• Title/Summary/Keyword: gas-slurry

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Acidification of pig slurry effects on ammonia and nitrous oxide emissions, nitrate leaching, and perennial ryegrass regrowth as estimated by 15N-urea flux

  • Park, Sang Hyun;Lee, Bok Rye;Jung, Kwang Hwa;Kim, Tae Hwan
    • Asian-Australasian Journal of Animal Sciences
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    • v.31 no.3
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    • pp.457-466
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    • 2018
  • Objective: The present study aimed to assess the nitrogen (N) use efficiency of acidified pig slurry for regrowth yield and its environmental impacts on perennial ryegrass swards. Methods: The pH of digested pig slurry was adjusted to 5.0 or 7.0 by the addition of sulfuric acid and untreated as a control. The pig slurry urea of each treatment was labeled with $^{15}N$ urea and applied at a rate of 200 kg N/ha immediately after cutting. Soil and herbage samples were collected at 7, 14, and 56 d of regrowth. The flux of pig slurry-N to regrowth yield and soil N mineralization were analyzed, and N losses via $NH_3$, $N_2O$ emission and $NO_3{^-}$ leaching were also estimated. Results: The pH level of the applied slurry did not have a significant effect on herbage yield or N content of herbage at the end of regrowth, whereas the amount of N derived from pig slurry urea (NdfSU) was higher in both herbage and soils in pH-controlled plots. The $NH_4{^+}-N$ content and the amount of N derived from slurry urea into soil $NH_4{^+}$ fraction ($NdfSU-NH_4{^+}$) was significantly higher in in the pH 5 plot, whereas $NO_3{^-}$ and $NdfSU-NO_3{^-}$ were lower than in control plots over the entire regrowth period. Nitrification of $NH_4{^+}-N$ was delayed in soil amended with acidified slurry. Compared to non-pH-controlled pig slurry (i.e. control plots), application of acidified slurry reduced $NH_3$ emissions by 78.1%, $N_2O$ emissions by 78.9% and $NO_3{^-}$ leaching by 17.81% over the course of the experiment. Conclusion: Our results suggest that pig slurry acidification may represent an effective means of minimizing hazardous environmental impacts without depressing regrowth yield.

Optimal Operation Condition of Spray Drying Sorber for Simultaneous Removal of Acidic and Organic Gaseous Pollutants (산성 및 유기성 가스의 동시제거를 위한 준건식 세정시스템의 적정 운전 조건)

  • 백경렬;구자공
    • Journal of Environmental Science International
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    • v.10 no.1
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    • pp.59-64
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    • 2001
  • The effect of major operating parameters in spray drying sorber(=SDS) for automatic control for the simultaneous removal of acidic and organic gaseous pollutants from solid waste incinerator was performed. The field experiment was carried out in pilot scale test for the quantification of major operating parameters of hydrophilic and the hydrophobic pollutants. The removal efficiencies of $SO_2$and HCI in the 5wt% slurry condition were being increased with the increase of the stoichiometric ration which is the molecular ratio of lime to the pollutant concentration, and with the decrease of inflow flue gas temperature in the pilot SDS reactor. The removal efficiency along the height of spray drying sorber was closely related to the temperature profile, and more than 90% of total removal efficiency was achieved in an absorption region. For the removal of acidic gas the optimum operating condition considering the economics and a stable operation is the 5wt% of slurry concentration, 1.2 of stoichiometric ratio and 25$0^{\circ}C$ of inflow flue gas temperature. For the organic gases of benzene and toluene the removal efficiencies were 20-60% which is much lower than that of acidic gas. The best removal efficiency was obtained at 1.5 of stoichiometric ratio and 25$0^{\circ}C$ of inflow flue gas temperature. The organic\`s removal efficiency along the height of spray drying sorber was quite different from that of acidic gas, that is, more than 60% of the total removal efficiency for benzene and 90% of the total removal for toluene were achieved in the dried adsorption region, which was formed at the lower or exit part of the reactor.

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Effects of Consumable on STI-CMP Process (STI-CMP 공정에서 Consumable의 영향)

  • Kim, Sang-Yong;Park, Sung-Woo;Jeong, So-Young;Lee, Woo-Sun;Kim, Chang-Il;Chang, Eui-Goo;Seo, Yong-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.185-188
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    • 2001
  • Chemical mechanical polishing(CMP) process is widely used for global planarization of inter-metal dielectric (IMD) layer and inter-layer dielectric (ILD) for deep sub-micron technology. However, as the IMD and ILD layer gets thinner, defects such as micro-scratch lead to severe circuit failure, which affect yield. In this paper, for the improvement of CMP process, deionized water (DIW) pressure, purified $N_2 \; (PN_2)$ gas, slurry filter and high spray bar were installed. Our experimental results show that DIW pressure and $PN_2$ gas factors were not related with removal rate, but edge hot-spot of patterned wafer had a serious relation. Also, the filter installation in CMP polisher could reduce defects after CMP process, it is shown that slurry filter plays an important role in determining consumable pad lifetime. The filter lifetime is dominated by the defects. However, the slurry filter is impossible to prevent defect-causing particles perfectly. Thus, we suggest that it is necessary to install the high spray bar of de-ionized water (DIW) with high pressure, to overcome the weak-point of slurry filter. Finally, we could expect the improvements of throughput, yield and stability in the ULSI fabrication process.

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Effects of Various Facility Factors on CMP Process Defects (CMP 공정의 설비요소가 공정 결함에 미치는 영향)

  • Park, Seong-U;Jeong, So-Yeong;Park, Chang-Jun;Lee, Gyeong-Jin;Kim, Gi-Uk;Seo, Yong-Jin
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.51 no.5
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    • pp.191-195
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    • 2002
  • Chemical mechanical Polishing (CMP) process is widely used for the global planarization of inter-metal dielectric (IMD) layer and inter-layer dielectric (ILD) for deep sub-micron technology. However, as the IMD and ILD layer gets thinner, defects such as micro-scratch lead to severe circuit failure, which affect yield. In this paper, for the improvement of CMP process, deionized water (DIW) pressure, purified $N_2$ ($PN_2$) gas, point of use (POU) slurry filler and high spray bar (HSB) were installed. Our experimental results show that DW pressure and P$N_2$ gas factors were not related with removal rate, but edge hot-spot of patterned wafer had a serious relation. Also, the filter installation in CMP polisher could reduce defects after CMP process, it is shown that slurry filter plays an important role in determining consumable pad lifetime. The filter lifetime is dominated by the defects. However, the slurry filter is impossible to prevent defect-causing particles perfectly. Thus, we suggest that it is necessary to install the high spray bar of de-ionized water (DIW) with high pressure, to overcome the weak-point of slurry filter Finally, we could expect the improvements of throughput, yield and stability in the ULSI fabrication process.

The Comparative Study on the Gasification Process between Coal Water Slurry and Dry Pulverized Coal (습식 및 건식 석탄가스화공정에 대한 비교 연구)

  • Shim, Hyun-Min;Wang, Hong-Yue;Jung, Su-Yong;Kim, Hyung-Taek
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.788-791
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    • 2007
  • 기존의 미분탄 화력발전을 대체할 수 있는 차기 주자인 가스화복합발전(Integrated Gasification Combined Cycle) 기술은 단순히 열과 전기를 얻는데 그치지 않고 $CO_2$ 저감뿐만 아니라 다양한 형태의 2차 에너지원과 화학원료를 생산할 수 있는 기술이다. 상용화 운전 중인 기존의 IGCC 플랜트는 석탄 공급에 있어 건조된 미분탄(dry pulverized coal) 형태로 공급하는 건식 형태와 석탄슬러리(Coal water slurry)의 액상으로 공급하는 습식 형태로 대별되고 있다. 본 연구에서는 ASPEN plus를 이용하여 상용화 IGCC 플랜트에 대한 기본 모델을 구축하였으며, 산지별로 대상 탄종을 illinois #6(미국), Shenhua(중국), Drayton(호주)로 선정하여 가스화공정에 대한 성능을 해석하였다. 동일한 발전 출력을 얻고자 하였을 때, 석탄의 공급방식에 따라 필요한 석탄과 유틸리티 공급량과 가스화기 전${\cdot}$후단에서의 운전특성과 생성되는 합성가스(syngas) 조성, 냉가스(cold gas) 효율 및 탄소 전환율을 통해 각 case에 대한 플랜트 특성을 비교하였다.

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Evaluation of Collection Efficiency of Electrostatic Precipitator for Removing Limestone Slurry Particles (석회석 슬러리 입자 제거를 위한 전기집진기 포집효율 평가)

  • Lee, Gi-Hyuk;Kim, Moon-Won;Yu, Tae-U;Yook, Se-Jin
    • Particle and aerosol research
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    • v.15 no.2
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    • pp.57-65
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    • 2019
  • Recently, there has been much research on the effect of fine dust on human body with increasing interest in the fine dust. Thermal power plant, which is considered as one of the main sources of fine dust, is reported to be responsible for 14% of the total amount of domestic fine dust in the Republic of Korea. Therefore, dust collecting devices in the thermal power plant need to be improved. In this study, the electrostatic precipitator (ESP) was considered to substitute for a mist eliminator used in flue gas desulfurization facility. By considering real situation in the flue gas desulfurization facility, the collection efficiency of the ESP was evaluated by using the sprayed limestone slurry particles. The collection efficiency of the ESP was higher than that of the mist eliminator, showing the possibility of replacing the mist eliminator with the ESP in flue gas desulfurization facility.

Analysis of Hydrodynamic Similarity of Pressurized Three-Phase Slurry Bubble Column for its Design and Scale-up (가압 삼상슬러리 기포탑의 설계 및 Scale-up을 위한 수력학적 Similarity 해석)

  • Seo, Myung Jae;Lim, Dae Ho;Jin, Hae Ryong;Kang, Yong;Jung, Heon;Lee, Ho Tae
    • Korean Chemical Engineering Research
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    • v.47 no.6
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    • pp.720-726
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    • 2009
  • Hydrodynamic similarity was investigated in pressurized three-phase slurry bubble columns by selecting the bubble holdup and pressure drop as objective functions, for the effective design and scale-up of it. In addition, effects of operating variables on the bubble holdup with variation of column diameter were also analyzed. Gas velocity($U_G$), viscosity(${\mu}_{SL,eff}$) and surface tension(${\rho}_{SL}$) of slurry phase, density difference between the slurry and gas phases(${\rho}_{SL}-{\rho}_G$) depending on the operating pressure, pressure drop per unit length(${\Delta}P/L$), column diameter(D) and gravitational acceleration(g) were chosen as governing parameters in determining the bubble holdup and pressure drop in the column. From the dimensional analysis, four kinds of dimensionless groups were derived from the 7 parameters and 4 fundamental dimensions. Effects of dimensionless groups such as Reynolds, Froude and Weber numbers on the bubble holdup in the column were discussed. The pressure drop and bubble holdup could be predicted from the correlation of dimensionless groups effectively, which could be used as useful information for the design and scale-up of pressurized slurry bubble columns.

Effects of Liquid Surface Tension on the Heat Transfer Coefficient in a Three-Phase Slurry Bubble Column (삼상슬러리 기포탑에서 액상의 표면장력이 열전달 계수에 미치는 영향)

  • Lim, Ho;Lim, Dae Ho;Jin, Hae-Ryong;Kang, Yong;Jung, Heon
    • Korean Chemical Engineering Research
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    • v.50 no.3
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    • pp.499-504
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    • 2012
  • Characteristics of overall heat transfer were investigated in a three-phase slurry bubble column with relatively low surface tension media, which has been frequently encountered in the fields of industry. The heat transfer phenomena was examined in the system which was composed of a coaxial vertical heater and a proper of bubble column. The heat transfer coefficient was estimated from the measured mean value of temperature difference between the heater surface and the column proper at the steady state condition. Effects of gas velocity ($U_G$), solid fraction in the slurry phase ($C_S$) and surface tension (${\sigma}_L$) of continuous liquid media on the overall heat transfer coefficient (h) in the bubble column were determined. The mean value of temperature difference was estimated from the data of temperature difference fluctuations with a variation of time. The amplitude and mean value of temperature difference fluctuations with respect to the elasped time appeared to decrease with decreasing the surface tension of liquid phase. The overall heat transfer coefficient between the immersed heated and the bubble column increased with an increase in the gas velocity or solid fraction in the slurry phase, but it decreased with an increase in the surface tension of continuous liquid media. The overall heat coefficient in the slurry bubble column with relatively low surface tension media was well correlated in term of operating variables and dimensionless groups within this experimental conditions.

Optimum Recovery of Biogas from Pig Slurry with Different Compositions (돈분 슬러리 성상에 따른 최적 바이오가스 회수)

  • Park, Woo-Kyun;Jun, Hang-Bae;Kwon, Soon-Ik;Chae, Kyu-Jung;Park, Noh-Back
    • Korean Journal of Environmental Agriculture
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    • v.29 no.2
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    • pp.197-205
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    • 2010
  • This study was conducted to investigate the optimum conditions for efficient methane production through anaerobic digestion of pig waste slurry. The examined parameters were organic matter content of the pig slurry, the ratio of seed sludge to pig slurry, and stirring intensity of the digestion reactor. The effects of types of slurry produced from different purpose-based pigs fed with different feeds were also tested. The methane concentration in the produced biogas was 45% when the ratio of seed sludge to pig slurry was 50% and total solid (TS) concentration was 1%, and it increased in proportional to TS concentration increases from 3 to 7%. At 3 and 5% of TS concentration, increasing mixing velocity from 80 to 160 rpm resulted in higher biogas production amount. However, mixing amount of seed sludge did not cause any significant effect on biogas production. Overall, the most efficient biogas production was achieved at 3-5% TS concentration in combination with 50% seed sludge inoculation and mixing velocity at 120 rpm. Among pig slurry types, gestating sow waste slurry showed the highest biogas production probably due to higher the degradation rate than other types of pig waste slurry being affected by the feeds components.

Infiltration behavior and face stability of carbonate-added slurry shield tunnel (탄산을 첨가한 슬러리 쉴드 터널에서의 침투 거동 및 굴진면 안정성 평가)

  • Lee, Ik-Bum;Choi, Ki-Hoon;Lee, In-Mo
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.15 no.4
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    • pp.401-413
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    • 2013
  • Slurry shield tunnelling ensures stability by pressurizing the tunnel face with the slurry contained in the chamber. It resists water and earth pressure in order to prevent the failure in the tunnel face during tunnel excavation. If the ground is relatively coarse, slurry can not clog the tunnel face and excessive slurry infiltration will occur. In this case chemical compounds or additives should be added to the slurry in order to improve the clogging phenomena at the tunnel face. In this study, the effect of the carbon dioxide gas as an additive to the slurry instead of chemical compounds on the capability of enhancing the clogging in the tunnel face is investigated. Bubbles arising from the carbonate-added slurry are trapped in the soil voids enhancing the clogging capability. This effect is studied in this paper by performing laboratory model tests simulating in-situ conditions, and by adopting the fine particle clogging theory. Tunnel face stability analysis was also performed and it was found that the effective size ($D_{10}$) of soils which can guarantee tunnel stability utilizing the carbonate-added slurry increased from 1.0 mm up to 2.6 mm. Moreover, Stability analysis showed that the tunnel face is stable if the ${\lambda}$(deposition coefficient) value is greater than $0.007sec^{-1}$.