• 제목/요약/키워드: hazardous waste

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A Numerical Simulation of Hazardous Waste Destruction in a Dump Incinerator (덤프 소각기에서 유해폐기물 분해에 대한 수치해석)

  • 전영남;정오진;채종성
    • Journal of Korean Society for Atmospheric Environment
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    • v.16 no.6
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    • pp.665-674
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    • 2000
  • A major source of the hazardous waste generated is from chemical industries producing plastics, herbicides, pesticides and chlorinated solvents. All of these processes produce a class if hazardous waste termed the chlorinated hydrocarbons(CHCs), either directly or from undesirable side reactions. In this study, we investigated the destruction characteristics of hazardous waste through incineration. A nonequilibrium combustion model was used to describe the effect of the chemical kinetics due to the flame inhibition characteristics of $CCl_4$ which was used as the surrogate of hazardous waste. A parametric screening studies was made in a dump incinerator proposed in this study. The dump incinerator showed high $CCl_4$ DRE(Destruction and Removal Efficiency) as 5 nines. $CCl_4$/CH$_4$ ratio appeared to be most important in the destruction of $CCl_4$ through incineration.

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Characteristics of hazardous oil & liquid fuel waste discharged from various industries (폐유 및 액상연료 공정 폐기물에서 무기물질류의 함량특성)

  • Shin, Sun-Kyoung;Jeong, Seong-Kyeong;Kim, Woo-Il;Jeon, Tae-Wan;Kang, Young-Yeul;Yeon, Jin-Mo;Cho, Yoon-A;Kim, Min-Sun
    • Analytical Science and Technology
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    • v.26 no.4
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    • pp.276-286
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    • 2013
  • This study was performed to investigate the contents characteristics of hazardous oil wastes and wastes of liquid fuels from different industrial process. In order to establish a hazardous waste list, samples of various industrial discharge have been analyzed for 16 non-regulated inorganic hazardous substances (i.e., Cu, Pb, Cd, CN, Hg, As, T-Cr, $Cr^{6+}$, Sb, Ni, F, V, Ba, Zn, Be, Se). In more detail, hazardous waste samples including waste hydraulic oils, waste engine, gear and lubricating oils, waste insulating and heat transmission oils, bilge oils, oil/water separator contents processing were collected from 37 workplaces and analyzed. We observed that the most of the inorganic substances exceeded the proposed criteria in many samples. Especially the concentration of Sb in heat transmission oil, bilge oil and gear & lubricating oils were ranged from 6 to 419 mg/kg whereas the proposed criteria is 50 mg/kg. The assessment result of hazardous waste in Korea according to the EWC showed that the out of 24 processes, 16 belongs to absolute entry and 8 belongs to mirror entry. In conclusion, we expect the outcome of this study to align the classification system of hazardous waste management in South Korea with international legislations, and consequently contribute to reduce environmental pollution as well as health risks by toxic wastes.

Preparation of the Applicable Regulatory Guideline on Mixed Waste in Korea Based on the Analysis of US Laws and Regulations

  • Sim, Eun-Jin;Lee, Sun-Kee;Kim, Chang-Lak;Kim, Tae-Man
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.19 no.1
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    • pp.141-160
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    • 2021
  • Unit 1 of the Kori Nuclear Power Plant (NPP) and Unit 1 of the Wolsong NPP are being prepared for decommissioning; their decommissioning is expected to generate large amounts of intermediate-level, low-level, and very low level Waste. Mixed waste containing both radioactive and hazardous substances is expected to be produced. Nevertheless, laws and regulations, such as the Korean Nuclear Safety Act and Waste Management Act, do not define clear regulatory guidelines for mixed waste. However, the United States has strictly enforced regulations on mixed waste, focusing on the human health and environmental effects of its hazardous components. The U.S. Nuclear Regulatory Commission and the U.S. Department of Energy regulate the radioactive components of mixed waste under the Atomic Energy Act. The U.S. Environmental Protection Agency regulates the hazardous waste component of mixed waste under the Resource Conservation and Recovery Act. In this study, the laws, regulations, and authorities pertaining to mixed waste in the United States are reviewed. Through comparison and analysis with waste management laws and regulations in Korea, a treatment direction for mixed waste is suggested. Such a treatment for mixed waste will increase the efficiency of managing mixed waste when decommissioning NPPs in the near future.

The Development of Hazardous Waste Compact Dump incinerator for Low Emissions (저공해 compact 유해폐기물 dump 소각기 개발)

  • 전영남;채종성;정오진
    • Journal of Korean Society for Atmospheric Environment
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    • v.16 no.6
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    • pp.653-663
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    • 2000
  • A lot of hazardous wastes are discharged as by-products of working process by industrial development. Hazardous wastes is physical characteristics of difficult destruction at hight temperature. Numerical simulation and combustion experiment performed of dump incinerator for hazardous waste incineration. For the numerical simulation, the SIMPLEST algorithm was used to ensure rapid converge A K-$\varepsilon$ model was incorporate for the enclosure of turbulence flow. Combustion model was used by ESCRS (extended simple chemically reacting system) model available of CHEMKIN thermodynamic data for the source term of species conservation equation or energy equation. Radiation model is used by six flux model. A parametric screening studies was carried out through numerical simulation and experiment. Residence time and concentration in the incinerator was strongly dependent on the parameters of mixture velocity, mixture equilibrium ratio, surrogate velocity and surrogate equilibrium ratio.

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On the Alternative Incineration Technologies for the Treatment of Hazardous Waste (유해폐기물 처리용 소각 대체기술 동향)

  • Yang, Hee-Chul;Cho, Yung-Zun;Eun, Hee-Chul;Kim, Eung-Ho
    • Korean Chemical Engineering Research
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    • v.45 no.4
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    • pp.319-327
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    • 2007
  • Incineration has been regarded as the best developed technology available for organically hazardous waste. However, permitting and siting incinerators to treat hazardous waste such as a waste containing PCBs is very difficult due to the public concerns associated with toxic air emissions. Recently, a lot of alternatives to an incineration have been developed and these technologies have the potential of alleviating public concerns by decreasing emissions of hazardous materials such as dioxins and furans. This paper reviews currently available alternative incineration technologies for various hazardous waste streams. Various categories of non-thermal and thermal alternative incineration technologies have been evaluated in terms of their process operating condition, applicability of a waste stream and their emission of secondary waste. Detailed descriptions of operating principles of several technologies are also provided.

The Effect of Cement Admixtures on Solidification of Tannery Sludge based Cement Method (피혁슬러지 고형화시 시멘트 혼화제의 영향)

  • 주소영;박상찬;전태성;손종렬;김태영
    • Journal of environmental and Sanitary engineering
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    • v.18 no.4
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    • pp.36-44
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    • 2003
  • The cement-based system among S/S(Solidification/Stabilization) is widely used to treat hazardous wastes. In this study, tannery sludge was solidified to evaluate the stabilization effects of using admixtures in the cement-based S/S. Fly ash as substitute also used to increase the strength of the S/S of hazardous waste. The compressive strength measurement and leaching experiment of chromium metal of solidified mortar were carried out to compare and evaluate the physical and chemical characteristics of solidified hazardous waste sludge. From the result of this study, there was increased of compressive strength by using AEW-3(early-hardening AE water reducing agent), and leaching concentration of chromium became low enough to satisfy the regulatory criteria. The successful solidification for the organic contaminant and heavy metal in hazardous waste should enable to treat by cement-based system using early-hardening AE water reducing admixture and fly ash as substituted cement.

Brief study on Restriction of Hazardous Substances Directive (RoHS) (유해물질(有害物質) 제한지침(制限指針)(Restriction of Hazardous Substances Directive, RoHS)의 현황(現況))

  • Kumar, J. Rajesh;Lee, Jin-Young;Kim, Joon-Soo;Shhn, Jeong-Soo
    • Resources Recycling
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    • v.17 no.6
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    • pp.3-9
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    • 2008
  • The Directive on the Restriction of the Use of Certain Hazardous Substances in Electrical and Electronic Equipment commonly referred to as the Restriction of Hazardous Substances Directive or RoHS was adopted in February 2003 by the European Union. The RoHS directive took effect on 1 July 2006, and is required to be enforced and become law in each member state. This directive restricts the use of six hazardous materials in the manufacture of various types of electronic and electrical equipment. It is closely linked with the waste electrical and electronic equipment directive (WEEE) 2002/96/EC which sets collection, recycling and recovery targets for electrical goods and is part of a legislative initiative to solve the problem of huge amounts of toxic e-waste.

Hazardous Substances in the old Personal Computer (구식PC에 함유된 유해물질에 관한 고찰)

  • 이성호
    • Journal of Korea Society of Industrial Information Systems
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    • v.5 no.4
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    • pp.47-54
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    • 2000
  • In general, computer industry is known as clean sector, but computer is a complicated assembly which is highly hazardous substances such as lead, cadmium, mercury, Hexavalent chromium, plastics etc. This paper was presented the quantity of hazardous substances in the personal computer and the problem of its disposition-incinerating, landfilling, recycling. Also EPR which is the solution of e-waste was introduced.

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Content and leaching characteristics of non-regulated hazardous substances in waste from the paint industry (국내 도료공정 발생 폐기물 중 미규제 중금속류의 배출특성)

  • Jeong, Seong-Kyeong;Kim, Woo-Il;Kang, Young-Yeul;Kim, Dong-Un;Cho, Yoon-A;Shin, Sun-Kyoung;Oh, Gil-Jong
    • Analytical Science and Technology
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    • v.24 no.5
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    • pp.387-394
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    • 2011
  • This study was performed to investigate the contents and leaching characteristics of hazardous wastes from the paint industry. In order to establish a hazardous waste list, samples from industrial discharge have been analyzed for 8 non-regulated inorganic hazardous substances (i.e., Sb, Ni, F, V, Ba, Zn, Be, Se). In more detail, hazardous waste samples from a total of 64 workplaces, e.g. manufacture, formulation, supply and use (MFSU) of coatings, adhesives, sealants and printing inks processing, have been chosen and analyzed. Contents and leaching tests for inorganic metal species in samples show that the non-regulated hazardous substances satisfy all the criteria, while quantitative analyses reveal that some samples of the discharged wastes exceeded the criteria proposed by NIER (National Instituted of Environmental Research). In conclusion, we expect the outcome of this study to align the classification system of hazardous waste management in South Korea with international legislations, and consequently contribute to reduce environmental pollution as well as health risks by toxic wastes.