• 제목/요약/키워드: heat of formation

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Formation and Thermal Decomposition of a Quasicrystalline Phase in Al-Fe-Mo Alloys (Al-Fe-Mo 합금에서 준결정상의 생성 및 열분해에 관한 연구)

  • Kim, Suk Hwan
    • Journal of the Korean Society for Heat Treatment
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    • v.18 no.6
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    • pp.362-368
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    • 2005
  • Formation and thermal stability of a quasicrystalline phases in Al-Fe-Mo alloys were investigated by means of melt-spinning process and subsequent heat treatment test. Thermal decomposition and phase transformation process of the as-spun alloys were studied using X-ray diffraction and electron microscopy. The melt-spun Al-Fe-Mo alloys contained an icosahedral quasicrystalline phase with a quasilattice constant of 0.457 nm. Icosahedral phase formed at a composition of $Al_{82.5}Fe_{14}Mo_{3.5}$ as a metastable phase during rapid solidification was transformed into the stable crystalline phases, cubic 1/0 approximant and monoclinic ${\lambda}$-phase, upon heating. A metastable icosahedral and cubic(a = 0.93 nm) phases in as-spun $Al_{65}Fe_{20}Mo_{15}$ alloy were decomposed into two cubic(a = 0.62, 0.31 nm) phases by heat treatment.

Frost Formation in a Straight Duct under Turbulent Flow (난류 유동 하에서 덕트 내의 착상)

  • Yang, Dong-Keun;Lee, Kwan-Soo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.27 no.8
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    • pp.1114-1121
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    • 2003
  • A mathematical model considering the air side and the frost layer is presented to predict the frost layer growth. The standard k-$\varepsilon$ model for the air flow and the diffusion and energy equations for the frost layer are employed. The numerical results are compared with experimental data to validate the present model, and agree well with experimental data within a maximum error of 10%. The present model predicts well the frost properties and heat and mass transfer with respect to the frosting time. The variation of total heat transfer strongly depends on the operating condition, and has a similar trend to that of the sensible heat transfer. The frost properties along the flow direction are also investigated.

NUMERICAL INVESTIGATION OF THE SPREADING AND HEAT TRANSFER CHARACTERISTICS OF EX-VESSEL CORE MELT

  • Ye, In-Soo;Kim, Jeongeun Alice;Ryu, Changkook;Ha, Kwang Soon;Kim, Hwan Yeol;Song, Jinho
    • Nuclear Engineering and Technology
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    • v.45 no.1
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    • pp.21-28
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    • 2013
  • The flow and heat transfer characteristics of the ex-vessel core melt (corium) were investigated using a commercial CFD code along with the experimental data on the spreading of corium available in the literature (VULCANO VE-U7 test). In the numerical simulation of the unsteady two-phase flow, the volume-of-fluid model was applied for the spreading and interfacial surface formation of corium with the surrounding air. The effects of the key parameters were evaluated for the corium spreading, including the radiation, decay heat, temperature-dependent viscosity and initial temperature of corium. The results showed a reasonable trend of corium progression influenced by the changes in the radiation, decay heat, temperature-dependent viscosity and initial temperature of corium. The modeling of the viscosity appropriate for corium and the radiative heat transfer was critical, since the front progression and temperature profiles were strongly dependent on the models. Further development is required for the code to consider the formation of crust on the surfaces of corium and the interaction with the substrate.

A study on the radiative heat transfer analysis in a laminar diffusion flame (층류확산화염의 출사열전달 해석에 관한 연구)

  • 이도형;최병륜
    • Journal of Advanced Marine Engineering and Technology
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    • v.13 no.3
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    • pp.48-55
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    • 1989
  • The purpose of present study is to evaluate both the radiative heat loss from a flame and the local formation and oxidation rate of soot. The present paper describes a comprehensive mathematical model to deal with combustion and radiative heat transfer simultaneously. The involved radiative heat transfer model was based on the "heat ray tracing method" originally proposed by Hayasaka et al.. Some predicted results were compared with the experiments.periments.

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The Microstructure and Coarsening Behavior of Cr2O3 Dispersoid in ODS Cu Produced by Reactive Milling (반응성 밀링에 의해 제조된 Cr2O3 분산강화형 Cu 합금의 미세조직과 입자조대화)

  • Park, Eun-Bum;Hwang, Seung-Joon
    • Journal of the Korean Society for Heat Treatment
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    • v.31 no.4
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    • pp.171-179
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    • 2018
  • Copper powder dispersed with 4 vol.% of $Cr_2O_3$ was successfully produced by a simple milling at 210 K with a mixture of $Cu_2O$, Cu and Cr elemental powders, followed by Hot Pressing (HP) at 1123 K and 50 MPa for 2h to consolidate the milled powder. The microstructure of the HPed material was characterized by standard metallographic techniques such as XRD (X-ray Diffraction), TEM and STEM-EDS. The results of STEMEDS analysis showed that the HPed materials comprised a mixture of nanocrystalline Cu matrix and $Cr_2O_3$ dispersoid with a homogeneous bimodal size distribution. The mechanical properties of the HPed materials were characterized by micro Vickers hardness test at room temperature. The thermodynamic considerations on the heat of formation, the incubation time to ignite MSR (Mechanically induced Self-sustaining Reaction), and the adiabatic temperature for the heat of displacement reaction between the oxide-metal are made for the delayed formation of $Cr_2O_3$ dispersoid in terms of MSR suppression. The results of TEM observation and hardness test indicated that the relatively large dispersoids in the HPed materials are attributed to the significant coarsening for the high temperature consolidation; this leads to the low Vickers hardness value. Based on the thermodynamic calculation for the operating processes with a limited number of parameters, the formation kinetics and coarsening of the $Cr_2O_3$ dispersoid are discussed.

Thermal stability enhancement of silicide by kinetic modifications (Kinetics 수정에 의한 실리사이드의 열적 안정성 향상에 대한 연구)

  • Nam, Hyoung-Gin
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.8 no.5
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    • pp.1042-1046
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    • 2007
  • In this study, we investigated the mechanism responsible for the thermal stability of CoSi by addition of a foreign chemical element. Addition of W was found to increase the heat of formation of CoSi. This increase was claimed to inhibit the glass formation, which is preferred by silicide formation kinetics depicted by the maximum system energy degradation rate. In this case, there forms at the interface between CoSi and Si wafer a crystalline structure, the effective diffusion coefficient of which is much less than the self-diffusion rate provided by the glass. It was stated that the phase transition requires a higher thermal energy as the consequence, thereby enhancing the thermal stability of CoSi.

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A Study on the Heat Transfer Performance of a Heat Spreader (히트 스프레더의 열전달 성능에 관한 연구)

  • Kim, Hyun-Tae;Lee, Yong-Duck;Oh, Min-Jung;Jang, Sung-Wook
    • Proceedings of the KSME Conference
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    • 2004.11a
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    • pp.1258-1263
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    • 2004
  • The present study proposes a new structure for a heat spreader which could embody a thin thickness, any shapes and high heat flux per unit area. It is on the structure for the formation of vapor passages and the support of the case of the heat spreader. A screen mesh is used as the one. To verify the validity of the one, the heat spreader of 1.4mm and 1.6mm thickness was made with 14 mesh and 100 mesh number. In this paper, The performance test of heat spreader conducted in order to compare with the heat transfer performance of conventional heat pipe. As the results, The heat spreader has excellent cooling and heat transfer performance.

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Heat Transfer Characteristics in the Evaporator of a Soft Ice Cream Maker (소프트 아이스크림 제조기 증발기의 전열 특성)

  • Byun, Ho-Won;Lee, Jin-Wook;Kim, Nae-Hyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.4
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    • pp.1466-1473
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    • 2012
  • Soft icecream is made by scraping an ice formed on the inside of the cylindrical evaporator, where R-404A is evaporating in the annulus. The heat transfer characteristics of the refrigerant evaporation and those during icecream formation were experimentally investigated. Results show that the refrigerant-side heat transfer coefficients are highly dependent on the location in the evaporator due to the complex annulus configuration. The heat transfer coefficient at the inlet is generally lower than those of other locations. The average heat transfer coefficient increases as heat flux increases or saturation temperature decreases. A correlation is developed to predict the refrigerant-side heat transfer coefficient. The icecream-side heat transfer coefficient oscillates continuously due to the periodic removal of ice formed on the surface. The average heat transfer coefficient during icecream formation is approximately 280 W/$m^2K$, and that during single-phase cooling increased from 150 W/$m^2K$ to 250 W/$m^2K$.

Influence of heat treatments on electrical properties of ZnO films grown by molecular-beam epitaxy

  • O, Dong-Cheol;Kim, Dong-Jin;Bae, Chang-Hwan;Gu, Gyeong-Wan;Park, Seung-Hwan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.34-34
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    • 2010
  • We report on the influence of heat treatments on the electrical properties of ZnO films grown by molecular-beam epitaxy. We note that the electrical resistance of the ZnO films is significantly changed by the heat treatments: the electrical resistance increases with the increase of ambient temperature, but above a critical temperature the resistance decreases with the increase of temperature, irrespective of ambient gases. On the other hand, it is found that the large amount of photocurrent is generated in the ZnO films, exposed to white sources: the photocurrent decreases with the increase of the obtained resistance, and the current increases with the decrease of the resistance. Also, it is shown that the X-ray diffraction linewidth of the ZnO films is significantly decreased by the heat treatments. These indicate that the increase/decrease of the electrical resistance is ascribed to the annihilation/formation of the residual donor-type defects in the ZnO films by the heat treatments. It is suggested that the increase of the electrical resistance is due to the annihilation of Zni-complex defects, while the decrease of the electrical resistance is due to the formation of VO-complex defects.

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Effect of retained austenite on mechanical properties in medium carbon steel (중탄소강의 기계적성질에 미치는 잔류오스테나이트의 영향)

  • Sun, C.G.;Kim, Y.H.;Kim, H.G.
    • Journal of the Korean Society for Heat Treatment
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    • v.8 no.3
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    • pp.229-235
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    • 1995
  • We were studied to the effect of alloying element and retained austenite on a mechnical properties and that used steels were composed three types composition. According to the soaking temperature, a retained austenite was pricipitated in the bainitic ferrite matrix and it was pricipitated to a flake type of about $2{\mu}m$, a mixture of massive and bar type and a flake type of about $1{\mu}m$ size. Through x-ray diffraction analysis, the amount of retained austenite was increased with addition of Si and Ni for equal heat treatment condition and it was best abundanted in the soaking temperature of $855^{\circ}C$. The balance value of strength and elongation were complexly controlled not only a retained austenite formation but also a formation characteristic and shape of the retained austenite and bainite. The balance value of strength and elongation were most satisfactory obtained with "B" and "C" specimens in a firstly heat treated at $855^{\circ}C$ and the best result was that a $2840kg/mm^2.%$ with the heat teratment condition of $855^{\circ}C-400^{\circ}C$ used for "C" specimen.

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