• Korean Journal of Materials Research
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• v.23 no.10
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• pp.592-598
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• 2013

Graphene oxide powders prepared by two different drying processes, freeze drying and spray drying, were studied to compare the effect of the drying method on the physical properties of graphene oxide powder. The graphene oxide dispersion was prepared from graphite by chemical delamination with the aid of sulfuric acid and permanganic acid, and the dispersion was further washed and re-dispersed in a mixed solvent of water and isopropyl alcohol. A freeze drying method can feasibly minimize damage to the sample, but it requires a long process time. In contrast, spray drying is able to remove a solvent in a relatively short time, though this process requires exposure to a high temperature for a rapid evaporation of the solvent. The powders prepared by freeze drying and spray drying were characterized and compared by Raman spectroscopy, X-ray diffraction, field-emission scanning electron microscopy, transmission electron microscopy, and by an elemental analysis. The graphene oxide powders showed similar chemical compositions; however, the morphologies of the powders differed in that the graphene oxide prepared by spray drying had a winkled morphology and a higher apparent density compared to the powder prepared by freeze drying. The graphene oxide powders were reduced at $900^{\circ}C$ in an atmosphere of $N_2$. The effect of the drying process on the properties of the reduced graphene oxide was examined by SEM, TEM and Raman spectroscopy.

• Carbon letters
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• v.11 no.2
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• pp.90-95
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• 2010

Carbon materials such as graphite and graphene exhibit high electrical conductivity. We examined the electrical conductivity of synthetic and natural graphene powders after the chemical reduction of synthetic and natural graphite oxide from synthetic and natural graphite. The trend of electrical conductivity of both graphene (synthetic and natural) was compared with different graphite materials (synthetic, natural, and expanded) and carbon nanotubes (CNTs) under compression from 0.3 to 60 MPa. We found that synthetic graphene showed a marked increment in electrical conductivity compared to natural graphene. Interestingly, the total increment in electrical conductivity was greater for denser graphite; however, an opposite behavior was observed in nanocarbon materials such as graphene and CNTs, probably due to the differing layer arrangement of nanocarbon materials.

• Computers and Concrete
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• v.25 no.4
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• pp.283-291
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• 2020

The present paper researches post-buckling behaviors of geometrically imperfect concrete beam resting on elastic foundation reinforced with graphene oxide powders (GOPs) based on finite element method (FEM). Distribution of GOPs are considered as uniform and linearly graded through the thickness. Geometric imperfection is considered as first buckling mode shape of the beam, the GOP reinforced beam is rested in initial position. The material properties of GOP reinforced composite have been calculated via employment of Halpin-Tsai micromechanical scheme. The provided refined beam element verifies the shear deformation impacts needless of any shear correction coefficient. The post-buckling load-deflections relations have been calculated via solving the governing equations having cubic non-linearity implementing FEM. Obtained findings indicate the importance of GOP distributions, GOP weight fraction, matrix material, geometric imperfection, shear deformation and foundation parameters on nonlinear buckling behavior of GOP reinforced beam.

• Journal of Powder Materials
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• v.26 no.5
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• pp.383-388
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• 2019

To improve the mechanical properties of aluminum, graphene has been used as a reinforcing material, yielding graphene-reinforced aluminum matrix composites (GRAMCs). Dispersion of graphene materials is an important factor that affects the properties of GRAMCs, which are mainly manufactured by mechanical mixing methods such as ball milling. However, the use of only mechanical mixing process is limited to achieve homogeneous dispersion of graphene. To overcome this problem, in this study, we have prepared composite materials by coating aluminum particles with graphene by a self-assembly reaction using poly vinylalcohol and ethylene diamine as coupling agents. The scanning electron microscopy and Fourier-transform infrared spectroscopy results confirm the coating of graphene on the Al surface. Bulk density of the sintered composites by spark plasma sintering achieved a relative density of over 99% up to 0.5 wt.% graphene oxide content.

• Computers and Concrete
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• v.26 no.1
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• pp.21-30
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• 2020

Buckling and post-buckling behaviors of geometrically imperfect annular sector plates made from nanoparticle reinforced composites have been investigated. Two types of nanoparticles are considered including graphene oxide powders (GOPs) and silicone oxide (SiO₂). Nanoparticles are considered to have uniform and functionally graded distributions within the matrix and the material properties are derived using Halpin-Tsai procedure. Annular sector plate is formulated based upon thin shell theory considering geometric nonlinearity and imperfectness. After solving the governing equations via Galerkin's technique, it is showed that the post-buckling curves of annular sector plates rely on the geometric imperfection, nanoparticle type, amount of nanoparticles, sector inner/outer radius and sector open angle.

• Advances in nano research
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• v.13 no.5
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• pp.427-435
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• 2022

Static stability behaviors of annular sandwich plates constructed from two layers of particle-reinforced nanocomposites have been investigated in the present article. The type of nanoscale particles has been considered to be graphene oxide powders (GOPs). The particles are assumed to have uniform and graded dispersions inside the matrix and the material properties have been defined according to Halpin-Tsai micromechanical model. The core layer is assumed to have honeycomb configuration. Annular plate has been formulated according to thin shell assumptions considering geometrical nonlinearities. After solving the governing equations via Galerkin's technique, it is showed that the post-buckling curves of annular sandwich plates rely on the core wall thickness, amount of GOP particles, sector radius, and thickness of layers.

• Journal of Powder Materials
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• v.23 no.4
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• pp.263-269
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• 2016

Graphene oxide (GO) powder processed by Hummer's method is mixed with p-type $Bi_2Te_3$ based thermoelectric materials by a high-energy ball milling process. The synthesized GO-dispersed p-type $Bi_2Te_3$ composite powder has a composition of $Bi_{0.5}Sb_{1.5}Te_3$ (BSbT), and the powder is consolidated into composites with different contents of GO powder by using the spark plasma sintering (SPS) process. It is found that the addition of GO powder significantly decreases the thermal conductivity of the pure BSbT material through active phonon scattering at the newly formed interfaces. In addition, the electrical properties of the GO/BSbT composites are degraded by the addition of GO powder except in the case of the 0.1 wt% GO/BSbT composite. It is found that defects on the surface of GO powder hinder the electrical transport properties. As a result, the maximum thermoelectric performance (ZT value of 0.91) is achieved from the 0.1% GO/BSbT composite at 398 K. These results indicate that introducing GO powder into thermoelectric materials is a promising method to achieve enhanced thermoelectric performance due to the reduction in thermal conductivity.

• Structural Engineering and Mechanics
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• v.83 no.4
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• pp.465-473
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• 2022

In this research, a numerical study has been provided for examining the nonlinear stability behaviors of sandwich beams having a cellular core and two face sheets made of nanocomposites. The nonlinear stability behaviors of the sandwich beam having geometrically perfect/imperfect shapes have been studied when it is subjected to a compressive buckling load. The nanocomposite face sheets are made of epoxy reinforced by graphene oxide powders (GOPs). Also, the core has the shape of a honeycomb with regular configuration. Using finite element method based on a higher-order deformation beam element, the system of equations of motions have been solved to derive the stability curves. Several parameters such as face sheet thickness, core wall thickness, graphene oxide amount and boundary conditions have remarkable influences on stability curves of geometrically perfect/imperfect sandwich beams.

• Journal of the Microelectronics and Packaging Society
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• v.26 no.3
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• pp.43-49
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• 2019

In this study, a new approach using graphene oxide (GO) powder-composited Sn-3.0Ag-0.5Cu(in wt.%) solder paste for improving the bending reliability of solder joints between a flexible substrate and small outline package (SOP) was suggested. The GO addition slightly affected the melting temperature, however, the change in the melting temperature was not significant. Meanwhile, we observed the addition of GO could suppress IMC growth and IMC thickness of solder joint during the reflow process. Moreover, the cyclic bending test was also performed for evaluation of reliability in solder joint and we could improve the cyclic bending reliability of solder joint by adding GO powders. For 0.2 wt.% of GO added to the solder joint, the bending lifetime was increased to 20% greater than that without GO. Pull strength and ductility of the solder joint with GO were also higher than those of the joint without GO and it was assumed that this effect by adding GO could contribute to improve cyclic bending reliability of solder joint.

• Advances in nano research
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• v.13 no.2
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• pp.113-120
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• 2022

In this paper, a finite element (FE) simulation has been developed in order to examine the nonlinear stability of reinforced sandwich beams with graphene oxide powders (GOPs). In this regard, the nonlinear stability curves have been obtained asuming that the beam is under compressive loads leading to its buckling. The beam is considered to be a three-layered sandwich beam with metal core and GOP reinforced face sheets and it is rested on elastic substrate. Moreover, a higher-order refined beam theory has been considered to formulate the sandwich beam by employing the geometrically perfect and imperfect beam configurations. In the solving procedure, the utalized finite element simulation contains a novel beam element in which shear deformation has been included. The calculated stability curves of GOP-reinforced sandwich beams are shown to be dependent on different parameters such as GOP amount, face sheet thickness, geometrical imperfection and also center deflection.