• Journal of Climate Change Research
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• v.4 no.1
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• pp.1-10
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• 2013

This study has purpose to minimize the impact of climate change of Siheung. Vulnerability assessment was carried out for establishing the Siheung Climate Change Master Plan. Climate change vulnerability assessment analyzed using climate exposure, sensitivity and adaptive capacity indicators. A proxy variable is selected from each indicator. Meteorological data uses the RCP scenarios provided by the Meteorological Administration, and this study assumes that the same trend will continues in the future. Siheung are vulnerable to heavy rains in the flooded roads and farmland. Also, it is necessary to be careful heat wave in summer. The size and scale of the damage depends on the city's ability to respond to the impacts of climate change. It is necessary to make a adaptation plan for climate change impact assessment and vulnerability analysis. This study will be used to make Siheung Climate Change Master Plan and to determine the priority of the policy as guideline. It is expected that this study is helpful to pursue climate change vulnerability assessment of other local governments.

• Clean Technology
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• v.25 no.3
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• pp.198-205
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• 2019

The adsorption equilibrium, kinetic, and thermodynamic parameters of brilliant green adsorbed by coconut based granular activated carbon were determined from various initial concentrations ($300{\sim}500mg\;L^{-1}$), contact time (1 ~ 12 h), and adsorption temperature (303 ~ 323 K) through batch experiments. The equilibrium adsorption data were analyzed by Langmuir, Freundlich, Temkin, Harkins-Jura, and Elovich isotherm models. The estimated Langmuir dimensionless separation factor ($R_L=0.018{\sim}0.040$) and Freundlich constant ($n^{-1}=0.176{\sim}0.206$) show that adsorption of brilliant green by activated carbon is an effective treatment process. Adsorption heat constants ($B=12.43{\sim}17.15J\;mol^{-1}$) estimated by the Temkin equation corresponded to physical adsorption. The isothermal parameter ($A_{HJ}$) by the Harkins-Jura equation showed that the heterogeneous pore distribution increased with increasing temperature. The maximum adsorption capacity by the Elovich equation was found to be much smaller than the experimental value. The adsorption process was best described by the pseudo second order model, and intraparticle diffusion was a rate limiting step in the adsorption process. The intraparticle diffusion rate constant increased because the dye activity increased with increases in the initial concentration. Also, as the initial concentration increased, the influence of the boundary layer also increased. Negative Gibbs free energy ($-10.3{\sim}-11.4kJ\;mol^{-1}$), positive enthalpy change ($18.63kJ\;mol^{-1}$), and activation energy ($26.28kJ\;mol^{-1}$) indicate respectively that the adsorption process is spontaneous, endothermic, and physical adsorption.

• Journal of Environmental Science International
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• v.28 no.3
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• pp.341-356
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• 2019

In this study, the impacts of local meteorology caused by tidal changes in the West Sea on ozone distributions in the Seoul Metropolitan Area (SMA) were analyzed using a meteorological model (WRF) and an air quality (CMAQ) model. This study was carried out during the day (1200-1800 LST) between August 3 and 9, 2016. The total area of tidal flats along with the tidal changes was calculated to be approximately $912km^2$, based on data provided by the Environmental Geographic Information Service (EGIS) and the Ministry of Oceans and Fisheries (MOF). Modeling was carried out based on three experiments, and the land cover of the tidal flats for each experiment was designed using the coastal wetlands, water bodies (i.e., high tide), and the barren or sparsely vegetated areas (i.e., low tide). The land cover parameters of the coastal wetlands used in this study were improved in the herbaceous wetland of the WRF using updated albedo, roughness length, and soil heat capacity. The results showed that the land cover variation during high tide caused a decrease in temperature (maximum $4.5^{\circ}C$) and planetary boundary layer (PBL) height (maximum 1200 m), and an increase in humidity (maximum 25%) and wind speed (maximum $1.5ms^{-1}$). These meteorological changes increased the ozone concentration (about 5.0 ppb) in the coastal areas including the tidal flats. The increase in the ozone concentration during high tide may be caused by a weak diffusion to the upper layer due to a decrease in the PBL height. The changes in the meteorological variables and ozone concentration during low tide were lesser than those occurring during high tide. This study suggests that the meteorological variations caused by tidal changes have a meaningful effect on the ozone concentration in the SMA.

• The Journal of the Acoustical Society of Korea
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• v.38 no.4
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• pp.459-466
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• 2019

When a laser pulse is irradiated on a CNT (Carbon Nanotube) and PDMS (Poly dimethylsiloxane) composite coated on a transparent PMMA (Poly methyl methacrylate) substrate, a strong ultrasonic wave is generated due to the thermoelastic effect. In this paper, the thermoacoustic theory related to the wave generation by the CNT/PDMS composite was established. The waveforms of ultrasonic waves when a laser pulse having a Gaussian waveform is irradiated on the composite with a thickness of $20{\mu}m$ were numerically simulated. From the results, it was confirmed that ultrasonic shock waves can be generated from the CNT/PDMS composite and the waveforms are changed little even if the physical properties of the composite are changed by ${\pm}20%$. It was found that the peak positive and negative pressures increase as the thermal expansion coefficient increases, or as density, heat capacity and sound speed decreased. However, those changes were not so sensitive with thermal conductivity. In addition, the physical properties of the CNT/PDMS composite fabricated in this study were estimated from the comparison of the measurement and simulation results.

• Asian-Australasian Journal of Animal Sciences
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• v.32 no.5
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• pp.721-733
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• 2019

Objective: The objectives of this study were to investigate the thermal gelation properties and molecular forces of actomyosin extracted from two classes of chicken breast meat qualities (normal and pale, soft and exudative [PSE]-like) during heating process to further improve the understanding of the variations of functional properties between normal and PSE-like chicken breast meat. Methods: Actomyosin was extracted from normal and PSE-like chicken breast meat and the gel strength, water-holding capacity (WHC), protein loss, particle size and distribution, dynamic rheology and protein thermal stability were determined, then turbidity, active sulfhydryl group contents, hydrophobicity and molecular forces during thermal-induced gelling formation were comparatively studied. Results: Sodium dodecyl sulphate-polyacrylamide gel electrophoresis showed that protein profiles of actomyosin extracted from normal and PSE-like meat were not significantly different (p>0.05). Compared with normal actomyosin, PSE-like actomyosin had lower gel strength, WHC, particle size, less protein content involved in thermal gelation forming (p<0.05), and reduced onset temperature ($T_o$), thermal transition temperature ($T_d$), storage modulus (G') and loss modulus (G"). The turbidity, reactive sulfhydryl group of PSE-like actomyosin were higher when heated from $40^{\circ}C$ to $60^{\circ}C$. Further heating to $80^{\circ}C$ had lower transition from reactive sulfhydryl group into a disulfide bond and surface hydrophobicity. Molecular forces showed that hydrophobic interaction was the main force for heat-induced gel formation while both ionic and hydrogen bonds were different significantly between normal and PSE-like actomyosin (p<0.05). Conclusion: These changes in chemical groups and inter-molecular bonds affected protein-protein interaction and protein-water interaction and contributed to the inferior thermal gelation properties of PSE-like meat.

• Journal of the Korean Geotechnical Society
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• v.37 no.4
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• pp.19-26
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• 2021

The high-level radioactive waste (HLW) produced from nuclear power plants is disposed in a rock-mass at a depth of hundreds meters below the ground level. Since HLW is very dangerous to human being, it must be disposed of safely by the engineered barrier system (EBS). The EBS consists of a disposal canister, backfill material, buffer material, and so on. When the components of EBS are installed, gaps inevitably exist not only between the rock-mass and buffer material but also between the canister and buffer material. The gap can reduce water-retarding capacity and heat release efficiency of the buffer material, so it is necessary to investigate properties of gap-filling materials and to analyze gap spacing effect. Furthermore, there has been few researches considering domestic disposal system compared to overseas researches. In this reason, this research derived the peak temperature of the bentonite buffer material considering domestic disposal system based on the numerical analysis. The gap between the canister and buffer material had a minor effect on the peak temperature of the bentonite buffer material, but there was 40% difference of the peak temperature of the bentonite buffer material because of the gap existence between the buffer material and rock mass.

• Journal of the Korea Organic Resources Recycling Association
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• v.30 no.4
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• pp.41-50
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• 2022

Recently, research on carbon adsorbents has been active as an interest in improving the environment such as indoor and outdoor air quality. Considering that causative substances deteriorate the air quality are basically volatile organic compounds, it is important to improve the hydrophobicity of the carbon materials for better removal efficiency. This study presents a method for improving hydrophobicity of carbon and a measurement of the hydrophobicity. Generally, methods of improving the hydrophobicity of carbon materials are heat treatment, acid/alkali treatment, coating and immersion with hydrophobic materials. However, it collapses the pore structure and reduces the adsorption capacity. Therefore, this study briefly introduce not only the general method for improving carbon materials' hydrophobicity but also the method for converting the precursor of the material is briefly introduced. Futhermore, this study introduces a analytical technique used to determine hydrophobic modification or not, and aims to enhance the understanding of carbon materials.

• New Physics: Sae Mulli
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• v.68 no.12
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• pp.1315-1323
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• 2018

We studied the carbonization due to the annealing condition of waste coffee powder for application as an active anode material for lithium-ion batteries (LIBs). The coffee powder used as an active anode material for LIBs was obtained from coffee beans, not from a coffee shells. The waste coffee powder was dried in air and heat-treated in an $Ar/H_2$ atmosphere to obtain a pore-forming activated carbon powder. The specific capacity of the sample annealed at $700^{\circ}C$ was still 303 mAh/g after 1000 cycles at a current density of 1000 mA/g and with a coulombic efficiency of over 99.5%. The number of pores and the pore size of the waste coffee powder were increased due to chemical treatment with KOH, which had the some effect as an increased specific surface area. The waste coffee powder is considered to be a very promising active anode material because of both its excellent electrochemical properties due to enhanced carrier conduction and its being a cost effective resource for use in LIBs.

• Tunnel and Underground Space
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• v.32 no.1
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• pp.59-77
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• 2022

Currently, the design reference temperature of the buffer material for disposing of high-level radioactive waste is less than 100℃, so if the heat dissipation capacity of the buffer material is improved, the spacings of the disposal tunnel and the deposition hole in the repository can be reduced. First of all, this study tries to analyze the criteria for thermal-hydraulic-mechanical performance of the buffer materials and to investigate the researches regarding the enhanced buffer materials with improved thermal conductivity. First, the thermal conductivity should be as high as possible and is affected by dry density, water content, temperature, mineral composition, and bentonite type. the organic content of the buffer material can have a significant effect on the corrosion performance of a canister, so the organic content should be low. In addition, hydraulic conductivity of the buffer material should be less than that of near-field rock and swelling pressure should be appropriate for buffer materials to function properly. For the development of enhanced buffer materials, additives such as sand, graphite, and graphite oxide are typically used, and a thermal conductivity can be greatly improved with a very small amount of graphite addition compared to sand.

• Membrane Journal
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• v.32 no.4
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• pp.218-226
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• 2022

Hydrogen, a carrier of large-capacity chemical and clean energy, is an important industrial gas widely used in the petrochemical industry and fuel cells. In particular, hydrogen is mainly produced from fossil fuels through steam reforming and gasification, and carbon dioxide is generated as a by-product. Therefore, in order to obtain high-purity hydrogen, carbon dioxide should be removed. This review focused on free-standing polymeric membranes and mixed-matrix membranes (MMMs) that separate hydrogen from carbon dioxide reported in units of Barrer [1 Barrer = 10^-10 cm³ (STP) × cm / (cm² × s × cmHg)]. By analyzing various recently reported papers, the structure, morphology, interaction, and preparation method of the membranes are discussed, and the structure-property relationship is understood to help find better membrane materials in the future. Robeson's upper bound limits for hydrogen/carbon dioxide separation were presented through reviewing the performance and characteristics of various separation membranes, and various MMMs that improve separation properties using technologies such as crosslinking, blending and heat treatment were discussed.