• Title/Summary/Keyword: hazardous substance

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Hazardous Substance Analysis of Disposable Diaper for Infant (유아용 일회용 기저귀의 유해성 평가)

  • 신정화;윤혜온;박미애;안윤경
    • Journal of the Korean Society of Clothing and Textiles
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    • v.28 no.1
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    • pp.165-171
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    • 2004
  • The analytical method of toxic heavy metals in disposable diapers was developed. Disposable diapers obtained from Korea, Japan, America and German were determinated and quantified. Sample treatment (Total Digestion) was wet chemical acid digestion for extraction of nine hazardous inorganic elements (Sb, As, Pb, Cd, Cr, Co, Cu, Ni, Hg) in disposable diapers. Inductively Coupled Plasma Mass Spectrometer (ICP-MS) and Inductively Coupled Plasma Atomic Emission Spectrometer (ICP-AES) have been used for analyzing nine hazardous inorganic elements. The results were as follows : The concentration of extractable Sb which was treated for 3 hours with artificial urine and disposable diapers was higher than those of 6 hours and 24 hours. The concentration of extractable Cr was same as Sb. On the other hands, the behavior of Cu and Ni were different from Sb and Cr. Concentrations of extractable Cu and Ni increased as increasing the reaction time between artificial urine and disposable diapers.

Analysis of Air Quality and the Management Plan for Exposure to Hazardous Substances in the Garage of a Fire Station (소방청사 차고지 공기질 분석 및 유해물질 노출 관리 방안)

  • Park, Je-Seop;Han, Dong-Hun
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.30 no.4
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    • pp.394-404
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    • 2020
  • Objectives: The aims of this study are to derive the characteristics of diesel exhaust gas emissions generated during vehicle checking in the garage of fire stations and of the related improvement plans for proper air quality management. Methods: The researcher measured changes in the air quality inside garages according to the operating conditions of the exhaust facility and before and after vehicle checking at three fire stations. Results: During the checking of fire engines, a large volume of hazardous substances exceeding management standards were generated, and improvement of the discharge facilities was required for proper air quality management. Conclusions: It is necessary to study the hazard evaluation of firefighters' exposure to exhaust gas, to operate exhaust gas ventilation facilities, and to prepare technical standards for proper indoor air quality management.

Status of Illegal Hazardous Information for Chemical on Internet - Monitoring Cases of Chemical Cyber Surveillance - (인터넷 상 화학물질 불법 유해정보 현황 고찰 - 화학물질 사이버감시단 신고 사례를 중심으로 -)

  • Hwang, Man Sik;Im, Ji Young;Jeon, Da Young;Song, Ki Bong;Lee, Sang Mok;Ryu, Ji Sung;Lee, Ji Ho
    • Korean Journal of Hazardous Materials
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    • v.6 no.2
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    • pp.13-22
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    • 2018
  • Recently, social crimes using chemicals at home and abroad are increasing. These chemicals are readily available in the internet. Therefore, the NICS(national institute of chemical safety) runs a 'Chemical Cyber Surveillance' to help the public take control of the internet and create a healthy cyberspace through voluntary participation of the public. The study analyzed more than 1,000 sites suspected illegal hazardous information or blocked among cyber surveillance 3,500 case reports in the past yeas. And, the number of illegal hazardous information reported in the past three years is analyzed by type and substance. They want to examine the characteristics of hazardous chemical information on the internet and use it as a basic data to establish illegal information management measures that spread over cyberspace.

Ammonia half-saturation constants of sludge with different community compositions of ammonia-oxidizing bacteria

  • Kayee, Pantip;Rongsayamanont, Chaiwat;Kunapongkiti, Pattaraporn;Limpiyakorn, Tawan
    • Environmental Engineering Research
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    • v.21 no.2
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    • pp.140-144
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    • 2016
  • Owing to the kinetic differences in ammonia oxidation among ammonia-oxidizing microorganisms (AOM), there is no standard set of kinetic values that can be used as a representative set for nitrifying wastewater treatment plant (WWTP) design. As a result, this study clarified a link between the half-saturation constants for ammonia oxidation (Ks) and the dominant ammonia-oxidizing bacterial (AOB) groups in sludge from full-scale WWTPs and laboratory-scale nitrifying reactors. Quantitative polymerase chain reaction analyses revealed that AOB affiliated with the Nitrosomonas oligotropha cluster were the dominant AOM groups in the sludge taken from the low-ammonia-level WWTPs, while AOB associate with the Nitrosomonas europaea cluster comprised the majority of AOM groups in the sludge taken from the high-ammonia-level WWTPs and nitrifying reactors. A respirometric assay demonstrated that the ammonia Ks values for the high-ammonia-level WWTPs and nitrifying reactors were higher than those of the low-ammonia-level plants. Using the Ks values of available AOM cultures as a reference, the Ks values of the analyzed sludge were mainly influenced by the dominant AOB species. These findings implied that.different sets of kinetic values may be required for WWTPs with different dominant AOM species for more accurate WWTP design and operations.

Analysis of Minor Additives and Polymer in Used-stripper Using Pyrolysis-Gas Chromatography/Mass Spectrometry and Electrospray Mass Spectrometry

  • Koo, Jeong-Boon;Park, Chang-Hyun;Han, Cheol;Na, Yun-Cheol
    • Bulletin of the Korean Chemical Society
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    • v.30 no.2
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    • pp.368-372
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    • 2009
  • The trace polymer and additives in used stripper solutions were analyzed by a combination of Py-GC/MS and ESI-MS. In the comparison of the pyrolysates produced by the pyrolysis of the pure stripper and photoresist at $500{^{\circ}C}$, the presence of novolac polymer in the used stripper was confirmed by the presence of the characteristic peaks of its pyrolysates, such as those of the methylphenol, di-methylphenol and methylenebis(methylphenol) isomers. The intact trace polymer was measured by ESI-MS, which showed the distribution of oligomers at intervals of 120 Da, indicating di-methylphenol to be the repeat unit. Additional MS/MS measurements demonstrated that the end group is methylphenol and the repeat groups are di-methylphenol. Some modified oligomers caused by the methylation or di-methylation of the repeat unit were also identified. Although the polymer is only present at a trace level in the used stripper, these combined analytical methods provided the means to qualify the stripper solution through the identification and structural determination of the polymer.

Improvement Method of Hazardous Materials Facilities Installation License of Manufacturer (위험물시설의 설치허가제도의 개선방안)

  • 이종영;이수경;김태환
    • Fire Science and Engineering
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    • v.15 no.3
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    • pp.21-35
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    • 2001
  • By rearing private experts to design hazardous facilities, Safety property is obstained. So it is necessary to limit within the designer of hazardous materials facilities who has some degree skill. After permission progress about the inspection of the design ascertain whether it is safety property Mayor/Do governor permits within the laws and their qualification. Accordingly, Korea Fire Equipment Inspection Corporation be come specialization about the design, inspection of construction completion. A inquire purpose of Fire Service Act be considered fitness. Subject by which the Korea Fire Equipment Inspection Corporation is entrusted, subject by which the a non-probit corporation in The Civil Law be possible to entrusted in separate. In this case, because of the level of one's technique and facilities are important, to limit as a nonprobit corporation in The Civil Law give rise to trouble. Consequently; established a business corporation, which the level of one's technique and facilities, in accordance with The Commercial Law can assign inspection of construction completion. The contents of the Fire Services Act is caused by the historic growth of hazardous facilities's safety management. Because we decide on a course about completed inspection of hazardous substance, it is needed that adjust the task performed by a corporation of the exert skill and the duty performed by the task that a authorized corporation on the civil law or the commercial law To adjust the duty, the Fire Service Act, that is suitable to the purpose and principle, should constitute a measure of the duty. With the object of insure the safety of the hazardous substance, when the fire survice act establish a corporation of the expert skill. There is the will of lawmakers that need organization to have the power of the professional technology. The state excise the will that insure the safety of hazardous materials facilities on the basis of the professional technology and facilities, and construct to establish a corporation of the expert skill. Therefore as concentrate on the technology to need to insure the safety of the facilities of hazardous substance to be suitable on the purpose of laws and take responsibility and reports to a corporation of the expert skill. The task to be given to the state will be done.

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In-house Contractors' Exposure to Risks and Determinants of Industrial Accidents; With Focus on Companies Handling Hazardous Chemicals

  • Shin, Kyusoo
    • Safety and Health at Work
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    • v.12 no.2
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    • pp.261-267
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    • 2021
  • Background: The series of serious industrial accidents in recent years at contractors to large companies has highlighted risk outsourcing as a real and urgent problem. This study aims to review the difference in the degree of risk exposure and the occurrence of industrial accidents depending on the type of company relations. Among in-house contractors, the focus will be on those handling hazardous chemicals that include companies for which outsourcing requires approval. Methods: This study uses the 9th wave of the Industrial Safety and Health Survey (2018). For determining the degree of risk exposure, the occurrence of industrial accidents, and industrial accident rate, multivariate, logistic, and fractional logit, regression analyses were used, respectively. Results: First, In-house contractors' degree of risk exposure is higher than that of the client companies. In particular, this gap is even greater for companies dealing with chemicals. Second, among only those that handle hazardous chemicals, in-house contractors do show a significantly higher rate of industrial accident occurrence. Third, In-house contractors have a significantly higher rate of industrial accidents from diseases than client companies. Conclusion: The analysis supports the intent of the legal amendment that strengthens the protection of in-house contracted workers who handle hazardous chemicals. Second, the results of this study suggest that safety and health management must go beyond legal compliance and ensure that it has substance and effectiveness. Last, there should be policy consideration is necessary to reduce attempts to hide industrial accidents.

An Investigation of Ingredients and Hazardous Substances in Some Consumer Products - Focusing on Cleaners and Disinfectants - (일부 생활화학용품에 함유된 성분 및 유해물질 조사 - 세정제와 소독제를 중심으로 -)

  • Heo, Da-An;Huh, Eun-Hae;Park, Ji Young;Moon, Kyong Whan;Lee, Kiyoung
    • Journal of Environmental Health Sciences
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    • v.41 no.5
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    • pp.314-326
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    • 2015
  • Objectives: This study was conducted to identify the ingredients used in ten consumer product categories and determine hazardous substances among these ingredients. Methods: A total of 542 commercial products in ten consumer product categories were selected. The consumer products were sticker removers, washing machine cleaners, multi-purpose cleaners, mold removers, glass cleaners, chlorinated sanitizers, air conditioner cleaners, disposal cleaners, drain cleaners and disinfectant sprays. The company list was complied from governmental records and a market survey. The respective companies were contacted for a list of ingredients found in the 542 products. Results: The corresponding companies listed 163 ingredients. According to European Union (EU) Directive 67/548/EEC, 38 of the 163 ingredients were classified as dangerous substances. Among these substances, 28 ingredients were hazardous to the skin, 15 were hazardous to the eye, and nine were hazardous if inhaled. Three ingredients were classified as CMR (carcinogenic, mutagenic or toxic for reproduction) substances: liquefied petroleum gases (LPG) with carcinogenicity and mutagenicity, and VM&P naphtha and ligroine with carcinogenicity. Conclusion: Various chemicals, including hazardous substances, were used in consumer products. Risk assessment of consumer products is required in order to protect the population from health risks.

The effect of ventilation on reducing the concentration of hazardous substances in the indoor air of a Korean living environment

  • Kim, Hyunjoo;Kim, Jin Seog;Lee, Jongman;Kim, Dalho
    • Analytical Science and Technology
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    • v.33 no.1
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    • pp.49-57
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    • 2020
  • Controlling the quality of indoor air is important in order to maintain a healthy life. In this study, we investigated the correlation between the hazardous substance concentration of indoor air and circulation based on different ventilation methods in the apartment, which is one of the representative housing types in Korea. As target substances, we considered the hazardous substances which are generated during the cooking process and radon gas which is originated from building materials. We measured the concentrations of carbon dioxide and fine particles in relation to type of food and ventilation methods in order to determine the change in the concentration levels of hazardous substances which are generated during the cooking process. On the other hand, we measured the concentration of radon gas before and after letting fresh air into a room through windows in order to determine the change in the concentration level of radon gas which is originated from building materials. The results show that turning on the ventilation fan plays a major role in reducing the concentration levels of hazardous substances in the kitchen, and that it is more effective to turn on the ventilation fan during cooking than after cooking to prevent the diffusion of hazardous materials produced by cooking through the indoor air. Also, the results indicate that letting fresh air into a room through windows more than one time a day is necessary to reduce the concentration level of radon gas in the room to safe concentration range.