• 제목/요약/키워드: heavy metal elements

검색결과 238건 처리시간 0.027초

대면적 절판지붕용 녹화시스템의 토성기반 수문학적 최적모델 도출을 위한 전산 모의연구 (Computer simulation study to generate an optimal hydrologic model based on the soil properties of the large area plate roof greenery system)

  • 김태한;이지원
    • KIEAE Journal
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    • 제16권1호
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    • pp.73-79
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    • 2016
  • This study aimed to investigate the flood prevention effect expected from the afforestation of a large area metal roof of an industrial complex located in an area prone to floods in the rainwater outflow reduction aspect through computer simulation based on soil, which is a key element of the system. In order to conduct a more realistic simulation, the properties of the surveyed soil were generated through substantive analysis, soil texture analysis, and saxton method. A comparative performance evaluation was conducted by using soil depth and ponding depth, which are key elements of the system, as variables. The study result showed that during the heavy rainfall period, the bottom ash artificial soil had 61% rainwater outflow reduction effect, which was 11% higher than the SWMM standard sand.

광미 자연풍화에 따른 광미공극수의 지구화학적 진화와 지하수 오염영향 - 시흥광산의 사례 (Geochemical evolution of mine tailing porewaters and groundwater pollution - Case for Shiheung mine)

  • 정예진;이상훈
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2001년도 총회 및 춘계학술발표회
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    • pp.19-21
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    • 2001
  • The Shiheung mine was closed in 1972 and has been abandoned since then. Although some restoration work has been done, there still remain mine failings in and around the mine, posing a potential environmental hazard. Mine tailings and the porewater extracted from the tailing were investigated to see any evidence of elemental release and migration to adjacent groundwater and soil in the field. The pHs of the tailing range from 6.24 to 7.23. Calcite in the studied area seems to influence on such neutral pH range. Depth profile of mine tailing demonstrate elements have been leached and removed as a consequence of weathering during disposal. This is also supported by the findings from porewater analysis, corresponding the trends in the mine tailings. The concentrations of Cu, Cd, Pb, Zn in the tailing porewater exceed the standard value of EPA for drinking water and this implies groundwater can be contaminated through infiltration of the porewaters, which ultimately will be discharged as leachate from the mine tailing. Groundwater samples collected near the mine area do not show high metal concentrations, except for Fe, which were detected over drinking water standard.

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Splicing and alternative splicing in rice and humans

  • E, Zhiguo;Wang, Lei;Zhou, Jianhua
    • BMB Reports
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    • 제46권9호
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    • pp.439-447
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    • 2013
  • Rice is a monocot gramineous crop, and one of the most important staple foods. Rice is considered a model species for most gramineous crops. Extensive research on rice has provided critical guidance for other crops, such as maize and wheat. In recent years, climate change and exacerbated soil degradation have resulted in a variety of abiotic stresses, such as greenhouse effects, lower temperatures, drought, floods, soil salinization and heavy metal pollution. As such, there is an extremely high demand for additional research, in order to address these negative factors. Studies have shown that the alternative splicing of many genes in rice is affected by stress conditions, suggesting that manipulation of the alternative splicing of specific genes may be an effective approach for rice to adapt to abiotic stress. With the advancement of microarrays, and more recently, next generation sequencing technology, several studies have shown that more than half of the genes in the rice genome undergo alternative splicing. This mini-review summarizes the latest progress in the research of splicing and alternative splicing in rice, compared to splicing in humans. Furthermore, we discuss how additional studies may change the landscape of investigation of rice functional genomics and genetically improved rice.

The Spectra Investigation of the Halo Planetary Nebula BoBn 1

  • Hyung, Siek;Otsuka, Masaaki;Tajitsu, Akito;Izumiura, Hideyuki
    • 천문학회보
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    • 제35권2호
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    • pp.72.2-72.2
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    • 2010
  • The extremely metal-poor halo planetary nebula BoBn 1 has been investigated based on IUE archive data, Subaru/HDS spectra, VLT/UVES archive data, and Spitzer/IRS spectra. We have measured a heliocentric radial velocity of $+191.6\pm1.3\;kms^{-1}$ and expansion velocity 2Vexp of $40.5\pm3.3\;kms^{-1}$ from an average over 300 lines. The estimations of C, N, O, and Ne abundances from the optical recombination lines (ORLs) and Kr, Xe, and Ba from the collisional excitation lines (CELs) are also done. We have detected 5 fluorine and several slow neutron capture elements (the s-process). The amounts of [F/H], [Kr/H], and [Xe/H] suggest that BoBn 1 is the most F-rich among F detected PNe and is a heavy s-process element rich PN. The photo-ionization models built with non-LTE theoretical stellar atmospheres indicate that the progenitor was a 1-1.5 $M_\bigstar$ that would evolve into a white dwarf with an $0.62M_{\odot}$ core mass and $0.09M_{\odot}$ ionized nebula. Careful examination implies that BoBn 1 has evolved from a binary and experienced coalescence during the evolution to become a visible PN. The elemental abundances except N could be explained by a binary model composed of $0.75M_{\odot}+1.5M_{\odot}$ stars.

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Recent Trend of Ultra-Pure Water Producing Equipment

  • Motomura, Yoshito
    • 한국막학회:학술대회논문집
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    • 한국막학회 1996년도 제4회 하계분리막 Workshop (초순수 제조와 막분리 공정)
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    • pp.121-147
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    • 1996
  • Since 1980, the water quality of ultra-pure water has been rapidly improved, and presently ultra-pore water producing equipment for 64Mbit is in operation. Table 1 shows the degree of integration of DRM and required water quality exlmple. The requirements of the ultra-pure water for 64Mbit are resistivity: 18.2 MQ/cm or higher, number of particulates: 1 pc/ml or less (0.05 $\mu$m or larger). bacteria count: 0.1 pc/l or less. TOC (Total Organic Carbon, index of organic snbstance) : 1ppb or less, dissolved oxygen: 5ppb or less, silica: 0.5ppb or less, heavy metal ions: 5ppb or less. The effect of metals on the silicon wafer has been well known, and recently it has been reported that the existence of organic substance in ultra-pure water is closely related to the device defect, drawing attention. It is reported that if organic substance sticks to the natural oxidation film, the oxide film remaims on the organic substance attachment in the hydrofluoric acid treatment (removal of natural oxidation film). The organic substance forms film on the silicon wafer, and harmful elements such as metals and N.P.S., components contained in the organic substance and the bad effect due to the generatinn of silicon carbide cannot be forgotten. In order to remove various impurities in raw water, many technological develoments (membrane, ion exchange, TOC removal, piping material, microanalysis, etc.) have been made with ultra-pure water producing equipment and put to practical use. In this paper, technologies put to practical use in recent ultra-pure vater producing equimeut are introduced.

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Fabrication of Visible-Light Sensitized ZnTe/ZnSe (Core/Shell) Type-II Quantum Dots

  • Kim, Misung;Bang, Jiwon
    • 한국세라믹학회지
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    • 제55권5호
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    • pp.510-514
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    • 2018
  • Colloidal semiconductor quantum dots (QDs), because of the novel optical and electrical properties that stem from their three-dimensional confinement, have attracted great interest for their potential applications in such fields as bio-imaging, display, and opto-electronics. However, many semiconductors that can be exploited for QD applications contain toxic elements. Herein, we synthesized non-toxic ZnTe/ZnSe (core/shell) type-II QDs by pyrolysis method. Because of the unique type-II character of these QDs, their emission can range over an extended wavelength regime, showing photoluminescence (PL) from 450 nm to 580 nm. By optimizing the ZnSe shell growth condition, resulting ZnTe/ZnSe type-II QDs shows PL quantum yield up to ~ 25% with 35 nm PL bandwidth. Using a simple two step cation exchange reaction, we also fabricated ZnTe/ZnSe type-II QDs with absorption extended over the whole visible region. The visible-light sensitized heavy metal free ZnTe/ZnSe type-II QDs can be relevant for opto-electronic applications such as displays, light emitting diodes, and bio-imaging probes.

광미와 오염토양 내 중금속 용출특성에 미치는 pH영향 : 청양과 서보중석광산 (The Effects of pH Control on the Leaching Behavior of Heavy Metals within Tailings and Contaminated Soils : Seobo and Cheongyang Tungsten Mine Areas)

  • 이평구;강민주;박성원;염승준
    • 자원환경지질
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    • 제36권6호
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    • pp.469-480
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    • 2003
  • 용출실험 연구는 서보 및 청양광산의 광미와 오염토양이 산성비(pH 5.0∼3.0)또는 강한 산성용액(pH 2.5∼l.0)과 반응하였을 때 용출될 수 있는 중금속의 함량을 예측하기 위하여 실시되었다. pH 5.0∼3.0인 용액에서, pH가 낮아질수록 광미 내 비소, 납, 아연의 용해도는 많이 증가하였다. 반면에 토양에서의 중금속의 용해도는 매우 제한적이었다. 이와 같은 결과로부터 산성비에 의하여 광미 내 납, 비소, 아연은 용출되나, 토양 내 이들 원소들은 고정되어 있음을 알 수 있다. pH 2.5∼l.0인 강한 산성과 반응시에는 pH가 낮아질수록 오염된 토양 내 아연, 카드뮴, 구리의 농도가 급격히 증가하는 반면, 광미 내에서는 납, 비소, 코발트의 용해도가 매우 증가한다 한편, CY4(청양광산)를 제외한 광미 내 아연, 카드뮴 및 구리의 용해도는 매우 낮은 pH(약 pH 1)에서 조차 낮은 용해도를 보여준다. 이것은 불완전 용해 또는 불용성의 광물상의 존재에 기인한다. 따라서 중금속의 용해도는 반응 용액의 pH뿐만 아니라 광미 및 오염토양 내 존재하는 금속의 존재형태에 영향을 받음을 알 수 있다. 반응용액의 pH가 5.0∼3.0인 경우, 광미에 함유된 원소들 간의 상대적인 이동도는 Pb>Zn>Cd)Co=Cu>As이었다. 반응용액의 pH가 2.5∼l.0사이인 경우, 금속원소들의 상대적인 이동도는 오염 토양의 경우 Zn>Cd>Cu≫Co>Pb=As이고, 광미로부터는 Pb≫Zn>Cd>As>Co>Cu이었다. 이러한 연구결과들은 이 지역에서 광산 폐기물의 환경적 영향에 대한 평가를 가능하게 하고, 복원 계획에 대한 유용한 자료로 사용될 수 있다.

보리 유식물에 처리한 수은의 분포 및 독성 연구 (Toxic Effects and Distribution of Mercury in Barley Seedlings)

  • 이춘환;장호식
    • 한국환경과학회지
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    • 제1권1호
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    • pp.13-21
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    • 1992
  • The inhibitory effects of mercury ions on the growth of barley seedlings were studied and the distribution of metal elements in the organs of treated plants was investigated by using synchrotron radiation induced X-ray emission (SRIXE). Although the treatment of mercury ions caused growth inhibition, the mercury-specific increase in variable fluorescence and the abolishment of energy-dependent quenching in broken barley chloroplasts as shown by Moon et at. (1992) were not observed in the leaves of growth-inhibited seedlings. Instead the treatment of mercury decreased Fmax and Fo values. However, Fmax/Fo ratio and photochemical and nonphotochemical quenching coefficients were not affected significantly. By SRIXE analysis of $10\mu\textrm{m}$ mercury chloride treated seedlings, accumulation of mercury in roots was observed after 1 hour of treatment and similar concentration was sustained for 48 hours. Relative contents of mercury was high in roots and underground nodes where seeds were attachedl but was very low in leaves. Iron and zinc were also distributed mainly in the lower parts of the seedlings. However after 72 hours of treatment the contents of these metals in roots decreased and their distribution became more uniform, which may lead to death of the plants. These results suggest that the observed inhibitory effects on barley seedlings upto 48 hours after the treatment is not due to direct damages in the photosynthetic apparatus, but due to its accumulation in roots and the consequent retardation of the growth of barley seedlings. The decrease in Fmax and Fo is probably due to the decrease in chlorophyll and protein contents caused by the retardation of growth. The observed slow expansion of primary leaves could be also explained by the retardation of growth, but the fluorescence induction pattern from the leaves did not show characteristic symptoms of leaves under water stress.

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서로 다른 모암과 토양의 미량원소 특성 및 리기다소나무의 원소 함량 (The Trace Element Characteristics of Rocks, Top Soils, and Pinus rigida Growing on Soils Derived from Different Parent Rocks)

  • 민일식;김명희;송석환
    • 한국환경생태학회지
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    • 제12권1호
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    • pp.22-29
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    • 1998
  • 충남지역의 사문암과 변성암 및 흑색셰일지역의 암석, 토양 및 그 위에서 생육하는 리기다소나무의 미량원소 함량을 측정하여 모암별 토양의 원소함량과 식물체의 흡수확계를 조사하였다. Ni, Cr 및 Co 함량은 사문암에서 매우 높았으며, Zn, Mo 및 Fe 함량은 변성암에서 높았다. 흑색셰일의 이들 원소는 사문암과 변성암보다 공히 낮았다. 사문암 토양의 Ni, Cr 및 Co 함량은 매우 높았으며, Zn과 Fe 함량은 사문암+변성암 혼합풍화토 및 흑색셰일 토양에서 높았다. 풍화토의 미량원소 함량은 암석의 함량보다 낮았으며, 그 패턴은 Mo를 제외하고는 모두 유사하였다. 사문암 풍화토의 pH 범위는 7.73~9.55로 매우 높았다. 사문암지역 리기다소나무의 Cr 흡수량은 토양내 Cr함량에 비하여 낮았으며, Zn 은 토양내의 원소함량에 비하여 리기다소나무에 의한 흡수량이 높았다. 리기다소나무에 의하여 흡수된 Ni, Fe 및 Co 함량에 대한 Fe/Ni, Co/Ni 비율은 사문암풍화토에서 가장 낮았다.

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GRACES Observations of Mg-Enhanced Metal-Poor Stars in the Milky Way

  • Hye-Eun Jang;Young Sun Lee;Wako Aoki;Tadafumi Matsuno;Wonseok Kang;Ho-Gyu Lee;Sang-Hyun Chun;Miji Jeong;Sung-Chul Yoon
    • 천문학회지
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    • 제56권1호
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    • pp.11-22
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    • 2023
  • We report the result of a high-resolution spectroscopic study on seven magnesium (Mg) enhanced stars. The high Mg abundances in these stars imply that they were born in an environment heavily affected by the nucleosynthesis products of massive stars. We measure abundances of 16 elements including Mg and they show various abundance patterns implying their diverse origin. Three of our program stars show a very high Mg to Si ratio ([Mg/Si] ≈ 0.18-0.25), which might be well explained by fall-back supernovae or by supernovae with rapid rotating progenitors having an initial mass higher than about 20 M. Another three of our program stars have high light to heavy s-process element ratios ([Y/Ba] ≈ 0.30-0.44), which are consistent with the theoretical prediction of the nucleosynthesis in rapidly rotating massive stars with an initial mass of about M = 40 M. We also report a star having both high Y ([Y/Fe] = 0.2) and Ba ([Ba/Fe] = 0.28) abundance ratios, and it also shows the highest Zn abundance ratio ([Zn/Fe] = 0.27) among our sample, implying the nucleosynthesis by asymmetric supernova explosion induced by very rapid rotation of a massive progenitor having an initial mass between 20 M ≲ M ≲ 40 M. A relative deficiency of odd-number elements, which would be a signature of the pair-instability nucleosynthesis, is not found in our sample.