• Title/Summary/Keyword: heat of formation

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The Fabrication of Low Cost High Temperature Superconducting Tape (저비용 고온초전도 선재 제조 연구)

  • 한상철;성태현;한영희;이준성;이영우;정년호;김상준
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2000.02a
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    • pp.85-88
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    • 2000
  • Cu-free Bi-Sr-Ca-O powder mixtures were screen-printed on Cu tapes and heat-treated at 850-$870^{\circ}C$ for several minutes in air, oxygen, nitrogen and low oxygen pressure. Cu-free precursors were composed of Bi_{x}$SrCaO_{y}$ (x=1.2-2). In order to obtain the optimum heat-treatment condition, we studied on an effect of the precursor composition, the printing thickness and the heat-treatment atmosphere on the superconducting properties of Bi2212 films and the reaction mechanism of their rapid formation. Microstructures and phases of thick films were analyzed by optical microscope and XRD. The electric properties of superconducting films were examined by the four probe method. At heat-treatment temperature, the thick films were in a partially molten state by liquid reaction between CuO in the oxidized copper tape and the precursors which were printed on Cu tapes.

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A Study of CaSO4 Scale Formation and Heat Transfer in a Vertical Tube Evaporator (수직 증발관에서 CaSO4 Scale 형성과 열전달에 관한 연구)

  • Hong, Choonkeun;Choi, Mansoo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.11
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    • pp.1363-1370
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    • 1999
  • A study of scaling and heat transfer has been carried out for a vertical tube evaporator in which $CaSO_4$ saturated water flows upward. Experimental apparatus including vacuum chambers and heaters has been designed and manufactured to study scaling phenomena for three different pressures(1atm, 0.27atm and 0.16atm). Overall heat transfer coefficients have been measured and shown to decrease with time as scaling proceeds. After the end of experiments, the vertical tube has been cut to measure the thickness of scale at different heights. Below the height where the bulk fluid temperature does not reach saturated temperature, the thickness of scale increases, however, beyond that height occurring saturated condition, the thickness does not vary much or even decreases a little. The measured fouling resistances also support these variations of scale thickness.

Surface Alloying of Iron Base Rapid Solidification Materials Using Laser Beam (레이저 빔을 이용한 철계 급랭 응고 재료의 표면 합금화)

  • Nam, K.S.;Lee, K.H.
    • Journal of the Korean Society for Heat Treatment
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    • v.9 no.4
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    • pp.229-233
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    • 1996
  • This work has been carried out to reduce the softening of heat affected zone on laser surface alloying. Iron based rapid solidification material with $Cr_{5-10}$, $V_{1-3}$, $Mo_{3-7}$, $W_{2-5}$, $B_{7-8}$, $C_{2-3}$, $Si_{0.5-1}at%$ was alloyed on the surface of SM45C steel. The excellent softening resistance in alloyed and heat affected zone showed, which could be attributed to the formation of stable high temperature precipitates.

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A study on the weld nugget formation in resistance spot welding of aluminum alloy (알루미늄 합금의 저항 점 용접시 용접너깃의 형성에 대한 연구)

  • 나석주;오세진
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.10 no.5
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    • pp.661-669
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    • 1986
  • In this study, the resistance spot welding process of an aluminum alloy was analyzed through the numerical simulation including the electric contact resistance and the heat generation in the electrode. The finite element model was used to solve the electro-thermal responses in weld cycles. The resistance of the contact area was represented as the contact element modeling, but the thermal resistance between the contact surfaces was neglected. Welding tests of Alclad 2024-T3 aluminum alloy were made not only to get the input data for the numerical simulation, but also to compare the numerical results. The contact resistance was determined initially by the contact resistance tests and assumed to decay exponentially up to the solidus temperature. The temperature distributions and dynamic resistance obtained numerically were in good agreement with the experimental results. Numerical results revealed that nugget growth depends mainly on the heat generated in the workpiece and its contact area. The heat generated in the electrode has, however, only a little effect on the nugget growth, and the heat generation in the electrode-workpiece interface is initially high but decrease repidly.

Effect of Ca Implantation on the Sintering and Crack Healing Behavior of High Purity Al2O3 Using Micro-lithographic Technique - I. Formation of Crack-like Pore and Its Morphological Evolution (Ion Implantation으로 Ca를 첨가한 단결정 Al2O3의 Crack-like Pore의 Healing 거동 - I. Crack-like Pore의 형성과 Morphological Evolution)

  • 김배연
    • Journal of the Korean Ceramic Society
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    • v.34 no.8
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    • pp.834-842
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    • 1997
  • Controlled Ca impurity implanted inner crack-like pore in the high purity alumina single crystal, sapphire, had been created by micro-fabrication technique, which includes ion implantation, photo-lithography, Ar ion milling, and hot press technique. The morphological change and the healing of cracklike pore in Ca doped high purity single crystal alumina, sapphire, during high temperature heat treatment in vacuum were observed using optical microscopy. The dot-like surface roughening was developed and hexagon like crystal appeared on inner surface of crack-like pore after heat treatment. Bar type crystals, probably CaO.6Al2O3, were observed on the inner surface after 1 hour heat treatment at 1, 50$0^{\circ}C$, but this bar type crystal disappeared after 1 hour heat treatment at 1, $600^{\circ}C$. This disappearance means that there should be a little increase of Ca solubility limit to alumina at this temperatures.

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Structural and Magnetic Properties of Z-type Barium Ferrite (Z-type 바리움 페라이트의 구조 및 자기적 성질)

  • Nam, In Tak
    • Journal of Industrial Technology
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    • v.28 no.A
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    • pp.119-123
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    • 2008
  • Structural and magnetic properties of $CO_{1-x}Zn_xZ$ ($Ba_3Co_{1-x}Zn_xFe_{24}O_{41}$) hexa-ferrite are studied using XRD, VSM and SEM, respectively. Powder was prepared from co-precipitation and firstly heat treated at $1350^{\circ}C$ for 6 hours in $O_2$ atmosphere. Second heat treatment was performed at 900, 1000, $1100^{\circ}C$ for 6 hours in air, respectively. Saturation magnetization value of first heat treated powder is acceptable and coercivity is high for applying to device. These result may be originated from incomplete formation reaction from M and Y phases to Z phase. Second heat treatment leads to small value of coercivity.

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Formation of $Nb_2O_5$ Thin Films by Sol-Gel Technique and Analysis of Their Crystalline Phases and Dielectric Characteristics (졸-겔법에 의한 $Nb_2O_5$ 유전박막의 형성 및 박막의 결정상과 유전특성의 분석)

  • 조남희;강희복;이전국;김윤호
    • Journal of the Korean Ceramic Society
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    • v.30 no.1
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    • pp.17-24
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    • 1993
  • Sol-gel spin-coating technique was used to produce Nb2O5 thin films on silicon substrates from Nb(OC2H5)5 precursor. The films were heat-treated at temperatures between $600^{\circ}C$ and 100$0^{\circ}C$ in oxygen atmosphere and their crystalline phases, chemical states, and dielectric characteristics were investigated by X-ray diffractometry (XRD), Auger electron spectroscopy (AES), and C-V measurements, respectively. After 1 hour heat-treatment at 80$0^{\circ}C$, T-type Nb2O5 was formed, and its chemical composition was homogeneous with no appreciable SiO2 oxide at interfaces between the films and substrates. The films heat-treated at temperatures between $600^{\circ}C$ and 80$0^{\circ}C$ exhibit dielectric constant of less than 20 while the films heat treated at 100$0^{\circ}C$ show dielectric constant of 28.

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CORRELATION BETWEEN THE TENSILE STRENGTH AND CORROSION BEHAVIOR OF HEAT TREATED ZR-1.0NB ALLOY

  • Kim, Tae-Kyu;Choi, Pyung-Sik;Yang, Sung-Ki;Lee, Chong-Tak;Sohn, Dong-Seong
    • Nuclear Engineering and Technology
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    • v.40 no.6
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    • pp.505-510
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    • 2008
  • The correlation between the tensile strength and corrosion behavior of Zr-1.0wt%Nb alloy heat treated at $480^{\circ}C$ for up to 32 hours was evaluated. The tensile strength at $400^{\circ}C$ was continuously reduced with an increasing heat treatment time, mainly due to a grain growth and a decreased area fraction of the precipitates. However, the corrosion resistance in an aqueous ammonia solution at $360^{\circ}C$ was enhanced, mainly due to the formation of $\beta$-Nb precipitates. It is thus concluded that a longer heat treatment time provides a better corrosion resistance while degrading the tensile strength.

Immunohistochemical Localization of the Heat Shock Protein 27 during Placenta Formation in the Rat (흰쥐 태반형성시의 Heat Shock Protein 27 분포에 대한 면역조직화학적 연구)

  • 최병태;강호성김한도조운복
    • The Korean Journal of Zoology
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    • v.38 no.2
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    • pp.153-159
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    • 1995
  • 임신 10일부터 20일까지 흰쥐 태반형성과정에서 heat shock protein 27(HSP27) 분포를 면역조직화학적으로 조사하였다 임신 10일 태반에 자궁간막 탈락막세포. 영양막세포 및 거대영양막세포가 찰찰되었다. 이후 탈락막세포수는 감소하고 영양막세포는 증가하는데 특히 임신 14일에 현저하며 영양막은 해면영양막과 미로영양막으로 구분되었다 거대영양 막세포수의 변화는 현저하지 않았다. 자궁간막 탈락막에서 HSP27은 임신 10일 및 12일에 탈락막세포의 세포질 또는 핵에 반응이 나타나고 특히 핵에 반응하는 세포수가 많았으며 임신 14일 이후 탈락막 세포수 감소와 함께 반응이 나타나지 않았다 거대영양막세포는 임신 10일부터 일부 세포의 세포질 또는 핵에 반응이 관찰되나 임신 18일부터는 반응이 나타나지 않았다 영양막의 HSP27은 임신 10 및 12일에 일부 세포에서만 세포질 또는 핵에 반응이 관찰되나, 임신 14일부터 반응세포수 증가와 함께 대부분 핵에 반응을 나타내고 반응정도는 임신 16일 및 18일에 가장 현저하였으며, 미로영양막에서 반응세포수가 더 많았다.

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Modeling of Spray Impingement and Fuel Film Formation in HSDI Diesel Engines (고속직분식 디젤엔진에서의 분무충돌과 연료액막형성 모델링)

  • Kim, Man-Sik;Min, Gyeong-Deok;Gang, Bo-Seon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.25 no.2
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    • pp.187-194
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    • 2001
  • Spray impingement and fuel film formation models were developed and incorporated into the computational fluid dynamics code. STAR-CD. The spray/wall interaction process was modeled by considering the change of behaviour with surface temperature conditions and the fuel film formation. We divided the behaviour of fuel droplets after impingement into rebound, spread and splash using the Weber number and the parameter K. The Spray impingement model accounts for mass conservation, energy conservation and heat transfer to the impinging droplets. The fuel film formation model was developed by integrating the continuity, Navier-Stokes and energy equations along the direction of fuel film thickness. Validation of the models was conducted using previous diesel spray experimental data and the present experimental results for the gasoline spray impingement. In all the cases, the prediction compared reasonably well with the experimental results. The spray impingement and fuel film formation models have been applied to the spray/wall impingement in high speed direct injection diesel engines.