• 제목/요약/키워드: glass structure

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생체 유리의 구조 및 물성에 미치는 Al2O3의 영향 (Effect of Al2O3 on the Structure and Properties of Bioglass)

  • 노종남;황진명;김철영
    • 한국세라믹학회지
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    • 제26권6호
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    • pp.811-819
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    • 1989
  • There have been many studies on the biological phenomena of Bioglasses, which nay be used as implant materials in human body. However, not many works on the Bioglass compositions have been reported. In the present study, the effect of Al2O3 substitution for SiO2 in Bioglass of Na2O-CaO-P2O5-SiO2 system on its structure and properties was examined. Infrared and Raman spectroscopic studies for the glass structural analysis, differential thermal analysis and X-ray diffraction analysis for crystallization of the glass were perfomed. Several physical properties, such as thermal expansion coefficient, softening point, microhardness and reaction phenomena, were also measured. The major crystalline phase, after heat treatment of the glasses, was Na2Ca2(SiO2)3 and the crystal was transformed into other phase with increased substitution of Al2O3. The added Al2O3 reduced non-bridging oxygen in glass structure and thermal expansion coefficient, but increased glass density, sofening point and microhardness. When the glasses are reacted in Tris-buffer solution, the substituted Al2O3 inhibited the formation of hydroxyapatite on the Bioglas surface, and no hydroxyapatite was formed for the sample which contained more than 6wt.% of Al2O3 even if they were reacted for 600 hours.

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다층 그래핀/유리 구조체의 적외선 열복사 특성 연구 (Thermal Radiative Properties of Multilayer Graphene/Glass Structure)

  • 박경아;임미경;정현준;김재현
    • 한국전기전자재료학회논문지
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    • 제34권1호
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    • pp.27-32
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    • 2021
  • In this study, we fabricated multilayer graphene on a glass substrate by stacking the monolayer graphene synthesized via chemical vapor deposition. The electrical sheet resistance and optical transmittance were evaluated to confirm the quality of the stacked multilayer graphene. Using the fabricated multilayer graphene/glass structure, we characterized its thermal radiative property in terms of the integrated emissivity. The integrated emissivity of the multilayer graphene/glass structure was tuned from 0.91 to 0.72 when the number of graphene layers was changed from 1 to 12. We also demonstrated that the emissivity tunability provided a way to control the apparent temperature of an object that can be used in infrared stealth applications.

Thermoforming용 長纖維强化 複合材料의 成形工程에 관한 硏究 分離$\cdot$配向의 相關계수 (A Study on the Processing of Long Fiber-Reinforced Composite Materials for Thermoforming On the Correlation Coefficient between Separation and Orientation)

  • 이동기;김정락;김상필;이우일;김이곤
    • 대한기계학회논문집
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    • 제17권5호
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    • pp.1106-1114
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    • 1993
  • 본 연구에서는우수한 섬유강화 고분자복합판의 제조 및 개량을 섬유구조의 분리. 배향의 관점에서 연구한다. 유리섬유매트는 유리섬유를 50mm의 길이로 균일하 게 절단하여 공기중에서 분산시켜 6~7mm두께로 만들고,이 유리섬유매트를 바늘의 종류와 스트레칭 횟수에 따라 니들펀칭하여 유리섬유의 매트구조를 변화시킨다. 유리 섬유의 매트구조 별로 모재와 적층시킨 다음 열압축프레스를 사용하여 1차로 시이트를 제작하고, 이 제작된 시이트를 가열로로 가열하여 2차 고온압축 프레스성형한다. 이 때 섬유와 모재의 분리 및 배향의 상관관계를 나타내는 상관계수를 구하고, 이 계수에 미치는 매트 구조의 영향에 대한 실험결과를 보고한다.

An approach to a novel modelling of structural reinforced glass beams in modern material components

  • Foti, Dora;Carnimeo, Leonarda;Lerna, Michela;Sabba, Maria Francesca
    • Advances in Computational Design
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    • 제7권3호
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    • pp.173-188
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    • 2022
  • In modern buildings, glass is considered a structurally unsafe material due to its brittleness and unpredictable failure behavior. The possible use of structural glass elements (i.e., floors, beams and columns) is generally prevented by its poor tensile strength and a frequent occurrence of brittle failures. In this study an innovative modelling based on an equivalent thickness concept of laminated glass beam reinforced with FRP (Fiber Reinforced Polymer) composite material and of glass plates punched is presented. In particular, the novel numerical modelling applied to an embedding Carbon FRP-rod in the interlayer of a laminated structural glass beam is considered in order to increase both its failure strength, together with its post-failure strength and ductility. The proposed equivalent modelling of different specimens enables us to carefully evaluate the effects of this reinforcement. Both the responses of the reinforced beam and un-reinforced one are evaluated, and the corresponding results are compared and discussed. A novel equivalent modelling for reinforced glass beams using FRP composites is presented for FEM analyses in modern material components and proved estimations of the expected performance are provided. Moreover, the new suggested numerical analysis is also applied to laminated glass plates with wide holes at both ends for the technological reasons necessary to connect a glass beam to a structure. Obtained results are compared with an integer specimen. Experimental considerations are reported.

A method for predicting approximate lateral deflections in thin glass plates

  • Xenidis, H.;Morfidis, K.;Papadopoulos, P.G.
    • Structural Engineering and Mechanics
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    • 제53권1호
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    • pp.131-146
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    • 2015
  • In the present paper a three-dimensional non-linear truss element and a short computer program for the modeling and predicting approximate lateral deflections in thin glass plates by the method of incremental loading are proposed. Due to the out-of-plane large deflections of thin glass plates compared to the plate thickness within each loading increment, the equilibrium and stiffness conditions are written with respect to the deformed structure. An application is presented on a thin fully tempered monolithic rectangular glass plate, laterally supported around its perimeter subjected to uniform wind pressure. The results of the analysis are compared with published experimental results and found to have satisfactory approximation. It is also observed that the large deflections of a glass plate lead to a part substitution of the bending plate behavior by a tensioned membrane behavior which is favorable.

EAF dust가 포함된 붕규산염계 결정화 유리의 구조 및 화학적 내구성 (Structure and chemical durability of borosilicate glass-ceramics containing EAF dust)

  • 안영수;강승구
    • 한국결정성장학회지
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    • 제17권2호
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    • pp.82-89
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    • 2007
  • 붕규산염계 유리에 EAF Dust를 $40{\sim}80wt%$ 첨가하고 후 용융하여 유리를 제조한 후 $700^{\circ}C$/10hr으로 열처리하여 결정화유리 시편을 합성하였다. FT-IR, SEM, 그리고 EDS 분석을 통하여 조성 및 열처리 조건에 따른 시편내 결정상 및 결합상태 변화를 관찰하고, 이를 TCLP(Toxic Characterization Leaching Procedure) 실험에서 얻은 결과와 연계시켜 시편의 화학적 내구성을 연구하였다. 유리에 더스트 첨가량이 증가함에 따라 FT-IR 스펙트럼 상의 가교산소 진동피크($1050{\sim}1060cm^{-1}$)와 비가교산소 진동피크($960cm^{-1}$)가 합쳐진 넓은 피크($1000cm^{-1}$ 부근)가 저파수쪽으로 이동하였다. 동시에 boroxol ring의 $B_2O_3$ 구조가 tetrhedral-, trigonal- 그리고 di-borate로 변화되는 것을 확인하였다. 결정화유리 시편에서 Fe-O 피크가 확인되었으며 이는 spinel이 생성되었다는 XRD 결과와 일치하였다. TCLP를 행한 유리시편의 표면은 균열이 심하였으나 결정화유리는 큰 변화가 없어, 결정상 생성이 화학적 내구성을 향상시킴을 확인하였다. Fe의 용출량은 더스트가 80wt% 첨가된 결정화유리의 경우, 유리시편에 비하여 1/15로 감소하였다. Zn은 더스트 첨가량이 70wt% 이하인 결정화유리에서 용출량이 유리에 비해 높았으나 80wt% 이상 시편에서는 유리보다 감소하였고 이는 willemite 생성과 연관이 있는 것으로 사료된다.

유리성형시스템의 힘측정기반 가압장치를 이용한 곡면유리 성형조건 (Forming Conditions of Curved Glass using Force Applying System of Glass Molding System)

  • 홍태경;김갑순
    • 한국정밀공학회지
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    • 제31권4호
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    • pp.335-342
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    • 2014
  • This paper describes the forming conditions of smart-phone curved glass using the glass molding system with force applying system. The force applying system is composed of a body, a motor and gear, a rectilinear movement structure, a force sensor, a LVDT sensor (Linear Variable Differential Transformer), a up and down moving block, and so on. The glass molding system for characteristic test to find the forming conditions consists of the force applying system and a chamber, a metallic mold, a upper heater, a lower heater and so on. The characteristic test for forming conditions of smart-phone curved glass was carried out at forming temperature $620^{\circ}C$ and $650^{\circ}C$ using the glass molding system. As a result of the characteristic test, the forming conditions of curved glass could be found, and it is thought that the conditions can be used to apply to the system for producing in large quantities.

평판 유리로 봉인된 유-무기 보호 박막을 갖는 OLED 봉지 방법 (Encapsulation Method of OLED with Organic-inorganic Protective Thin Films Sealed with Flat Glass)

  • 박민경;주성후
    • 한국전기전자재료학회논문지
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    • 제25권5호
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    • pp.381-386
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    • 2012
  • To study encapsulation method for large-area organic light emitting diodes (OLEDs), red emitting OLEDs were fabricated, on which $Alq_3$ as organic buffer layer and LiF and Al as inorganic protective layers were deposited to protect the damage of OLED by epoxy. And then the OLEDs were attached to flat glass by printing method using epoxy. The basic structure of OLED doped with rubrene of 1 vol.% as emitting layer is ITO(150 nm) / 2-TNATA(50 nm) / ${\alpha}$-NPD(30 nm) / $Alq_3$:Rubrene(30 nm) / $Alq_3$(30 nm) / LiF(0.7 nm) / Al(100 nm). In case of depositing $Alq_3$, LiF and Al and then attaching of flat glass onto OLED, current density, luminance, efficiency and driving voltage were not changed and lifetime was increased according to thickness of Al as inorganic protective layers. The lifetime of OLED/$Alq_3$/LiF/Al_4/glass structure was 139 hours increased by 15.8 times more than bare OLED of 8.8 hours and 1.6 times more than edge sealed OLED of 54.5 hours.

비구면 유리렌즈 성형용 SiC 코어의 DLC 코팅에 관한 연구 (A Research on DLC Thin Film Coating of a SiC Core for Aspheric Glass Lens Molding)

  • 박순섭;원종호
    • 한국정밀공학회지
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    • 제27권12호
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    • pp.28-32
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    • 2010
  • Technical demands for aspheric glass lens formed in market increases its application from simple camera lens module to fiber optics connection module in optical engineering. WC is often used as a metal core of the aspheric glass lens, but the long life time is issued because it fabricated in high temperature and high pressure environment. High hard thin film coating of lens core increases the core life time critically. Diamond Like Carbon(DLC) thin film coating shows very high hardness and low surface roughness, i.e. low friction between a glass lens and a metal core, and thus draw interests from an optical manufacturing industry. In addition, DLC thin film coating can removed by etching process and deposit the film again, which makes the core renewable. In this study, DLC films were deposited on the SiC ceramic core. The process variable in FVA(Filtered Vacuum Arc) method was the substrate bias-voltage. Deposited thin film was evaluated by raman spectroscopy, AFM and nano indenter and measured its crystal structure, surface roughness, and hardness. After applying optimum thin film condition, the life time and crystal structure transition of DLC thin film was monitored.

V급와동에 충전한 심미성 수복재의 치질과의 접합도에 관한 주사전자현미경적 연구 (A SEM STUDY ON THE ADAPTATION OF ESTHETIC RESTORATIVE MATERIALS TO TOOTH STRUCTURE IN CLASS V CAVITIES)

  • 조영곤;고창현
    • Restorative Dentistry and Endodontics
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    • 제18권2호
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    • pp.413-422
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    • 1993
  • The purpose of this study was to evaluate the adaptation of light cured glass ionomer cement and composite resin using all- etch technique to tooth structure. In this study, class V cavities were prepared on the buccal surfaces of 10 extracted human premolar teeth with cementum margin and teeth were randomly assigned 2 groups of 5 teeth each. The cavities of glass ionomer cement group were filled with the light cured glass ionomer cement(Fuji II LC) and the cavities of composite resin group were filled with the light cured composite resion(P - 50) using all- etch technique with All- Bond 2. The restored teeth were stored in 100 % relative humidity at $37^{\circ}C$ for 48 hours. And then, the roots of the teeth were removed with the tapered fissure bur and the remaining crowns were sectioned occlusogingivally through the center of restorations. Adaptation at tooth - restoration interface were assessed occlusally, gingivally, and axially by scanning electron microscope. The results were as follows : 1. The adaptation to enamel walls of composite resin restorations using All - Bond 2 showed better than glass ionomer restorations. 2. The adaptation to gingival and axial walls of glass ionomer restorations showed better than composite resin restorations using All - Bond 2. 3. In both groups, occlusal margins of restorations showed better adaptation than gingival margins of restorations.

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