• Title/Summary/Keyword: heat of fusion

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A Study on the Synthesis and Electrochemical Characteristics of Carbonized Coffee Powder for Use as a Lithium-Ion Battery Anode (리튬 이온 이차전지 음극 활물질용 탄화 커피 분말 제조 및 전기화학적인 특성연구)

  • Kim, Tae Gyun;Cho, Jin Hyuk;Pham-Cong, De;Jeon, Injun;Hwang, Jin Hyun;Kim, Kyoung Hwa;Cho, Chae Ryong
    • New Physics: Sae Mulli
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    • v.68 no.12
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    • pp.1315-1323
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    • 2018
  • We studied the carbonization due to the annealing condition of waste coffee powder for application as an active anode material for lithium-ion batteries (LIBs). The coffee powder used as an active anode material for LIBs was obtained from coffee beans, not from a coffee shells. The waste coffee powder was dried in air and heat-treated in an $Ar/H_2$ atmosphere to obtain a pore-forming activated carbon powder. The specific capacity of the sample annealed at $700^{\circ}C$ was still 303 mAh/g after 1000 cycles at a current density of 1000 mA/g and with a coulombic efficiency of over 99.5%. The number of pores and the pore size of the waste coffee powder were increased due to chemical treatment with KOH, which had the some effect as an increased specific surface area. The waste coffee powder is considered to be a very promising active anode material because of both its excellent electrochemical properties due to enhanced carrier conduction and its being a cost effective resource for use in LIBs.

Transduction of Familial Amyotrophic Lateral Sclerosis-related Mutant PEP-1-SOD Proteins into Neuronal Cells

  • An, Jae Jin;Lee, Yeom Pyo;Kim, So Young;Lee, Sun Hwa;Kim, Dae Won;Lee, Min Jung;Jeong, Min Seop;Jang, Sang Ho;Kang, Jung Hoon;Kwon, Hyeok Yil;Kang, Tae-Cheon;Won, Moo Ho;Cho, Sung-Woo;Kwon, Oh-Shin;Lee, Kil Soo;Park, Jinseu;Eum, Won Sik;Choi, Soo Young
    • Molecules and Cells
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    • v.25 no.1
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    • pp.55-63
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    • 2008
  • Amyotrophic lateral sclerosis (ALS) is a progressive neurodegenerative disorder characterized by the selective death of motor neurons. Mutations in the SOD1 gene are responsible for a familial form of ALS (FALS). Although many studies suggest that mutant SOD1 proteins are cytotoxic, the mechanism is not fully understood. To investigate the role of mutant SOD1 in FALS, human SOD1 genes were fused with a PEP-1 peptide in a bacterial expression vector to produce in-frame PEP-1-SOD fusion proteins (wild type and mutants). The expressed and purified PEP-1-SOD fusion proteins were efficiently transduced into neuronal cells. Neurones harboring the A4V, G93A, G85R, and D90A mutants of PEP-1-SOD were more vulnerable to oxidative stress induced by paraquat than those harboring wild-type proteins. Moreover, neurones harboring the mutant SOD proteins had lower heat shock protein (Hsp) expression levels than those harboring wild-type SOD. The effects of the transduced SOD1 fusion proteins may provide an explanation for the association of SOD1 with FALS, and Hsps could be candidate agents for the treatment of ALS.

Transduced HSP27 protein protects neuronal cell death by enhancing FALS-associated SOD1 mutant activity

  • An, Jae-Jin;Lee, Yeom-Pyo;Kim, Dae-Won;Sohn, Eun-Joung;Jeong, Hoon-Jae;Kang, Hye-Won;Shin, Min-Jae;Kim, Mi-Jin;Ahn, Eun-Hee;Jang, Sang-Ho;Kang, Jung-Hoon;Kang, Tae-Cheon;Won, Moo-Ho;Kwon, Oh-Shin;Cho, Sung-Woo;Lee, Kil-Soo;Park, Jin-Seu;Eum, Won-Sik;Choi, Soo-Young
    • BMB Reports
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    • v.42 no.3
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    • pp.136-141
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    • 2009
  • Familial Amyotrophic lateral sclerosis (FALS) is a progressive neurodegenetative disorder induced by mutations of the SOD1 gene. Heat shock protein 27 (HSP27) is well-defined as a stress-inducible protein, however the its role in ALS protection has not yet been established. To investigate the role HSP27 may have in SOD1 mutant-mediated apoptosis, human SOD1 or HSP27 genes were fused with a PEP-1 peptide in a bacterial expression vector to produce a genetic in-frame fusion protein, which was then transduced into cells. We found the purified PEP-1-HSP27 fusion proteins can be transduced efficiently into neuronal cells and protect against cell death by enhancing mutant SOD1 activity. Moreover, transduced PEP-1-HSP27 efficiently prevents protein aggregation produced by oxidative stress. These results suggest that transduced HSP27 fusion protein may be explored as a potential therapeutic agent for FALS patients.

Thermal Analysis of 3D package using TSV Interposer (TSV 인터포저 기술을 이용한 3D 패키지의 방열 해석)

  • Suh, Il-Woong;Lee, Mi-Kyoung;Kim, Ju-Hyun;Choa, Sung-Hoon
    • Journal of the Microelectronics and Packaging Society
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    • v.21 no.2
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    • pp.43-51
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    • 2014
  • In 3-dimensional (3D) integrated package, thermal management is one of the critical issues due to the high heat flux generated by stacked multi-functional chips in miniature packages. In this study, we used numerical simulation method to analyze the thermal behaviors, and investigated the thermal issues of 3D package using TSV (through-silicon-via) technology for mobile application. The 3D integrated package consists of up to 8 TSV memory chips and one logic chip with a interposer which has regularly embedded TSVs. Thermal performances and characteristics of glass and silicon interposers were compared. Thermal characteristics of logic and memory chips are also investigated. The effects of numbers of the stacked chip, size of the interposer and TSV via on the thermal behavior of 3D package were investigated. Numerical analysis of the junction temperature, thermal resistance, and heat flux for 3D TSV package was performed under normal operating and high performance operation conditions, respectively. Based on the simulation results, we proposed an effective integration scheme of the memory and logic chips to minimize the temperature rise of the package. The results will be useful of design optimization and provide a thermal design guideline for reliable and high performance 3D TSV package.

A Mechanism of AMOC Decadal Variability in the HadGEM2-AO (HadGEM2-AO 모델이 모의한 AMOC 수십 년 변동 메커니즘)

  • Wie, Jieun;Kim, Ki-Young;Lee, Johan;Boo, Kyung-on;Cho, Chunho;Kim, Chulhee;Moon, Byung-kwon
    • Journal of the Korean earth science society
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    • v.36 no.3
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    • pp.199-209
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    • 2015
  • The Atlantic meridional overturning circulation (AMOC), driven by high density water sinking around Greenland serves as a global climate regulator, because it transports heat and materials in the climate system. We analyzed the mechanism of AMOC on a decadal time scale simulated with the HadGEM2-AO model. The lead-lag regression analysis with AMOC index shows that the decadal variability of the thermohaline circulation in the Atlantic Ocean can be considered as a self-sustained variability. This means that the long-term change of AMOC is related to the instability which is originated from the phase difference between the meridional temperature gradient and the ocean circulation. When the overturning circulation becomes stronger, the heat moves northward and decreases the horizontal temperature-dominated density gradients. Subsequently, this leads to weakening of the circulation, which in turn generates the anomalous cooling at high latitudes and, thereby strengthening the AMOC. In this mechanism, the density anomalies at high latitudes are controlled by the thermal advection from low latitudes, meaning that the variation of the AMOC is thermally driven and not salinity driven.

Evaluation of Fracture Toughness in Steel Weldment for Inner Wall of LNG Storage Tank (LNG 저장탱크 내조용 강 용접부의 파괴인성 평가)

  • Jang J.-i.;Ju J.-B.;Yang Y.-c.;Kim W.-s.;Hong S. H.;Kwon D.
    • Journal of the Korean Institute of Gas
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    • v.2 no.1
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    • pp.7-13
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    • 1998
  • In this study, for the safety performance of LNG storage tank, the fracture toughness in X-grooved weld HAZ(heat-affected zone) of $9\%$ Ni steel was evaluated qualitatively and quantitatively, and the relation with the change in microstructure was analyzed. The toughness assessment was peformed through the modified CTOD test proposed for thick weldment with X-groove. Additionally, microstructures of HAZ were evaluated by OM, SEM and XRD. From the results, HAZ toughness of SMA(shielded metal arc)-welded $9\%$ Ni steel decreased as the evaluated region approached the fusion line. The decrease in toughness was apparently caused by the increase in the fraction of coarse-grained zone within HAZ. On the other hand, toughness drop with decreasing test temperature in F.L.(fusion line) ${\~}$F.L.+3mm was larger than that in F.L.+5mm${\~}$F.L.+7mm region due to the fact that in the former regions, retained austenite had poor stability.

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EFFECTS OF AGING TREATMENT ON MICROSTRUCTURE AND STRENGTH OF WELD HEAT AFFECTED ZONE OF 6N01-T5 ALUMINUM ALLOY

  • Yoshida, Naoharu;Shibao, Masami;Ema, Mitsuhiro;Sasabe, Seiji;Hirose, Akio;Kobayashi, Kojiro F.
    • Proceedings of the KWS Conference
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    • 2002.10a
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    • pp.59-64
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    • 2002
  • Effects of the aging treatments on the microstructure and strength of heat affected zone(HAZ) in the welds of a age-hardened Al-Mg-Si alloy, 5N01-T5, were investigated. The base metal aging treatments before MIG welding were conducted at 423K to 473K for 28.8ks Post weld heat treatment(PWHT) to recover the HAZ strength was performed at 448K for 28.8ks. Microstructure observations, hardness measurements and tensile tests were conducted to study properties of the MIG weld joints. The position of the softest region in HAZ where the hardness insufficiently recovered after natural aging and PWHT was at a distance of approximately 15mm from the center of the fusion zone. Hardness of the softest regions after natural aging and PWHT decreased with increase in the base metal aging temperature. TEM observation clarified that strengthening ${\beta}$"(Mg$_2$Si) precipitates and coarse ${\beta}$′ precipitates affected the hardnes of HAZ. Incomplete recover of hardness in HAZ after PWHT was caused by the precipitating of non-hardening ${\beta}$′ phase during the weld thermal cycle. In order to examine the effects of weldheat input and welding speed, the laser weld joints were also investigated and compared with the MIG weld ones. Laser welding had the narrower width of the softened regions in HAZ compared with MIG welding. The hardness of the softest regions of the laser welds after PWHT was higher than that of the MIG welds. Quantitative relations between hardness of the softest region and base metal aging temperature were obtained for both welding processes. Accordingly, the equations to estimate the strength of the weld joints after PWHT with varying base metal temperatures were proposed for MIG welding and laser welding.

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Analysis of Heat Dissipation Characteristics for Standard 25 [W] LED Module of Korea Expressway Corporation: Using CFD Analysis (CFD 해석을 이용한 한국도로공사 표준 25 [W] LED 모듈의 방열 특성 분석)

  • Lee, Se-Il;Her, In-Sung;Lee, A-Ram;Jung, Min-Joo;Yu, Young-Moon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.8
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    • pp.541-546
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    • 2014
  • Korea Expressway Corporation established standard of LED lighting fixture in Dec. 2013. To raise compatibility, the standard requires a fixed form and it is applied to street lights and tunnel lights, etc. Because streetlight has different circumstance condition from tunnel light that is down light and exposed to constant wind velocity over height of 8 meters, in case of LED module which has the same shape, characteristic of radiant heat can be different. In this paper, we designed 25 [W] LED Module that is designated by standard of Korea Expressway Corporation and analyzed characteristics of radiant heat about natural convection and forced convection. It is dropped 10.12[$^{\circ}C$] that max temperature is decreased by increasing 20 mm of bended height of heatsink at the condition of natural convection. Radiant heat characteristic of bended height 35 mm became 78.08[$^{\circ}C$] at the condition of natural convection, 55.30[$^{\circ}C$] at the condition of forced convection so that 22.78[$^{\circ}C$] is decreased that is 29.1[%] decrease. Bended height 55mm became 67.96[$^{\circ}C$] at the condition of natural convection, 48.04[$^{\circ}C$] at the condition of forced convection so that 19.92[$^{\circ}C$] is decreased that is 29.3% decrease.

Characteristic and Measurement Technology of Inner Welding Residual Stresses in Thick Steel Structures (극후물재 용접부 내부잔류응력 측정기술 및 특성)

  • Park, Jeong-ung;An, Gyu-baek;Woo, Wanchuck
    • Journal of Welding and Joining
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    • v.34 no.2
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    • pp.16-21
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    • 2016
  • Recent keywords of the heavy industries are large-scale structure and productivity. Especially, the sizes of the commercial vessels and the offshore structures have been gradually increased to deliver goods and explore or produce oil and natural gas in the Arctic. High heat input welding processes such as electro gas welding (EGW) have been widely used for welding thick steel plates with flux-cored arc welding (FCAW), especially in the shipbuilding industries. Because high heat input welding may cause the detrimental effects on the fracture toughness of the welded joint and the heat affected zone, it is essential to obtain the sufficient toughness of welded joint. There are well known that the fracture toughness like CTOD, CVN, and KIC were very important factors in order to secure the safety of the structures. Furthermore, the welding residual stress should be considered to estimate the unstable fracture in both EGW and FCAW. However, there are no references on the welding residual stress distribution of EGW and FCAW with thick steel plates. Therefore the welding residual stresses were very important elements to evaluate the safety of the welded structure. Based on the measurement results, the characteristics of residual stress distribution through thickness were compared between one-pass electron gas welding and multi-pass flux-cored arc welding. The longitudinal residual stress in the multi-pass flux-cored arc welding is tensile through all thicknesses in the welding fusion zone. Meanwhile, longitudinal residual stress of EGW is tensile on both surfaces and compressive at the inside of the plate. The magnitude of residual stresses by electron gas welding is lower than that by flux-cored arc welding.

Physical Properties Effect of Dry-Heat and Microwave-Cured Acrylic Resins depending on the Irradiation-Induced Changes (유도광선변화에 따른 건식중합과 마이크로파중합 아크릴레진의 물리적 성질영향)

  • Kim, Gyu-Ri
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.7
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    • pp.4388-4397
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    • 2015
  • The purpose of this study was to research the property change of acrylic resins depending on the induced-beam change and research the improved physical property of dry-heat and microwave-cured dental place acrylic resin in order to develop the acrylic resins with the optimum characteristic. As a result of observing flexural rigidity, hardness and color difference, the dry-heat-cured specimens of Vertex RS and Paladent 20 showed ideal property at 5, 15, and 25 kGy irradiation. The microwave-cured specimens of Vertex RS and Paladent 20 showed ideal property at 5 kGy irradiation. The correlation analysis showed a positive correlation among ARD, flexural rigidity (0 418), E coefficient (0.675) and Barcol hardness (0 588). The radiation cure technology is helpful for relieving the contamination caused by the manufacture of polymer composite. It can significantly contribute to the fusion of ultra violet cure technology and nano technology and the improvement of mechanical property without giving effect to the workability of polymer.