• Title/Summary/Keyword: gas-discharge

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Water Repellent Finish of Polyester Fabric Using Carbontetrafluoride Plasma Treatment (4불화탄소 플라즈마처리에 의한 폴리에스테르 직물의 발수가공)

  • 모상영;이용운;김태년;천태일
    • Textile Coloration and Finishing
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    • v.6 no.3
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    • pp.27-36
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    • 1994
  • In order to produce a water repellent surface on polyester fabric, samples were treated in the atmosphere of $CF_4$ glow discharge plasma. The samples used in the study were ployester fabric and poyester film. The purpose of film treatment is for the comparison of hydrophobicity with fabric sample at same treatment condition. Radio frequency(13.56MHz) generator was used as electric source and its in put power is 100 Watt. Water repellency was evaluated by contact angle measurement. Result obtained are as follows. 1) Fiber interstice of original fabric was ana lysed as 0.43$\mu$m, and this value was sufficiently ideal for making water repellent fabric. 2) The most favorable setting position of substrate was the center area between two electrodes. 3) Fabric contact angle was higher than film contact angle at same treatment condition, and its difference was more than 50${\circ}$. And it was incapalbe of fabric contact angle measurement when the film contact angle was less than 90${\circ}$. because the fabric is susceptible to absorption of water by the capillary effect. 4) Fabric contact angle can not revealed the precise defferences of surface hydrophobicity, however, the film contact angle showed the real hydrophobic nature. 5) It was not sufficient method to evaluate the hydrophobicity of fabric surface by merely measure of the water contact angle. 6) It showed high water repellent nature at 0.06 torr of $CF_4$ plasma gas pressure and duration of 45 seconds treatment, and it can not be anticipated more improved nature if the pressure and duration of treatment time were increased.

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A Study on Adsorption Characteristics of Benzene over Activated Carbons Coated with Insulating Materials and Desorption by Microwave Irradiation (절연물질이 코팅된 활성탄의 벤젠 흡착특성 및 마이크로파에 의한 탈착에 관한 연구)

  • Kim, Ki-Joong;Ahn, Ho-Geun
    • Applied Chemistry for Engineering
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    • v.19 no.4
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    • pp.445-451
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    • 2008
  • In order to regenerate the activated carbon polluted by volatile organic compounds (VOCs) using microwave, adsorption and desorption characteristics of benzene over activated carbon (AC) coated with insulating materials were investigated. Physical characteristics of activated carbon and insulator-coated ACs were investigated by means of $N_2$ gas adsorption and scanning electron microscopy (SEM). The amount of VOC adsorbed showed a positive relationship with the specific surface area of the ACs, and spark discharge over insulator-coated ACs did not occur. Potassium silicate (PS) was the best binder for coating of insulating materials on AC. Amount of benzene desorbed by microwave irradiation was dependent on output power of microwave. Nearly same performance was obtained even though the adsorption-desorption operation under microwave irradiation was repeated 5 times. Finally, it was known that the microwave heating was a very effective mean for regenerating the polluted AC.

Performance Enhancement and Recovery Method of Open Cathode PEMFC (오픈 캐소드형 고분자전해질 연료전지의 성능향상과 회복기법)

  • Lee, Kitaek;Kim, Junbom
    • Applied Chemistry for Engineering
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    • v.28 no.1
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    • pp.118-124
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    • 2017
  • An air cooling, open cathode type polymer electrolyte membrane fuel cell (PEMFC) has the advantages of system simplification and cost effectiveness. Open cathode PEMFC could suffer from reduced performance due to the membrane dehydration in low humidity of air. Effects of the cathode air flow rate, anode purge interval and long term storage on PEMFC performance were investigated in this work. Fan voltage is an important factor on air cooling PEMFC performance because the cathode air flow rate and stack temperature were controlled by fan voltage. The dead ended anode (DEA) method was applied to increase hydrogen usage. Periodical purge was used to discharge accumulated water and gas. The influence of long term non-operating condition on PEMFC performance degradation due to the membrane dehydration was also studied and the quick recovery method was developed.

The $SO_2$ effect on NOx removal by Corona Shower System (코로나 샤워 시스템을 이용한 NOx제거에서 $SO_2$의 영향)

  • Park, Jae-Yoon;Kim, Ick-Kewn;Lee, Jae-Dong;Kim, Jong-Dal;Lee, Duck-Chool;Chang, J.S.
    • Proceedings of the KIEE Conference
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    • 1998.07e
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    • pp.1794-1796
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    • 1998
  • In this study, the $SO_2$ addition effect on NOx removal has been conducted from a combustion flue gases by the do corona discharge-activated radical shower systems. The simulated flue gases were consisted of NO-O_2-$N_2$, NO-$CO_2-N_2-O_2$ and $NO-SO_2-CO_2-Na-O_2$([NO]o:200ppm and $[SO_2]o$:800ppm). The injection gases used as radical source gases were $NH_3$-Ar-air. $SO_2$ and NOx removal efficiency and the other by-products were measured by Fourier Transform Infrared(FTIR) as well as $SO_2$. NOx and $NO_2$ gas detectors. By-product aerosol particles were also observed by Condensation Nucleation Particle Counter(CNPC) and SEM images after sampling. The results showed that asignificant aerosol Particle formation was observed during a removal operation in corona radical shower systems. The NOx removal efficiency significantly increased with increasing applied voltage and $NH_3$ molecule ratio. The $SO_2$ removal efficiency was not significantly effected by applied voltage and slightly increased with increasing $NH_3$ molecule ratio. The NOx removal efficiency for NO-$SO_2-CO_2-N_2-O_2$ was better than that for NO-$CO_2-N_2-O_2$.

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Electrochemical Properties of Li1.1V0.75W0.075Mo0.075O2/Graphite Composite Anodes for Lithium-ion Batteries

  • Kim, Hyung-Sun;Kim, Sang-Ok;Kim, Yong-Tae;Jung, Ji-Kwon;Na, Byung-Ki;Lee, Joong-Kee
    • Bulletin of the Korean Chemical Society
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    • v.33 no.1
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    • pp.65-68
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    • 2012
  • Novel type $Li_{1.1}V_{0.9-2x}W_xMo_xO_2$ powders were prepared by a solid-state reaction of $Li_2CO_3$, $V_2O_3$, $WO_2$ and $MoO_2$ precursors in a nitrogen atmosphere containing 10 mol % hydrogen gas, and assessed as anode materials in lithium-ion batteries. The specific charge and discharge capacities of the $Li_{1.1}V_{0.9-2x}W_xMo_xO_2$ anodes were higher than those of the bare $Li_{1.1}V_{0.9}O_2$ anode. The cyclic efficiency of these anodes was approximately 73.3% at the first cycle, regardless of the presence of W and Mo doping. The composite anode, which was composed of $Li_{1.1}V_{0.75}W_{0.075}Mo_{0.075}O_2$ (20 wt %) and natural graphite (80 wt %), demonstrated reasonable specific capacity, high cyclic efficiency, and good cycling performance, even at high rates without capacity fading.

Output characteristics of ac excited $CO_2$ laser as a adjusting a phase angle and frequency (위상각와 주파수 제어에 따른 상용주파 AC 여기 방식의 펄스형 $CO_2$ 레이저 전원장치 개발에 관한 연구)

  • Chung, Hyun-Ju;Kim, Do-Wan;Lee, Dong-Hoon;Kim, Joong-Mann;Kim, Mee-Je;Cho, Jung-Soo
    • Proceedings of the KIEE Conference
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    • 2000.07c
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    • pp.2098-2100
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    • 2000
  • We propose pulsed $CO_2$ laser below 30W by the AC(60Hz) switching control of leakage transformer primary which has some advantage of cost and size compared to a typical pulsed power supply. Pulse repetition rate is adjusted from 5Hz to 60Hz to control laser output. In this laser, a low voltage open loop control for high voltage discharge circuit is employed to avoid the HV sampling or switching and high voltage leakage transformer is used to convert rectified low voltage pulse to high voltage one. A ZCS(Zero Cross Switch) circuit and a PIC one-chip microprocessor are used to control gate signal of SCR precisely. The pulse repetition rate is limited by 60Hz due to the frequency of AC line and a high leakage inductance. The maximum laser output was obtained about 23W at pulse repetition rate of 60Hz, total gas mixture of $CO_{2}/N_{2}$/He = 1/9/15, SCR gate trigger angle 90$^{\circ}$, and total pressure of 18Torr.

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A Computational Study on Cooling Analysis of the Flame Deflector for the 75 tonf Class Propulsion Test Facility (75톤급 추진기관 시험설비 화염유도로 냉각해석에 관한 수치적 연구)

  • Moon, Seong-Mok;Cho, Nam-Kyung;Kim, Seong-Lyong;Jun, Sung-Bok;Lee, Kyoung-Hoon;Kim, Dong-Hwan
    • Journal of the Korean Society of Propulsion Engineers
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    • v.19 no.2
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    • pp.55-64
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    • 2015
  • In this study, a 3-D flame cooling analysis is conducted to examine thermal safety for the flame deflector of the 75 tonf class propulsion test facility, and the safe discharge of the exhaust gas is assessed by using numerical results. The Mixture multiphase model is adopted for the simulation of heat transfer and phase exchange process between flame and cooling water, and the computational study using the single species unreacted model for the exhaust plume is carried out for the flame cooling. Numerical analysis predicts maximum temperature on the flame deflector wall for different water flow rates, and evaluates the safe minimum flow rate of water corresponding to the fire-resistant temperature for concrete.

An Investigation on the Technical Background for Carbon-14 Monitoring in Radioactive Effluents (원자력시설의 Carbon-14 방사성유출물에 대한 감시배경의 조사)

  • Kim, Hee-Geun;Kong, Tae-Young;Jeong, Woo-Tae;Kim, Seok-Tae
    • Journal of Radiation Protection and Research
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    • v.34 no.4
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    • pp.195-200
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    • 2009
  • effluents to the environment. The activity of carbon-14, one of the radioactive effluents, in the environment is already high level and its effect on radiation exposure to the public and the environment is insignificant; thus, NPPs did not perform the carbon-14 monitoring in effluents in the past. By the way, effluents of noble gas and particulate radioactive materials originated from nuclear fuels has been continuously reduced due to both the advancement of manufacturing and integrity technology for nuclear fuels and the improvement of operation methods of NPPs. Futhermore, the portion of dose assessment by tritium and carbon-14 to the public has been relatively increased because the lower limit of detection for low-energy beta sources, such as tritium and carbon-14, is low due to the advancement of radiation detection technology. In this paper, the technical background for carbon-14 monitoring in nuclear facilities was investigated using United States technical reports and papers. This paper also reviews whether carbon-14 monitoring is necessary or not based on the investigated documents.

Study on CO2 Decomposition using Ar/CO2 Inductively Coupled Plasma (아르곤/이산화탄소 혼합가스의 유도 결합 플라즈마를 이용한 이산화탄소 분해 연구)

  • Kim, Kyung-Hyun;Kim, Kwan-Yong;Lee, Hyo-Chang;Chung, Chin-Wook
    • KEPCO Journal on Electric Power and Energy
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    • v.1 no.1
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    • pp.135-140
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    • 2015
  • Decomposition of carbon dioxide is studied using $Ar/CO_2$ mixture inductively coupled plasmas (ICP). Argon gas was added to generate plasma which has high electron density. To measure decomposition rate of $CO_2$, optical emission actinometry is used. Changing input power, pressure and mixture ratio, the plasma parameters and the spectrum intensity were measured using single Langmuir probe and spectroscope. The source characteristic of Carbon dioxide ICP observed from the obtained plasma parameters. The decomposition rate is evolved depending on the reaction and discharge mode. This result is analyzed with both the measurement of the plasma parameters and the dissociation mechanism of $CO_2$.

Residual Voltage Reduction of Coaxial Surge Arrestor Using Ceramic Filler (세라믹 필터를 이용한 동축 서지어레스터의 잔류전압 저감)

  • Eom, Ju-Hong;Cho, Sung-Chul;Lee, Tae-Hyung;Lee, Young-Chul
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.21 no.2
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    • pp.46-53
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    • 2007
  • Extension of the mobile communication and the rapidly developing services connected with wireless multimedia(W-CDMA, DMB, Wibro, and so on) need great many base station transceiver systems, antennas, and many signal transmission line to embody these services. The min communication appliances system is exposed always in danger of transient overvoltage by direct stroke or induced lightning surge flowing in through antenna because the antenna of base station transceiver system or relay equipment is combined with expensive communication network equipments through signal transmission line. Now, gas discharge tube(GDT) or narrow band stub arrestor which is used by the surge protector for communication use is exposing limitations as for lightning surge protective means of the communication facility with high speed and wide frequency band. Therefore, for improving performance of surge arrestor, we applied ceramic filter which can reduce lightning surge invading from antenna effectively, and proved that ceramic filter is effective in residual voltage reduction through the experimental research.