• Title/Summary/Keyword: granular size fraction

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Evaluation of Granular Activated Carbon Process Focusing on Molar mass and size distribution of DOM (DOM의 분자량과 크기분포에 따른 입상활성탄 공정의 평가)

  • Chae, Seon H.;Lee, Kyung H .
    • Journal of Korean Society of Water and Wastewater
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    • v.22 no.1
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    • pp.31-38
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    • 2008
  • The primary objective of this study was to evaluate the variation of the molecular size distribution by granular activated carbon (GAC) adsorption. GAC adsorption was assessed by using the rapid small-scale column test (RSSCT) and high-performance size-exclusion chromatography (HPSEC) was used to analyze the molecular size distribution (MSD) in the effluent of GAC column. RSSCT study suggested that GAC adsorption exhibited excellent interrelationship between dissolved organic carbon (DOC) breakthrough and MSD as function of bed volumes passed. After GAC treatment, the nonadsorbable fraction which was about 25percents of influent DOC corresponded to the hydrophilic (HPI) natural organic carbon (NOM) of NOM fractions and was composed entirely of <300 molecular weight (MW) in the HPSEC at the initial stage of the RSSCT operation. The dominant MW fraction in the source water was 1,000~5,000daltons. At the bed volumes 2,500, MW <500 of GAC treated water was risen rather than it of source water. After the bed volumes 7,300 of operation, the MW 1,000~3,000 fraction was closed to about 80percents of DOC found in the GAC influent. The Number-average molecular weight (Mn) value determined using HPSEC for the effluent of GAC column was gently increased as DOC breakthrough progress. The quotient p(Mw/Mn) can be used to estimate the degree of polydispersity was shown greatest value for the GAC effluent at the initial stage of the RSSCT operation.

Differentiation in Nitrogen-Converting Activity and Microbial Community Structure between Granular Size Fractions in a Continuous Autotrophic Nitrogen Removal Reactor

  • Qian, Feiyue;Chen, Xi;Wang, Jianfang;Shen, Yaoliang;Gao, Junjun;Mei, Juan
    • Journal of Microbiology and Biotechnology
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    • v.27 no.10
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    • pp.1798-1807
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    • 2017
  • The differentiations in nitrogen-converting activity and microbial community structure between granular size fractions in a continuous completely autotrophic nitrogen removal over nitrite (CANON) reactor, having a superior specific nitrogen removal rate of $0.24g/(g\;VSS{\cdot}h)$, were investigated by batch tests and high-throughput pyrosequencing analysis, respectively. Results revealed that a high dissolved oxygen concentration (>1.8 mg/l) could result in efficient nitrite accumulation with small granules (0.2-0.6 mm in diameter), because aerobic ammonium-oxidizing bacteria (genus Nitrosomonas) predominated therein. Meanwhile, intermediate size granules (1.4-2.0 mm in diameter) showed the highest nitrogen removal activity of $40.4mg/(g\;VSS{\cdot}h)$ under sufficient oxygen supply, corresponding to the relative abundance ratio of aerobic to anaerobic ammonium-oxidizing bacteria (genus Candidatus Kuenenia) of 5.7. Additionally, a dual substrate competition for oxygen and nitrite would be considered as the main mechanism for repression of nitrite-oxidizing bacteria, and the few Nitrospira spp. did not remarkably affect the overall performance of the reactor. Because all the granular size fractions could accomplish the CANON process independently under oxygen limiting conditions, maintaining a diversity of granular size would facilitate the stability of the suspended growth CANON system.

Characterization of Thermal Properties for Glass Beads - Rubber Mixture (글라스 비즈 - 고무 분말 혼합물의 열전달 특성 연구)

  • Lee, Jung-Hwoon;Yun, Tae-Sup;Evans, T. Matthew
    • Journal of the Korean Geotechnical Society
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    • v.27 no.11
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    • pp.39-45
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    • 2011
  • This study presents the thermal behaviors of glass beads-rubber mixtures depending on the volumetric fraction of each constituent and relative size between them. The transient plane source method is used to measure the effective thermal conductivity of mixtures. The discrete element method (DEM) and the thermal network model are integrated to investigate the particle-scale mechanism of heat transfer in granular packings. Results show that 1) the effective thermal conductivity decreases as the rubber fraction increases, and 2) the relative size between two solid particles dominates the spatial configuration of inter-particle contact condition that in tum determines the majority of heat propagation path through particle contacts. For the mixtures whose volumetric fraction of rubber is identical, the less conductive materials (e.g., rubber particles) with a large size facilitate heat transfer in granular materials. The experimental results and particle-scale observation highlight that the thermal conduction behavior is dominated not only by the volumetric fraction but also the spatial configuration of each constituent.

Effect of Vanadium and Boron on Microstructure and Low Temperature Impact Toughness of Bainitic Steels (베이나이트강의 미세조직과 저온 충격 인성에 미치는 바나듐과 보론의 영향)

  • Huang, Yuanjiu;Lee, Hun;Cho, Sung Kyu;Seo, Jun Seok;Kwon, Yongjai;Lee, Jung Gu;Shin, Sang Yong
    • Korean Journal of Materials Research
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    • v.31 no.3
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    • pp.139-149
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    • 2021
  • In this study, three kinds of bainitic steels are fabricated by controlling the contents of vanadium and boron. High vanadium steel has a lot of carbides and nitrides, and so, during the cooling process, acicular ferrite is well formed. Carbides and nitrides develop fine grains by inhibiting grain growth. As a result, the low temperature Charpy absorbed energy of high vanadium steel is higher than that of low vanadium steel. In boron added steel, boron segregates at the prior austenite grain boundary, so that acicular ferrite formation occurs well during the cooling process. However, the granular bainite packet size of the boron added steel is larger than that of high vanadium steel because boron cannot effectively suppress grain growth. Therefore, the low temperature Charpy absorbed energy of the boron added steel is lower than that of the low vanadium steel. HAZ (heat affected zone) microstructure formation affects not only vanadium and boron but also the prior austenite grain size. In the HAZ specimen having large prior austenite grain size, acicular ferrite is formed inside the austenite, and granular bainite, bainitic ferrite, and martensite are also formed in a complex, resulting in a mixed acicular ferrite region with a high volume fraction. On the other hand, in the HAZ specimen having small prior austenite grain size, the volume fraction of the mixed acicular ferrite region is low because granular bainite and bainitic ferrite are coarse due to the large number of prior austenite grain boundaries.

Microstructure of Semi-solid A356 Alloys made Using Cooling Plate (냉각판을 이용한 반응고 A356합금의 미세조직)

  • 엄정필;김득규;윤병은;임수근
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 1997.06a
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    • pp.148-159
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    • 1997
  • In this study, microstructure, size of primary $\alpha$, solid fraction and hardness of A356 Al alloy, were investigated. Semi-solid A356 allos were obtained by semi-solid continuous casting apparatus consists of melting furnace, formation apparatus of granular primary $\alpha$ and continuous casting apparatus. Size of promary $\alpha$ and fraction solid were decreased with decreasing temperature, and with increasing volume of cooling water. At the cooling water temperature of 15$^{\circ}C$ and cooling water volume of 18.2$\ell$/min, the sizes of primary $\alpha$ phases were decreased up to 40${\mu}{\textrm}{m}$, and fraction solid was 0.68.

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Effect of particle size on direct shear deformation of soil

  • Gu, Renguo;Fang, Yingguang;Jiang, Quan;Li, Bo;Feng, Deluan
    • Geomechanics and Engineering
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    • v.28 no.2
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    • pp.135-143
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    • 2022
  • Soils are natural granular materials whose mechanical properties differ according to the size and composition of the particles, so soils exhibit an obvious scale effect. Traditional soil mechanics is based on continuum mechanics, which can not reflect the impact of particle size on soil mechanics. On that basis, a matrix-reinforcing-particle cell model is established in which the reinforcing particles are larger-diameter sand particles and the matrix comprises smaller-diameter bentonite particles. Since these two types of particles deform differently under shear stress, a new shear-strength theory under direct shear that considers the stress concentration and bypass phenomena of the matrix is established. In order to verify the rationality of this theory, a series of direct shear tests with different reinforcing particle diameter and volume fraction ratio are carried out. Theoretical analysis and experimental results showed that the interaction among particles of differing size and composition is the basic reason for the size effect of soils. Furthermore, the stress concentration and bypass phenomena of the matrix enhance the shear strength of a soil, and the volume ratio of reinforcing particles has an obvious impact on the shear strength. In addition, the newly proposed shear-strength theory agrees well with experimental values.

Effect of Carbon on the Micro Structure and Hardness of Internally Hardened Ductile Cast Iron Roll (내부 경화형 구상흑연주철 롤 동체와 넥의 미세조직과 경도에 미치는 탄소 영향)

  • Sang-Mook Lee;Ki-Hang Shin;Byung-Chul Choi;Ki-Woo Nam
    • Journal of the Korean Society of Industry Convergence
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    • v.26 no.1
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    • pp.79-86
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    • 2023
  • This study was investigated the effect of carbon on the micro-structure and hardness of ductile cast iron roll with internal curing capacity. Spheroidal graphite existed at roll body with rapid cooling, but granular graphite existed at roll neck with slow cooling. The volume fraction of graphite increased at roll body with rapid cooling, That of roll neck with slow cooling decreased, but graphite size increased. The volume fraction of cementite decreased, but volume fraction increased. The cementite size was larger at roll neck than roll body. The hardness was decreased at roll body and roll neck due to volume fraction of cementite. The hardness of roll body was higher than roll neck.

Role of Detached Particles During Initial Filtration Phase (여과초기에서의 탈착된 입자의 거동)

  • Kim, Ja-Kyum;Tobiason, John E.
    • Journal of Korean Society of Water and Wastewater
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    • v.19 no.1
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    • pp.16-24
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    • 2005
  • Mathematical model was developed to verify a sequential particle removal taking place in a granular media gravity filter. Consequential multi-layer filtration cycle model was applied to verify the fraction of filter effluent particles that are filter influent particles that were never removed as well as the fraction of filter effluent particles that were detached after deposition were performed through laboratory experiments. Three sizes of marker particles were injected ahead of the filter column as a pulse in the presence of four sizes of polystyrene particles that were used as a primary source of particles in the raw suspension to investigate particle attachment alone in contrast to net removal from attachment and detachment. Microscopic counting of filter effluent particles was assumed to reflect attachment. Experimental results indicated that particle detachment is significant beginning from the early phase of filtration. For each size of fluorescent microspheres at one filter depth, fluorescent microsphere removal increased with filter runtime to a maximum due to ripening. The detached fraction of effluent particles increased with particle size and filter depth. The presence of detached particles and the increasing fraction of detached particles in deeper bed were confirmed.