• 제목/요약/키워드: heat of hydration,

검색결과 712건 처리시간 0.025초

저 분말도 슬래그를 사용한 슬래그 시멘트의 특성 (The Characteristics of Blastfurnace Slag Blended Cement with Low Blaine Slag Powder)

  • 변승호;최현국;김재영;송종택
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1998년도 가을 학술발표회 논문집(I)
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    • pp.19-24
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    • 1998
  • In this study, blended cement with low blaine(2000, 3000$\textrm{cm}^2$/g) blast-furnace slag power by 10-70wt.% was investigated through the measurement hydration heat, physical properties. The experiment results indicated compressive strength was decreased as low blaine slag blended, but hydration heat was reduced significantly and flow of the cement paste was increased.

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소성Dolomite 수화물계의 축열시스템에 관한 연구 - 소성Dolomite 수화반응층의 전열해석 - (A Study on Heat Storage System Using Calcined Dolomite - Numerical Analysis of Heat Transfer in Calcined Dolomite Hydration Pocked Bed -)

  • 박영해;김종식
    • 한국태양에너지학회 논문집
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    • 제22권1호
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    • pp.9-21
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    • 2002
  • To develope chemical heat pump using available energy sources, solar heat and other kinds of waste thermal energy, we have studied the heat transfer rate in cylindrical bed reactor packed with calcined Dolomite. Two dimensional (radial and circumferential) Partial differential equations, concerning heat and mass transfer in packed bed of calcined Dolomite, are solved numerically to describe the characteristics of the reaction of calcined Dolomite and heat transfer. The results obtained by numerical analysis about two dimensional profiles of temperature and conversion of reactant in the packed bed reactor and the amount of exothermic heat released from the reactor are follows. It was found that all of calcined Dolomite packed bed kept the reaction temperature of about 750K throughout the entire part of the bed, immediately after the steam was introduced exothermic reaction of hydration was proceeded from the packed bed inpu to output and from wall side to center. The rate of thermochemical reaction depends on the temperature and concentration and it is also governed by the boundary conditions and heat transfer rate in the particle packed bed.

슬래그-석고계 수화반응에 대한 기초 연구 (A Study on Hydration of Slag-Gypsum System)

  • 지정식;최상흘
    • 한국세라믹학회지
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    • 제15권4호
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    • pp.205-212
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    • 1978
  • The hydration reaction of the slag-gypsum system was studied by X-ray diffraction, differential thermal analysis, optical icroscopic observation, and measurement of heat liberation of hydration. 1. Domestic granulated slag was almost noncrystalized state, and its mineral compositions calculated were 46.53% of gehlenite, 28.14% of akermanite, and 19.04% of wollastonite. 2. The slag quenched with water at relatively high temperature had better reactivity. 3. The production of ettringite, CSH gel and AH3 gel were stimulated by effect of $Ca(OH)_2$, $Mg(OH)_2$ and calcined dolomite as activators, and the strength of hardened body would be developed by forming compacted microstructure.

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철근의 영향을 고려한 콘크리트 구조물의 수화열 해석 (An Analysis on the Effect of Reinforced Steel Bar to the Beat of Hydration in the Concrete Structures)

  • 양옥빈;윤동용;민창식
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2002년도 봄 학술발표회 논문집
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    • pp.35-40
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    • 2002
  • This paper presents a numerical study on the heat of hydration of reinforced concrete with different steel ratio. And this study intends to determine the effect of the steel on the variation of temperatures during hydration. In order to do this, the thermal analyses of the pier-foundation models were carried out using the finite element analysis program, ADINA. As the steel rate increased, the maximum temperature and the internal-external temperature difference decreased.

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초음파 및 유전성을 이용한 모르타르(Mortar) 수화(Hydration) 과정의 정밀측정 (Precision Measurement of the Hydration of Mortar by Ultrasonic and Dielectric Method)

  • 한응교;이명호;김세영
    • 비파괴검사학회지
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    • 제9권1호
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    • pp.56-68
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    • 1989
  • Recently, there are many fields have been required for the precision measurements, as an advanced example of which, a precise change of inner structure during the hydration process of mortar was observed by ultrasonic and dielectric measurements. The results show that it is possible to determine the safety of mortar and mixing ratio, and strength growth and shrinkage rate by heat evolution.

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매스콘크리트의 계절에 따른 온도이력과 압축강도에 관한 실험 (Study on Temperature History and Compressive Strength of Mock-up Concrete Considering Seasonal Change)

  • 김영주;공민호;김광기;양동일;박무영;정상진
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2005년도 추계 학술논문 발표대회
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    • pp.89-92
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    • 2005
  • Our country has experienced variations in temperature as belong to the area of the continental climate that shows four significant seasons. These occur quality of construction. As the hydration of cement processes, the strength of concrete is developed. In order to improve the quality of concrete, various conditions including temperature and humidity should be maintained appropriately and concrete itself should be cured sufficiently This paper is basic experiment for estimating influence of strength by seasonal mock-up concrete's heat of hydration and estimate relationship of compressive strength development by curing temperature. And show basic document as quality control.

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황산염나트륨 자극제를 사용한 플라이 애쉬 혼입 시멘트 페이스트의 초기 수화 특성에 관한 기초적 연구 (A Study on Sodium Sulfate Activited the Hydration Properties of Fly Ash-cement Paste)

  • 왕자호;순양;이한승
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2021년도 봄 학술논문 발표대회
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    • pp.129-130
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    • 2021
  • In order to solve the problem of low early-age compressive strength of high volume fly ash concrete. This paper studies the effect of 2% sodium sulfate (Na2SO4) as a chemical activator on the paste with 40% fly ash content and a water-binder ratio of 0.30. The results indicate that the addition of Na2SO4 can effectively improve the early-age compressive strength of the fly ash-cement system, and the strength improvement rate on the first day reached nearly 70%. In addition, calorimetric analysis reveals that the incorporation of Na2SO4 promotes the early hydration of cement and fly ash, increases the cumulative hydration heat and delays the heat peak of the aluminum phase.

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액상 및 중화 레드머드를 첨가한 시멘트 페이스트의 수화특성 (Hydration Characteristics of Cement Paste Added Liquid and Neutralized Red Mud)

  • 강혜주;강석표
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2020년도 가을 학술논문 발표대회
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    • pp.104-105
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    • 2020
  • Red mud is a highly alkaline waste by-product of the aluminum industry. Although recycling of red mud is being actively researched, a feasible technological solution has not been found yet. In this study, we propose that neutralization of red mud alkalinity could assist in its use as a construction material. Neutralized red mud ( pH 6-8) was prepared by adding sulfuric acid to liquefied red mud (pH 10-12). After adding liquid and neutralized red mud to the cement paste, the heat of hydration was measured. As a result of the experiment, the calorific value of the cement paste with liquid red mud was lowered and delayed compared to the cement paste with neutralized red mud.

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고성능 콘크리트 개발에 관한 실험적 연구 제 1보 : 고미분말 슬래그 혼합시멘트의 물성 (Experimental Study on the Development of High-Performance Concrete)

  • 구자술;이영진;김남호;정재동
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1993년도 가을 학술발표회 논문집
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    • pp.45-50
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    • 1993
  • This paper describes some results of various tests which were carried out with varying the fineness of salg from 6000 to 10000$\textrm{cm}^2$/g and the slag content in cement from 30 to 50wt% for the perpose of utilizing finely ground blast-furnace slag as an ingredient for high-performance concrete. Test for heat of hydration, microstructural and hydration characteristics in paste, and fluidity and compressive strength in mortar were carried out. From these test results, it was found that, by properly determining the content and fineness of the slag, it is possible to manufacture high-performance concrete that has low heat of hydration, high early strength development, fine pore size and a highly densified microstructure.

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Tricalcium Silicate의 초기수화반응(I) (Early Hydration of Ticalcium Silicate(I))

  • 오희갑;최상흘
    • 한국세라믹학회지
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    • 제23권5호
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    • pp.35-40
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    • 1986
  • The early hydration of tri-calcium silicate $(C_3S)$ with different cooling conditions was studied by varing water/solid ratio and atmosphere. The cooling condition and water/solid ratio affected to the second peak of heat liberation but it had no correlation to the induction period. The $Ca^{2+}$ concentration in the aqueous solution was maximized at the starting point of the second peak of heat liberation but in the $CO_2$ exsistence the $Ca^{2+}$ concentration was low and $SiO_2$ con-centration was increased. The hydration rate of $C_3S$ was so accelerated that the induction period could not appear in the $CO_2$ exsistence.

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