• Journal of Electrochemical Science and Technology
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• v.15 no.1
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• pp.96-110
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• 2024

Polymer electrolyte membrane fuel cells (PEMFCs) are green energy conversion devices, for which commercial markets have been established, owing to their application in fuel cell vehicles (FCVs). Development of cathode electrocatalysts, replacing commercial Pt/C, plays a crucial role in factors such as cost reduction, high performance, and durability in FCVs. PtNi octahedral catalysts are promising for oxygen reduction reactions owing to their significantly higher mass activity (10-15 times) than that of Pt/C; however, their application in membrane electrode assemblies (MEAs) is challenged by their low stability. To overcome this durability issue, various approaches, such as third-metal doping, composition control, halide treatment, formation of a Pt layer, annealing treatment, and size control, have been explored and have shown promising improvements in stability in rotating disk electrode (RDE) testing. In this review, we aimed to compare the features of each strategy in terms of enhancing stability by introducing a stability improvement factor for a direct and reasonable comparison. The limitations of each strategy for enhancing stability of PtNi octahedral are also described. This review can serve as a valuable guide for the development of strategies to enhance the durability of octahedral PtNi.

• Journal of Bio-Environment Control
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• v.22 no.4
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• pp.400-407
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• 2013

This study was performed to analyze the effect of light quality of discharge lamp on growth and phytochemicals contents of lettuce (Lactuca sativa L. cv. Jeokchima) grown under metal halide (MH) lamp, high-pressure sodium (HPS) lamp, and xenon (XE) lamp in a plant factory. Cool-white fluorescent (FL) lamp was used as the control. Photoperiod, air temperature, relative humidity, $CO_2$ concentration, and photosynthetic photon flux (PPF) in a plant factory were 16/8 h (day/night), $22/18^{\circ}C$, 70%, 400 ${\mu}mol{\cdot}mol^{-1}$, and 200 ${\mu}mol{\cdot}m^{-2}{\cdot}s^{-1}$, respectively. MH lamp had the greatest fraction of blue light (400-500 nm) of 23.0%. However, HPS lamp had the lowest fraction of 4.7% for blue light and the greatest fraction of 38.0% for red light (600-700 nm). At 11 and 21 days after transplanting, leaf length, leaf width, leaf area, shoot fresh weight, and shoot dry weight of lettuce as affected by the light quality of the discharge lamp were significantly different. The leaf area of lettuce grown under HPS, MH, and XE lamp increased by 45.7%, 16.3%, and 9.5%, respectively, as compared to the control. These results were similar for shoot fresh weight. Growth characteristics of lettuce grown under HPS lamp increased since HPS lamp had more fraction of red light. However, growth of lettuce grown under MH and XE lamp decreased since they had more fraction of blue light. As compared to the control, the ascorbic acid in lettuce leaves grown under discharge lamp decreased. The greatest anthocyanins accumulation of 0.70 mg/100 g was found at MH treatment. Anthocyanins content in lettuce leaves grown under XL and HPS lamp were 79.3% and 8.6%, respectively, compared with the control. Growth and phytochemicals contents of lettuce were highly affected by the different spectral distribution of the discharge lamp. These results indicate that the combination of discharge lamp or LED lamp for enhancing the light quality of discharge lamps is required to increase the growth and phytochemicals accumulation of lettuce in controlled environment such as plant factory.

• Journal of Bio-Environment Control
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• v.27 no.2
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• pp.158-165
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• 2018

The effects of different kinds of supplementary lighting or heating lamps on the yield, cut flower life, and leaf color of cut rose were compared and analyzed. For this purpose, light emitting diode lamp (LED), metal halide lamps (MH), and high-pressure sodium lamps (HPS) as the supplementary lamps, and carbon fiber infrared lamp (NCFI) were installed on hydroponic cultivation bed in a cut rose farm. The yield of cut flower rose and the number of marketable flowers were greatly increased in spring and autumn by HPS treatment, but not in winter. The length of flower stalk was longer than that of control in the spring but decreased in winter. It seemed likely that the shorter flower stalk in winter was due to the shortened period of vegetative growth compared to the control because flowering was promoted by supplementary lighting. Vase life was not different among treatments in the autumn when the lighting time was short, but in winter, it was prolonged to 3 more days by only HPS, compared with the control. Leaf color was significantly affected by light treatment in winter rather than autumn. Leaf color was darkened in all supplementary lamps (LED, MH, HPS) treatment, whereas NCFI was similar to the control in leaf color. In conclusion, HPS is considered to be a very good supplementary lamp because it increases the length of flower stalk and the yield and prolongs vase life in cut roses. Even though NCFI could function as a heating lamp radiating a lot of heat, it was considered that the role as a supplementary light is unsatisfactory because the number of marketable flowers decreases and the quality index of cut rose deteriorates by NCFI.

• Journal of the Korean Chemical Society
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• v.45 no.3
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• pp.242-246
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• 2001

The quaternary thiophosphates, $A_2NiP_2S_6$ (A=Rb, Cs), have been synthesized with halide fluxes and structurally characterized by single-crystal X-ray diffraction technique. These compounds crystallize in the space group $C_{2h}^5-P2_1/n$ of the monoclinic system with two formula units in a cell of dimensions a=5.960(2), b=12.323(4), $c=7.491(3)\AA$, $\beta=97.05(3)^{\circ}$, and $V=546.0(3)\AA^3$ for Rb2NiP2S6 and a=5.957(4), b=12.696(7), $c=7.679(4)\AA$, $b=93.60(5)^{\circ}$, and $V=579.7(5)\AA^3$ for $Cs_2NiP_2S_6.$ These compounds are isostructural. The structure of $Cs_2NiP_2S_6$ is made up of one-dimensional $_\infty^1[NiP_2S_6^{2-}]$ chains along the a axis and these chains are isolated by $Cs^+$ ions. The Ni atom is octahedrally coordinated by six S atoms. These Ni$S_6$ octahedral units are linked by sharing three m-S atoms of the $[P_2S_6^{4-}]$ anions to form the infinite one-dimensional $_\infty^1[NiP_2S_6^{2-}]$ chain. For $Cs_2NiP_2S_6$, the magnetic susceptibility reveals an antiferromagnetic exchange interaction below 8K,which corresponds to the Neel temperature ($T_N$). Above $T_N$, this compound obeys Curie-Weiss law. The magnetic moment, C, and ${\theta}forCs_2NiP_2S_6$ are 2.77 B.M., 0.9593 K, and -19.02 K, respectively. The effective magnetic moment obtained from the magnetic data is agreed with the spin-only value of $Ni^{2+}d^8$(2.83 B.M.) system.

• Fire Science and Engineering
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• v.33 no.6
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• pp.105-113
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• 2019

This study investigates the toxicity characteristics of two Non-Class 1E Cables (For security reasons, we refer to company A and company B) used in nuclear power plants according to the accelerated deterioration period. In accordance with NES 713 test equipment and standards, tests were carried out on non-aged cables and the cables subjected to 20- and 40-year-accelerated-deterioration; each of the cables was further classified into sheath and insulation. The test results showed that the toxicity indices of 20- and 40-year-accelerated-aged cables were higher than those for the non-aged cables, and 20-year-aged cables of both A and B companies showed the highest toxicity indices. This is attributed to the extensive emissions of carbon monoxide and halide gases such as hydrogen chloride and hydrogen bromide. Furthermore, to analyze the toxicity indices of sheath and insulation in detail, the US Department of Defense standard (MIL-DTL) was applied to determine whether the Toxicity index (T.I.) allowance was exceeded, and the results showed that the insulating materials emitted considerably more than the allowable limit.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.47 no.3
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• pp.183-193
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• 2011

This study made a comparative analysis of behavioral reaction of squid to red (624nm), green (524nm), blue (460nm) & white LED light, its arrival time for the shadow section by making the shadow section in the central section of a water tank just like the bottom part of a squid jigging vessel, and on-site catching efficiency of LED fishing lamp with control fishing vessel. The color LED light showing the highest squidgathering rate as against the shadow section was found to be blue LED light with 39.3% rate under the dark (0.05lx) condition. Under the brighter condition than 0.05lx, white LED light was found to have the highest gathering rate of 41.5%. In addition, it was found that squid gathering rate was high at the shadow section which showed 6.3-fold brightness difference between the shadow section and bright section. As for the arrival time for the shadow section, blue LED light was found to be the fastest in attracting squids in 192.7 seconds under the dark condition while the red LED light was the fastest in luring squids in 164.6 seconds under the bright condition. The ratio of the squid-jigging operation and sailing in fuel consumption of the fishing vessel loaded with LED fishing lamp is about 7 to 1, showing most of the fuel is consumed more in sailing than in squid-jigging operation. As for a catch of squid, the control vessel loaded with MH (Metal Halide) fishing lamp had more catch of 600-7,080 squids than the vessel loaded with LED fishing lamp having a catch of 260-1,700 squids. In addition, even in the comparison of a catch per automatic jigging machine, the catch of the vessel loaded with MH fishing lamp excelled that of the vessel loaded with LED fishing lamp in 6 operations of squid jigging out of 9 operations. The ratio of hand-jigging and automatic jigging machine (one line) in the LED fishing lamp vessel was 1:1.1 excepting the case of having a catch only using an automatic jigging machine, showing almost the same with each other in catches, while in case of a MH fishing lamp vessel, its ratio against hand-jigging was 1 to 5.8, showing hand-jigging excelled in catches.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.48 no.3
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• pp.187-194
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• 2012

This study surveyed the fishing efficiency for Japanese common squid based on improvements made to LED fishing lamps by utilizing the training ship of Gangwon Provincial College. The training ship, Haesong-ho (24 tons), was equipped with seventy-two 150W electric power LED fishing lamps (10.8kW), and their fishing efficiency and fuel consumption level were surveyed for a total of ten times during the period between June 15, 2009 and July 27, 2009. In addition, the training ship was equipped with seventy-one 300W electric power LED fishing lamps (21.3kW) and their fishing efficiency and fuel consumption level were surveyed for a total of five times during the period between January 17, 2010 and August 4, 2010. In order to compare the fishing efficiency of LED fishing lamps, the catch of another fishing vessel equipped with Metal Halide (MH) fishing lamps of 120kW for the same period and at the same fishing grounds. The fuel consumption levels during the fishing operation of Haesong-ho was about 1,047.7 liters which was approximately 19.9% of the total fuel consumption level of 5,262.6 liters, and the fuel consumption level per operation hour was on average 9.2 liters. The number of Japanese common squid caught by the LED fishing lamp-equipped fishing vessel ranged from 12 to 1,640 squid for each fishing trial and the average quantity was 652. The number of Japanese common squid caught by the MH fishing lamp-equipped 10 fishing vessels ranged from 40 to 4,800 squid and the average quantity was 2,055. The fishing of Japanese common squid was done by the use of hand lines and an automatic jigging machine. The number of Japanese common squid caught per hand line and a single roller of the automatic jigging machine was in the proportion of 50.8% to 49.2% with respect to the LED fishing lamp-equipped fishing vessel. However, the number of Japanese common squid caught per hand line and a single roller of the automatic jigging machine was in the proportion of 86.4% to 13.6% with respect to the MH fishing lamp-equipped fishing vessel where most of the catch was made by hand lines. On the other hand, in comparing the number of Japanese common squid caught per automatic jigging machine, the number of squid caught by the LED fishing lamp-equipped fishing vessel was about the same or greater than the number of squid caught by the MH fishing lamp-equipped fishing vessel.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.16 no.3
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• pp.233-244
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• 2006

Of many volatile organic detergents for metals, benzine(CAS No. 8030-30-6), of which the toxicity has not yet been proven, has been used as an alternative of the halide compounds in the consideration of toxic effects, global warming and the destruction of ozone layer. In order to evaluate the effects of the benzine on human body by investigating the subchronic inhalation toxicity, to obtain the basic data for establishing the criteria of exposure in working environments and to classify the hazardousness in compliance with the Industrial Safety and Health Act by evaluating the hazardousness, repeated inhalation exposure test was carried with SD rats. The rats were grouped by 10 females and males each. The repetitive inhalation exposures were carried out at 4 levels of concentration of 0 ppm, 60 ppm, 300 ppm, and 1,500 ppm, for 6 hours a day, 5 days a week, for 13 weeks. The results are described hereunder. 1. No death of the animals of the exposed and controlled groups in the test period. Not any specific clinical symptoms, change in feed intake quantity, abnormality in eye test, or change in activity were observed. 2. In the 300 ppm and 1,500 ppm groups, weight reduction in the female groups and weight increase of liver and kidney in the male groups compared with control group were observed with statistical significance(p<0.05). 3. In the blood test, the HCT increased in the male 300 ppm group and the number of hematocyte increased, MCV and MCH decreased in the male 1,500 ppm group. In the female 1,500 ppm group, the HB decreased and the distribution width of the hematocyte particle size increased. In the blood biochemistry test, the TP in the male 1,500 ppm group and the LDH in the female 1,500 ppm group were increased with statistical significance(p<0.05). 4. Under the test conditions of the present study with SD rats, the NOEL was evaluated to be from 60 ppm to 300 ppm for both male and female groups. By extrapolation, the NOEL for human who work 8 hours a day was evaluated to be from 128 ppm to 640 ppm 5. Since the NOEL evaluated in this study do not exceed 60ppm(0.184 mg/L) the test material does not belong to the classification of the hazardous substance "NOEL${\leq}$0.5mg/L/6hr/90day(rat), for continuous inhalation of 6hours a day for 90 days" nor to the basic hazardous chemical substance class 1(0.2 mg/L/6hr/90day(rat) defined by the GHS which is a criteria of classification and identification of chemical compounds. However, considering the boiling point($30-204^{\circ}C$), flashing point($-40^{\circ}C$), vapor pressure(40 mmHg), and the inflammable range(1.0 - 6.0 %), sufficient care should be taken for handling in the safety aspects including fire or explosion.

• Journal of Bio-Environment Control
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• v.19 no.4
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• pp.333-342
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• 2010

For the energy-saving production of fresh vegetables in poor environment such as the Antarctic, a container-type plant factory was designed and developed. To maximize space usage of the 20 feet container ($L5.9m{\times}W2.4m{\times}H2.4m$), a three-level hydroponic cultivation system was installed and the nutrient solution was supplied by bottom watering. Using this system, 3 lettuce cultivars were grown under different the light source (light intensity). After 2 weeks from the transplanting, fluorescent lamp ($145\;{\mu}mol{\cdot}m^{-2}{\cdot}s^{-1}$) showed the best fresh weight of top part and leaf area. However, After 4 weeks, fluorescent lamp plus metal halide lamp ($150\;{\mu}mol{\cdot}m^{-2}{\cdot}s^{-1}$) led to the optimum growth of the each lettuce cultivar. The cultivar, 'Cheongchima', showed the best fresh weight of top part and leaf area, followed by 'Jeokchukmyeon' and 'Lollo rosa'. The chlorophyll concentrations (SPAD) showed no significant difference among the sources of lights. However, 'Cheongchima' showed relatively high chlorophyll concentration. With the above results, we found that the growth of lettuce is depend on light intensity and even at same intensity, the growth is different among the cultivars. Therefore, the selection of optimum cultivar should be considered in the plant factory system that has only weak light density.

• Journal of Bio-Environment Control
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• v.17 no.2
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• pp.132-137
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• 2008

This experiment was conducted to investigate the effect of supplemental lighting of low light intensities on growth and yield of rose 'Vital' in a forcing culture. Metal halide lamp (MH), High pressure sodium lamp (HSP), and MH+HSP were used as the light sources, and they were set up at a $310\;cm{\times}450\;cm$ interval and at 120cm above the culture beds. Light intensity at 1m point distance from supplemental lighting sources was $32{\sim}34\;{\mu}mol{\cdot}m^{-2}{\cdot}s^{-1}$. Days to the 1st and 2nd harvests decreased by $5{\sim}8$ and $3{\sim}5$days, respectively in supplemental lighting treatment as compared to the control. Days to harvesting was the shortest in MH+HPS treatment, followed by BPS and MH, although there was no significant difference between HPS and MH treatments. The growth was better and incidence of blind shooting decreased by $5{\sim}7%$ in supplemental lighting treatments than the control, increasing marketable cut flowers. The incidence of blind shoot was the lowest in MH+BPS treatment, and there were no significant difference between MH and BPS treatments. In conclusion, supplemental lighting of low light intensities was effective in reducing days to flowering and reduced occurrence of blind shoots.