• 제목/요약/키워드: glaze

검색결과 213건 처리시간 0.032초

Ceramic Ink-jet Printing on Glass Substrate Using Oleophobic Surface Treatment

  • Lee, Ji-Hyeon;Hwang, Hae-Jin;Kim, Jin-Ho;Hwang, Kwang-Taek;Han, Kyu-Sung
    • Journal of the Korean Ceramic Society
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    • 제53권1호
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    • pp.75-80
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    • 2016
  • Ink-jet printing has become a widespread technology with the society's increase in aesthetic awareness. Especially, ink-jet printing using glazed ceramic ink can offer huge advantages including high quality decoration, continuous processing, glaze patterning, and direct reproduction of high resolution images. Recently, ceramic ink-jet printing has been rapidly introduced to decorate the porcelain product and the ceramic tiles. In this study, we provide an effective method to apply ceramic ink-jet decorations on the glass substrates using a oleophobic coating with perfluorooctyl trichlorosilane. The ink-jet printed patterns were much clearer on the oleophobically coated glass surface than the bare glass surface. The contact angle of the ceramic ink was maximized to the value of $64.0^{\circ}$ on the glass surface, when it was treated with 1 vol% PFTS solution for 1 min. The effects of the printing conditions and firing process on the ink-jet printed patterns on the oleophobically coated glass were also investigated.

Effect of Modifiers on the Electrical Resistivity of $SiO_2-Al_2O_3-B_2O_3-RO-Na_2O$ Glasses ($SiO_2-Al_2O_3-B_2O_3-RO-Na_2O$계 유리의 전지저항에 미치는 수식체의 영향)

  • 김대기;김철영
    • Journal of the Korean Ceramic Society
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    • 제33권4호
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    • pp.385-390
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    • 1996
  • The electrical resistivity of the ceramic glaze coated on ceramic substrate plays an important role on the characteristics of the thick and thin film electrical circuits. In this study the effects of the various modifiers on the electrical resistivity were examined in SiO2-Al2O3-B2O3-RO-Na2O (RO=CaO , SrO, BaO, PbO) glass system. In alkali free glasses where divalent cations are responsible for electrical conduction the electrical conductivity of th glasses increased with the ionic size of divalent cations due to the decrease in the bond strength between oxyben and divalent cation. In Na2O containing glasses however where Na+ ion is responsible for electrical conduction the ionic conductivity decreased with the ionic size of divalent cations because the blocking effect of the cations on Na+ ion movement increased with larger divalent cations. Na+ ionic conduction also depended on the glass structure relaxation due to the corrdination number changes of B2O3 and Al2O3 which varied with the NaO2 content in the glass.

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Effect of TiO2 on the Color Generation in Celadon Glaze (산화티타늄이 청자유약의 발색에 끼치는 영향에 관한 연구)

  • No, Hyunggoo;Kim, Ungsoo;Kim, Jongyoung;Cho, Wooseok;Kim, Chulsung;Kim, Chinmo
    • Journal of the Korean Ceramic Society
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    • 제51권3호
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    • pp.150-155
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    • 2014
  • In aprevious study, the mutual interaction between $Fe_2O_3$ and $TiO_2$ was found to influence the color of celadon glaze. Celadon samples were prepared with varying concentrations of $TiO_2$ at a fixed level of $Fe_2O_3$. The electronic states of Fe and Ti were analyzed by M$\ddot{o}$ssbauer spectroscopy and electron spin-resonance spectroscopy, respectively. These results were examined with the celadon colors measured according to CIELAB values. This study revealed that an increase of $Ti^{3+}$ in the glassy phase decreased the $Fe^{2+}/Fe^{3+}$ ratio, resulting in a color change of the celadon samples in the GY and Y groups. The maximum reflectance wavelength was shifted from 505 nm to 610 nm with an increase in the $TiO_2$ concentration.

A Scientific Study for Physical Properties of Celadon in Firing Experiment (소성실험을 통한 청자의 물리적 특성 변화 연구)

  • Han, Min-su;Hong, Jong-Uk;Park, Ji-hee
    • 보존과학연구
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    • 통권27호
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    • pp.145-163
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    • 2006
  • This study is to be investigated through firing experiment in studio in order to reveal a physical properties of celadon according to change firing temperature. The results can be briefly summarized as below; Firstly, in measurement of color chromaticity, samples of first firing in body were effective in differentiating of changed color in samples from each other but there of second firing were not. The color of the glaze was more effective change than that of the body. Secondly, bulk density of body was increased with temperature and it was attained highest point in $1200^{\circ}C$ Additionally, water absorption ratio was most rapidly changed between $1000^{\circ}C$ and $1200^{\circ}C$Thirdly, in the microstructural analysis, body of samples in first firing have not specific characteristics in the changed patterns of microstructure. body and glaze of samples in second firing have many that. Consequently, we knew that this experiment can be provided researcher with physical properties and firing mechanisms of celadon.

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Tribological Behavior of Whiteware with Different Transparent Glazes

  • Heo, Sujeong;Kim, Soomin;Kim, Ungsoo;Pee, Jaehwan;Han, Yoonsoo;Kim, Seongwon;Lee, Sungmin;Kim, Hyungtae;Oh, Yoonsuk
    • Journal of the Korean Ceramic Society
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    • 제52권3호
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    • pp.186-191
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    • 2015
  • Tribological properties of whiteware with various transparent glazes, which have different composition and microstructure, were investigated. The wear resistance and friction behavior of the glazed whiteware are a very important aspect if the whiteware is used as tableware and for sanitation purposes. Generally, the wear property is influenced by the microstructure and surface morphology of the material. The whiteware specimens with two kinds of transparent glazes were fabricated by using the commercially available porcelain body. Furthermore, the commercial tableware, such as bone china, and traditional tableware were also examined as reference materials. All of the specimens showed that different pore structures might affect the mechanical and tribological properties. It seems that the wear resistance of whiteware is substantially related to the pore size and distribution of glaze rather than the hardness value of the specimen.

Effect of sintering programs and surface treatments on monolithic zirconia

  • Seren Nur Dokuzlu ;Meryem Gulce Subasi
    • The Journal of Advanced Prosthodontics
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    • 제16권1호
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    • pp.25-37
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    • 2024
  • PURPOSE. To investigate the effect of sintering programs and surface treatments on surface properties, phase transformation and flexural strength of monolithic zirconia. MATERIALS AND METHODS. Zirconia specimens were sintered using three distinct sintering programs [classic (C), speed (S), and superspeed (SS)] (n = 56, each). One sample from each group underwent scanning electron microscopy (SEM) and grain size analysis following sintering. Remaining samples were divided into five subgroups (n = 11) based on the surface treatments: control (CL), polish (P), glaze (G), grind + polish (GP), and grind + glaze (GG). One sample from each subgroup underwent SEM analysis. Remaining samples were thermally aged. Monoclinic phase volume, surface roughness, and three-point flexural strength were measured. Monoclinic phase volume and surface roughness were analyzed by Kruskal-Wallis and Dunn tests. Flexural strength was analyzed by two-way ANOVA and Weibull analysis. The relationships among the groups were analyzed using Spearman's correlation analysis. RESULTS. Sintering program, surface treatment, and sintering × surface treatment (P ≤ .010) affected the monoclinic phase volume, whereas the type of surface treatment and sintering × surface treatment affected the surface roughness (P < .001). Type of sintering program or surface treatment did not affect the flexural strength. Weibull analysis revealed no significant differences between the m and σo values. Monoclinic phase volume was positively correlated with surface roughness in the SGG and SSP groups. CONCLUSION. After sintering monolithic zirconia in each of the three sintering programs, each of the surface treatments can be used. However, for surface quality and aging resistance, G or GG can be recommended as a surface finishing method.

A Study of the Chemical Composition of Korean Traditional Ceramics (III): Comparison of Punch'$\breve{o}$ng with Kory$\breve{o}$ Ware and Chos$\breve{o}$n Whiteware (한국 전통 도자기의 화학 조성에 대한 연구 (III): 분청에 대한 고려자기와 조선백자와의 비교)

  • KohChoo, Carolyn Kyong-Shin;Choo, Woong-Kil;Ahn, Sang-Doo;Lee, Young-Eun;Kim, Gyu-Ho;Lee, Yeon-Sook
    • Journal of Conservation Science
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    • 제27권1호
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    • pp.75-90
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    • 2011
  • At the beginning of the Chos$\breve{o}$n dynasty, punch'$\breve{o}$ng began as a simplified form of inlaid celadon, and in the two following centuries it developed into a popular folk craft in various styles and expressive decorations; overtime, it was increasingly made to resemble whiteware, and its production stopped after the Japanese invasion of Korea. In the present study, the body and glaze compositions of punch'$\breve{o}$ng were examined and compared with those of celadon and whiteware, whose compositions have previously been compared with those of Chinese ceramics. Here, the analyzed shards were organized into 28 groups based on their production sites and archaeological characteristics. For each group, the body and glaze compositions of several shards(usually three to five) were obtained, averaged, and compared with those of the other groups. These comparisons showed that the majority of the punch'$\breve{o}$ng bodies were formed, like those of celadon and whiteware, with mica-quartz porcelain stone, which was commonly used in Yuezhou, Jingdezhen, and other southern Chinese kilns. The glazes consisted of clay materials and flux components made from various proportions of wood ash, burnt limestone (glaze ash) and crushed limestone. Overall, the punch'$\breve{o}$ng glazes resembled the Kory$\breve{o}$ celadon and Kory$\breve{o}$ whiteware glazes more closely than the Chos$\breve{o}$n white wareglazes. However, the $TiO_2$ levels found in the tested punch'$\breve{o}$ng were low, similar to those of Chos$\breve{o}$n whiteware; this indicated that glaze stone was used as the clay component of the punch'$\breve{o}$ng glazes, as was the case for Chos$\breve{o}$n whiteware. This study of the material characteristics of punch'$\breve{o}$ng may be used as a comparative framework for analyzing ceramic shards discovered at current and future excavations within Korea.

A Study on Sensibility Evaluation of Ceramic Surface: Comparison between Tactility and Visual Tactility (세라믹 표면의 감성 평가 연구: 촉감과 시각적 촉감의 비교를 중심으로)

  • Kim, Jihyun;Song, Min Jeong
    • Science of Emotion and Sensibility
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    • 제19권2호
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    • pp.101-112
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    • 2016
  • Selecting appropriate materials can be significantly important to make different image in the product and also give distinguished express to the users. A material for the ceramic product surface consists of the combination between a glaze and a body, and each attribution of materials and the way of the combination creates different texture and color. This study analyzes the difference between visually and tactually sensibility of ceramic surface to through the simulating both visual and tactual stimulation by verbal evaluation method. Totally 13 adjectives are selected from homepage of local and global ceramic product brand. And totally 12 ceramic samples are created with the consideration of color, glossiness and roughness. These 12 samples are the combination between four ceramic bodies (White porcelain, Celadon_c, Sancheong and Black soil) and three glazes (Transparent, Celadon_g, Black glaze). The respondents of first survey were asked to rub, touch and hold before evaluating the sensibility of ceramic surface and other respondents of second survey were asked to evaluate visual images of 9 samples which showed meaningfully difference from first survey. The surface which scored the highest sensibility with the first survey was 'pure' on a surface of White porcelain body with Transparent glaze, and the lowest was also 'pure' on a surface of Black soil body with Transparent glaze. The highest score in the second survey was the same result as the first survey, but the lowest scored 'casual' and the surface was Black soil body with Celadon glaze. By the comparison with two survey results, not every sensibility is same result shown as the first survey and the second survey, but the tactile sensibilities such as 'artistic', 'luxurious', 'sensuous', 'romantic' and 'mysterious' can be experienced by via visual materials of ceramic surfaces.

Characteristics Analysis of on Blackware and Whiteware at Excavated Kiln in Gilmyeong-ri Pocheon-si Gyeonggi-do, Korea (경기도 포천시 길명리 가마터 출토 흑유자기와 백자에 대한 특성분석)

  • Koh, Min-Jeong;Kim, Gyu-Ho
    • Journal of Conservation Science
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    • 제22권
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    • pp.43-60
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    • 2008
  • This study is investigated the characteristics and the comparison on blackware and whiteware at Gilmyeong-ri kilns, located Poncheon-si, Geonggi province at AD 19c using scientific analysis. It is measured by scientific analysis classified as microstructure observation, physical methods which involved chromaticity, specific gravity, absorption ratio and porosity, and chemical analysis of components of body and glaze. As a result, a particle and a pore of body surface appeared differently by the degree of vitrification. In glaze, Blackware have better on good vitrification than whiteware in the microstructure observation. The physical characteristics of chromaticity, specific gravity, absorption ratio and porosity differed according to degree of vitrification rather than porcelain types. In composition, body of blackware have higher ratio of $Fe_2O_3$ and $TiO_2$ than of whiteware. Also glaze of blackware have higher ratio of $Fe_2O_3$ and $TiO_2$, and lower ratio of $SiO_2$ and $Al_2O_3$ than whiteware. Especially, blackware have higher ratio in the composition of CaO and $P_2O_5$ by which ash is used or not.

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