• Korean Journal of Crystallography
• /
• v.8 no.2
• /
• pp.119-123
• /
• 1997

The complex [Ni(L)]I2 (1) (L:3,5,10,12-Tetramethly-1,4,8,11-tetraazacyclotetradecane) has been prepared and characterized by X-ray diffraction methods. The complex 1 crystallized in the orthorhombic system, space group Pcab with cell parameters a=13.293(1) Å, b=28.550(7) Å, c=10.804(1) Å, z=8. Least-squares refinement of 1 led to a R(Rw) factor of 0.043 (0.046) for 1851 observed reflections of Fo>3o (Fo). The crystal structure of 1 has a slightly distorted square-planar geometry and adopts the trans-III conformation.

• ETRI Journal
• /
• v.33 no.4
• /
• pp.517-527
• /
• 2011

Currently, there is a considerable interest in 3D object reconstruction using terrestrial laser scanner (TLS) systems due to their ability to automatically generate a considerable amount of points in a very short time. To fully map an object, multiple scans are captured. The different scans need to be registered with the help of the point cloud in the overlap regions. To guarantee reliable registration, the scans should have large overlap ratio with good geometry for the estimation of the transformation parameters among these scans. The objective of this paper is to propose a registration method that relaxes/eliminates the overlap requirement through the utilization of photogrammetrically reconstructed features. More specifically, a point-based procedure, which utilizes non-conjugate points along corresponding linear features from photogrammetric and TLS data, will be used for the registration. The non-correspondence of the selected points along the linear features is compensated for by artificially modifying their weight matrices. The paper presents experimental results from simulated and real datasets to illustrate the feasibility of the proposed procedure.

• Geomechanics and Engineering
• /
• v.10 no.5
• /
• pp.657-676
• /
• 2016

In this paper, the active lateral earth pressure is evaluated using the stress characteristics or slip line method. The lateral earth pressure is expressed as the lateral earth pressure coefficients due to the surcharge, the unit weight and cohesion of the backfill soil. Seismic horizontal and vertical pseudo-static coefficients are used to consider the seismic effects. The equilibrium equations along the characteristics lines are solved by the finite difference method. The slope of the ground surface, the wall angle and the adhesion and friction angle of the soil-wall interface are also considered in the analysis. A computer code is provided for the analysis. The code is capable of solving the characteristics network, determining active lateral earth pressure distribution and calculating active lateral earth pressure coefficients. Closed-form solutions are provided for the lateral earth pressure coefficients due to the surcharge and cohesion. The results of this study have a good agreement with other reported results. The effects of the geometry of the retaining wall, the soil and soil-wall interface parameters are evaluated. Non-dimensional graphs are presented for the active lateral earth pressure coefficients.

• Structural Engineering and Mechanics
• /
• v.74 no.1
• /
• pp.91-104
• /
• 2020

A mathematical analysis has been carried out for understanding the traversal attributes of torsional waves in a Voigt-type viscoelastic porous layer bounded with corrugated surfaces resting over a heterogeneous transversely isotropic gravitating semi-infinite medium. Both the media are assumed to be under the effect of initial stresses acting along horizontal directions. In the presumed geometry, continuous and periodic type of corrugation has been considered. The condensed form of dispersion relation has been obtained analytically with the aid of the Whittaker's function and suitable boundary conditions. The influence of viscoelasticity, porosity, initial stresses, heterogeneity, gravity, undulation and position parameters on the phase and damped velocities has been illustrated graphically. In addition, relative examination investigating the impact of corrugated and planar bounded surfaces on the dispersion and damping characteristics is one of the important highlights of this study.

• Geomechanics and Engineering
• /
• v.21 no.2
• /
• pp.153-164
• /
• 2020

Tunnel excavation in shallow soft ground conditions of urban areas experiences inevitable surface settlements that threaten the stability of nearby infrastructures. Surface settlements during shield TBM tunneling are related to a number of factors including geotechnical conditions, tunnel geometry and excavation methods. In this paper, a database collected from a construction section of Hong Kong subway was used to analyze the correlation of settlement-inducing factors and surface settlements monitored at different locations of a transverse trough. The Pearson correlation analysis result revealed a correlation between the factors in consideration. Factors such as the face pressure, advance speed, thrust force, cutter torque, twin tunnel distance and ground water level presented a modest correlation with the surface settlement, while no significant trends between the other factors and the surface settlements were observed. It can be concluded that an integrated effect of the settlement-inducing factors should be related to the magnitude of surface settlements.

• Proceedings of the KSME Conference
• /
• 2008.11b
• /
• pp.2454-2459
• /
• 2008

The objective of this paper is to find out the most effective injection angle for the purpose of deicing through SC/Tetra, a commonly used CFD software. Nowadays, vehicles are developed giving priority to an improved interior which emphasizes a pleasant environment and thermal comfort without decreasing the basic performance. Clear visibility is one of the most important phenomenon. The primary factors which affect the efficiency of deicing are 3D geometry of Defrost Nozzle, the inlet velocity and temperature of the flow and the injection angle. However in this paper, all these parameters are optimized by changing the injection angle. A wide range of injection angle from 5 degree to 50 degree have been considered for analysis. A very good defrosting performance has been achieved with 45 degree injection angle which can satisfy the condition of NHTSA.

• Journal of Magnetics
• /
• v.6 no.3
• /
• pp.90-93
• /
• 2001

Co/$Al_O_3$/NiFe and CO/$Al_O_3$/Co tunnel junctions were fabricated by a radio frequency magnetron sputtering at room temperature with hard mask on glass and $4^{\circ}$ tilt cut Si (111) substrates. The barrier layer was formed through two steps. After the Al layer was deposited, it was oxidized in the chamber of a reactive ion etching system (RIE) with $O_2$plasma at various conditions. The dependence of the TMR value and junction resistance on the thickness of Al layer (before oxidation) and oxidation parameters were investigated. Magnetoresistance value of 7% at room temperature was obtained by optimizing the Al layer thickness and oxidation conditions. Circular shape junctions on $4^{\circ}$tilt cut Si (111) substrate showed 4% magnetoresistance. Photovoltaic energy conversion effect was observed with the cross-strip geometry junctions on Si substrate.

• Journal of IKEEE
• /
• v.21 no.3
• /
• pp.309-319
• /
• 2017

The research investigates the inhibition of fatty acid biosynthesis of the human Acetyl-CoA Carboxylase enzyme by the aromatic-structure inhibitors (also known as ligands) containing variables of substituents, contributing an important role in the treatment of fatty-acid metabolic syndrome expressed by the group of cardiovascular risk factors increasing the incidence of coronary heart disease and type-2 diabetes. The effective interoperability between ligand and enzyme is characterized by a 50% concentration of enzyme inhibitor ($IC_{50}$) which was determined by experiment, and the factor of geometry structure of the ligands which are modeled by quantum mechanical methods using HyperChem 8.0.10 and Gaussian 09W softwares, combining with the calculation of quantum chemical and chemico-physical structural parameters using HyperChem 8.0.10 and Padel Descriptor 2.21 softwares. The result data are processed with the combination of classical statistical methods and modern bioinformatics methods using the statistical softwares of Department of Pharmaceutical Technology - Jadavpur University - India and R v3.3.1 software in order to accomplish a model of the quantitative structure - activity relationship between aromatic-structure ligands inhibiting fatty acid biosynthesis of the human Acetyl-CoA Carboxylase.

• Journal of the Korean Chemical Society
• /
• v.57 no.3
• /
• pp.311-315
• /
• 2013

The geometry structures of hexa-coordinated [NiLX]X complexes ($X=Cl^-,\;Br^-,\;I^-$) {L = 8,9,18,19-tetrahydro-7H,17H-dibenzo[f,o] [1,5,9,13]dioxadiaza cyclohexadecine-8,18-diol} are optimized by density functional theory (DFT) using B3LYP/LANL2DZ. The calculated geometric parameters are in good agreement with the corresponding experimental values. Calculation results about these complexes show that dipole moment decreases, and the energy levels of HOMOs descend from iodo-complex to chloro-complex. The energy levels of HOMOs descend gently from iodo-complex to chloro-complex, while the energy levels of LUMOs in the present complexes are almost similar; therefore the energy gapes between HOMOs and LUMOs increased from iodo-complex to chloro-complex.

• Korean Journal of Crystallography
• /
• v.9 no.1
• /
• pp.6-10
• /
• 1998

The complex[Cu(L)](ClO4)2 (1) (L:3,5,10,12-Tetramethyl-1,4,8,11-tetraazacyclotetradecane) has been synthesized and structurally characterized. The complex 1 crystallizes in the monoclinic system, space group P21/n with cell parameters a=8.208(2)Å, b=13.339(6) Å, c=10.752(5) Å, β=111.02(4)˚ Z=2. Least-squares refinement of 1 led to a R(RW)factor of 0.073 (0.142) for 617 observed reflections of F0>40(F0). The crystal structure of 1 has a square-planar geometry and adopts the trans-III conformation.