• Title/Summary/Keyword: gel materials

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Preoperative Evaluation of Lower Rectal Cancer by Pelvic MR with and without Gel Filling (하부직장암 환자에서 초음파겔 삽입 전후의 골반 자기공명영상의 비교)

  • Kim, Dae Jung;Kim, Joo Hee;Lim, Joon Seok;Chung, Jae-Joon;Yu, Jeong-Sik;Kim, Myeong-Jin;Kim, Ki Whang
    • Investigative Magnetic Resonance Imaging
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    • v.18 no.4
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    • pp.323-331
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    • 2014
  • Purpose : To assess the usefulness of rectal filling using ultrasonographic gel in patients with lower rectal cancer. Materials and Methods: Twenty five patients with lower rectal cancer were enrolled. High resolution pelvic MR was performed twice before and after gel filling. Independently and retrospectively, two radiologists reviewed each set of MR images using five-grade scales for sphincter involvement, CRM (circumferential resection margin) involvement and depiction of the tumor. Same two radiologists retrospectively performed consensus review of each set of MR images for tumor distance from the anal verge and T&N staging. Results: Tumor depiction scores from MR with gel filling were significantly higher than those of MR without distention (p<0.001). Compared to MR without distension, MR with gel filling had no significant differences in prediction of CRM or sphincter involvement (p>0.05). Distance from the anal verge was significantly different between MR with gel filling and rigid endoscopy ($6.8{\pm}1.6cm$ vs. $5.8{\pm}1.6cm$, p=0.001). There were no significant differences between pathological staging and MR staging with or without gel filling. Conclusion: MR with gel filling improved tumor depiction. And also MR with gel filling revealed same ability for the predictions of CRM or sphincter invasion in patients with lower rectal cancer, comparing with MR without gel filling.

Synthesis of Oxide Ceramic Powders by Polymerized Organic-Inorganic Complex Route

  • Lee, Sang-Jin;Lee, Chung-Hyo;Waltraud M. Kriven
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 2000.06a
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    • pp.151-163
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    • 2000
  • A polymerized organic-inorganic complexation route is introduced for the synthesis of oxide ceramic powders. Polyvinyl alcohol was used as the organic carrier for precursor ceramic gel. Porous and soft powders, which have a high specific surface area, were obtained after calcinating the aerated precursors. The PVA content and its degree of polymerization had a significant influence on the homogeneity of the final powder. In particular, attrition milling process with the porous powder resulted in ultra-fine particles. In the case of the preparation of cordierite powder, nano-size powder, which has a high specific surface area of 181 ㎡/g, was obtained by the milling process. The complexation route was also applied to the synthesis of unstable phase in room temperature like beta-cristobalite, high temperature form of silica.

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Mixed Design of Grouting Materials for Settlement Restoration Using Micro Cement (마이크로시멘트를 이용한 침하복원용 그라우팅재료의 배합 설계)

  • Lee, Il-Wha;Lee, Sung-Jin;Yun, Won-Min;Park, Sung-Ki
    • Proceedings of the KSR Conference
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    • 2011.05a
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    • pp.1786-1792
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    • 2011
  • If the concrete track is settled excessively, it must be restored or reinforced immediately. Especially, reinforcement/restoration method should be applied without affecting on train operation. To deal with this problem, special equipment, process and material should be prepared. This paper suggest a special mixing ratio to restore the settled concrete track. Materials are classified the quick hardening mortar and the middle hardening mortar. The quick hardening mortar is used to restore the settled track and the middle hardening mortar is used to fill the void. These materials must have the appropriate gel time(1-40sec) and compressive strength($5kg/cm^2$). Various compounds is used and the micro cement is used as a main base.

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Adsorption of Ruthenium on the alkaline Earth Metal Compounds (알카리토금속 화합물에 의한 루테늄의 흡착)

  • 류경옥;문세기;이근범
    • Journal of the Korean Ceramic Society
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    • v.19 no.2
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    • pp.145-151
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    • 1982
  • Many materials such as silica gel, metallic oxide, activated alumina and alkaline earth metal carbonates were employed as filter media for gaseous oxides of ruthenium volatilized during high level radioactive waste processing. The adsorption efficiency of ruthenium on these materials was evaluated. For the purpose of observing behavior of ruthenium oxides, thermogravimetric analysis of ruthenium oxide in a stream of oxygen was carried out. The rate of volatilization was proportional to the square root of oxygen partial pressure, and increased exponentially with temperature. At $650^{\circ}C$, gaseous ruthenium oxides showed a strongly marked effect of deposition. Of all the materials available, calcium oxide proved to be the best that could be used to adsorb ruthenium.

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Preparation of Silica Microcapsules containing Water-Soluble UV Absorbers by a W/O Microemulsion Sol-Gel Process (W/O 마이크로에멀젼 졸-겔 법을 이용한 수용성 UV 흡수제를 함유한 실리카 마이크로캡슐의 제조)

  • 함경국;안복엽;석상일
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.220-220
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    • 2003
  • The microencapsulation of droplets or particles within a solid shell leads to the formation of core-shell particles. Microencapsulation provides protection and controlled release of core materials such as drugs, vitamins, enzymes, perfumes, and the like. Such particles have, therefore, found a diverse range of applications in the pharmaceutical, agricultural, cosmetic, and food industries. UV absorbers are widely used for cosmetics to screen out ultra violet (UV) rays which have side effects on human skin. The absorbers are made generally from synthetic organic compounds, which can stimulate the human skins to develop allergic phenomena.

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Enhanced Light Harvesting from F$\ddot{o}$rst-type resonance Energy Transfer in the Quasi-Solid State Dye-Sensitized Solar Cells (F$\ddot{o}$rst energy transfer 를 적용한 준고체 DSSC 의 효율향상)

  • Cheon, Jong Hun;Lee, Jeong Gwan;Yang, Hyeon Seok;Kim, Jae Hong
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.117.1-117.1
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    • 2011
  • We have demonstrated Forst-type resonance energy transfer (FRET) in the quasi-solid type dye-sensitized solar cells between organic fluorescence materials as an energy donor doped in polymeric gel electrolyte and ruthenium complex as an energy acceptor on surface of $TiO_2$. The strong spectral overlap of emission/absorption of energy donor and acceptor is required to get high FRET efficiency. The judicious choice of energy donor allows the enhancement of light harvesting characters of energy acceptor in quasi-solid dye sensitized solar cells which increase the power conversion efficiency. The enhanced light harvesting effect by the judicious choice/design of the fluorescence materials and sensitizing dyes permits the enhancement of photovoltaic performance of DSSC.

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A Study on the dynamic viscoelasticity of UV curing polymer and alkyd resin composite materials (UV경화성 수지와 Alkyd수지 복합재료의 경화거동과 동적 점탄성에 관한 연구)

  • 정원식;최정병;김용욱
    • Journal of the Korean Graphic Arts Communication Society
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    • v.16 no.3
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    • pp.29-41
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    • 1998
  • The ultraviolet(UV)-curable materials wildly have been used as a ink and coating materials. A according to measure UV polymerization phase separation of acryl groups 2,3,4-functional monomer, a few experiments were performed gel fraction, dynamic viscosity of alkyd resin blend system. Dependence of photoiniator concentration and various monomer, alkyd resin content investigated structural changes of films cured by UV irradiation. Curing rate measured UV irradiation under $25^{\circ}C$, cell gap 7cm and film thickness 100${\mu}{\textrm}{m}$. In results, it was through that the viscoelastic properties of films cured with increasing the ratios of monomer/alkydresin contents are network polymer in properties such as viscoelasticity.

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Rietveld Refinement of Oxysulfide $LiAl_{0.24}Mn_{1.76}O_{4-y}S_y (y=0, 0.02)$ Spinel Materials

  • Park, Hyun-Min;Y.K Cho;Sun, Yang-Kook
    • Korean Journal of Crystallography
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    • v.14 no.2
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    • pp.110-114
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    • 2003
  • LiAl/sub 0.24/Mn/sub 1.76/O/sub 4-y/S/sub y/ (y=0, 0.02) were synthesized by the sol-gel method. Both structures were refined by Rietveld method, its structure refined as a cubic spinel, space group Fd-3m, a=8.17937(30) Å and 8.18331(19) Å respectively. Though it has been made a charge/discharge experiment above 20 times, there was no change of 3 V/4 V capacity degradation. It was considered that the volume change of MnO/sub 6/ octahedron induced by sulfur substitution plays a key role in keeping the 3 V/4 V capacity. The refined composition of the compound could be confirmed with the ICP analysis.

Titanium Dioxide Nanofibers Prepared by Using Electrospinning Method

  • Ding, Bin;Kim, Chul Ki;Kim, Hak Yong;Seo, Min Kang;Park, Soo Jin
    • Fibers and Polymers
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    • v.5 no.2
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    • pp.105-109
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    • 2004
  • The synthesis of titanium dioxide nanofibers with 200-300nm diameter was presented. The new inorganic-organic hybrid nanofibers were prepared by sol-gel processing and electrospinning technique using a viscous solution of titanium isopropoxide (TiP)/poly(vinyl acetate) (PVAc). Pure titanium dioxide nanofibers were obtained by high temperature calcination of the inorganic-organic composite fibers. SEM, FT-IR, and WAXD techniques were employed to characterize these nanofibers. The titanium dioxide nanostructured fibers have rougher surface and smaller diameter compare with PVAc/TiP composite nanofibers. The anatase to rutile phase transformation occurred when the calcination temperature was increased from $600^{\circ}C$ to $1000^{\circ}C$.

Preparation of Self-standing Mesoporous Bioactive Glass/biodegradable Polymer Composite thin Films using Water Casting Method (수면전개법을 이용한 메조다공성 생체활성유리-생분해성 고분자 복합체 자립박막의 제조)

  • Yun, Hui-Suk;Yoon, Jun-Jin;Park, Eui-Kyun;Kim, Seung-Eon;Hyun, Yong-Taek
    • Journal of the Korean Ceramic Society
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    • v.45 no.10
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    • pp.631-637
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    • 2008
  • Self-standing mesoporous bioactive glass/poly($\varepsilon$-caprolactone) composite thin films with good molding capability, bioactivity, and biocompatibility in vitro, which may find potential applications in tissue engineering and drug storage, were prepared using a combination of the sol-gel, polymer templating, and water casting method. The thickness of self-standing films was affected by the difference of dielectric constant between distilled water and organic solvent.