• Title/Summary/Keyword: heat of hydration,

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Fundamental characteristics of high early strength low heat concrete according to mineral binder and high early strength material combination (광물질 결합재 및 조강형 재료 조합에 따른 조강형 저발열 콘크리트의 기초적 특성)

  • Kim, Kyoungmin;Son, Hojung
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.24 no.1
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    • pp.27-32
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    • 2014
  • This study analyzed the fundamental characteristics of concrete according to a ternary system mixing in order to reduce hydration heat of mass concrete and to improve early age strength. The results are as follows. The fluidity of unconsolidated concrete satisfied the target scope regardless of the binder conditions. When the replacement ratio between FA and BS increased, the slump of low heat-A mix and low heat-B mix increased, and air content was not affected by the change of binders. As for setting time, low heat cement mix had the fastest regardless of W/B, and high early strength low heat mix achieved 6 hours' reduction compared with low heat-B mix at initial set, and 12 hours' reduction at the final set respectively. As for the simple hydration heat, the low mix peak temperature was the highest and low heat-B mix had the lowest temperature. And high early strength low heat mix was similar with that of low heat-B. The compressive strength of hardened concrete had similar strength scope in all mixes except for low heat-B mix at early ages, and had unexceptionally similar one without huge differences at long-term ages.

Reducing Hydration Heat of Mass Concrete by Applying Combination of Powdered Materials and CGS as Fine Aggregate (분체계 재료조합 및 석탄 가스화 용융 슬래그를 잔골재로 활용한 매스 콘크리트 수화열 저감)

  • Park, Sang-Won;Han, Jun-Hiu;Han, Min-Cheol
    • Journal of the Korea Institute of Building Construction
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    • v.24 no.2
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    • pp.169-180
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    • 2024
  • In this study, to suggest an efficient method of using coal gasification slag(CGS), a byproduct from integrated gasification combined cycle(IGCC), as a combined fine aggregate for concrete mixture, the diverse performances of concrete mixtures with combined fine aggregates of CGS, river sand, and crushed sand were evaluated. Additionally, using CGS, the reduction of the hydration heat and the strength developing performance were analyzed to provide a method for reducing the heat of hydration of mass concrete by using combined fine aggregate with CGS and replacing fly ash with cement. The results of the study can be summarized as follows: as a method of recycling CGS from IGCC as concrete fine aggregate, a combination of CGS with crushed sand offers advantages for the concrete mixture. Additionally, when the CGS combined aggregate is used with low-heat-mix designed concrete with fly ash, it has the synergistic effect of reducing the hydration heat of mass concrete compared to the low-heat-designed concrete mixture currently in wide use.

A Study on the Estimation of Corrosion Protection Performance of Concrete Containing Ground Granulated Blast-Furnace Slag for Massive Coastal Structures (매시브한 해양구조물 적용을 위한 고로슬래그 혼입 콘크리트의 방청성능 평가에 관한 연구)

  • Yoo, Jae-Kang;Kim, Dong-Suk;Park, Sang-Joon;Won, Chul;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2002.11a
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    • pp.87-91
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    • 2002
  • This paper investigates the corrosion inhibition and the reduction of hydration heat properties of Ground Granulated Blast-Furnace Slag (GGBFS) added concrete. Since the massive civil structure is vulnerable to the thermal crack by hydration. adiabatic temperature rising tests were performed for water-binder ratios from 43.2% to 47.3%, while replacing 15% to 50% of cement with GGBFS of equal weight. Then, the corrosion protection performance was evaluated using cylindrical specimens embedded with steel reinforcement according to the combination of 3 W/B ratios and 2 levels of chloride ion quantity. The corrosion area of the embedded steel ban was determined using the high pressure steam curing method specified in KS F 2561. The test results showed that the replacement of GGBFS was effective in reducing the hydration heat. The corrosion area of the embedded steel ban decreased as the replacement of GGBFS increased. However, the corrosion area of the steel bar was proportional to the autoclave cycle and the chloride ion quantity. Among the tested specimens, compressive strength, reduction of hydration heat, and corrosion inhibition performance were excellent when 50% of cement was replaced with GGBFS of equal weight.

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Field Application of the Difference of Setting Time of Improving Super Retarding Agent of Foundation Mat Mass Concrete (기초매트 매스 콘크리트의 초지연제를 활용한 응결시간차공법의 현장적용)

  • Noh, Sang-Kyun;Baek, Dae-Hyun;Kwon, Hae-Won;Bae, Yeoun-Ki;Chung, Sung-Jin;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2008.11a
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    • pp.57-60
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    • 2008
  • According to the recent tendency that the buildings in the downtown concerning rising land prices and efficient use of building are gradually Manhattanized mainly the grand scaled residential buildings, structure of the buildings relates to safety and so the very thick mat concrete is selected as the foundation of architectures. Because mat concretes can not be simultaneously pour in a great quantity due to the circumstance at the field, not only the questions on the unification between the concretes pour on the upper layer and the lower layer are presented but also the cracks by the internal force from the difference of hydration exothermic period are occurred because of the time lag. Thus, this study checked the efficiency to apply "The hydration heat controlling method of mass concrete for horizontal partition pouring construction" to the skyscraper sites under construction at Haiundai in Busan. After applying this method, the result of observation that the cracks by hydration heat in all over the placement surface did never be founded. Also, in case of the economic analysis that the hydration heat reduction method using super retarding agent by difference of setting time is approximately 80% cheaper than the hydration heat reduction method by pipe cooling in the construction expenses.

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Theoretical Study of Hydration of Zeolite NaA (제올라이트 NaA의 수화에 관한 이론적 연구)

  • Kyoung Tai No;Mu Shik Jhon
    • Journal of the Korean Chemical Society
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    • v.23 no.6
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    • pp.374-384
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    • 1979
  • Hydration scheme and hydration energy are determined in ${\alpha}$ cage of zeolite NaA. The selectivity between Na(1) and Na(2) is determined from energy calculation. The waters in ${\alpha}$ cage form a distorted dodecahedral cage. The average binding energies of water(1), water(2) and water(3) are -29.847, -25.344 and -15.888 kcal/mole respectively. The positions of oxygens of hydrated waters are in good agreement with the X-ray data. The heat of immersion curve is also obtained. This result is in good agreement with the differential heat of sorption curve obtained from differential thermal analysis. It is concluded that theoretical method provides considerable uses in the determination and understanding of the hydration and interaction energy of zeolites sorbate binding.

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Effects of Hydration Treatments on the Phase Transition of Anodic Aluminum Oxide Layers (알루미늄 양극산화 피막의 상전이에 미치는 수화처리의 영향)

  • Joo, E.K.;Kim, S.S.;Oh, H.J.;Cho, S.H.;Chi, C.S.
    • Korean Journal of Materials Research
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    • v.12 no.7
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    • pp.540-544
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    • 2002
  • Hydration treatments were performed on the pure aluminum substrate at $100^{\circ}C$ followed by anodizing and heat treatments on the layers. The transformation behaviors of the oxide layers according to the hydration treatment were studied using TEM, XRD, RBS etc. Above $90^{\circ}C$ the hydrous oxide film could be formed, which were turned out to be hydrous oxides(AlOOH $nH_2$O). The anodization on the hydrous oxide film was more effective for the transition of amorphous anodic oxides to the crystalline $\Upsilon-Al_2$ $O_3$ comparing with the case for anodizing on the aluminum substrate without hydration treatment And additional heat treatments were also helpful for the acceleration of the transformation of the hydrous oxide to $\Upsilon-Al_2$ $O_3$. During the heat treatment the interface between $\Upsilon-Al_2$ $O_3$and the hydrous oxide layers migrated to the outer side of hydrous layer.

Temperature development and cracking characteristics of high strength concrete slab at early age

  • Wu, Chung-Hao;Lin, Yu-Feng;Lin, Shu-Ken;Huang, Chung-Ho
    • Structural Engineering and Mechanics
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    • v.74 no.6
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    • pp.747-756
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    • 2020
  • High-strength concrete (HSC) generally is made with high amount of cement which may release large amount of hydration heat at early age. The hydration heat will increase the internal temperature of slab and may cause potential cracking. In this study, slab specimens with a dimension of 600 × 600 × 100 mm were cast with concrete incorporating silica fume for test. The thermistors were embedded in the slabs therein to investigate the interior temperature development. The test variables include water-to-binder ratio (0.25, 0.35, 0.40), the cement replacement ratio of silica fume (RSF; 5 %, 10 %, 15 %) and fly ash (RFA; 10 %, 20 %, 30 %). Test results show that reducing the W/B ratio of HSC will enhance the temperature of first heat peak by hydration. The increase of W/B decrease the appearance time of second heat peak, but increase the corresponding maximum temperature. Increase the RSF or decrease the RFA may decrease the appearance time of second heat peak and increase the maximum central temperature of slab. HSC slab with the range of W/B ratio of 0.25 to 0.40 may occur cracking within 4 hours after casting. Reducing W/B may lead to intensive cracking damage, such as more crack number, and larger crack width and length.

A Study on Effect of Specimen Thickness and Curing Temperature on Properties of Low Heat Concrete by Analysis Program for Heat of Hydration (수화열 해석 프로그램에 의한 저발열 콘크리트의 특성에 미치는 부재두께 및 양생온도의 영향에 관한 연구)

  • Lee, Seung-Min;Rho, Hyoung-Nam;Lee, Sang-Soo;Song, Ha-Young
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2008.11a
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    • pp.31-36
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    • 2008
  • This study aims to examine the effects of thickness of the concrete members and curing temperature on the properties of low heat concrete through heat of hydration analysis. Type of the members that was analyzed in the experiment is ternary mixture of ordinary portland cement, blast-furnace slag incorporating ratio(20%) and fly ash incorporating ratio(30%), which formed a mat foundation. Thicknesses of the concrete members were 1, 2 and 3(m) and three levels of curing temperatures were 10, 20 and 30(℃). They were applied to analyze the effects on the temperature and thermal cracking index. As a result, for temperature history, temperature difference between the central area and the surface tended to decrease as the thickness of the concrete members get thinner. For the temperature cracking index, on the other hand, the risk of cracking tended to decrease as the curing temperature gets higher and as the thickness gets thinner.

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Mock-up Test of Low Heat Concrete Using High Volume Mineral Admixture (혼화재를 다량 사용한 저발열 콘크리트의 모의부재실험)

  • Kim, Yong-Ro;Song, Young-Chan;Kim, Hyo-Rak;Park, Jong-Ho;Yoo, Jung-Hoon;Jeong, Yong
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2011.05b
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    • pp.31-34
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    • 2011
  • In this study, for the evaluation of field application of low heat concrete using high volume mineral admixture, the characteristics of hydration heat generation and engineering properties of low heat concrete was investigated by mock-up test according to the replacement ratio of mineral admixture. Also, it was evaluated the compressive strength of low heat concrete with curing temperatures and ages for effective concrete mix design considering seasonal change.

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Quality Comparison of Rice Cooked on Heat Plate, Induction Heat, and Heat Plate with Pressure (취반기의 가열 방식별 취반미의 특성 비교 분석)

  • Kim, Sang Sook;Chung, Hae Young
    • The Korean Journal of Food And Nutrition
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    • v.30 no.3
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    • pp.464-472
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    • 2017
  • The qualities of rice cooked on heat plate, induction heat and heat plate with pressure, were investigated. The weight, volume, water soluble index (WSI), hydration by SEM (Scanning Electron Microscope), and gelatinization by DSC (Differential Scanning Calorimetry), as well as the consumer acceptability of cooked rice were analyzed. The weight, volume and WSI of rice cooked on heat plate with pressure were higher than those of rice cooked on heat plate and induction heat. The rice cooked on heat plate with pressure also showed higher degree of hydration and gelatinization, and lower degree of enthalpy of gelatinization than the rice cooked on heat plate and induction heat for 5~15 min. The consumer acceptability revealed that the odor, appearance, taste, texture and overall acceptance of rice cooked on induction heat were better than those of rice cooked on heat plate and heat plate with pressure. During storage in a cooker for 0~12 h, there was a decrease in the consumer acceptability of cooked rice. Overall results indicate that the qualities of rice cooked on induction heat and heat plate with pressure were higher than those of rice cooked on heat plate.