• Title/Summary/Keyword: generated voltage

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Experimental Study on Four Cation Exchange Membranes in Electrosynthesis of Ammonium Persulfate

  • Wang, Chao;Zhou, Junbo;Gao, Liping
    • Journal of Electrochemical Science and Technology
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    • v.9 no.1
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    • pp.37-43
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    • 2018
  • In order to improve current efficiency and decrease energy consumption in the electrosynthesis of ammonium persulfate, electrolytic properties of four cation exchange membranes, namely, the $JCM-II^{(R)}$ membrane, $Nafion^{(R)}$ 324 membrane CMI-$7000^{(R)}$ membrane and a self-made perfluorosulfonic ion exchange membrane (PGN membrane) were investigated using a sintered platinized titanium anode and a Pb-Sb-Sn alloy cathode in a self-made electrolytic cell. The effect of cell voltage and electrolyte flow rate on the current efficiency and the energy consumption were investigated. The results indicated that the PGN membrane could improve current efficiency to 94.85% and decrease energy consumption to $1119kWh\;t^{-1}$ (energy consumption per ton of the ammonium persulfate generated) under the optimal operating conditions and the highest current efficiency of the $JCM-II^{(R)}$ membrane, $Nafion^{(R)}$ 324 membrane and CMI-$7000^{(R)}$ membrane were 80.73%, 77.76% and 73.22% with their lowest energy consumption of $1323kWh\;t^{-1}$, $1539kWh\;t^{-1}$ and $2256kWh\;t^{-1}$, respectively. The PGN membrane has the advantages of high current efficiency and energy power consumption and has sufficient mechanical strength with the reinforced mesh. Therefore the PGN membrane will has good value in popularization in the industrial electrosynthesis of ammonium persulfate in the future.

POLYMER SURFACE MODIFICATION WITH PLASMA SOURCE ION IMPLANTATION TECHNIQUE

  • Han, Seung-Hee;Lee, Yeon-Hee;Lee, Jung-Hye;Yoon, Jung-Hyeon;Kim, Hai-Dong;Kim, Gon-ho;Kim, GunWoo
    • Journal of the Korean institute of surface engineering
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    • v.29 no.5
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    • pp.345-349
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    • 1996
  • The wetting property of polymer surfaces is very important for practical applications. Plasma source ion implantation technique was used to improve the wetting properties of polymer surfaces. Poly(ethylene terephtalate) and other polymer sheets were mounted on the target stage and an RF plasma was generated by means of an antenna located inside the vacuum chamber. High voltage pulses of up to -10kV, 10 $\mu$sec, and up to 1 kHz were applied to the stage. The samples were implanted for 5 minutes with using Ar, $N_2,O_2,CH_4,CF_4$ and their mixture as source gases. A contact angle meter was used to measure the water contact angles of the implanted samples and of the samples stored in ambient conditions after implantation. The modified surfaces were analysed with Time-Of-Flight Mass Spectrometer (TOF-SIMS) and Auger Electron Spectroscopy (AES). The oxygen-implanted samples showed extremely low water contact angles of $3^{\circ}C$ compared to $79^{\circ}C$ of unimplanted ones. Furthermore, the modified surfaces were relatively stable with respect to aging in ambient conditions, which is one of the major concerns of the other surface treatment techniques. From TOF-SIMS analysis it was found that oxygen-containing functional groups had been formed on the implanted surfaces. On the other hand, the $CF_4$-implanted samples turned out to be more hydro-phobic than unimplanted ones, giving water contact angles exceeding $100^{\circ}C$ . The experiment showed that plasma source ion implantation is a very promising technique for polymer surface modification especially for large area treatment.

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Generalized Circulating Current Control Method in Parallel Three-Phase Boost Converters (병렬 삼상 부스트 컨버터에서 일반화된 순환전류 제어 방법)

  • Lim, Chang-Soon;Lee, Kui-Jun;Kim, Rae-Young;Hyun, Dong-Seok
    • The Transactions of the Korean Institute of Power Electronics
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    • v.16 no.3
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    • pp.250-257
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    • 2011
  • This paper analyzes characteristic of the three-phase coupled inductor connected to ac source to effectively mitigate the high-frequency circulating current generated in parallel three-phase boost converters. The three-phase coupled inductor analysis presented in this paper uses the three-phase coupled inductor structure and voltage equations. Based on this analysis, the three-phase coupled inductor is added to the conventional low-frequency averaged model. As a result, the novel averaged model which can reduce the low and high-frequency circulating current simultaneously is developed. Using the zero-sequence component of the novel averaged model, each total inductance to the circulating current of the three-phase coupled inductor and line inductor can be obtained. Simulation and experiment results verify the usefulness of three-phase coupled inductor in parallel three-phase boost converters.

Multi-Band RF Energy Harvesting System Using Buck-Boost DC-DC Converter (Buck-Boost DC-DC Converter를 이용한 다중 대역 RF 에너지 수집 시스템)

  • Cho, Choon Sik
    • Journal of Satellite, Information and Communications
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    • v.12 no.2
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    • pp.89-93
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    • 2017
  • This paper introduces an energy harvesting system that generates energy by collecting multi-band RF signals using buck-boost DC-DC converter. In an environment where the resistance of load using the collected electric energy is constantly changing, a buck-boost DC-DC converter is used in which the input resistance of the DC-DC converter does not change even if the load resistance changes. Since the frequency band of the input RF signal varies, the rectifier is designed for each band so that multiple bands can be processed, and a matching circuit is added to each band in front of the rectifier. For a rectifier to collect very small RF signals, a circuit is designed so that a constant voltage is obtained according to a very small input signal by devising a method of continuously accumulating the voltages collected and generated in each band. It is confirmed that the output efficiency can reach up to 20% even for the RF signal having the input of -20 dBm.

A New Current Control Algorithm for Torque Ripple Reduction of BLDC Motors (BLDC 전동기의 토크리플 저감을 위한 새로운 전류제어 알고리즘에 대한 연구)

  • 김태성;안성찬;현동석
    • The Transactions of the Korean Institute of Power Electronics
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    • v.6 no.5
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    • pp.416-422
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    • 2001
  • The BLDC(Brushless DC) Motor is characterized by linear torque to current and speed to voltage. It has low acoustic noise and fast dynamic response. Moreover, it has high power density with high proportion of torque to inertia in spite of small size drive. However, when armature current is commutated, the current ripple is generated by the motor inductance components in stator windings and back-EMF. This current ripple caused to torque ripple. Therefore, it is difficult to apply the BLDC motor to a precision servo drive system. In this paper, a new current control algorithm using fourier series coefficients is proposed. This proposed algorithm can minimize torque ripple due to the phase current commutation of BLDC motor. Simulation and Experimental results prove the effectiveness at the Proposed algorithm through comparison with the conventional unipolar PWM method.

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A Single-Phase Quasi Z-Source AC-AC Converter with a Series Connection of the Output Terminals (출력이 직렬 결합된 단상 Quasi Z-소스 AC-AC 컨버터)

  • Oum, Jun-Hyun;Jung, Young-Gook;Lim, Young-Cheol;Choi, Joon-Ho
    • The Transactions of the Korean Institute of Power Electronics
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    • v.16 no.5
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    • pp.415-429
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    • 2011
  • In this study, a single-phase quasi Z-source AC-AC converters with a series connection of the output terminals is proposed. The proposed system has configuration that the input terminals of two quasi Z-source AC-AC converters are connected in parallel and its output terminals are connected in series. The out of phase mode and in phase mode of the proposed system are presented. To verify the validity of the proposed converter, a DSP controlled hardware was made and PSIM simulation was executed. As a result, controlling the duty ratio of the converter, the desired buck-boost output voltages could be generated. For each modes, as compared with the single converter operation, the proposed converter could enhance the efficiency and input power factor according to different loads. Also, in case of the out of phase mode under the constant load, the efficiency and input power factor of the proposed system are increased 10[%], 35[%] respectively in compared with the single converter. And, the output voltage is constantly controlled in dynamic state in case while the load is suddenly changed.

TRANSFORMER EXPLOSION AND FIRE PREVENTION (변압기 폭발/화재 방지 기술)

  • Kim, Hyung-Seung;Magnier, Philippe
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.93-94
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    • 2007
  • An essential step for SERGI is to show the TRANSFORMER PROTECTOR (TP) efficacy for all transformers and all types of rupture of insulation. Its research program philosophy is thus to maintain a strong connection between experiments and the theoretical developments. Up to now, two TP test campaigns have been performed, both under the worst conditions by creating low impedance faults leading to electrical arcs inside the transformer tank dielectric oil. In 2002, Electricite de France performed 28 TP tests. Then, in 2004, a second campaign of 34 TP tests was carried out by CEPEL, the Brazilian independent High Voltage Laboratory. For the 62 tests, each transformer was equipped with the TP, which reacts directly to the moving dynamic pressure peak, shock wave, caused by the low impedance fault. When an electrical arc occurs, only one pressure peak is generated. The initial energy transfer is almost instantaneous, and so is the phase change. Because of the oil inertia, the gas is very quickly pressurised. As it is more difficult to vaporise a liquid than to crack oil-vapour into smaller molecules, the arc location would mainly remain in the gaseous phase after and less gas will be produced. As a result, when comparing tests for which pressure peaks are respectively equal to 8 bar (116 psi) and 8.8 bar (127 psi), the corresponding arc energies vary by an order 10 of magnitude (0.1 MJ and 1 MJ respectively). The correlation of the results obtained between arc energy and dynamic pressure demonstrates that the arc energy is not the key parameter during transformer tank explosion, which is in opposition with the common electrical engineers belief.

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Plasma source ion implantations for shallow $p^+$/n junction

  • Jeonghee Cho;Seuunghee Han;Lee, Yeonhee;Kim, Lk-Kyung;Kim, Gon-Ho;Kim, Young-Woo;Hyuneui Lim;Moojin Suh
    • Proceedings of the Korean Vacuum Society Conference
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    • 2000.02a
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    • pp.180-180
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    • 2000
  • Plasma source ion implantation is a new doping technique for the formation of shallow junction with the merits of high dose rate, low-cost and minimal wafer charging damage. In plasma source ion implantation process, the wafer is placed directly in the plasma of the appropriate dopant ions. Negative pulse bias is applied to the wafer, causing the dopant ions to be accelerated toward the wafer and implanted below the surface. In this work, inductively couples plasma was generated by anodized Al antenna that was located inside the vacuum chamber. The outside wall of Al chamber was surrounded by Nd-Fe-B permanent magnets to confine the plasma and to enhance the uniformity. Before implantation, the wafer was pre-sputtered using DC bias of 300B in Ar plasma in order to eliminate the native oxide. After cleaning, B2H6 (5%)/H2 plasma and negative pulse bias of -1kV to 5 kV were used to form shallow p+/n junction at the boron dose of 1$\times$1015 to 5$\times$1016 #/cm2. The as-implanted samples were annealed at 90$0^{\circ}C$, 95$0^{\circ}C$ and 100$0^{\circ}C$during various annealing time with rapid thermal process. After annealing, the sheet resistance and the junction depth were measured with four point probe and secondary ion mass spectroscopy, respectively. The doping uniformity was also investigated. In addition, the electrical characteristics were measured for Schottky diode with a current-voltage meter.

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Measurement of electron temperature and density using Stark broadening of the coaxial focused plasma for extreme ultraviolet (EUV) lithography

  • Lee, Sung-Hee;Hong, Young-June;Choi, Eun-Ha
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.475-475
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    • 2010
  • We have generated Ar plasma in dense plasma focus device with coaxial electrodes for extreme ultraviolet (EUV) lithography and investigated an emitted visible light for electro-optical plasma diagnostics. We have applied an input voltage 4.5 kV to the capacitor bank of 1.53 uF and the diode chamber has been filled with Ar gas of pressure 8 mTorr. The inner surface of the cylindrical cathode has been attatched by an acetal insulator. Also, the anode made of tin metal. If we assumed that the focused plasma regions satisfy the local thermodynamic equilibrium (LTE) conditions, the electron temperature and density of the coaxial plasma focus could be obtained by Stark broadening of optical emission spectroscopy (OES). The Lorentzian profile for emission lines of Ar I of 426.629 nm and Ar II of 487.99 nm were measured with a visible monochromator. And the electron density has been estimated by FWHM (Full Width Half Maximum) of its profile. To find the exact value of FWHM, we observed the instrument line broadening of the monochromator with a Hg-Ar reference lamp. The electron temperature has been calculated using the two relative electron density ratios of the Stark profiles. In case of electron density, it has been observed by the Stark broadening method. This experiment result shows the temporal behavior of the electron temperature and density characteristics for the focused plasma. The EUV emission signal whose wavelength is about 6 ~ 16 nm has been detected by using a photo-detector (AXUV-100 Zr/C, IRD). The result compared the electron temperature and density with the temporal EUV signal. The electron density and temperature were observed to be $10^{16}\;cm^{-3}$ and 20 ~ 30 eV, respectively.

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Improved IPMCs and It's Application for Flapping Actuator (IPMCs(Ionic Polymer Metal Composites) 성능 개선 및 날갯짓 작동기로의 응용)

  • Lee, Soon-Gie;Yoo, Young-Tai;Heo, Seok;Park, Hoon-Cheol
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2005.11a
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    • pp.723-726
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    • 2005
  • The two major obstacles in the application of IPMC to flapping actuators operated in the air are solvent loss and actuation force. In this paper, solvent loss of various IPMCs made of Nafion$^{TM}$117(183$\mu$m thickness) has been experimentally investigated to find out the best combination of cation and solvent for minimal solvent loss in IPMCs and higher actuation force. For this purpose. experiments for the internal solvent loss measurement of IMPCs have been conducted for various combinations of cation and solvent. From the experiments, it was found that heavy water showed improvement in the operating time up to more than two minutes. in the tip force measurement of IPMCs, it was found that smaller and thicker IPMCs produced larger tip forces. However, the shorter IPMCs generated reduced actuation displacements and created flapping motion with decreased natural frequency. For the design of flapping device actuated by 5mm wide, 10mm long, 0.2mm thick IPMCs were used in the stacked form. Since the actuation force is a few gram-force, we stacked five IPMCs to improve actuation force. To amply the actuation force, rack-and-pin ion type hinge was used for the flapping device and insect (Cicadidae) wing was attached to the stacked IPMC actuator. In the flapping test, the device could generate flapping angle of 15$^{\circ}$ at 6Hz excitation by 2.5 voltage square wave input.

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