• Title/Summary/Keyword: hazardous elements

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Characterization of Leaching Behaviour of Recycled Concrete for Environmental Assessment (용출특성규명을 통한 재생골재 환경성 평가)

  • Kang, S.H.;Lee, S.H.;Kwak, K.S.;Lee, J.Y.;Chung, M.K.
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.3
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    • pp.293-301
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    • 2005
  • We conducted several different leaching experiments for assessing the potential environmental risk when utilizing recycled concrete for stabilizing bridge pier. The methods include continuous batch leaching test (DIN 38414-S4), availability test (NEN 7341), pH-stat test (CEN/TC 292/WG6) and tank diffusion test (NEN 7345). The concentration ranges vary depending on the testing method. Nearly all the trace elements were low, some elements recording under detection limit. The maximum concentrations for trace elements leached throughout the whole tests are (as mg/L); Cd (0.029), Cu (0.437), Pb (0.14), Ni, Zn (0.95), Hg (0.005). Although the testing methods we used in this study are much more rigorous than other commonly adapted method including TCLP and domestic testing method for solid waste, the trace elemental concentrations are under the criteria for hazardous material set by the TCLP and domestic method. The result seems to suggest that applying the recycled concrete on stream water will be accepatable practice as for as trace elements are concerned. However, the influence of inorganics such as Ca, Mg, Ni and $SO_4^{2-}$ on aquatic ecology should be further examined.

Trace Element Analysis and Source Assessment of Parking Lot Dust in Large Shopping Mall (대형유통업소주차장의 축적먼지 중 미량원소성분 분석과 오염원 평가)

  • Song, Hee-Bong;Ahn, Jeong-Eem;Jung, Yeoun-Wook;Yoon, Ho-Suk;Keum, Jong-Lok;Do, Hwa-Seok;Kim, Sun-Suk;Kim, Jong-Woo
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.3
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    • pp.168-176
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    • 2012
  • A total of 48 dust samples were collected from large shopping mall parking lots in Daegu metropolitan city in March 2011. Samples were sieved through a 100 ${\mu}m$ mesh and the concentration of 14 elements have been determined using by ICP after acid extraction. Results showed that Ca, Fe, K, Mg, Mn, Na and V were affected by natural sources while Cd, Cr, Cu, Ni, Pb and Zn were affected by anthropogenic sources. The measured values were remarkably higher in components from natural sources than in components from anthropogenic sources. Anthropogenic trace element concentrations of ground roof dust were higher than those of ground and underground indoor dust. A large percentage of trace elements came from natural sources rather than anthropogenic sources. The percentage composition of chemicals of ground roof dust were higher than those of ground and underground indoor dust. This study showed that investigated parking lots were rarely contaminated with hazardous heavy metals. The heavy metal pollution of ground roof were higher than those of ground and underground indoors. The correlation analysis among trace elements suggest that components in ground roof were more highly correlated than those in ground and underground indoor. Also anthropogenic trace element levels were well correlated with parking lot age and parking density.

A Legal Analysis on the Liability and Redress Regime under the Cartagena Protocol on Biosafety (바이오안전성의정서에서의 책임복구체제에 관한 법적 고찰)

  • Lee, Jae-Hyup
    • Journal of Environmental Policy
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    • v.2 no.1
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    • pp.107-135
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    • 2003
  • This study reviews the proposed liability and redress regime under the Cartagena Protocol on Biodiversity. Several core elements for the regime are discussed in comparison with those listed in the 1999 Basel Protocol on Liability and Compensation for Damage resulting from the Transboundary Movements of Hazardous Wastes and their Disposal. These are (1) scope of the rules and procedures; (2) channeling of liability; (3) legal standing; (4) definition of damage; (5) standard of care; (6) ancillary sources of compensation; (7) limitation of liability; (8) financial guarantees; and (9) mutual recognition and enforcement of judgments. Korea has given relatively little attention to the issue of liability and redress in the context of LMOs trade. As the Protocol is expected to enter into force soon, Korea needs to develop appropriate implementing domestic mechanisms for the Biosafety Protocol. Establishing an adequate domestic liability and compensation scheme will be one of the most important mechanisms not only to comply the Protocol but to ensure safety of LMOs in general. A further research is needed on the basis of a comparision of relevant legislations in different countries as well as analysis of current laws related to the accidents arising from LMOs trade, such as product liability laws, food safety laws, liability provisions in some environmental legislations.

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A Study on the Development of Agricultural and Stockbreeding Products Information System Using IOT Based Connected System IOT (기반 Connected System을 이용한 농축산물정보시스템 구축)

  • Lee, Sung-Ha;Park, Chul-Ju
    • Korean Journal of Artificial Intelligence
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    • v.5 no.2
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    • pp.26-42
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    • 2017
  • This study perceived that there are limits to prompt and accurate monitoring when an accident occurs and the correct information of egg production stage, such as the date of spawning, cleaning, and refrigerating cannot be identified, since eggshell codes using barcode only show numbers identifying a city and province and the name of producers. To fix this problem, this study partially suggested the RFID (Radio Frequency Identification) technology and IoT-based Connected System. The proposed system in this study shares data with related agencies as the system of agricultural and livestock product information runs as the main server, and the database information of the proposed system is provided by farmhouses, distributors, and sellers. Through various media such as a webpage or mobile application built to provide the relevant information, customers can search and obtain information about agricultural and livestock products they want. Since the information on an entire process is open to the public, information ranging from simple to clear, additional ones such as hazardous elements can be viewed.

Rhodamine derivative synthesis: dual-detectable chemosensor

  • Son, Young-A;Kim, Hyung-Joo;Park, June-Min;Lee, A-Reum;Lee, Jun-Hee;Lee, Do-Hyun
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2012.03a
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    • pp.29-29
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    • 2012
  • Rhodamine chromophore/fluorophore have been attracted to many researchers due to its excellent photophysical properties. In this study, we have designed and synthesized a strong emissive fluorescent dye chemosensor for toxic elements. A rhodamine-based sensor was prepared by incorporation the rhodamine fluorophore and several functional host groups with high affinity to hazardous metal and anion. This sensor shows a high selectivity and an excellent sensitivity and is a dual-responsive colorimetric and fluorescent metal/anion-specific sensor. In addition, the 1:1 binding mode was proposed based on Job's plot method. Finally, computational calculation was simulated and calculated to approach for HOMO/LUMO of this dye chemosensor.

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A Study on the Toys Assessment of Harmful Substances and Control (완구제품에 함유된 유해물질 및 관리방안에 대한 연구)

  • Kim, Seung-Don;Son, Ki-Sang
    • Journal of the Korean Society of Safety
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    • v.25 no.5
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    • pp.27-32
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    • 2010
  • This study is to investigate and compare domestic hazardous toys with harmful substances with foreign toys so that we can find out management criteria for in cognitive infants. Actually, commercially used toys have been collected and tested to find out more effective management standard. it is tried to produce evaluation criteria of environmentally harmful substance but variety of product is needed for overcoming actual barrier due to lot of difficulty huge cost, time, objectiveness. Therefore, This study does not cover all the above. Establishment of evaluation criteria for product harmfulness made by Government or Local government should be continued to improve. Foreign reference material for toy product in Europe, USA, Japan have been investigated and domestic product have been collected and tested for containing heavy metals, formaldehyde, phthalate in the study. All the test have been made in accordance with KSM ISO 2124 to measure heavy metal transfer into body. Toy product used for the study have been purchased in the real market and some of them contains harmful elements with over standard. Post management system such as RAPEX to control periodically should be established for plastic toy with low quality product.

Foliar Transfer of Dust and Heavy Metals on Roadside Plants in a Subtropical Environment

  • Gajbhiye, Triratnesh;Kim, Ki-Hyun;Pandey, Sudhir Kumar;Brown, Richard J.C.
    • Asian Journal of Atmospheric Environment
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    • v.10 no.3
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    • pp.137-145
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    • 2016
  • In this study, the contents of dust and associated heavy metals on roadside plants were investigated to assess their foliar transfer. The study was conducted at six different locations (four roadside and two industrial) near an industrial area in Bilaspur (Chhattisgarh), India. Six metals (Fe, Mn, Pb, Cu, Cr, and Cd) were examined in this study. The concentrations of heavy metals in foliar dust were found to be in the order of Fe>Mn>Pb>Cu>Cr>Cd. However, this relative order changed in the case of leaf concentrations to Fe>Mn>Cd>Cu>Pb>Cr. The metal concentrations in the dust and leaves can be attributed mainly to industrial and vehicular emissions. In contrast to other metals, Cd showed significant accumulation in the leaves compared to the respective dust samples. This study showed different patterns in the distributions of heavy metals between the dust deposited on the leaves and the metal accumulated in the leaves. These results suggest that the dust retention and heavy metal accumulation in native plant species should be explored in an attempt to manage these hazardous metallic elements.

Soil stabilization by ground bottom ash and red mud

  • Kim, Youngsang;Dang, My Quoc;Do, Tan Manh;Lee, Joon Kyu
    • Geomechanics and Engineering
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    • v.16 no.1
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    • pp.105-112
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    • 2018
  • This paper presents results of a compressive investigation conducted on weathered soil stabilized with ground bottom ash (GBA) and red mud (RM). The effects of water/binder ratio, RM/GBA ratio, chemical activator (NaOH and $Na_2SiO_3$) and curing time on unconfined compressive strength of stabilized soils were examined. The results show that the water/binder ratio of 1.2 is optimum ratio at which the stabilized soils have the maximum compressive strength. For 28 days of curing, the compressive strength of soils stabilized with alkali-activated GBA and RM varies between 1.5 MPa and 4.1 MPa. The addition of GBA, RM and chemical activators enhanced strength development and the rate of strength improvement was more significant at the later age than at the early age. The potential environmental impacts of stabilized soils were also assessed. The chemical property changes of leachate from stabilized soils were analyzed in terms of pH and concentrations of hazardous elements. The observation revealed that the soil mixture with ground bottom ash and red mud proved environmentally safe.

A Study on Developing a Safety Management Evaluation Program (안전관리 평가 시스템 구축에 관한 연구)

  • Kim Yun-Hwa;Lim Dong-Yun;In Cha-Soon;Ko Jae-Wook;Lim Dong-Ho;Choi Soo Hyoung
    • Journal of the Korean Institute of Gas
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    • v.2 no.3
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    • pp.96-100
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    • 1998
  • Chemical plants with high-technological equipments and complex processes are continually increasing potential hazards that may result in huge industrial accidents. If an incident breaks out, it will have a hazardous effect on in-plant workers, neighboring inhabitants or the surrounding environment. Therefore, it is necessary to develop a safety management system that can pre-evaluate the safety and reduce the risk of a chemical plants. The safety management evaluation program developed in this study can implement an effective loss control management in chemical plants. It integrates important lists in safety management lists and legal measures to analyze elements systematically. It also includes incident case analysis and the required components in domestic laws.

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The Study on Pre-treatment Method of Filter for Analysing the Heavy Metals in Air Quality (대기중의 중금속 분석을 위한 여지의 전처리 방법에 관한 연구)

  • 김광래;이상칠;어수미;김민영;신재영;이재영
    • Proceedings of the Korean Environmental Health Society Conference
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    • 2002.04a
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    • pp.16-19
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    • 2002
  • This study was carried out to establish the standardized analysis method in order to decide accurate concentrations of hazardous metals in the air. Acid decomposition method used usually was compared to microwave digestion method. Comparing results of tested background concentration in blank filter, we found that the magnitude of element concentration was Na, Ca, K, Mg, Al and Ba by order. The element concentrations of Glass fiber filter were higher than those of Quartz fiber filter, and the number of undetected components in Glass fiber filter was lower than that in Quartz fiber filter. Thus it is supposed that the concentration of background elements in Glass fiber filter was higher than those in Quartz fiber filter The extraction rate of microwave digestion method was superior to those of acid decomposition method during the test of blank filter as well as SRM of NIST. In case of the SRM of NIST, the average extraction efficiency of acid decomposition Method and microwave pretreatment is 53.8∼82.7%, 81.3∼97.1%, respectively. This result might be caused by the closed system of Microwave, which make outflow and loss of components less. Also microwave digestion method has other merits such as the minimization of time, reagents, and contamination. Furthermore, if the extraction condition, extraction time and used acids are optimized, the better results will be represented.

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