • v.14 no.3
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    • pp.253-262
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    • 1995
  • The heavy metal contents of soils which had been contaminated with mine residues and green onion and lettuce which were grown on these soils were analyzed. The results obtained are summarized as follows: 1. Heavy metal contents in the soil where green onion and lettuce died back or were poor in growth were unusually high. 2. Heavy metal contents in the plants grown in the soil of high level of metals were also high, in the order of root > leaf > stem. In case of Mn, however, the content was the highest in the leaf. 3. Contents of Cd, Cu, Zn and Ni in soil were positively correlated with those in plant. In case of Pb, there was no consistent relationship between the contents in soil and plant. 4. Even in the soils where plant growth appeared to be normal the heavy metal contents both in soil and in plant were higher than the national average.

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The Effects of the Short-term Cultivation and Incorporation of Legume Green Manures on the Chemical Properties of Soil Contaminated with Heavy Metals (중금속 오염토양에서 두과 녹비작물의 단기재배 및 환원이 토양 화학성에 미치는 영향)

  • Kim, Min-Suk;Min, Hyungi;Lee, Byeongjoo;Kim, Jeong-Gyu;Lee, Sang-Hwan
    • Korean Journal of Environmental Agriculture
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    • v.33 no.3
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    • pp.155-163
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    • 2014
  • BACKGROUND: Recent studies for heavy metal stabilization in soil were mainly focused on finding out new materials and its efficiency. But, such a stabilization method can cause disturbance to soil, leading improper environment for agriculture. The object of this study was to demonstrate the effect of the incorporation of green manure crops on heavy metal-contaminated soil. METHODS AND RESULTS: Soil contaminated with heavy metals was collected from the agricultural soils affected by the abandoned mine. Lime stone was selected and treated to contaminated soil. Three kinds of legume green manure crops; Alfalfa (Medicago sativa), Hairy vetch (Vicia villosa), Red clover (Trifolium pratense) were subsequently cultivated in greenhouse condition. It was found that lime stone increased soil pH and decreased the amount of heavy metal absorption by green manure. The application of green manure residues on soil increased soil pH and inorganic nitrogen. CONCLUSION: The C/N ratio of three green manures was low, indicating fast decomposition rate, resulting in nitrogen supplement, consequently. Considering the point that the soil was used for agricultural purpose, it was recommended that hairy vetch and red clover were preferred. Nevertheless, the heavy metal availability was also increased. Thus, it seemed that further study was needed to confirm that how long maintain a phenomenon.

Heavy Metals Contens and Organochlorine Pestieide Residues in Commercial Salted and Fermented Sea Foods (시판 젓갈중의 중금속 및 유기염소 잔유농약의 함량)

  • Ryu, Beung-Ho;Ha, Mi-Suck;Kim, Dong-Seuk;Sin, Dong-Bun;Hur, Ho-Jang;Jung, Jong-Soon
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.15 no.3
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    • pp.207-212
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    • 1986
  • Heavy metal contents and residues level of organochlorine pesticides were analyzed for commercial salted and fermented sea-food which bought from pusan area. Heavy metal contents ranged from 0.11 to 0.46 ppm of mercury, trace to 1.1 ppm of lead, 0.01 to 0.34 ppm of cadmium, 0.4 to 5.98 ppm of cupper, 0.16 to 4.5 ppm of zinc, trace to 0.49 ppm of manganese and trace to 1.35 ppm of arsenic. Residue level of organochlorine pesticides in salted and fermented sea-foods ranged from 0.3 ppb to 1.825 ppb of total BHC Organochlorine pesticides of DDE, dieldrine, pp'-DDD and pp'-DDT were detected a small amount from Ge jeot and Myeol-Chi jeot. In conclusion. the heavy metal and levels of organochlorine pesticides residues were safety to eat the salted and fermented sea foods.

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Residues of the Organochlorine Pesticides and Heavy Metal in Culture Environment of Ginseng on Sangju (경북 상주의 인삼 재배환경 중 유기염소계 농약 및 중금속의 잔류)

  • Kim Jung-Ho
    • Environmental Analysis Health and Toxicology
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    • v.19 no.2
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    • pp.183-189
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    • 2004
  • To obtain the residual organochlorine pesticides in the culture environment of ginseng on Sangju, Gyeongbuk, the analytical methods for BHC isomers, Aldrin, DDE, Dieldrin, DDD, Endrin and DDT by GCECD are surveyed. The relative retention times for $\alpha$-BHC, $\beta$-BHC, ${\gamma}$-BHC, $\delta$-BHC, Aldrin, DDE, Dieldrin, DDD, Endrin and DDT were 1.000, 1.042, 1.049, 1.086, 1.202, 1.335, 1.341, 1.371, 1.391 and 1.439, respectively The BHC isomers, Aldrin, DDE, Dieldrin, DDD, Endrin and DDT were separated on the base line. The qualified detection concentration for $\alpha$-BHC, $\beta$-BHC, ${\gamma}$-BHC and $\delta$-BHC is 0.43, 1.33, 0.54 and 1.63 ng/g and it's of Aldrin, DDE, Dieldrin, DDD, Endrin and DDT were 0.63, 0.50, 0.66, 0.74, 0.96 and 0.88ng/g, respectively. BHC isomers, Aldrin, DDE, Dieldrin, DDD, Endrin and DDT were not detected in culture environment of ginseng on Sanaju, Gyeongbuk. The detection concentration for Hg, Cd, Pb, Cr, and As in ginseng were 0.0086ppm, 0.0020ppm, 0.0200ppm, 0.0271ppm and 0.0220ppm, respectively, which were also lower than the 30ppm Korea Food & Drug Administration advisory level for heavy metal in herbal medicines.

Residues of Heavy metals in Culture Environment of Ginseng at Gyeongbuk, Korea (경북지역 인삼 재배 환경 중 중금속의 잔류)

  • Park Moon-Ki;Kim Jung-Ho
    • Journal of Environmental Science International
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    • v.15 no.2
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    • pp.163-167
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    • 2006
  • To obtain the safety evaluation of the ginseng, residues of heavy metals in culture environment of ginseng on Punggi and Sangju, Kyeongbuk are surveyed. The concentration for component of ginseng on Punggi and Sangju were 14.12mg/kg and 15.74mg/kg, respectively. The concentration for general component such as crude fiber, ash, crude lipid, crude protein, carbohydrate, of ginseng were coincided between Punggi and Sangju. The concentration for As, Pb, Cd, and Hg in soil on Punggi were 14.24 ppb, 43.13 ppb, 8.73 ppb and 0.82 ppb, respectively. The concentration for As, Pb, Cd, and Hg in soil on Sangju were 19.20 ppb, 54.82 ppb, 15.90 ppb and 1.04, respectively. Residual heavy metals are not polluted in the soil with culture ginseng on Punggi and Sangju. The concentration for As, Pb, Cd, and Hg with ginseng on Punggi were 29.30ppb, 21.78 ppb, 1.32 ppb and 2.72 ppb, respectively. The concentration for As, Pb, Cd, and Hg with ginseng on Sangju were 3.22 ppb, 24.43 ppb, 1.44 ppb and 4.74 ppb, respectively. Also the detection concentration for As, Pb, Cd, and Hg in ginseng were also lower than the Korea Food & Drug Administration advisory level for heavy metal in herbal medicines. Residual heavy metals are not polluted in the ginseng on Punggi and Sangju at Kyeongbuk, Korea.