• Title/Summary/Keyword: green-house gas

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Effects of Magnetite added with Metallic Oxide on the Decomposition Reaction of Carbon Dioxide (CO$_2$ 분해 반응에서 금속 산화물이 첨가된 $Fe_2O_4$의 영향)

  • Kim, Seung-Ho;Park, Young-Goo
    • Journal of Environmental Health Sciences
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    • v.24 no.1
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    • pp.32-37
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    • 1998
  • The Carbon Dioxide is the gas, which causes green house effects, unusual changes in the weather, destruction of the life. Almost every nation in the world is trying to search the countermeasure to this poisonous gas. I synthesized $Fe_3O_4$ and NaOH, in order to decompose the Carbon Dioxide. Among the particles synthesizing $Fe_3O_4$, I chose the equivalent ratio 1.00 which can decompose the Carbon Dioxide best, and fixed that equivalent ratio and added the 0.005-3.00 mole percentage of NiCl$_2$ and synthesized $Fe_3O_4$. I studied the decomposition of the Carbon Dioxide and methanized reaction, by measuring its crystal structure, thermochemistrical character and specific surface area. In decomposing the Carbon Dioxide, I used oxygen-deficit Magnetite which I produced by injecting the hydrogen gas into the synthesized sample. I observed the methanization reaction by raising the temperature of sample up to 650$\circ$C and having it reacted with the hydrogen gas. The decomposition of the Carbon Dioxide was added 0.005, 0.03, 0.05 mole percentage of NiCl$_2$ was more effective than pure $Fe_3O_4$. All sample in which the decomposition of the Carbon Dioxide took place produced the methane gas.

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A Study on the Optimal Conditions of the Biogas Sorting by Using the Polysulfone Membrane (다공성 분리막을 이용한 최적의 Bio-gas 분리인자 도출)

  • Lee, Seung-Won;Jeong, Chang-Hoon;Kim, Jung-Kwon
    • Journal of Environmental Science International
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    • v.20 no.8
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    • pp.1011-1019
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    • 2011
  • The objective of this research is to evaluate optimal conditions of permeability and selectivity on the polysulfone membrane for efficiency of separation of $CH_4$ by checking four factors which are temperature, pressure, gas compositions and gas flow rates. When higher pressure was applied at the input, lower efficiency of recovery of $CH_4$ and higher efficiency of separation of $CH_4$ were shown. It has the tendency to show lower efficiency of recovery of $CH_4$ and higher efficiency of separation of $CH_4$ at the output as higher temperature at input. The lower flow rates make higher efficiency of recovery of $CH_4$ and lower efficiency of separation of $CH_4$. Finally, over 90% efficiency for $CH_4$ separation and recovery conditions are temperature ($-5^{\circ}C$), pressure (8 bar), gas composition rate (6:4) ($CH_4:CO_2$) and gas flow rate ($5\ell$/min). These conditions make higher separation and recovery efficiency such as 90.1% and 92.1%, respectively.

Characteristics of Solid Electrolyte $CO_2$ Gas Sensors (고체전해질을 사용한 $CO_2$가스센서의 응답기구)

  • Kim, G.Y.;Park, Y.P.;Lee, S.I.;Lee, W.J.;Hong, J.W.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.562-564
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    • 2002
  • In recent years, environments of our globe has been getting worse as a result of rapid growth of socioeconomic activities. The global environmental issues of acid rain, green house effect and ozone depletion are caused by various chemical pollutants, emitted from industries, automobiles and home. Most of these pollutants are produced by combustion processes. CO2 as a chief criminal of the greenhouse effect is a main combustion product of fossil fuels. Development of solid-state electrochemical devices for detecting CO2 is demonstrated based on various combination of solid electrolytes and auxiliary sensing materials. The object of this research is to develop various sensor performance for solid electrolyte gas sensor, and to test gas sensor performance manufactured. So we try to present a guidance for developing potential type gas sensor. We concentrated on development of manufacturing process and performance test.

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Analysis on Ventilation Efficiency of Standard Duck House using Computational Fluid Dynamics (전산유체역학을 이용한 표준 오리사 설계안에 대한 환기효율성 분석)

  • Yeo, Uk-Hyeon;Jo, Ye-Seul;Kwon, Kyeong-Seok;Ha, Tae-Hwan;Park, Se-Jun;Kim, Rack-Woo;Lee, Sang-Yeon;Lee, Seung-No;Lee, In-Bok;Seo, Il-Hwan
    • Journal of The Korean Society of Agricultural Engineers
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    • v.57 no.5
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    • pp.51-60
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    • 2015
  • In Korea, 69.4 % of duck farms had utilized conventional plastic greenhouses. In this facilities, there are difficulties in controlling indoor environments for raising duck. High rearing density in duct farms also made the environmental control difficult resulting in getting more stressed making their immune system weaker. Therefore, a facility is needed to having structurally enough solidity and high efficiency on the environmental control. So, new design plans of duck house have recently been conducted by National Institute of Animal Science in Korea. As a study in advance to establish standard, computational fluid dynamics (CFD) was used to estimate the aerodynamic problems according to the designs by means of overall and regional ventilation efficiencies quantitatively and qualitatively. Tracer gas decay (TGD) method was used to calculate ventilation rate according to the structural characteristics of duck houses including installation of indoor circulation fan. The results showed that natural ventilation rate was averagely 164 % higher than typically designed ventilation rate, 1 AER ($min^{-1}$). Meanwhile, mechanically ventilated duck houses made 81.2 % of summer ventilation rate requirement. Therefore, it is urgent to develop a new duck house considering more structural safety as well as higher efficiency of environmental control.

Development of Standard Gas Mixtures for the Measurement of Green-house Gas (온실가스 측정을 위한 표준가스 개발)

  • 문동민;이진복;김진석;최재천;박기준;한태희;이진홍
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.11a
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    • pp.362-363
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    • 2003
  • 지구 온난화가 심화되면서 국제적으로 기후변화 협약에서는 한층 강제력 있는 온실기체의 감축목표를 권고하고 있다. 지난 1998년에 교토 기후협약에 가입한 우리나라도 실질적인 감축목표를 결정해야 하고 능동적으로 대처해야 하는바, 이를 소홀히 한다면 무역뿐만 아니라 산업활동에도 차질이 빚어질 것이다. 이를 위해 가장 기본적인 자료라 할 수 있는 온실기체($CO_2$, CH$_4$, $N_2$O, CFCs, PFCs)의 지속적이고도 체계적인 관측과 세계적으로 인정받을 수 있는 정확한 측정값의 제시가 필수적이다. (중략)

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An analysis of the fuel saving effect during low carbon flight procedures (저탄소 운항절차에 따른 연료절감 효과분석)

  • Kim, Yongseok;Lee, Juhyung
    • Journal of the Korean Society for Aviation and Aeronautics
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    • v.21 no.1
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    • pp.39-44
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    • 2013
  • The amount of greenhouse gas (GHG) emissions has been increasing steadily over the last 4 years, averaging 6.8 percent a year, due to the growth of low cost carriers and the increased demand for air transportations. For the aviation GHG reduction, various fuel saving activities are implemented in many areas such as high-efficiency aircraft and bio-fuel development in the technical part and low carbon flight procedures, short cut route development in the operational approach. Among the various reduction technologies, we focused on low carbon flight procedures that are crucial to GHG reduciton and suggested a reduction effect according to target implementation rate using by fuel saving estimation data in each aircraft type.

Biogas Reforming through Microwave Receptor Heating (마이크로웨이브 수용체 가열을 통한 바이오가스 개질)

  • Young Nam Chun;June An
    • New & Renewable Energy
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    • v.20 no.1
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    • pp.126-134
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    • 2024
  • Biogas, composed mainly of methane (CH4) and carbon dioxide (CO2), is a renewable gas that can serve as an alternative energy source. In this study, we developed a new microwave reformer and analyzed its reforming characteristics. We observed that higher temperatures of the microwave receptor led to increased reforming efficiency. By supplying appropriate amounts of methane and steam, we could prevent carbon generated from the thermal decomposition reaction of carbon dioxide from depositing on the catalytic active layer, thus avoiding the inhibition of catalytic activity. Hydrogen generation was enhanced when maintaining the biogas ratio and steam supply at adequate levels. Increasing the SiC ratio in the receptor improved the uniformity of temperature distribution and growth rate, resulting in higher conversion rates of the reforming process.

Preparation and Gas Permeability Measurements of PVDF-HFP/Ionic Liquid Gel Membranes (PVDF-HFP/이온성 액체 겔 분리막 제조 및 기체 투과도 측정)

  • Ko, Youngdeok;Park, Doohwan;Baek, Ilhyun;Hong, Seong Uk
    • Applied Chemistry for Engineering
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    • v.25 no.6
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    • pp.559-563
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    • 2014
  • It is well known that $CO_2$ can be dissolved easily in imidazolium-based room temperature ionic liquids (RTILs). Because of the high $CO_2$ solubility in RTILs, membranes containing RTILs can separate easily gas mixtures such as $CO_2/N_2$ and $CO_2/CH_4$. In this study, we prepared poly(vinylidene fluoride)-hexafluoropropyl copolymer (PVDF-HFP) gel membranes with several RTILs and measured permeabilities of several gases. When the anion of ionic liquids was tetrafluoroborate($BF{_4}^-$), both $CO_2$ permeability and selectivities decreased as the carbon number of the cation increased. When the cation of ionic liquids was 1-ethyl-3-methylimidazolium[emim], $CO_2$ permeability of gel membranes containing bis(trifluoromethane) sulfoneimide($Tf_2N^-$) anion was double compared to those containing tetrafluoroborate($BF{_4}^-$) anion. However, $CO_2/N_2$ and $CO_2/CH_4$ selectivities of the $Tf_2N^-$ case were decreased, whereas the $H_2$ selectivity was almost the same for two cases.

The Outlook of Future Aeropropulsion System (미래 항공기 추진기관의 전망)

  • Lee, Chang-Ho
    • Journal of the Korean Society of Propulsion Engineers
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    • v.13 no.3
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    • pp.58-63
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    • 2009
  • The global restriction on pollutant emissions and the soaring of crude oil price are expected to result in the change of future transportation system. Hydrogen is considered to be the leading candidate as an alternative energy source before other new alternative energy sources emerge. Scientists anticipate that hydrogen fuel gas turbine engine and fuel cell will be the power plant of the aircraft in the near future. To realize the aircraft powered by fuel cell system in the future, the technologies such as fuel cell with higher energy density, compressed gas or liquid storage system of hydrogen fuel, and efficient and lightweight electric motor have to be developed first.

A Study of Nitrous Oxide Thermal Decomposition and Reaction Rate in High Temperature Inert Gas (고온 불활성 기체 분위기에서 아산화질소 열분해 및 반응속도에 관한 연구)

  • Lee, Han Min;Yun, Jae Geun;Hong, Jung Goo
    • Journal of ILASS-Korea
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    • v.25 no.3
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    • pp.132-138
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    • 2020
  • N2O is hazardous atmosphere pollution matter which can damage the ozone layer and cause green house effect. There are many other nitrogen oxide emission control but N2O has no its particular method. Preventing further environmental pollution and global warming, it is essential to control N2O emission from industrial machines. In this study, the thermal decomposition experiment of N2O gas mixture is conducted by using cylindrical reactor to figure out N2O reduction and NO formation. And CHEMKIN calculation is conducted to figure out reaction rate and mechanism. Residence time of the N2O gas in the reactor is set as experimental variable to imitate real SNCR system. As a result, most of the nitrogen components are converted into N2. Reaction rate of the N2O gas decreases with N2O emitted concentration. At 800℃ and 900℃, N2O reduction variance and NO concentration are increased with residence time and temperature. However, at 1000℃, N2O reduction variance and NO concentration are deceased in 40s due to forward reaction rate diminished and reverse reaction rate appeared.