• Title/Summary/Keyword: heat of hydration,

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Optimum Mix Proportion and Characteristics of the Combined Self Compacting Concrete according to Cement Types (시멘트 종류에 따른 병용계 자기충전 콘크리트의 최적배합비와 특성)

  • Kwon, Yeong-Ho
    • Journal of the Korea Concrete Institute
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    • v.21 no.1
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    • pp.55-64
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    • 2009
  • This study is aimed to derive the optimum mix proportion of the combined self compacting concrete according to cement types (blast-furnace slag cement and belite cement) and to propose the basic data to field construction work after evaluating the quality properties. Specially, lime stone powder (LSP) as binder and viscosity agent are used in the combined self compacting concrete because slurry wall of an underground LNG storage tank should be kept stability of quality during concrete working. Replacement ratio of LSP is determined by confined water ratio test and main design factors including fine aggregate ratio ($S_r$), coarse aggregate ratio ($G_v$) and water-cement ratio (W/C) are selected. Also, quality properties including setting time, bleeding content, shortening depth and hydration heat on the optimum mix proportion of the combined self compacting concrete according to cement type are compared and analyzed. As test results, the optimum mix proportion of the combined self compacting concrete according to cement type is as followings. 1) Slag cement type-replacement ratio of LSP 13.5%, $S_r$ 47% and W/C 41%. 2) Belite cement type-replacement ratio of LSP 42.7%, Sr 43% and W/C 51%. But optimum coarse aggregate ratio is 53% regardless of cement types. Also, as test results regarding setting time, bleeding content, shortening depth and hydration heat of the combined self compacting concrete by cement type, belite cement type is most stable in the quality properties and is to apply the actual construction work.

A Study on Constructability Estimation of Multi-component High Fluidity Concrete based on Mock-up Test (모의실험체에 의한 다성분계 고유동 콘크리트의 시공성능 평가에 관한 연구)

  • Kwon, Ki-Joo;Noh, Jea-Myoung
    • Journal of the Korea Institute of Building Construction
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    • v.10 no.4
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    • pp.75-82
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    • 2010
  • As structures become larger, taller, and more diverse, a high degree of technology and expertise are required in the construction industry. However, it has been becoming difficult to construct under severe conditions and to fulfill the high performance needs of structures due to a lack of skilled construction engineers. To compensate for these weak points, high-performance concrete and performance specifications have been developed. The application of reliable high-fluidity concrete, which is one of these efforts, is expected to be effective in terms of overcoming severe conditions, reducing the number of workers required, and shortening the construction period. In order to apply high fluidity concrete in the field, practical mock-up tests were carried out to estimate whether self-compaction concrete could satisfy constructability needs. From the results, it was verified that the multi-component high fluidity concrete has excellent flowability in practical structures. In addition, it was shown that the temperature distribution in the concrete due to hydration heat is satisfactory. As a result, it is judged that multi-component high fluidity concrete can be utilized as an effective building material for various structures, including structures related to the electric power industry.

Durability Characteristics in Concrete with Ternary Blended Concrete and Low Fineness GGBFS (삼성분계 콘크리트와 저분말도 슬래그를 혼입한 콘크리트의 내구 특성)

  • Kim, Tae-Hoon;Jang, Seung-Yup;Kwon, Seung-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.4
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    • pp.287-294
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    • 2019
  • GGBFS(Ground Granulated Blast Furnace Slag) has been widely used in concrete for its excellent resistance chloride and chemical attack, however cracks due to hydration heat and dry shrinkage are reported. In many International Standards, GGBFS with low fineness of 3,000 grade is classified for wide commercialization and crack control. In this paper, the mechanical and durability performance of concrete were investigated through two mix proportions; One (BS) has 50% of w/b(water to binder) ratio and 60% replacement ratio with low-fineness GGBFS, and the other (TS) has 50% of w/b and 60% replacement ratio with 4000 grade and FA (Fly Ash). The strength difference between TS and BS concrete was not great from 3 day to 91 day of age, and BS showed excellent performance for chloride diffusion and carbonation resistance. Two mixtures also indicate a high durability index (more than 90.0) for freezing-thawing since they contain sufficient air content. Through improvement of strength in low fineness GGBFS concrete at early age, mass concrete with low hydration heat and high durability can be manufactured.

Recent Progress in Air-Conditioning and Refrigeration Research: A Review of Papers Published in the Korean Journal of Air-Conditioning and Refrigeration Engineering in 2011 (설비공학 분야의 최근 연구 동향: 2011년 학회지 논문에 대한 종합적 고찰)

  • Han, Hwa-Taik;Lee, Dae-Young;Kim, Seo-Young;Choi, Jong-Min;Paik, Yong-Kyoo;Kim, Su-Min
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.24 no.6
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    • pp.521-537
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    • 2012
  • This article reviews the papers published in the Korean Journal of Air-Conditioning and Refrigeration Engineering during 2011. It is intended to understand the status of current research in the areas of heating, cooling, ventilation, sanitation, and indoor environments of buildings and plant facilities. Conclusions are as follows. (1) Research trends of thermal and fluid engineering have been surveyed as groups of fluid machinery and fluid flow, thermodynamic cycle, and new and renewable energy. Various topics were presented in the field of fluid machinery and fluid flow. Research issues mainly focused on the rankine cycle in the field of thermodynamic cycle. In the new and renewable energy area, researches were presented on geothermal energy, fuel cell, biogas, reformer, solar water heating system, and metane hydration. (2) Research works on heat transfer area have been reviewed in the categories of heat transfer characteristics, pool boiling and condensing heat transfer, nanofluids and industrial heat exchangers. Researches on heat transfer characteristics included heat transfer above liquid helium surface in a cryostat, methane hydrate formation, heat and mass transfer in a liquid desiccant dehumidifier, thermoelectric air-cooling system, heat transfer in multiple slot impinging jet, and heat transfer enhancement by protrusion-in-dimples. In the area of pool boiling and condensing heat transfer, researches on pool boiling of water in low-fin and turbo-B surfaces, pool boiling of R245a, convective boiling two-phase flow in trapezoidal microchannels, condensing of FC-72 on pin-finned surfaces, and natural circulation vertical evaporator were actively performed. In the area of nanofluids, thermal characteristics of heat pipes using water-based MWCNT nanofluids and the thermal conductivity and viscosity were measured. In the area of industrial heat exchangers, researches on fin-tube heat exchangers for waste gas heat recovery and Chevron type plate heat exchanger were implemented. (3) Refrigeration systems with alternative refrigerants such as $CO_2$, hydrocarbons, and mixed refrigerants were studied. Heating performance improvement of heat pump systems were tried applying supplementary components such as a refrigerant heater or a solar collector. The effects of frost growth were studied on the operation characteristic of refrigeration systems and the energy performance of various defrost methods were evaluated. The current situation of the domestic cold storage facilities was analyzed and the future demand was predicted. (4) In building mechanical system fields, a variety of studies were conducted to achieve effective consumption of heat and maximize efficiency of heat in buildings. Various researches were performed to maximize performance of mechanical devices and optimize the operation of HVAC systems. (5) In the fields of architectural environment and energy, diverse purposes of studies were conducted such as indoor environment, building energy, and renewable energy. In particular, renewable energy and building energy-related researches have mainly been studied as reflecting the global interests. In addition, various researches have been performed for reducing cooling load in a building using spot exhaust air, natural ventilation and energy efficiency systems.

A Study on Synthesis of Ca and Mg Compounds from Dolomite with Salt Additional React (MgCl2·6H2O) (염 첨가 반응(MgCl2·6H2O)을 이용하여 백운석으로부터 Ca 화합물과 Mg 화합물 합성에 관한 연구)

  • Hwang, Dae Ju;Yu, Young Hwan;Cho, Kye Hong;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.59 no.3
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    • pp.399-409
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    • 2021
  • In order to utilize dolomite as a calcium/magnesium compound material, it was prepared highly reactive calcined dolomite(CaO·MgO) using a microwave kiln (950 ℃, 60 min). The experiment was performed according to the standard of the hydration test (ASTM C 110) and hydration reactivity was analyzed as medium reactivity (max 74.1 ℃, 5 min). Experiments were performed with calcined dolomite and salt (MgCl2·6H2O) (a) 1:1, (b) 1:1.5, and (c) 1:2 wt% based on the hydration reaction of calcined dolomite. The result of X-ray diffraction analysis confirmed that MgO of calcined dolomite increased to Mg(OH)2 as the salt addition ratio increased. After the separating reaction, calcium was stirred at 80 ℃, 24 hr that produced CaCl2 of white crystal. XRD results, it was confirmed calcium chloride hydrate (CaCl2·(H2O)x) and CaO of calcined dolomite and salt additional reaction was separated into CaCl2. And it was synthesized with Ca(OH)2 99 wt% by NaOH adding reaction to the CaCl2 solution, and the synthesized Ca(OH)2 was manufactured CaO through the heat treatment process. In order to prepare calcium carbonate, CaCO3 was synthesized by adding Na2CO3 to CaCl2 solution, and the shape was analyzed in cubic form with a purity of 99 wt%.

Reducing Thermal Cracking of Mat-foundation Mass Concrete Applying Different Mix Designs for Upper and Lower Placement Lifts (상하부 배합을 달리함에 의한 기초 매트 매스콘크리트의 수화열 균열저감)

  • Han, Cheon-Gu;Kim, Min-Ho
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.1
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    • pp.39-46
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    • 2017
  • In this research, considering the practical conditions at field, thermal cracking reducing method was suggested based on the comparative analysis between predicted value and actual value obtained from the actual structure member with optimum mix design. The optimum mix design was deduced from the various mix designs with various proportions of cementitious binder for upper and lower placement lifts of mat-foundation mass concrete. Therefore, before field applications, the mix designs were obtained from the theoretical analysis obtained by MIDAS GEN for upper lift was OPC to FA of 85 to 15, and for lower lift was OPC to FA to BS of 50 : 20 : 30. Based on this mix design, the actual concrete for field was determined and all concrete properties were reached within the predicted range. Especially, the temperature properties of mass concrete at core was approximately $39^{\circ}C$ of temperature difference for low-heat mix design, while approximately $54^{\circ}C$ was shown for normal mix design currently used. Additionally, in the case of cracking index, the low heat mix design showed about 1.4 of relatively high value while the normal mix design showed 1.0. Therefore, it can be stated that applying low heat mix design and different heating technique between upper and lower placement lifts for mass concrete are efficient to control the thermal cracking.

Effect of spatial variability of concrete materials on the uncertain thermodynamic properties of shaft lining structure

  • Wang, Tao;Li, Shuai;Pei, Xiangjun;Yang, Yafan;Zhu, Bin;Zhou, Guoqing
    • Structural Engineering and Mechanics
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    • v.81 no.2
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    • pp.205-217
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    • 2022
  • The thermodynamic properties of shaft lining concrete (SLC) are important evidence for the design and construction, and the spatial variability of concrete materials can directly affect the stochastic thermal analysis of the concrete structures. In this work, an array of field experiments of the concrete materials are carried out, and the statistical characteristics of thermophysical parameters of SLC are obtained. The coefficient of variation (COV) and scale of fluctuation (SOF) of uncertain thermophysical parameters are estimated. A three-dimensional (3-D) stochastic thermal model of concrete materials with heat conduction and hydration heat is proposed, and the uncertain thermodynamic properties of SLC are computed by the self-compiled program. Model validation with the experimental and numerical temperatures is also presented. According to the relationship between autocorrelation functions distance (ACD) and SOF for the five theoretical autocorrelation functions (ACFs), the effects of the ACF, COV and ACD of concrete materials on the uncertain thermodynamic properties of SLC are analyzed. The results show that the spatial variability of concrete materials is subsistent. The average temperatures and standard deviation (SD) of inner SLC are the lowest while the outer SLC is the highest. The effects of five 3-D ACFs of concrete materials on uncertain thermodynamic properties of SLC are insignificant. The larger the COV of concrete materials is, the larger the SD of SLC will be. On the contrary, the longer the ACD of concrete materials is, the smaller the SD of SLC will be. The SD of temperature of SLC increases first and then decreases. This study can provide a reliable reference for the thermodynamic properties of SLC considering spatial variability of concrete materials.

A Study on the Optimum Mix Proportion of the Mass Concrete Designed as Massive and Deep Structure

  • Kwon Yeong-Ho;Lee Hwa-Jin
    • Journal of the Korea Concrete Institute
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    • v.17 no.2 s.86
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    • pp.293-302
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    • 2005
  • This study describes data from determination of the optimum mix proportion and site application of the mass concrete placed in bottom slab and side wall having a large depth and section as main structures of LNG in-ground tank. This concrete requires low heat hydration, excellent balance between workability and consistency because concreting work of LNG in-ground tank is usually classified by under-pumping, adaptation of longer vertical and horizontal pumping line than ordinary pumping condition. For this purpose, low heat Portland cement and lime stone powder as cementitious materials are selected and design factors including unit cement and water content, water-binder ratio, fine aggregate ratio and adiabatic temperature rising are tested in the laboratory and batch plant. As experimental results, the optimum unit cement and water content are selected under $270kg/m^3$ and $l55{\~}l60 kg/m^3$ separately to control adiabatic temperature rising below $30^{\circ}C$ and to improve properties of the fresh and hardened concrete. Also, considering test results of the confined water ratio($\beta$p) and deformable coefficient(Ep), $30\%$ of lime stone powder by cement weight is selected as the optimum replacement ratio. After mix proportions of 5cases are tested and compared the adiabatic temperature rising($Q^{\infty}$, r), tensile and compressive strength, modulus of elasticity, teases satisfied with the required performances are chosen as the optimum mix design proportions of the side wall and bottom slab concrete. $Q^{\infty}$ and r are proved smaller than those of another project. Before application in the site, properties of the fresh concrete and actual mixing time by its ampere load are checked in the batch plant. Based on the results of this study, the optimum mix proportions of the massive concrete are applied successfully to the bottom slab and side wall in LNG in-ground tank.

An Experimental Study on the Setting Time and Compressive strength of Mortar using Ferronickel Slag Powder (페로니켈슬래그 미분말을 사용한 모르타르의 응결시간 및 압축강도특성에 관한 실험적 연구)

  • Kim, Young-Uk;Kim, Do-Bin;Choi, Se-Jin
    • Journal of the Korea Institute of Building Construction
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    • v.18 no.6
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    • pp.551-558
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    • 2018
  • This study evaluate the fluidity and hardening properties of mortar by replacement ratio of ferronickel slag powder to estimate the applicability of ferronickel slag powder for cement replacement materials. Ferronickel slag powder was replaced by 0, 5, 10, 15 and 20% of the cement weight. In addition, blast furnace slag powder and fly ash were also used for comparing with the mixtures using ferronickel slag powder. As the test results, the micro-hydration heat of the mixture containing the ferronickel slag powder was lower than that of the mixtures containing the same amount of blast furnace slag powder and fly ash. The flow of the sample with ferronickel slag powder was relatively higher than the other mixtures. In all ages, the compressive strength of the mixture with ferronickel slag powder and fly ash was similar to that of the mix containing only fly ash. In case of drying shrinkage, the mixture containing ferronickel slag powder exhibited lower drying shrinkage than the mixture using blast furnace slag powder, and similar to the mixture containing fly ash.

Effect of MgO in Synthesis of Alinite Clinker (Alinite계 클링커 제조(製造) 시 MgO의 영향(影響))

  • Yoo, Kwang-Suk;Ahn, Ji-Whan;Han, Dong-Yoon;Cho, Kye-Hong;Oh, Myung-Hwan
    • Resources Recycling
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    • v.18 no.3
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    • pp.49-54
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    • 2009
  • The effect of MgO in synthesis of alinite clinker was investigated. Clinker of alinite composition ratio and alintite clinker substituted for MgO of 3.77% were sintered at $760^{\circ}C$ and between $800^{\circ}C$ and $1,400^{\circ}C$ at the interval of $100^{\circ}C$. Synthesized phases and hydration heat of alinite clinker with MgO and without MgO were then investigated. As a result, alinite, CCA, ${\beta}-C_2S$ and f-CaO phases are synthesized in alinite clinker without MgO sintered at $1,300^{\circ}C$, while only alinite phase is synthesized in alinite clinker with MgO sintered at $1,300^{\circ}C$ with the highest synthesis rate. Heat evolution of alinite clinker with MgO has no induction period.